JP2012503016A5 - - Google Patents
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- JP2012503016A5 JP2012503016A5 JP2011528043A JP2011528043A JP2012503016A5 JP 2012503016 A5 JP2012503016 A5 JP 2012503016A5 JP 2011528043 A JP2011528043 A JP 2011528043A JP 2011528043 A JP2011528043 A JP 2011528043A JP 2012503016 A5 JP2012503016 A5 JP 2012503016A5
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- 125000004432 carbon atoms Chemical group C* 0.000 description 6
- 125000005843 halogen group Chemical group 0.000 description 4
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 125000004093 cyano group Chemical group *C#N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- -1 poly (chlorotetrafluorosulfanyl Chemical group 0.000 description 2
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N iodine atom Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- ZGJYJNYANHLEHS-UHFFFAOYSA-N pentafluoro-[2,3,5,6-tetrafluoro-4-(pentafluoro-$l^{6}-sulfanyl)phenyl]-$l^{6}-sulfane Chemical compound FC1=C(F)C(S(F)(F)(F)(F)F)=C(F)C(F)=C1S(F)(F)(F)(F)F ZGJYJNYANHLEHS-UHFFFAOYSA-N 0.000 description 1
Description
（式中、Ｒ １” 、Ｒ ２” 、Ｒ ３” 、Ｒ ４” 、及びＲ ５” の１つ又は２つはＳＦ４Ｃｌであり、残りのそれぞれは、水素原子、ハロゲン原子、１〜１８個の炭素原子、好ましくは１〜１０個の炭素原子、より好ましくは１〜４個の炭素原子を有する置換又は非置換アルキル基、ニトロ基、及びシアノ基である）
によって表される新規なポリ（クロロテトラフルオロスルファニル）芳香族化合物を提供する。
によって表される新規なポリ（クロロテトラフルオロスルファニル）芳香族化合物を提供する。
（式中、（式中、Ｒ １” 、Ｒ ２” 、Ｒ ３” 、Ｒ ４” 、及びＲ ５” の１つ又は２つはＳＦ４Ｃｌであり、残りのそれぞれは、水素原子、ハロゲン原子、１〜１８個の炭素原子、好ましくは１〜１０個の炭素原子、より好ましくは１〜４個の炭素原子を有する置換又は非置換アルキル基、ニトロ基、及びシアノ基である）
によって表される新規なポリ（クロロテトラフルオロスルファニル）芳香族化合物も提供する。残りは、好ましくは、水素原子及びハロゲン原子からなる群から選択される。ハロゲン原子は、フッ素原子、塩素原子、臭素原子、又はヨウ素原子であってよい。
によって表される新規なポリ（クロロテトラフルオロスルファニル）芳香族化合物も提供する。残りは、好ましくは、水素原子及びハロゲン原子からなる群から選択される。ハロゲン原子は、フッ素原子、塩素原子、臭素原子、又はヨウ素原子であってよい。
[00108]本発明はまた、式（Ｉ”）：
[00126]１，４−ビス（ペンタフルオロスルファニル）−２，３，５，６−テトラフルオロベンゼン（Ｉｅ）；融点：１２９．２〜１３０．０℃；19F-NMR (CDCl3)δ71.0-74.4 (m, 10F), -130.8 (m, 4F)；13C-NMR (CDCl3)δ144.9 (m), 141.3 (m), 133.3 (m)；GC-Mass m/z 402 (M+)。元素分析；Ｃ６Ｆ１４Ｓ２に関する計算値；Ｃ，１７．９２％，Ｈ，０．００％；測定値；Ｃ，１７．９９％，Ｈ，＜０．０５％。
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9897508P | 2008-09-22 | 2008-09-22 | |
| US61/098,975 | 2008-09-22 | ||
| US14356409P | 2009-01-09 | 2009-01-09 | |
| US61/143,564 | 2009-01-09 | ||
| PCT/US2009/057714 WO2010033930A1 (en) | 2008-09-22 | 2009-09-21 | Processes for preparing poly(pentafluorosulfanyl)aromatic compounds |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014089361A Division JP5761583B2 (ja) | 2008-09-22 | 2014-04-23 | ポリ（ペンタフルオロスルファニル）芳香族化合物の製造方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012503016A JP2012503016A (ja) | 2012-02-02 |
| JP2012503016A5 true JP2012503016A5 (ja) | 2012-09-27 |
| JP5574280B2 JP5574280B2 (ja) | 2014-08-20 |
Family
ID=42039908
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011528043A Active JP5574280B2 (ja) | 2008-09-22 | 2009-09-21 | ポリ（ペンタフルオロスルファニル）芳香族化合物の製造方法 |
| JP2014089361A Active JP5761583B2 (ja) | 2008-09-22 | 2014-04-23 | ポリ（ペンタフルオロスルファニル）芳香族化合物の製造方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014089361A Active JP5761583B2 (ja) | 2008-09-22 | 2014-04-23 | ポリ（ペンタフルオロスルファニル）芳香族化合物の製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8653302B2 (ja) |
| EP (1) | EP2334661B1 (ja) |
| JP (2) | JP5574280B2 (ja) |
| KR (1) | KR101676054B1 (ja) |
| CN (2) | CN102224147B (ja) |
| WO (1) | WO2010033930A1 (ja) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7265247B1 (en) | 2006-07-28 | 2007-09-04 | Im&T Research, Inc. | Substituted phenylsulfur trifluoride and other like fluorinating agents |
| US8399720B2 (en) * | 2007-03-23 | 2013-03-19 | Ube Industries, Ltd. | Methods for producing fluorinated phenylsulfur pentafluorides |
| UA105354C2 (uk) | 2007-03-23 | 2014-05-12 | Юби Индастриз, Лтд. | Спосіб одержання пентафторидів арилсірки |
