JP2011527374A - 成膜が改善されたフルオロポリマー水性ハイブリッド組成物 - Google Patents
成膜が改善されたフルオロポリマー水性ハイブリッド組成物 Download PDFInfo
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- JP2011527374A JP2011527374A JP2011517454A JP2011517454A JP2011527374A JP 2011527374 A JP2011527374 A JP 2011527374A JP 2011517454 A JP2011517454 A JP 2011517454A JP 2011517454 A JP2011517454 A JP 2011517454A JP 2011527374 A JP2011527374 A JP 2011527374A
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- Prior art keywords
- fluoropolymer
- composition
- monomer
- vinyl
- stable aqueous
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 179
- 229920002313 fluoropolymer Polymers 0.000 title claims abstract description 119
- 239000004811 fluoropolymer Substances 0.000 title claims abstract description 119
- 230000015572 biosynthetic process Effects 0.000 title claims description 4
- 239000000178 monomer Substances 0.000 claims abstract description 164
- 239000006185 dispersion Substances 0.000 claims abstract description 41
- 229920002554 vinyl polymer Polymers 0.000 claims description 45
- 229920000642 polymer Polymers 0.000 claims description 31
- -1 pH adjusters Substances 0.000 claims description 26
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 22
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 15
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
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- 239000008199 coating composition Substances 0.000 claims description 10
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical group FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 8
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
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- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- 229920000028 Gradient copolymer Polymers 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 3
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 claims description 2
- 239000004606 Fillers/Extenders Substances 0.000 claims description 2
- 239000012963 UV stabilizer Substances 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
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- 238000000518 rheometry Methods 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 229920006243 acrylic copolymer Polymers 0.000 claims 3
- 239000004971 Cross linker Substances 0.000 claims 1
- 239000013020 final formulation Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 33
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 17
- 239000011248 coating agent Substances 0.000 abstract description 17
- 230000009477 glass transition Effects 0.000 abstract description 7
- 238000010556 emulsion polymerization method Methods 0.000 abstract description 2
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- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 20
- 239000000243 solution Substances 0.000 description 19
- 239000003999 initiator Substances 0.000 description 18
- 239000012855 volatile organic compound Substances 0.000 description 18
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- 239000003973 paint Substances 0.000 description 14
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 11
- 239000010408 film Substances 0.000 description 11
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 10
- 229910052786 argon Inorganic materials 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000002033 PVDF binder Substances 0.000 description 7
