JP2012518247A5 - - Google Patents
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- Publication number
- JP2012518247A5 JP2012518247A5 JP2011549591A JP2011549591A JP2012518247A5 JP 2012518247 A5 JP2012518247 A5 JP 2012518247A5 JP 2011549591 A JP2011549591 A JP 2011549591A JP 2011549591 A JP2011549591 A JP 2011549591A JP 2012518247 A5 JP2012518247 A5 JP 2012518247A5
- Authority
- JP
- Japan
- Prior art keywords
- flow battery
- redox flow
- ionic liquid
- redox
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002608 ionic liquid Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 7
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 4
- 150000007942 carboxylates Chemical class 0.000 claims description 4
- 125000005525 methide group Chemical group 0.000 claims description 4
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 4
- 239000003792 electrolyte Substances 0.000 claims 12
- 229910052749 magnesium Inorganic materials 0.000 claims 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 claims 3
- WTKZEGDFNFYCGP-UHFFFAOYSA-O Pyrazolium Chemical compound C1=CN[NH+]=C1 WTKZEGDFNFYCGP-UHFFFAOYSA-O 0.000 claims 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-O Pyrrolidinium ion Chemical compound C1CC[NH2+]C1 RWRDLPDLKQPQOW-UHFFFAOYSA-O 0.000 claims 3
- 125000002015 acyclic group Chemical group 0.000 claims 3
- 125000001931 aliphatic group Chemical group 0.000 claims 3
- 125000003118 aryl group Chemical group 0.000 claims 3
- 229910052799 carbon Inorganic materials 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 150000001768 cations Chemical class 0.000 claims 3
- 125000004122 cyclic group Chemical group 0.000 claims 3
- 125000000524 functional group Chemical group 0.000 claims 3
- 229910052736 halogen Inorganic materials 0.000 claims 3
- 150000002367 halogens Chemical group 0.000 claims 3
- 125000005842 heteroatom Chemical group 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims 3
- SMWDFEZZVXVKRB-UHFFFAOYSA-O hydron;quinoline Chemical compound [NH+]1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-O 0.000 claims 3
- LFLZOWIFJOBEPN-UHFFFAOYSA-N nitrate, nitrate Chemical compound O[N+]([O-])=O.O[N+]([O-])=O LFLZOWIFJOBEPN-UHFFFAOYSA-N 0.000 claims 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 3
- 239000010452 phosphate Substances 0.000 claims 3
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims 3
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 claims 3
- 229920006395 saturated elastomer Polymers 0.000 claims 3
- 229910052712 strontium Inorganic materials 0.000 claims 3
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 claims 3
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims 3
- 229910052684 Cerium Inorganic materials 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 229910052788 barium Inorganic materials 0.000 claims 2
- 229910052791 calcium Inorganic materials 0.000 claims 2
- 229910003460 diamond Inorganic materials 0.000 claims 2
- 239000010432 diamond Substances 0.000 claims 2
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 239000003381 stabilizer Substances 0.000 claims 2
- 229910052716 thallium Inorganic materials 0.000 claims 2
- 229910001456 vanadium ion Inorganic materials 0.000 claims 2
- 229910052725 zinc Inorganic materials 0.000 claims 2
