JP2012527518A - リチウムイオン電池電極用の導電性ポリマーバインダ - Google Patents

リチウムイオン電池電極用の導電性ポリマーバインダ Download PDF

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JP2012527518A
JP2012527518A JP2012511937A JP2012511937A JP2012527518A JP 2012527518 A JP2012527518 A JP 2012527518A JP 2012511937 A JP2012511937 A JP 2012511937A JP 2012511937 A JP2012511937 A JP 2012511937A JP 2012527518 A JP2012527518 A JP 2012527518A
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cooh
electrode
polymer
conductive
silicon
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JP2012527518A5 (enExample
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リウ、ガオ
シュン、シディ
エス. バッタリア、ビンセント
チェン、ホンヘ
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University of California
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624Electric conductive fillers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/10Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aromatic carbon atoms, e.g. polyphenylenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/005Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/121Charge-transfer complexes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0402Methods of deposition of the material
    • H01M4/0409Methods of deposition of the material by a doctor blade method, slip-casting or roller coating
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0402Methods of deposition of the material
    • H01M4/0416Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134Electrodes based on metals, Si or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1395Processes of manufacture of electrodes based on metals, Si or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/386Silicon or alloys based on silicon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621Binders
    • H01M4/622Binders being polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10Definition of the polymer structure
    • C08G2261/12Copolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/31Monomer units or repeat units incorporating structural elements in the main chain incorporating aromatic structural elements in the main chain
    • C08G2261/314Condensed aromatic systems, e.g. perylene, anthracene or pyrene
    • C08G2261/3142Condensed aromatic systems, e.g. perylene, anthracene or pyrene fluorene-based, e.g. fluorene, indenofluorene, or spirobifluorene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/50Physical properties
    • C08G2261/51Charge transport
    • C08G2261/516Charge transport ion-conductive
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2365/00Characterised by the use of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Derivatives of such polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Composite Materials (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Dispersion Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
JP2012511937A 2009-05-18 2010-05-17 リチウムイオン電池電極用の導電性ポリマーバインダ Ceased JP2012527518A (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US17925809P 2009-05-18 2009-05-18
US61/179,258 2009-05-18
US24307609P 2009-09-16 2009-09-16
US61/243,076 2009-09-16
PCT/US2010/035120 WO2010135248A1 (en) 2009-05-18 2010-05-17 Electronically conductive polymer binder for lithium-ion battery electrode

Publications (2)

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JP2012527518A true JP2012527518A (ja) 2012-11-08
JP2012527518A5 JP2012527518A5 (enExample) 2013-06-27

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US (2) US8852461B2 (enExample)
EP (1) EP2433323A4 (enExample)
JP (1) JP2012527518A (enExample)
CN (1) CN102460781B (enExample)
WO (1) WO2010135248A1 (enExample)

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JP2015043316A (ja) * 2013-07-24 2015-03-05 三菱化学株式会社 非水系二次電池負極用活物質並びにそれを用いた負極及び非水系二次電池
JP2017515278A (ja) * 2014-07-30 2017-06-08 バイエリシエ・モトーレンウエルケ・アクチエンゲゼルシヤフト 電気化学セルのための複合電極および電気化学セル
US10199638B2 (en) 2014-12-31 2019-02-05 Samsung Electronics Co., Ltd. Composite anode active material, method of preparing the same, and anode and lithium secondary battery including the composite anode active material
KR20190134329A (ko) * 2018-05-25 2019-12-04 큐레스 주식회사 복합체, 이의 제조방법 및 이를 포함하는 전극 재료