| US8030516B2 (en) | 2007-10-19 | 2011-10-04 | Ube Industries, Ltd. | Methods for producing perfluoroalkanedi(sulfonyl chloride) |
| TW201006787A (en) * | 2008-03-07 | 2010-02-16 | Im & T Res Inc | Fluorination processes with arylsulfur halotetrafluorides |
| CN102186812A (zh) * | 2008-08-18 | 2011-09-14 | 宇部兴产株式会社 | 制备氟烷基芳基亚磺酰基化合物及其氟化的化合物的方法 |
| EP2334661B1 (en) | 2008-09-22 | 2017-08-30 | Ube Industries, Ltd. | Processes for preparing poly(pentafluorosulfanyl)aromatic compounds |
| US20100174096A1 (en) * | 2009-01-05 | 2010-07-08 | Im&T Research, Inc. | Methods for Production of Optically Active Fluoropyrrolidine Derivatives |
| WO2010081014A1 (en) | 2009-01-09 | 2010-07-15 | Im&T Research, Inc. | Novel 4-fluoropyrrolidine-2-carbonyl fluoride compounds and their preparative methods |
| US9108910B2 (en) * | 2011-02-15 | 2015-08-18 | Ube Industries, Ltd. | Industrial methods for producing arylsulfur pentafluorides |
| WO2014052650A2 (en) * | 2012-09-26 | 2014-04-03 | Massachusetts Institute Of Technology | Modification of peptides via snar reactions of thiols with fluorinated aromatics |
| WO2014062221A1 (en) | 2012-10-18 | 2014-04-24 | The Research Foundation For The State University Of New York | Aryl tetrafluorosulfanyl compounds |
| DE102013104346A1 (de) | 2013-04-29 | 2014-10-30 | Institute Of Organic Chemistry And Biochemistry As Cr, V.V.I. | Verfahren zur herstellung von arylschwefelpentafluoriden |
| US9181297B1 (en) | 2014-05-15 | 2015-11-10 | Massachusetts Institute Of Technology | Cysteine arylation directed by a genetically encodable π-clamp |
| CN110621658B (zh) * | 2017-02-28 | 2021-09-24 | 宇部兴产株式会社 | 五氟硫烷基芳香族化合物的制造方法 |
| US11985841B2 (en) | 2020-12-07 | 2024-05-14 | Oti Lumionics Inc. | Patterning a conductive deposited layer using a nucleation inhibiting coating and an underlying metallic coating |
| JPWO2022186304A1 (ja) * | 2021-03-02 | 2022-09-09 |
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| US8030516B2 (en) * | 2007-10-19 | 2011-10-04 | Ube Industries, Ltd. | Methods for producing perfluoroalkanedi(sulfonyl chloride) |
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| TW201006787A (en) * | 2008-03-07 | 2010-02-16 | Im & T Res Inc | Fluorination processes with arylsulfur halotetrafluorides |
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| CN102186812A (zh) * | 2008-08-18 | 2011-09-14 | 宇部兴产株式会社 | 制备氟烷基芳基亚磺酰基化合物及其氟化的化合物的方法 |
| EP2334661B1 (en) | 2008-09-22 | 2017-08-30 | Ube Industries, Ltd. | Processes for preparing poly(pentafluorosulfanyl)aromatic compounds |
| US20100174096A1 (en) * | 2009-01-05 | 2010-07-08 | Im&T Research, Inc. | Methods for Production of Optically Active Fluoropyrrolidine Derivatives |
| WO2010081014A1 (en) | 2009-01-09 | 2010-07-15 | Im&T Research, Inc. | Novel 4-fluoropyrrolidine-2-carbonyl fluoride compounds and their preparative methods |
| US20110301382A1 (en) * | 2009-12-07 | 2011-12-08 | Ube Industries, Ltd. | Processes for Preparing 1,3-Dinitro-5-(Pentafluorosulfanyl)Benzene and its Intermediates |
| US20120157716A1 (en) * | 2010-07-08 | 2012-06-21 | Ube Industries, Ltd. | Methods for Preparing Diaryl Disulfides |
-
2009
- 2009-09-21 EP EP09815342.2A patent/EP2334661B1/en active Active
- 2009-09-21 CN CN200980146510.7A patent/CN102224147B/zh active Active
- 2009-09-21 WO PCT/US2009/057714 patent/WO2010033930A1/en active Application Filing
- 2009-09-21 US US13/119,367 patent/US8653302B2/en active Active
- 2009-09-21 JP JP2011528043A patent/JP5574280B2/ja active Active
- 2009-09-21 KR KR1020117009153A patent/KR101676054B1/ko active IP Right Grant
- 2009-09-21 CN CN2013102785083A patent/CN103382173A/zh active Pending
-
2014
- 2014-04-23 JP JP2014089361A patent/JP5761583B2/ja active Active
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