JP2013248612A5 - - Google Patents
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- Publication number
- JP2013248612A5 JP2013248612A5 JP2013115929A JP2013115929A JP2013248612A5 JP 2013248612 A5 JP2013248612 A5 JP 2013248612A5 JP 2013115929 A JP2013115929 A JP 2013115929A JP 2013115929 A JP2013115929 A JP 2013115929A JP 2013248612 A5 JP2013248612 A5 JP 2013248612A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- range
- silver
- palladium
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 claims description 36
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 34
- 229910052763 palladium Inorganic materials 0.000 claims description 16
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 15
- 229910052709 silver Inorganic materials 0.000 claims description 15
- 239000004332 silver Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 239000000725 suspension Substances 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 2
- 238000005984 hydrogenation reaction Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 4
- 239000003513 alkali Substances 0.000 claims 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 3
- 239000002243 precursor Substances 0.000 claims 3
- 239000000243 solution Substances 0.000 claims 3
- 238000004230 steam cracking Methods 0.000 claims 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims 2
- 239000012696 Pd precursors Substances 0.000 claims 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims 2
- 239000011324 bead Substances 0.000 claims 2
- 238000004523 catalytic cracking Methods 0.000 claims 2
- 239000003638 chemical reducing agent Substances 0.000 claims 2
- 238000001914 filtration Methods 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 239000000377 silicon dioxide Substances 0.000 claims 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical group [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical group COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229910021607 Silver chloride Inorganic materials 0.000 claims 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims 1
- 239000004280 Sodium formate Substances 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 239000008346 aqueous phase Substances 0.000 claims 1
- 239000011668 ascorbic acid Substances 0.000 claims 1
- 235000010323 ascorbic acid Nutrition 0.000 claims 1
- 229960005070 ascorbic acid Drugs 0.000 claims 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims 1
- 235000015165 citric acid Nutrition 0.000 claims 1
- 239000008121 dextrose Substances 0.000 claims 1
- 238000009826 distribution Methods 0.000 claims 1
- 238000010304 firing Methods 0.000 claims 1
- 235000019253 formic acid Nutrition 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical group [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000007791 liquid phase Substances 0.000 claims 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 235000006408 oxalic acid Nutrition 0.000 claims 1
- 229910003445 palladium oxide Inorganic materials 0.000 claims 1
- NXJCBFBQEVOTOW-UHFFFAOYSA-L palladium(2+);dihydroxide Chemical compound O[Pd]O NXJCBFBQEVOTOW-UHFFFAOYSA-L 0.000 claims 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical group Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 claims 1
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 claims 1
- JQPTYAILLJKUCY-UHFFFAOYSA-N palladium(ii) oxide Chemical compound [O-2].[Pd+2] JQPTYAILLJKUCY-UHFFFAOYSA-N 0.000 claims 1
- CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 claims 1
- 229940071536 silver acetate Drugs 0.000 claims 1
- 229940071575 silver citrate Drugs 0.000 claims 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims 1
- 229910001961 silver nitrate Inorganic materials 0.000 claims 1
- 229960001516 silver nitrate Drugs 0.000 claims 1
- XNGYKPINNDWGGF-UHFFFAOYSA-L silver oxalate Chemical compound [Ag+].[Ag+].[O-]C(=O)C([O-])=O XNGYKPINNDWGGF-UHFFFAOYSA-L 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 239000001632 sodium acetate Substances 0.000 claims 1
- 235000017281 sodium acetate Nutrition 0.000 claims 1
- 239000012279 sodium borohydride Substances 0.000 claims 1
- 229910000033 sodium borohydride Inorganic materials 0.000 claims 1
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims 1
- 235000019254 sodium formate Nutrition 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- QUTYHQJYVDNJJA-UHFFFAOYSA-K trisilver;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Ag+].[Ag+].[Ag+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QUTYHQJYVDNJJA-UHFFFAOYSA-K 0.000 claims 1
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910021124 PdAg Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1201572A FR2991197B1 (fr) | 2012-05-31 | 2012-05-31 | Catalyseur comprenant du palladium et de l'argent et son application en hydrogenation selective |
| FR1201572 | 2012-05-31 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013248612A JP2013248612A (ja) | 2013-12-12 |
| JP2013248612A5 true JP2013248612A5 (enExample) | 2016-06-30 |
| JP6302627B2 JP6302627B2 (ja) | 2018-03-28 |