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- AVTLBBWTUPQRAY-UHFFFAOYSA-N 2-(2-cyanobutan-2-yldiazenyl)-2-methylbutanenitrile Chemical compound CCC(C)(C#N)N=NC(C)(CC)C#N AVTLBBWTUPQRAY-UHFFFAOYSA-N 0.000 description 6
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 6
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 230000008569 process Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 239000011342 resin composition Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- ORDRGXFSRBRQQG-UHFFFAOYSA-N 6-methylheptyl 2-sulfanylpropanoate Chemical compound CC(C)CCCCCOC(=O)C(C)S ORDRGXFSRBRQQG-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 238000007720 emulsion polymerization reaction Methods 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 238000011010 flushing procedure Methods 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000010926 purge Methods 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000012986 chain transfer agent Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 239000003002 pH adjusting agent Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
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- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
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- 150000001412 amines Chemical class 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
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- 239000002280 amphoteric surfactant Substances 0.000 description 2
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- 239000012736 aqueous medium Substances 0.000 description 2
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- NSGQRLUGQNBHLD-UHFFFAOYSA-N butan-2-yl butan-2-yloxycarbonyloxy carbonate Chemical compound CCC(C)OC(=O)OOC(=O)OC(C)CC NSGQRLUGQNBHLD-UHFFFAOYSA-N 0.000 description 2
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- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
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- 230000000153 supplemental effect Effects 0.000 description 2
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- OQMIRQSWHKCKNJ-UHFFFAOYSA-N 1,1-difluoroethene;1,1,2,3,3,3-hexafluoroprop-1-ene Chemical group FC(F)=C.FC(F)=C(F)C(F)(F)F OQMIRQSWHKCKNJ-UHFFFAOYSA-N 0.000 description 1
- SKYXLDSRLNRAPS-UHFFFAOYSA-N 1,2,4-trifluoro-5-methoxybenzene Chemical compound COC1=CC(F)=C(F)C=C1F SKYXLDSRLNRAPS-UHFFFAOYSA-N 0.000 description 1
- DVMSVWIURPPRBC-UHFFFAOYSA-N 2,3,3-trifluoroprop-2-enoic acid Chemical compound OC(=O)C(F)=C(F)F DVMSVWIURPPRBC-UHFFFAOYSA-N 0.000 description 1
- FTALTLPZDVFJSS-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl prop-2-enoate Chemical compound CCOCCOCCOC(=O)C=C FTALTLPZDVFJSS-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
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- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
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- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
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- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 1
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- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
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- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical class [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- CLFBXKHKECKSQM-UHFFFAOYSA-N Pseudopalmatine Chemical compound COC1=C(OC)C=C2C=C(C3=C(C=C(C(=C3)OC)OC)CC3)[N+]3=CC2=C1 CLFBXKHKECKSQM-UHFFFAOYSA-N 0.000 description 1
