JP2012527518A - リチウムイオン電池電極用の導電性ポリマーバインダ - Google Patents

リチウムイオン電池電極用の導電性ポリマーバインダ Download PDF

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JP2012527518A
JP2012527518A JP2012511937A JP2012511937A JP2012527518A JP 2012527518 A JP2012527518 A JP 2012527518A JP 2012511937 A JP2012511937 A JP 2012511937A JP 2012511937 A JP2012511937 A JP 2012511937A JP 2012527518 A JP2012527518 A JP 2012527518A
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cooh
electrode
polymer
conductive
silicon
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JP2012527518A5 (enExample
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リウ、ガオ
シュン、シディ
エス． バッタリア、ビンセント
チェン、ホンヘ
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University of California
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/10—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aromatic carbon atoms, e.g. polyphenylenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/005—Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/121—Charge-transfer complexes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0409—Methods of deposition of the material by a doctor blade method, slip-casting or roller coating
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0416—Methods of deposition of the material involving impregnation with a solution, dispersion, paste or dry powder
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/386—Silicon or alloys based on silicon
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/12—Copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/31—Monomer units or repeat units incorporating structural elements in the main chain incorporating aromatic structural elements in the main chain
    • C08G2261/314—Condensed aromatic systems, e.g. perylene, anthracene or pyrene
    • C08G2261/3142—Condensed aromatic systems, e.g. perylene, anthracene or pyrene fluorene-based, e.g. fluorene, indenofluorene, or spirobifluorene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/50—Physical properties
    • C08G2261/51—Charge transport
    • C08G2261/516—Charge transport ion-conductive
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2365/00—Characterised by the use of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Derivatives of such polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Composite Materials (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Dispersion Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
JP2012511937A 2009-05-18 2010-05-17 リチウムイオン電池電極用の導電性ポリマーバインダ Ceased JP2012527518A (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US17925809P 2009-05-18 2009-05-18
US61/179,258 2009-05-18
US24307609P 2009-09-16 2009-09-16
US61/243,076 2009-09-16
PCT/US2010/035120 WO2010135248A1 (en) 2009-05-18 2010-05-17 Electronically conductive polymer binder for lithium-ion battery electrode

Publications (2)

Publication Number Publication Date
JP2012527518A true JP2012527518A (ja) 2012-11-08
JP2012527518A5 JP2012527518A5 (enExample) 2013-06-27

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US (2) US8852461B2 (enExample)
EP (1) EP2433323A4 (enExample)
JP (1) JP2012527518A (enExample)
CN (1) CN102460781B (enExample)
WO (1) WO2010135248A1 (enExample)

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JP2015043316A (ja) * 2013-07-24 2015-03-05 三菱化学株式会社 非水系二次電池負極用活物質並びにそれを用いた負極及び非水系二次電池
JP2017515278A (ja) * 2014-07-30 2017-06-08 バイエリシエ・モトーレンウエルケ・アクチエンゲゼルシヤフト 電気化学セルのための複合電極および電気化学セル
US10199638B2 (en) 2014-12-31 2019-02-05 Samsung Electronics Co., Ltd. Composite anode active material, method of preparing the same, and anode and lithium secondary battery including the composite anode active material
KR20190134329A (ko) * 2018-05-25 2019-12-04 큐레스 주식회사 복합체, 이의 제조방법 및 이를 포함하는 전극 재료
JP2024505385A (ja) * 2021-01-13 2024-02-06 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア リチウム電池に有用な導電性ポリマーおよび電極加工