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JP2012527518A (ja) * 2009-05-18 2012-11-08 ザ、リージェンツ、オブ、ザ、ユニバーシティ、オブ、カリフォルニア リチウムイオン電池電極用の導電性ポリマーバインダ
US9077039B2 (en) * 2009-05-18 2015-07-07 The Regents Of The University Of California Electronically conductive polymer binder for lithium-ion battery electrode
KR101861212B1 (ko) 2010-09-09 2018-06-29 캘리포니아 인스티튜트 오브 테크놀로지 전기화학적 에너지 저장 시스템 및 방법
US9379368B2 (en) 2011-07-11 2016-06-28 California Institute Of Technology Electrochemical systems with electronically conductive layers
US10158110B2 (en) 2011-07-11 2018-12-18 California Institute Of Technology Separators for electrochemical systems
US10461358B2 (en) * 2011-10-11 2019-10-29 Samsung Sdi Co., Ltd. Rechargeable lithium battery
US9705127B2 (en) * 2012-02-01 2017-07-11 The Regents Of The University Of California Conductive polymer and Si nanoparticles composite secondary particles and structured current collectors for high loading lithium ion negative electrode application
US9450223B2 (en) 2012-02-06 2016-09-20 Samsung Sdi Co., Ltd. Lithium secondary battery
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KR102392086B1 (ko) 2012-04-10 2022-04-28 캘리포니아 인스티튜트 오브 테크놀로지 전기화학 시스템들용 신규 세퍼레이터들
EP2858150B1 (en) * 2012-05-31 2017-03-15 Hitachi, Ltd. Lithium ion secondary battery
JP2016531398A (ja) * 2013-07-29 2016-10-06 ザ・ペン・ステイト・リサーチ・ファウンデイションThe Penn State Research Foundation シリコン系負極用弾性ゲルポリマー結合剤
US20150171398A1 (en) 2013-11-18 2015-06-18 California Institute Of Technology Electrochemical separators with inserted conductive layers
US10714724B2 (en) 2013-11-18 2020-07-14 California Institute Of Technology Membranes for electrochemical cells
CN103904299B (zh) * 2014-03-24 2015-10-28 宁德新能源科技有限公司 锂离子二次电池及其负极极片
US20150364755A1 (en) * 2014-06-16 2015-12-17 The Regents Of The University Of California Silicon Oxide (SiO) Anode Enabled by a Conductive Polymer Binder and Performance Enhancement by Stabilized Lithium Metal Power (SLMP)
US10263246B2 (en) 2014-11-20 2019-04-16 Ut-Battelle, Llc Lithiated and passivated lithium ion battery anodes
KR20160139240A (ko) 2015-05-27 2016-12-07 주식회사 엘지화학 전극 합제, 이의 제조방법 및 이를 포함하는 이차전지
US10340528B2 (en) 2015-12-02 2019-07-02 California Institute Of Technology Three-dimensional ion transport networks and current collectors for electrochemical cells
WO2017119861A1 (en) 2016-01-07 2017-07-13 Enwair Enerji Teknolojileri A. S. Usage of conductive and flexible polymers in lithium batteries
US10903484B2 (en) 2016-10-26 2021-01-26 The Regents Of The University Of Michigan Metal infiltrated electrodes for solid state batteries
US10424784B2 (en) * 2016-10-28 2019-09-24 GM Global Technology Operations LLC Negative electrode including silicon nanoparticles having a carbon coating thereon
EP3648200A4 (en) * 2017-09-28 2020-06-03 LG Chem, Ltd. METHOD FOR PREDICTING THE PROCESSABILITY OF ELECTRODE SLUDGE AND FOR SELECTING AN ELECTRODE BINDING AGENT
JP2020510953A (ja) 2018-01-19 2020-04-09 エンウェア エネルジ テクノロジレリ アー エスEnwair Enerji Teknolojileri A.S. 高性能リチウムイオン電池用のゲル(架橋)ポリマーバインダー
US11205778B2 (en) 2019-06-12 2021-12-21 The Regents Of The University Of California Conductive polymer emulsion
US11374218B2 (en) 2019-08-21 2022-06-28 GM Global Technology Operations LLC Multilayer siloxane coatings for silicon negative electrode materials for lithium ion batteries
US11843110B2 (en) 2019-10-30 2023-12-12 GM Global Technology Operations LLC Methods for controlling formation of multilayer carbon coatings on silicon-containing electroactive materials for lithium-ion batteries
CN111769285B (zh) * 2020-07-01 2022-04-01 苏州凌威新能源科技有限公司 锂电池负极胶粘剂及负极片
KR20230131874A (ko) * 2021-01-13 2023-09-14 더 리전츠 오브 더 유니버시티 오브 캘리포니아 리튬 배터리에 유용한 전도성 중합체 및 전극 처리
CN114539537B (zh) * 2022-02-21 2023-06-06 中化国际(控股)股份有限公司 一种锂离子电池电极材料的粘结剂及其制备方法

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US20120119155A1 (en) 2012-05-17
WO2010135248A8 (en) 2011-06-16
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