- 150000007513 acids Chemical class 0.000 claims 1
- 229910052785 arsenic Inorganic materials 0.000 claims 1
- 229910052790 beryllium Inorganic materials 0.000 claims 1
- 229910052745 lead Inorganic materials 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- -1 hexafluorophosphate Chemical compound 0.000 description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- 150000003949 imides Chemical class 0.000 description 2
- DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical class [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-M toluene-4-sulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-M 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009009357A DE102009009357B4 (de) | 2009-02-18 | 2009-02-18 | Redox-Flow-Batterie zur Speicherung von elektrischer Energie in ionischen Flüssigkeiten |
| DE102009009357.5 | 2009-02-18 | ||
| PCT/EP2010/051872 WO2010094657A1 (de) | 2009-02-18 | 2010-02-15 | Methode zur speicherung von elektrischer energie in ionischen flüssigkeiten |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012518247A JP2012518247A (ja) | 2012-08-09 |
| JP2012518247A5 true JP2012518247A5 (https=) | 2013-09-12 |
| JP5468090B2 JP5468090B2 (ja) | 2014-04-09 |
Family
ID=42229119
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011549591A Expired - Fee Related JP5468090B2 (ja) | 2009-02-18 | 2010-02-15 | イオン性液体中に電気エネルギーを蓄える方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8802265B2 (https=) |
| EP (1) | EP2399317B1 (https=) |
| JP (1) | JP5468090B2 (https=) |
| KR (2) | KR20110126623A (https=) |
| CA (1) | CA2751982C (https=) |
| DE (1) | DE102009009357B4 (https=) |
| DK (1) | DK2399317T3 (https=) |
| ES (1) | ES2539957T3 (https=) |
| WO (1) | WO2010094657A1 (https=) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7820321B2 (en) | 2008-07-07 | 2010-10-26 | Enervault Corporation | Redox flow battery system for distributed energy storage |
| US8785023B2 (en) | 2008-07-07 | 2014-07-22 | Enervault Corparation | Cascade redox flow battery systems |
| CA2748146C (en) * | 2010-03-12 | 2012-10-02 | Sumitomo Electric Industries, Ltd. | Redox flow battery |
| DK2581976T3 (da) * | 2010-04-27 | 2014-05-12 | Sumitomo Electric Industries | Redox-flow-batteri |
| US8628880B2 (en) | 2010-09-28 | 2014-01-14 | Battelle Memorial Institute | Redox flow batteries based on supporting solutions containing chloride |
| US9960443B2 (en) * | 2010-09-28 | 2018-05-01 | Battelle Memorial Institute | Redox flow batteries having multiple electroactive elements |
| US8980484B2 (en) | 2011-03-29 | 2015-03-17 | Enervault Corporation | Monitoring electrolyte concentrations in redox flow battery systems |
| US8916281B2 (en) | 2011-03-29 | 2014-12-23 | Enervault Corporation | Rebalancing electrolytes in redox flow battery systems |
| CN102244285B (zh) * | 2011-05-24 | 2016-03-02 | 周成壁 | 一种高浓度锌钒氧化还原电池 |
| CN102856573A (zh) * | 2011-06-30 | 2013-01-02 | 中国科学院大连化学物理研究所 | 一种锌钒液流储能电池 |
| DE102011107185B3 (de) | 2011-07-13 | 2012-08-16 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Luftatmende Brennstoffzelle und Zellstapel für die Oxidation von Ionen mit Sauerstoff |
| US10003097B2 (en) * | 2011-08-02 | 2018-06-19 | Vizn Energy Systems, Incorporated | Process for operating a redox flow battery system |
