FR3102614B1 - Composition electrolytique a base d’acide sulfonique comprenant un additif phosphore - Google Patents

Composition electrolytique a base d’acide sulfonique comprenant un additif phosphore Download PDF

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Publication number
FR3102614B1
FR3102614B1 FR1911889A FR1911889A FR3102614B1 FR 3102614 B1 FR3102614 B1 FR 3102614B1 FR 1911889 A FR1911889 A FR 1911889A FR 1911889 A FR1911889 A FR 1911889A FR 3102614 B1 FR3102614 B1 FR 3102614B1
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FR
France
Prior art keywords
sulfonic acid
composition based
electrolytic composition
phosphorus additive
composition
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FR1911889A
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English (en)
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FR3102614A1 (fr
Inventor
Thierry Aubert
Dominique Plee
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Arkema France SA
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Arkema France SA
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Filing date
Publication date
Priority to FR1911889A priority Critical patent/FR3102614B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to US17/769,115 priority patent/US20230107478A1/en
Priority to PCT/FR2020/051898 priority patent/WO2021079062A1/fr
Priority to JP2022524272A priority patent/JP2022554223A/ja
Priority to CN202080073746.9A priority patent/CN114600287B/zh
Priority to AU2020370808A priority patent/AU2020370808B2/en
Priority to KR1020227016939A priority patent/KR20220084388A/ko
Priority to EP20807078.9A priority patent/EP4049330A1/fr
Publication of FR3102614A1 publication Critical patent/FR3102614A1/fr
Application granted granted Critical
Publication of FR3102614B1 publication Critical patent/FR3102614B1/fr
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184—Regeneration by electrochemical means
    • H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0002—Aqueous electrolytes
    • H01M2300/0005—Acid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • H01M2300/008—Halides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

COMPOSITION ELECTROLYTIQUE A BASE D’ACIDE SULFONIQUE COMPRENANT UN ADDITIF PHOSPHORE La présente invention concerne une composition aqueuse d’électrolyte(s) comprenant un acide sulfonique, éventuellement de l’acide sulfurique, des ions métalliques redox, et au moins un additif inorganique (A) comprenant au moins un atome de phosphore dont le degré d’oxydation est inférieur ou égal à +5. La présente invention concerne également une cellule électrochimique comprenant ladite composition d’électrolyte(s) et une batterie à oxydoréduction (également appelée batterie redox) comprenant une telle cellule. Figure : néant
FR1911889A 2019-10-24 2019-10-24 Composition electrolytique a base d’acide sulfonique comprenant un additif phosphore Active FR3102614B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR1911889A FR3102614B1 (fr) 2019-10-24 2019-10-24 Composition electrolytique a base d’acide sulfonique comprenant un additif phosphore
PCT/FR2020/051898 WO2021079062A1 (fr) 2019-10-24 2020-10-21 Composition electrolytique a base d'acide sulfonique comprenant un additif phosphore
JP2022524272A JP2022554223A (ja) 2019-10-24 2020-10-21 リン添加物を含むスルホン酸に基づく電解質組成物
CN202080073746.9A CN114600287B (zh) 2019-10-24 2020-10-21 包含磷添加剂的基于磺酸的电解质组合物
US17/769,115 US20230107478A1 (en) 2019-10-24 2020-10-21 Electrolytic composition based on sulfonic acid comprising a phosphorus additive
AU2020370808A AU2020370808B2 (en) 2019-10-24 2020-10-21 Electrolytic composition made from sulphonic acid comprising a phosphorous additive
KR1020227016939A KR20220084388A (ko) 2019-10-24 2020-10-21 인 첨가제를 포함하는 설폰산 기반 전해 조성물
EP20807078.9A EP4049330A1 (fr) 2019-10-24 2020-10-21 Composition electrolytique a base d'acide sulfonique comprenant un additif phosphore

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1911889 2019-10-24
FR1911889A FR3102614B1 (fr) 2019-10-24 2019-10-24 Composition electrolytique a base d’acide sulfonique comprenant un additif phosphore

Publications (2)

Publication Number Publication Date
FR3102614A1 FR3102614A1 (fr) 2021-04-30
FR3102614B1 true FR3102614B1 (fr) 2023-05-05

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
FR1911889A Active FR3102614B1 (fr) 2019-10-24 2019-10-24 Composition electrolytique a base d’acide sulfonique comprenant un additif phosphore

Country Status (8)