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- KYIKRXIYLAGAKQ-UHFFFAOYSA-N abcn Chemical compound C1CCCCC1(C#N)N=NC1(C#N)CCCCC1 KYIKRXIYLAGAKQ-UHFFFAOYSA-N 0.000 description 1
- WDJHALXBUFZDSR-UHFFFAOYSA-M acetoacetate Chemical compound CC(=O)CC([O-])=O WDJHALXBUFZDSR-UHFFFAOYSA-M 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
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- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 230000010100 anticoagulation Effects 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
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- UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
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- 238000012512 characterization method Methods 0.000 description 1
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- 230000001276 controlling effect Effects 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
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- BSVQJWUUZCXSOL-UHFFFAOYSA-N cyclohexylsulfonyl ethaneperoxoate Chemical compound CC(=O)OOS(=O)(=O)C1CCCCC1 BSVQJWUUZCXSOL-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- WBZKQQHYRPRKNJ-UHFFFAOYSA-L disulfite Chemical compound [O-]S(=O)S([O-])(=O)=O WBZKQQHYRPRKNJ-UHFFFAOYSA-L 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
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- 125000003700 epoxy group Chemical group 0.000 description 1
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
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- 125000004428 fluoroalkoxy group Chemical group 0.000 description 1
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- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
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- 239000001530 fumaric acid Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 239000001034 iron oxide pigment Substances 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 229940094506 lauryl betaine Drugs 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- WFKDPJRCBCBQNT-UHFFFAOYSA-N n,2-dimethylprop-2-enamide Chemical compound CNC(=O)C(C)=C WFKDPJRCBCBQNT-UHFFFAOYSA-N 0.000 description 1
- DNTMQTKDNSEIFO-UHFFFAOYSA-N n-(hydroxymethyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCO DNTMQTKDNSEIFO-UHFFFAOYSA-N 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- GYDSPAVLTMAXHT-UHFFFAOYSA-N pentyl 2-methylprop-2-enoate Chemical compound CCCCCOC(=O)C(C)=C GYDSPAVLTMAXHT-UHFFFAOYSA-N 0.000 description 1
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000005634 peroxydicarbonate group Chemical group 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
- YPVDWEHVCUBACK-UHFFFAOYSA-N propoxycarbonyloxy propyl carbonate Chemical compound CCCOC(=O)OOC(=O)OCCC YPVDWEHVCUBACK-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 229940001474 sodium thiosulfate Drugs 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
- 235000019187 sodium-L-ascorbate Nutrition 0.000 description 1
- 239000011755 sodium-L-ascorbate Substances 0.000 description 1