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US9077039B2 (en) * 2009-05-18 2015-07-07 The Regents Of The University Of California Electronically conductive polymer binder for lithium-ion battery electrode
JP2012527518A (ja) 2009-05-18 2012-11-08 ザ、リージェンツ、オブ、ザ、ユニバーシティ、オブ、カリフォルニア リチウムイオン電池電極用の導電性ポリマーバインダ
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WO2013009750A2 (en) 2011-07-11 2013-01-17 California Institute Of Technology Novel separators for electrochemical systems
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WO2013116711A1 (en) 2012-02-01 2013-08-08 The Regents Of The University Of California Conductive polymer coated si nanoparticles composite and current collectors for lithium ion negative electrode
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US20130244080A1 (en) * 2012-03-16 2013-09-19 Samsung Sdi Co., Ltd. Separator for lithium secondary battery
KR102118212B1 (ko) 2012-04-10 2020-06-02 캘리포니아 인스티튜트 오브 테크놀로지 전기화학 시스템들용 신규 세퍼레이터들
JP5941144B2 (ja) * 2012-05-31 2016-06-29 株式会社日立製作所 リチウムイオン二次電池
KR20160040227A (ko) * 2013-07-29 2016-04-12 더 펜 스테이트 리서어치 파운데이션 실리콘-계 음극을 위한 탄성 겔 고분자 바인더
US10714724B2 (en) 2013-11-18 2020-07-14 California Institute Of Technology Membranes for electrochemical cells
WO2015074037A2 (en) 2013-11-18 2015-05-21 California Institute Of Technology Separator enclosures for electrodes and electrochemical cells
CN103904299B (zh) * 2014-03-24 2015-10-28 宁德新能源科技有限公司 锂离子二次电池及其负极极片
US20150364755A1 (en) * 2014-06-16 2015-12-17 The Regents Of The University Of California Silicon Oxide (SiO) Anode Enabled by a Conductive Polymer Binder and Performance Enhancement by Stabilized Lithium Metal Power (SLMP)
US10263246B2 (en) 2014-11-20 2019-04-16 Ut-Battelle, Llc Lithiated and passivated lithium ion battery anodes
KR20160139240A (ko) * 2015-05-27 2016-12-07 주식회사 엘지화학 전극 합제, 이의 제조방법 및 이를 포함하는 이차전지
US10340528B2 (en) 2015-12-02 2019-07-02 California Institute Of Technology Three-dimensional ion transport networks and current collectors for electrochemical cells
DE112016005500T5 (de) 2016-01-07 2018-09-20 Enwair Enerji Teknolojileri A. S. Verwendung von leitfähigen und flexiblen polymeren in lithiumbatterien
US10903484B2 (en) 2016-10-26 2021-01-26 The Regents Of The University Of Michigan Metal infiltrated electrodes for solid state batteries
US10424784B2 (en) 2016-10-28 2019-09-24 GM Global Technology Operations LLC Negative electrode including silicon nanoparticles having a carbon coating thereon
CN110679014B (zh) * 2017-09-28 2023-04-04 株式会社Lg新能源 预测电极浆料的工艺性和选择电极粘合剂的方法
WO2019143306A1 (en) 2018-01-19 2019-07-25 Enwair Enerji̇ Teknoloji̇leri̇ A.Ş. Gel (cross linked) polymeric binder for high performance lithium ion batteries
US20200328403A1 (en) * 2019-04-10 2020-10-15 Nanotek Instruments, Inc. Conducting polymer network-enabled particulates of anode active material particles for lithium-ion batteries
US11205778B2 (en) 2019-06-12 2021-12-21 The Regents Of The University Of California Conductive polymer emulsion
US11374218B2 (en) 2019-08-21 2022-06-28 GM Global Technology Operations LLC Multilayer siloxane coatings for silicon negative electrode materials for lithium ion batteries
US11843110B2 (en) 2019-10-30 2023-12-12 GM Global Technology Operations LLC Methods for controlling formation of multilayer carbon coatings on silicon-containing electroactive materials for lithium-ion batteries
CN111769285B (zh) * 2020-07-01 2022-04-01 苏州凌威新能源科技有限公司 锂电池负极胶粘剂及负极片
CN114539537B (zh) * 2022-02-21 2023-06-06 中化国际(控股)股份有限公司 一种锂离子电池电极材料的粘结剂及其制备方法

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US20120119155A1 (en) 2012-05-17
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