Country Link
US (1) US20230107478A1 (fr)
EP (1) EP4049330A1 (fr)
JP (1) JP2022554223A (fr)
KR (1) KR20220084388A (fr)
CN (1) CN114600287B (fr)
AU (1) AU2020370808B2 (fr)
FR (1) FR3102614B1 (fr)
WO (1) WO2021079062A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102647426B1 (ko) 2022-08-24 2024-03-14 한국지질자원연구원 바나듐 레독스 흐름 배터리의 전해액을 제조하는 방법 및 이로부터 제조된 바나듐 레독스 흐름 배터리의 전해액
DE102022128209B4 (de) 2022-10-25 2024-05-02 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein Chlorid-freie Elektrolytzusammensetzung für einen längeren Betrieb bei hohen Temperaturen (>40°C) in Vanadium Redox-Flow-Batterien

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989005526A1 (fr) * 1987-12-10 1989-06-15 Unisearch Limited Batterie redox entierement en vanadium et additifs
JP2994210B2 (ja) * 1994-08-22 1999-12-27 住友電気工業株式会社 バナジウム系レドックスフロー型電池の電解液
US6468688B2 (en) * 1995-05-03 2002-10-22 Pinnacle Vrb Limited High energy density vanadium electrolyte solutions, methods of preparation thereof and all-vanadium redox cells and batteries containing high energy vanadium electrolyte solutions
JP3897544B2 (ja) * 2001-06-07 2007-03-28 住友電気工業株式会社 レドックスフロー電池用電解液およびレドックスフロー電池
WO2010143634A1 (fr) * 2009-06-09 2010-12-16 シャープ株式会社 Batterie à circulation d'oxydoréducteur
US8951665B2 (en) * 2010-03-10 2015-02-10 Imergy Power Systems, Inc. Methods for the preparation of electrolytes for chromium-iron redox flow batteries
DK2387092T3 (da) 2010-03-12 2013-06-10 Sumitomo Electric Industries Redox-flow-batteri
KR102014986B1 (ko) * 2012-10-04 2019-08-27 삼성전자주식회사 유기 전해액 및 이를 포함하는 레독스 플로우 전지
JP2014127358A (ja) * 2012-12-26 2014-07-07 Nihon Univ レドックスフロー電池
WO2014125331A1 (fr) * 2013-02-14 2014-08-21 Hydraredox Technologies Inc. Système de batterie à flux d'oxydoréduction au tout vanadium employant un couple d'oxydoréduction v+4/v+5 et un couple d'oxydoréduction ce+3/ce+4 auxiliaire dans la solution d'électrolyte positive
EP2770568B1 (fr) * 2013-02-26 2016-08-10 Fundacio Institut Recerca en Energia de Catalunya Formulations d'électrolyte pour utilisation dans des batteries à flux redox
US9865895B2 (en) 2013-03-12 2018-01-09 Ess Tech, Inc. Methods to prepare stable electrolytes for iron redox flow batteries
JP6204069B2 (ja) * 2013-05-23 2017-09-27 旭化成株式会社 電解液及びレドックスフロー電池
JP2014235946A (ja) * 2013-06-04 2014-12-15 旭化成イーマテリアルズ株式会社 電解液及びレドックスフロー電池
US10615441B2 (en) * 2014-12-22 2020-04-07 Sumitomo Electric Industries, Ltd. Redox flow battery
JP6845666B2 (ja) * 2016-02-12 2021-03-24 学校法人同志社 レドックスフロー電池用電解液およびそれを用いたレドックスフロー電池
FR3070694B1 (fr) 2017-09-01 2020-07-03 Arkema France Inhibiteurs de corrosion metallique
US11177497B2 (en) * 2018-03-12 2021-11-16 Washington University Redox flow battery
CN111146485A (zh) * 2019-12-31 2020-05-12 中南大学 一种高浓度全钒液流电池正极电解液

Also Published As

Publication number Publication date
KR20220084388A (ko) 2022-06-21
WO2021079062A1 (fr) 2021-04-29
JP2022554223A (ja) 2022-12-28
FR3102614A1 (fr) 2021-04-30
EP4049330A1 (fr) 2022-08-31
US20230107478A1 (en) 2023-04-06
AU2020370808B2 (en) 2024-03-28
CN114600287B (zh) 2024-07-09
AU2020370808A1 (en) 2022-05-26
CN114600287A (zh) 2022-06-07

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