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- JREYOWJEWZVAOR-UHFFFAOYSA-N triazanium;[3-methylbut-3-enoxy(oxido)phosphoryl] phosphate Chemical compound [NH4+].[NH4+].[NH4+].CC(=C)CCOP([O-])(=O)OP([O-])([O-])=O JREYOWJEWZVAOR-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical class OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical class OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/08—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
- C08F14/22—Vinylidene fluoride
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/062—Copolymers with monomers not covered by C08L33/06
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- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Graft Or Block Polymers (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Description
a) フルオロポリマーと;
b) 前記フルオロポリマーと混和可能である第1のビニルポリマーと;
c) 前記第1のビニルポリマーと異なる組成を有し、かつ30℃未満のTgを有する第2のビニルポリマーと;
d) 任意にはその他のビニルポリマーと、
を有する組成物であって、前記フルオロポリマー分散が、20℃未満の最低成膜温度(MFFT)を有する組成物に関する。
a) フルオロポリマー粒子が300nm未満の粒径を有する、水性フルオロポリマーシード分散の形成ステップと;
b) 前記フルオロポリマーの存在下で少なくとも2つの異なるビニルモノマー組成物を順次重合させて安定したフルオロポリマー組成物を形成するステップと、
を含む方法であって、第1のビニルモノマー組成物が前記フルオロポリマーと混和可能なポリマーを形成し、第2のビニルモノマー組成物が30℃未満のTgを有するポリマーを形成し、かつ前記フルオロポリマー組成物が20℃未満の最低成膜温度(MFFT)を有する、プロセスにも関する。
フルオロポリマーラテックス(樹脂組成物は75/25wt%のVF2/25HFPを有し、ラテックスは36.7重量パーセントの固形分を有する、450g)、VAZO(登録商標)−67(Dupont)、POLYSTEP B7ラウリル硫酸アンモニウム(Stepan、30wt%水溶液)をそのままの状態で使用する。メタクリル酸メチル、アクリル酸ブチル、メタクリル酸、およびアクリル酸エチルはAldrich製であり、受入れたままの状態でこれを使用する。
フルオロポリマーラテックス(樹脂組成物は75/25wt%のVF2/25HFPを有し、ラテックスは40重量パーセントの固形分を有する、1200g)、VAZO(登録商標)−67(Dupont)、POLYSTEP B7ラウリル硫酸アンモニウム(Stepan、30wt%水溶液)を受入れたままの状態で使用する。Arkema製のNORSOCRYL104は、メタクリル酸メチル中50%溶液であり、これを、受入れたままの状態で使用した。メタクリル酸メチル、アクリル酸ブチル、メタクリル酸、およびアクリル酸エチルはAldrich製であり、受入れたままの状態でこれを使用した。
フルオロポリマーラテックス(樹脂組成物は75/25wt%のVF2/25HFPを有し、ラテックスは43.5重量パーセントの固形分を有する、1100g)、VAZO(登録商標)−67(Dupont)、POLYSTEP B7ラウリル硫酸アンモニウム(Stepan、30wt%水溶液)を受入れたままの状態で使用する。Arkema製のNORSOCRYL104は、メタクリル酸メチル中50%溶液であり、これを、受入れたままの状態で使用した。メタクリル酸メチル、アクリル酸ブチル、メタクリル酸、およびアクリル酸エチルはAldrich製であり、受入れたままの状態でこれを使用した。
フルオロポリマーラテックス(樹脂組成物は75/25wt%のVF2/25HFPを有し、ラテックスは36.7重量パーセントの固形分を有する、1100g)、VAZO(登録商標)−67(Dupont)、およびPOLYSTEP B7ラウリル硫酸アンモニウム(Stepan、30wt%水溶液)を受入れたままの状態で使用する。Arkema製のNORSOCRYL104は、メタクリル酸メチル中50%溶液であり、これを、受入れたままの状態で使用した。メタクリル酸メチル、アクリル酸ブチル、およびメタクリル酸はAldrich製であり、受入れたままの状態でこれを使用した。
実施例1〜4のラテックス試料を、28%のアンモニア水または有機アミン(Angus Chemical Company製のAMP−95、またはTraminco製Vantex(登録商標)T)を用いて、8〜9の間のpHに中和した。これらの中和した試料のMFFTを測定し、塗料の調合にこの試料を使用した。ギャップ50ミクロンのドローダウンアプリケータ(draw down applicator)キューブを用いてMFFTバー(Paul Gardner Inc.)の表面にラテックスの薄膜を塗布し、1時間コーティングを乾燥させ、次に、ラテックスが透明な亀裂の無い膜を形成する最低温度を書き留めることにより、MFFTを測定した。
以下の手順は、モノマー混合物Aおよびモノマー混合物Bについて以下のビニルモノマー組成物を用いて実施例5〜8を調製するために用いられた一般的方法を網羅している(表2)。
実施例9〜16を、プレエマルジョンAおよびプレエマルジョンBについて以下のビニルモノマー組成物を用いて、実施例2の一般的方法にしたがって調製した。全ての数量はグラム単位である。
Claims (19)
- 安定した水性フルオロポリマーハイブリッド組成物において、
a) フルオロポリマーと;
b) 前記フルオロポリマーと混和可能である第1のビニルポリマーと;
c) 前記第1のビニルポリマーと異なる組成を有し、かつ30℃未満のTgを有する第2のビニルポリマーと;
d) 任意にはその他のビニルポリマーと、
を含む組成物であって、前記フルオロポリマー分散が、20℃未満の最低成膜温度(MFFT)を有する組成物。 - 前記第1および第2のビニルポリマーの少なくとも1つがアクリル(コ)ポリマーを含む、請求項1に記載の安定した水性フルオロポリマーハイブリッド組成物。
- 前記第1および第2の両方のビニルポリマーがアクリル(コ)ポリマーを含む、請求項1に記載の安定した水性フルオロポリマーハイブリッド組成物。
- 前記第1および第2のビニルポリマーがアクリル(コ)ポリマーで構成されている、請求項1に記載の安定した水性フルオロポリマーハイブリッド組成物。
- 前記フルオロポリマーが50〜100重量パーセントのフッ化ビニリデン単位、0〜30重量パーセントのヘキサフルオロエチレン単位、およびフッ化ビニリデンと共重合可能な0〜30重量部のビニルモノマー単位を含む、請求項1に記載の安定した水性フルオロポリマーハイブリッド組成物。
- 70〜100重量パーセントのフッ化ビニリデン単位を含む、請求項5に記載の安定した水性フルオロポリマーハイブリッド組成物。
- 前記フルオロポリマーが30J/g未満の結晶化度を有する、請求項1に記載の安定した水性フルオロポリマーハイブリッド組成物。
- 前記第1および第2のビニルポリマーが10:90〜90:10の比率で分散中に存在する、請求項1に記載の安定した水性フルオロポリマーハイブリッド組成物。
- 前記第1および第2のビニルポリマーが25:75〜75:25の比率で分散中に存在する、請求項1に記載の安定した水性フルオロポリマーハイブリッド組成物。