Family
ID=48170402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013115929A Active JP6302627B2 (ja) | 2012-05-31 | 2013-05-31 | パラジウムおよび銀を含む触媒、並びに、選択的水素化のためのその使用 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US20130303813A1 (enExample) |
| EP (1) | EP2669005B1 (enExample) |
| JP (1) | JP6302627B2 (enExample) |
| CN (1) | CN103447031B (enExample) |
| DK (1) | DK2669005T3 (enExample) |
| FR (1) | FR2991197B1 (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4883162B2 (ja) * | 2009-10-02 | 2012-02-22 | トヨタ自動車株式会社 | Ｃｏ又はｈｃ浄化用の排ガス浄化触媒 |
| US10493433B2 (en) * | 2014-10-07 | 2019-12-03 | Basf Corporation | Synthesis of colloidal precious metals nanoparticles with controlled size and morphology |
| FR3033267B1 (fr) * | 2015-03-05 | 2017-03-10 | Ifp Energies Now | Catalyseur comprenant de l'or disperse et du palladium et son application en hydrogenation selective |
| FR3051685B1 (fr) * | 2016-05-30 | 2018-06-08 | IFP Energies Nouvelles | Procede de preparation d'un catalyseur d'hydrogenation selective . |
| FR3051684B1 (fr) * | 2016-05-30 | 2020-09-04 | Ifp Energies Now | Catalyseur d'hydrogenation selective comprenant un support extrude |
| KR101688894B1 (ko) * | 2016-08-08 | 2016-12-23 | 주식회사 지엔티엔에스 | 고온 연소촉매를 이용한 버너 |
| KR101912251B1 (ko) | 2016-09-19 | 2018-10-29 | 한국과학기술연구원 | 개미산의 탈수소화 반응용 촉매 및 이의 제조방법 |
| FR3059252B1 (fr) | 2016-11-29 | 2018-11-16 | IFP Energies Nouvelles | Catalyseur d’hydrogenation selective de coupes c3 de vapocraquage et/ou de craquage catalytique |
| FR3059253B1 (fr) * | 2016-11-29 | 2020-01-17 | IFP Energies Nouvelles | Catalyseur d'hydrogenation selective d'une coupe d'hydrocarbures c3. |
| TW202035019A (zh) * | 2018-11-13 | 2020-10-01 | 瑞士商克萊瑞特國際股份有限公司 | 氧化鋁上含鉻之脫氫觸媒及其製備與使用之方法 |
| CN110773163B (zh) * | 2019-12-02 | 2023-07-07 | 上海华谊（集团）公司 | 甲基丙烯醛选择加氢制甲基烯丙醇的催化剂及其制备方法 |
| FR3115474A1 (fr) | 2020-10-28 | 2022-04-29 | IFP Energies Nouvelles | Catalyseur d’hydrogenation selective a base de palladium sur un support en oxyde de zinc |
| FR3115794B1 (fr) * | 2020-10-29 | 2023-01-13 | Ifp Energies Now | Procede d’hydrogenation selective mettant en œuvre un catalyseur de forme mousse |
| RU2768115C1 (ru) * | 2021-04-13 | 2022-03-23 | Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" (Ооо "Нгт-Синтез") | Катализатор и способ его получения |
| RU2768118C1 (ru) * | 2021-04-13 | 2022-03-23 | Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" (Ооо "Нгт-Синтез") | Способ получения катализатора |
| US11772078B2 (en) * | 2022-01-21 | 2023-10-03 | GM Global Technology Operations LLC | Layered catalyst structures and methods of making the same |
| FR3134015A1 (fr) | 2022-03-31 | 2023-10-06 | IFP Energies Nouvelles | Catalyseur a base de palladium et de zinc sur un support d’alumine |
| FR3134016A1 (fr) | 2022-03-31 | 2023-10-06 | IFP Energies Nouvelles | Catalyseur a base de palladium et de fluor sur un support d’alumine |
| CN119857480B (zh) * | 2023-10-19 | 2025-11-11 | 中国石油化工股份有限公司 | 一种超薄蛋壳型高分散催化剂及其制备方法与应用 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4484015A (en) * | 1981-05-06 | 1984-11-20 | Phillips Petroleum Company | Selective hydrogenation |
| FR2720956B1 (fr) * | 1994-06-09 | 1996-08-30 | Inst Francais Du Petrole | Catalyseur d'hydrogénation contenant du palladium, au moins un élément du groupe IB et au moins un métal alcalin et procédé d'hydrogénation catalytique utilisant ce catalyseur. |
| US5583274A (en) * | 1995-01-20 | 1996-12-10 | Phillips Petroleum Company | Alkyne hydrogenation process |
| FR2742679B1 (fr) * | 1995-12-22 | 1998-01-16 | Inst Francais Du Petrole | Catalyseur d'hydrogenation selective et procede utilisant ce catalyseur |
| US6054409A (en) * | 1995-06-06 | 2000-04-25 | Institut Francais Du Petrole | Selective hydrogenation catalyst and a process using that catalyst |
| FR2882531B1 (fr) | 2005-02-25 | 2007-04-27 | Inst Francais Du Petrole | Procede de preparation de catalyseurs multimetalliques utilisables dans des reactions de transformation des hydrocarbures |
| DE102007025442B4 (de) * | 2007-05-31 | 2023-03-02 | Clariant International Ltd. | Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
| FR2922784B1 (fr) * | 2007-10-29 | 2011-05-13 | Inst Francais Du Petrole | Catalyseur comprenant du palladium et son application en hydrogenation selective |
| FR2963344B1 (fr) * | 2010-07-29 | 2012-07-27 | IFP Energies Nouvelles | Procede d'hydrogenation selective en presence d'un catalyseur a base d'un metal du groupe viii prepare au moyen d'au moins un oligosaccharide cyclique |
-
2012
- 2012-05-31 FR FR1201572A patent/FR2991197B1/fr active Active
-
2013
- 2013-04-10 DK DK13305467.6T patent/DK2669005T3/da active
- 2013-04-10 EP EP13305467.6A patent/EP2669005B1/fr active Active
- 2013-05-31 JP JP2013115929A patent/JP6302627B2/ja active Active
- 2013-05-31 US US13/906,567 patent/US20130303813A1/en not_active Abandoned
- 2013-05-31 CN CN201310211742.4A patent/CN103447031B/zh active Active
-
2016
- 2016-12-06 US US15/370,705 patent/US10099205B2/en active Active
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