| US9123943B1 (en) | 2011-08-04 | 2015-09-01 | Sandia Corporation | Synthesis of electroactive ionic liquids for flow battery applications |
| JP5780090B2 (ja) * | 2011-09-28 | 2015-09-16 | 凸版印刷株式会社 | 二次電池用の電極材料 |
| EP2862225A4 (en) | 2012-06-15 | 2015-12-30 | Univ Delaware | DESIGN OF A REDOX FLUX BATTERY WITH SEVERAL MEMBRANES AND SEVERAL ELECTRODES |
| US9537192B2 (en) * | 2012-08-01 | 2017-01-03 | Sharp Laboratories Of America, Inc. | Battery with low temperature molten salt (LTMS) cathode |
| KR102038619B1 (ko) | 2013-01-08 | 2019-10-30 | 삼성전자주식회사 | 레독스 플로우 전지 |
| CN105264704A (zh) | 2013-02-14 | 2016-01-20 | 海卓瑞道克斯技术控股有限公司 | 采用正电解质溶液中的氧化还原电对V+4/V+5和辅助氧化还原电对Ce+3/Ce+4的全钒氧化还原液流电池系统 |
| US8980454B2 (en) | 2013-03-15 | 2015-03-17 | Enervault Corporation | Systems and methods for rebalancing redox flow battery electrolytes |
| JP2016177868A (ja) * | 2013-08-07 | 2016-10-06 | 住友電気工業株式会社 | レドックスフロー電池 |
| CN105474446B (zh) * | 2013-08-07 | 2018-07-03 | 住友电气工业株式会社 | 氧化还原液流电池 |
| KR102364280B1 (ko) | 2013-09-25 | 2022-02-16 | 록히드 마틴 에너지, 엘엘씨 | 플로우 배터리를 위한 전해질 평형화 방법 |
| KR102126034B1 (ko) | 2013-11-01 | 2020-06-23 | 삼성전자주식회사 | 이온 교환막, 그 제조방법 및 그것을 포함한 레독스 플로우 전지 |
| DE102013222716B4 (de) | 2013-11-08 | 2020-06-04 | Solarworld Industries Gmbh | Elektrochemischer Energiespeicher, Energiegewinnungsanlage und Verfahren zum Betrieb eines elektrochemischen Energiespeichers |
| KR102163726B1 (ko) | 2013-11-22 | 2020-10-08 | 삼성전자주식회사 | 레독스 플로우 전지 |
| US9748595B2 (en) | 2013-11-25 | 2017-08-29 | Battelle Memorial Institute | High-energy-density, aqueous, metal-polyiodide redox flow batteries |
| CN103794813B (zh) * | 2014-03-07 | 2015-12-02 | 江西理工大学 | 铕铈液流电池 |
| DE102014103292A1 (de) | 2014-03-12 | 2015-09-17 | Schmid Energy Systems Gmbh | Verbund von elektrochemischen Zellen |
| DE102014103291A1 (de) | 2014-03-12 | 2015-09-17 | Schmid Energy Systems Gmbh | Elektrochemische Zelle und Verbund aus elektrochemischen Zellen |
| DE102014103286B4 (de) * | 2014-03-12 | 2022-10-27 | Schmid Energy Systems Gmbh | Seriell verschalteter Verbund aus Zellen, insbesondere für ein Redoxflow-Speichersystem, und Verfahren zu dessen Herstellung |
| AU2015328395B2 (en) * | 2014-10-06 | 2020-05-07 | Battelle Memorial Institute | All-vanadium sulfate acid redox flow battery system |
| JP2016164859A (ja) * | 2015-03-06 | 2016-09-08 | 古河電池株式会社 | バナジウムレドックス電池 |
| KR102127055B1 (ko) * | 2015-09-24 | 2020-06-26 | 주식회사 메디포럼제약 | 레독스흐름전지용 전해액을 위한 알킬기 치환된 이온성 액체 제조방법 |
| KR102003299B1 (ko) * | 2015-09-25 | 2019-07-24 | 주식회사 엘지화학 | 광재생 전지 |
| JP6682852B2 (ja) * | 2015-12-25 | 2020-04-15 | Ｊｆｅエンジニアリング株式会社 | レドックスフロー電池 |
| CA3019132A1 (en) | 2016-04-01 | 2017-10-05 | NOHMs Technologies, Inc. | Modified ionic liquids containing phosphorus |
| FR3052598B1 (fr) * | 2016-06-10 | 2018-06-01 | Universite De Rennes 1 | Utilisation de liquides ioniques comme adjuvant en electrochimie |
| WO2019018432A1 (en) | 2017-07-17 | 2019-01-24 | NOHMs Technologies, Inc. | ELECTROLYTES CONTAINING PHOSPHORUS |
| JP2021121983A (ja) * | 2018-05-02 | 2021-08-26 | 昭和電工株式会社 | レドックスフロー電池の運転方法 |
| DE102018116293A1 (de) * | 2018-07-05 | 2020-01-09 | Albert-Ludwigs-Universität Freiburg | Flussbatterie |
| CN109638329A (zh) * | 2018-12-19 | 2019-04-16 | 中国科学技术大学 | 一种水系液流电池 |