- 前記第1のビニルポリマーが、酢酸ビニル、アクリル酸メチル、アクリル酸エチル、メタクリル酸メチル、メタクリル酸エチル、メタクリル酸アセトアセトキシエチルおよびアクリロニトリルからなる群から選択される少なくとも70重量パーセントのモノマーと、10wt%未満のヒドロキシ官能性モノマー、酸官能性モノマー、スチレンまたはアルファメチルスチレンとを含む、請求項1に記載の安定した水性フルオロポリマーハイブリッド組成物。
- 前記第2のビニルポリマーが、−50℃〜20℃のTgを有する、請求項1に記載の安定した水性フルオロポリマーハイブリッド組成物。
- 前記第2のビニルポリマーが、0℃〜20℃のTgを有する、請求項11に記載の安定した水性フルオロポリマーハイブリッド組成物。
- 100重量部のフルオロポリマーあたり20〜300重量部の合計ビニルモノマーを含む、請求項1に記載の安定した水性フルオロポリマーハイブリッド組成物。
- 100重量部のフルオロポリマーあたり60〜150重量部の合計ビニルモノマーを含む、請求項13に記載の安定した水性フルオロポリマーハイブリッド組成物。
- 前記ビニルポリマーの少なくとも1つがグラジエントコポリマーである、請求項1に記載の安定した水性フルオロポリマーハイブリッド組成物。
- 環境に無害なフルオロポリマーハイブリッド組成物を形成する方法において;
a) 前記フルオロポリマー粒子が300nm未満の粒径を有する、水性フルオロポリマーシード分散の形成ステップと;
b) 前記フルオロポリマーの存在下で少なくとも2つの異なるビニルモノマー組成物を順次重合させて安定したフルオロポリマー組成物を形成するステップと、
を含む方法であって、前記第1のビニルモノマー組成物が前記フルオロポリマーと混和可能なポリマーを形成し、前記第2のビニルモノマー組成物が30℃未満のTgを有するポリマーを形成し、かつ前記フルオロポリマー組成物が20℃未満の最低成膜温度(MFFT)を有する、方法。 - 20℃未満の最低成膜温度(MFFT)および50g/(1リットルの水)未満のVOCを有する、請求項1に記載の安定した水性フルオロポリマーハイブリッド組成物を含むコーティング組成物。
- UV安定化剤、pH調整剤、着色剤、染料、水溶性樹脂、レオロジー制御添加剤および増粘剤ならびに顔料および顔料増量剤そして充填材をさらに含む、請求項17に記載のコーティング組成物。
- 外部架橋剤が最終調合物中に添加される、請求項17に記載のコーティング組成物。
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Cited By (8)
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JP2015520256A (ja) * | 2012-04-17 | 2015-07-16 | アーケマ・インコーポレイテッド | 水性フルオロポリマーガラスコーティング |
JP2015520664A (ja) * | 2012-04-17 | 2015-07-23 | アーケマ・インコーポレイテッド | 水性フルロロポリマーコーティングを用いてガラス基材をコーティングするための方法 |
JP2017052879A (ja) * | 2015-09-09 | 2017-03-16 | ダイキン工業株式会社 | 複合重合体粒子及びその製造方法 |
JP2017525835A (ja) * | 2014-07-01 | 2017-09-07 | アーケマ・インコーポレイテッド | 安定な水系フルオロポリマーコーティング組成物 |
JP2019502766A (ja) * | 2015-11-25 | 2019-01-31 | アーケマ・インコーポレイテッド | 改良された機械的湿し性を有するフルオロポリマー組成物 |
JP2020073708A (ja) * | 2015-09-09 | 2020-05-14 | ダイキン工業株式会社 | 複合重合体粒子及びその製造方法 |
JP7376365B2 (ja) | 2017-06-15 | 2023-11-08 | アルケマ フランス | 改良された接着性を有するフッ素化ポリマーをベースとするインク |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103080151B (zh) | 2010-09-01 | 2016-02-03 | 阿科玛股份有限公司 | 用酸功能化的单体来生产氟聚合物的方法 |
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JPWO2021200647A1 (ja) | 2020-03-31 | 2021-10-07 | ||
KR20230125234A (ko) * | 2020-12-23 | 2023-08-29 | 알케마 인코포레이티드 | 분산 점도가 감소된 코팅을 위한 신규한 pvdf 분말 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07258499A (ja) * | 1994-03-23 | 1995-10-09 | Japan Synthetic Rubber Co Ltd | 含フッ素重合体水性分散液 |
JP2003231722A (ja) * | 2002-02-13 | 2003-08-19 | Daikin Ind Ltd | フッ素樹脂水性分散組成物 |
WO2007026949A1 (en) * | 2005-09-02 | 2007-03-08 | Nippon Shokubai Co., Ltd. | Emulsion type resin composition |
WO2007030152A2 (en) * | 2005-05-19 | 2007-03-15 | Arkema Inc. | Highly weatherable roof coatings containing aqueous fluoropolymer dispersions |
JP2007145977A (ja) * | 2005-11-28 | 2007-06-14 | Dainippon Ink & Chem Inc | 水性コーティング液及び機能性皮膜 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4537916A (en) * | 1984-06-25 | 1985-08-27 | The Dow Chemical Company | Structured latex particles which are film forming and a process for their preparation |
DE68911814T2 (de) * | 1988-09-20 | 1994-05-05 | Japan Synthetic Rubber Co Ltd | Wässrige, Fluorid enthaltende Kunststoffdispersion und wässrige Dispersion von Fluorid enthaltendem Kunststoff und wasserlöslichem Harz und/oder wasserdispergierbarem Harz. |
US5349003A (en) * | 1988-09-20 | 1994-09-20 | Japan Synthetic Rubber Co., Ltd. | Aqueous fluorine-containing polymer dispersion and aqueous dispersion containing fluorine-containing polymer and water-soluble resin and/or water dispersible resin |
EP0748826B1 (en) * | 1993-09-22 | 2001-06-13 | Daikin Industries, Limited | Aqueous fluorocopolymer dispersion |
DE69500430T2 (de) * | 1994-04-01 | 1998-02-26 | Toagosei Co | Wässrige, fluorhaltige Anstrichzusammensetzung und Herstellungsverfahren |
EP0698644B1 (en) * | 1994-08-26 | 1997-07-23 | Nippon Carbide Kogyo Kabushiki Kaisha | Aqueous resin dispersion |
JP3298321B2 (ja) * | 1994-08-31 | 2002-07-02 | ダイキン工業株式会社 | ビニリデンフルオライド系共重合体水性分散液、ビニリデンフルオライド系シード重合体水性分散液およびそれらの製法 |
US5756573A (en) | 1995-10-05 | 1998-05-26 | Sc Johnson Commerical Markets, Inc. | Seed polymerized latex polymer having a gradient polymeric morphology and process for preparing the same |
US6680357B1 (en) * | 1999-07-14 | 2004-01-20 | Atofina Chemicals, Inc. | Crosslinkable aqueous fluoropolymer based dispersions |
DE10049791A1 (de) * | 2000-10-09 | 2002-04-18 | Basf Ag | Pigmenthaltige Beschichtungsmittel auf Wasserbasis |
US7081216B2 (en) * | 2001-02-15 | 2006-07-25 | Arkema Inc. | Foams and coatings |
JP4144020B2 (ja) * | 2001-10-23 | 2008-09-03 | 旭硝子株式会社 | フッ素樹脂粉体塗料用粉末及びそれを用いた塗料組成物 |
JP4103399B2 (ja) * | 2002-01-22 | 2008-06-18 | 旭硝子株式会社 | 含フッ素樹脂粉体塗料組成物および塗膜を有する物品 |
US7893157B2 (en) * | 2002-08-26 | 2011-02-22 | Rohm And Haas Company | Polymeric compositions having low glass transition temperatures |
-
2009
- 2009-06-18 WO PCT/US2009/047769 patent/WO2010005756A1/en active Application Filing
- 2009-06-18 CN CN200980126789.2A patent/CN102083876B/zh active Active
- 2009-06-18 KR KR1020117000296A patent/KR101717073B1/ko active IP Right Grant
- 2009-06-18 JP JP2011517454A patent/JP5698127B2/ja active Active
- 2009-06-18 EP EP09794948.1A patent/EP2297215B1/en active Active
- 2009-06-18 US US13/001,878 patent/US20110118403A1/en not_active Abandoned
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07258499A (ja) * | 1994-03-23 | 1995-10-09 | Japan Synthetic Rubber Co Ltd | 含フッ素重合体水性分散液 |
JP2003231722A (ja) * | 2002-02-13 | 2003-08-19 | Daikin Ind Ltd | フッ素樹脂水性分散組成物 |
WO2007030152A2 (en) * | 2005-05-19 | 2007-03-15 | Arkema Inc. | Highly weatherable roof coatings containing aqueous fluoropolymer dispersions |
JP2008540798A (ja) * | 2005-05-19 | 2008-11-20 | アーケマ・インコーポレイテッド | フッ素ポリマー分散体を含んだ高耐候性屋根用コーティング |
WO2007026949A1 (en) * | 2005-09-02 | 2007-03-08 | Nippon Shokubai Co., Ltd. | Emulsion type resin composition |
JP2009507082A (ja) * | 2005-09-02 | 2009-02-19 | 株式会社日本触媒 | エマルション型樹脂組成物 |
JP2007145977A (ja) * | 2005-11-28 | 2007-06-14 | Dainippon Ink & Chem Inc | 水性コーティング液及び機能性皮膜 |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015520256A (ja) * | 2012-04-17 | 2015-07-16 | アーケマ・インコーポレイテッド | 水性フルオロポリマーガラスコーティング |
JP2015520664A (ja) * | 2012-04-17 | 2015-07-23 | アーケマ・インコーポレイテッド | 水性フルロロポリマーコーティングを用いてガラス基材をコーティングするための方法 |
JP2014152186A (ja) * | 2013-02-05 | 2014-08-25 | Jsr Corp | 水性フッ素樹脂組成物 |
JP2017525835A (ja) * | 2014-07-01 | 2017-09-07 | アーケマ・インコーポレイテッド | 安定な水系フルオロポリマーコーティング組成物 |
JP2017052879A (ja) * | 2015-09-09 | 2017-03-16 | ダイキン工業株式会社 | 複合重合体粒子及びその製造方法 |
JP2020073708A (ja) * | 2015-09-09 | 2020-05-14 | ダイキン工業株式会社 | 複合重合体粒子及びその製造方法 |
JP7301010B2 (ja) | 2015-09-09 | 2023-06-30 | ダイキン工業株式会社 | 複合重合体粒子及びその製造方法 |
JP2019502766A (ja) * | 2015-11-25 | 2019-01-31 | アーケマ・インコーポレイテッド | 改良された機械的湿し性を有するフルオロポリマー組成物 |
JP7376365B2 (ja) | 2017-06-15 | 2023-11-08 | アルケマ フランス | 改良された接着性を有するフッ素化ポリマーをベースとするインク |
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