| WO2020209274A1 (ja) | 2019-04-08 | 2020-10-15 | ＡＲＭ Ｔｅｃｈｎｏｌｏｇｉｅｓ株式会社 | レドックスフロー電池用負極電解液及びレドックスフロー電池 |
| FR3102614B1 (fr) * | 2019-10-24 | 2023-05-05 | Arkema France | Composition electrolytique a base d’acide sulfonique comprenant un additif phosphore |
| DE102021126138A1 (de) | 2021-01-13 | 2022-07-14 | Schaeffler Technologies AG & Co. KG | Redox-Flussbatterie |
| EP4278402A1 (de) | 2021-01-13 | 2023-11-22 | Schaeffler Technologies AG & Co. KG | Redox-flussbatterie |
| DE102022128209B4 (de) * | 2022-10-25 | 2024-05-02 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Chlorid-freie Elektrolytzusammensetzung für einen längeren Betrieb bei hohen Temperaturen (>40°C) in Vanadium Redox-Flow-Batterien |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4786567A (en) | 1986-02-11 | 1988-11-22 | Unisearch Limited | All-vanadium redox battery |
| JPH09507950A (ja) * | 1993-11-17 | 1997-08-12 | ユニサーチ リミテッド | 安定電解液およびその製造方法と、レドックス電池の製造方法、および安定した電解液を含む電池 |
| NZ306364A (en) * | 1995-05-03 | 1999-04-29 | Unisearch Ltd | High energy density vanadium electrolyte solutions, preparation thereof and redox cells and batteries containing the electrolyte solution |
| JP2001189156A (ja) | 2000-01-06 | 2001-07-10 | Sumitomo Electric Ind Ltd | 電池用電極および電池 |
| DE10061959A1 (de) * | 2000-12-13 | 2002-06-20 | Creavis Tech & Innovation Gmbh | Kationen-/protonenleitende, mit einer ionischen Flüssigkeit infiltrierte keramische Membran, Verfahren zu deren Herstellung und die Verwendung der Membran |
| US7060169B2 (en) * | 2002-08-14 | 2006-06-13 | Mst Technology Gmbh | Electrochemical cell for gas sensor |
| JP2004111182A (ja) * | 2002-09-18 | 2004-04-08 | Sumitomo Electric Ind Ltd | レドックスフロー電池用電極の再賦活方法 |
| JP2004168560A (ja) * | 2002-11-15 | 2004-06-17 | Sumitomo Electric Ind Ltd | バナジウム化合物の生成方法及びバナジウム電解液の生成方法 |
| JPWO2005036573A1 (ja) * | 2003-10-09 | 2006-12-28 | 株式会社カネカ | 電極複合体および電解質、ならびにレドックスキャパシター |
| JP2007179745A (ja) * | 2004-08-26 | 2007-07-12 | Yokohama National Univ | プロトン伝導体 |
| US20090017379A1 (en) * | 2005-05-31 | 2009-01-15 | Matsushita Electric Industrial Co., Ltd. | Secondary battery, power supply system using same and usage of power supply system |
| JP5158403B2 (ja) * | 2006-09-19 | 2013-03-06 | ソニー株式会社 | 燃料電池および燃料電池システム、並びに電子機器 |
| EP2146949B1 (de) * | 2007-05-05 | 2017-03-01 | Basf Se | Ionische flüssigkeiten mit polyethercarboxylaten als anionen, deren herstellung und verwendung |
| JP2010086935A (ja) * | 2008-09-03 | 2010-04-15 | Sharp Corp | レドックスフロー電池 |
-
2009
- 2009-02-18 DE DE102009009357A patent/DE102009009357B4/de not_active Expired - Fee Related
-
2010
- 2010-02-15 ES ES10711357.3T patent/ES2539957T3/es active Active
- 2010-02-15 DK DK10711357T patent/DK2399317T3/en active
- 2010-02-15 JP JP2011549591A patent/JP5468090B2/ja not_active Expired - Fee Related
- 2010-02-15 WO PCT/EP2010/051872 patent/WO2010094657A1/de not_active Ceased
- 2010-02-15 KR KR1020117018958A patent/KR20110126623A/ko not_active Ceased
- 2010-02-15 KR KR1020147000660A patent/KR20140017017A/ko not_active Withdrawn
- 2010-02-15 EP EP10711357.3A patent/EP2399317B1/de not_active Not-in-force
- 2010-02-15 US US13/201,813 patent/US8802265B2/en not_active Expired - Fee Related
- 2010-02-15 CA CA2751982A patent/CA2751982C/en not_active Expired - Fee Related
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