JP2011523422A5 - - Google Patents
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- Publication number
- JP2011523422A5 JP2011523422A5 JP2010542356A JP2010542356A JP2011523422A5 JP 2011523422 A5 JP2011523422 A5 JP 2011523422A5 JP 2010542356 A JP2010542356 A JP 2010542356A JP 2010542356 A JP2010542356 A JP 2010542356A JP 2011523422 A5 JP2011523422 A5 JP 2011523422A5
- Authority
- JP
- Japan
- Prior art keywords
- acid
- modifier
- poly
- copolymer
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003607 modifier Substances 0.000 claims description 61
- 239000000203 mixture Substances 0.000 claims description 50
- 239000002253 acid Substances 0.000 claims description 44
- 229920001577 copolymer Polymers 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 9
- 150000001718 carbodiimides Chemical class 0.000 claims description 8
- 229920000728 polyester Polymers 0.000 claims description 8
- WHBMMWSBFZVSSR-UHFFFAOYSA-N 3-hydroxybutyric acid Chemical compound CC(O)CC(O)=O WHBMMWSBFZVSSR-UHFFFAOYSA-N 0.000 claims description 6
- REKYPYSUBKSCAT-UHFFFAOYSA-N 3-hydroxypentanoic acid Chemical compound CCC(O)CC(O)=O REKYPYSUBKSCAT-UHFFFAOYSA-N 0.000 claims description 6
- ALRHLSYJTWAHJZ-UHFFFAOYSA-N 3-hydroxypropionic acid Chemical compound OCCC(O)=O ALRHLSYJTWAHJZ-UHFFFAOYSA-N 0.000 claims description 6
- FMHKPLXYWVCLME-UHFFFAOYSA-N 4-hydroxy-valeric acid Chemical compound CC(O)CCC(O)=O FMHKPLXYWVCLME-UHFFFAOYSA-N 0.000 claims description 6
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 6
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 229920001893 acrylonitrile styrene Polymers 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 claims description 6
- SJZRECIVHVDYJC-UHFFFAOYSA-N 4-hydroxybutyric acid Chemical compound OCCCC(O)=O SJZRECIVHVDYJC-UHFFFAOYSA-N 0.000 claims description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
- 239000005977 Ethylene Substances 0.000 claims description 5
- -1 diimide compound Chemical class 0.000 claims description 5
- 229920001038 ethylene copolymer Polymers 0.000 claims description 5
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- QOSSAOTZNIDXMA-UHFFFAOYSA-N Dicylcohexylcarbodiimide Chemical group C1CCCCC1N=C=NC1CCCCC1 QOSSAOTZNIDXMA-UHFFFAOYSA-N 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 4
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 229920006225 ethylene-methyl acrylate Polymers 0.000 claims description 4
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 229920006132 styrene block copolymer Polymers 0.000 claims description 4
- AFENDNXGAFYKQO-VKHMYHEASA-N (S)-2-hydroxybutyric acid Chemical compound CC[C@H](O)C(O)=O AFENDNXGAFYKQO-VKHMYHEASA-N 0.000 claims description 3
- 229940006015 4-hydroxybutyric acid Drugs 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- BDNKZNFMNDZQMI-UHFFFAOYSA-N 1,3-diisopropylcarbodiimide Chemical compound CC(C)N=C=NC(C)C BDNKZNFMNDZQMI-UHFFFAOYSA-N 0.000 claims description 2
- LMDZBCPBFSXMTL-UHFFFAOYSA-N 1-Ethyl-3-(3-dimethylaminopropyl)carbodiimide Substances CCN=C=NCCCN(C)C LMDZBCPBFSXMTL-UHFFFAOYSA-N 0.000 claims description 2
- KZDCPJDWDXMJRA-UHFFFAOYSA-N 2-hydroxybutanoic acid;pentanoic acid Chemical compound CCCCC(O)=O.CCC(O)C(O)=O KZDCPJDWDXMJRA-UHFFFAOYSA-N 0.000 claims description 2
- FPQQSJJWHUJYPU-UHFFFAOYSA-N 3-(dimethylamino)propyliminomethylidene-ethylazanium;chloride Chemical compound Cl.CCN=C=NCCCN(C)C FPQQSJJWHUJYPU-UHFFFAOYSA-N 0.000 claims description 2
- OXSSIXNFGTZQMZ-UHFFFAOYSA-N 3-hydroxyheptanoic acid Chemical compound CCCCC(O)CC(O)=O OXSSIXNFGTZQMZ-UHFFFAOYSA-N 0.000 claims description 2
- HPMGFDVTYHWBAG-UHFFFAOYSA-N 3-hydroxyhexanoic acid Chemical compound CCCC(O)CC(O)=O HPMGFDVTYHWBAG-UHFFFAOYSA-N 0.000 claims description 2
- IWHLYPDWHHPVAA-UHFFFAOYSA-N 6-hydroxyhexanoic acid Chemical compound OCCCCCC(O)=O IWHLYPDWHHPVAA-UHFFFAOYSA-N 0.000 claims description 2
- ABIKNKURIGPIRJ-UHFFFAOYSA-N DL-4-hydroxy caproic acid Chemical compound CCC(O)CCC(O)=O ABIKNKURIGPIRJ-UHFFFAOYSA-N 0.000 claims description 2
- 229920000954 Polyglycolide Polymers 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 239000002174 Styrene-butadiene Substances 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 2
- QYMGIIIPAFAFRX-UHFFFAOYSA-N butyl prop-2-enoate;ethene Chemical compound C=C.CCCCOC(=O)C=C QYMGIIIPAFAFRX-UHFFFAOYSA-N 0.000 claims description 2
- 239000011258 core-shell material Substances 0.000 claims description 2
- 229910000071 diazene Inorganic materials 0.000 claims description 2
- 150000001993 dienes Chemical class 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 claims description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 2
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 claims description 2
- 229920006226 ethylene-acrylic acid Polymers 0.000 claims description 2
- 229920006245 ethylene-butyl acrylate Polymers 0.000 claims description 2
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 claims description 2
- 230000007062 hydrolysis Effects 0.000 claims description 2
- 238000006460 hydrolysis reaction Methods 0.000 claims description 2
- 238000001746 injection moulding Methods 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- CMESPBFFDMPSIY-UHFFFAOYSA-N n,n'-diphenylmethanediimine Chemical compound C1=CC=CC=C1N=C=NC1=CC=CC=C1 CMESPBFFDMPSIY-UHFFFAOYSA-N 0.000 claims description 2
- 238000004806 packaging method and process Methods 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229920006124 polyolefin elastomer Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 239000005060 rubber Substances 0.000 claims description 2
- 239000011115 styrene butadiene Substances 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 238000003856 thermoforming Methods 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims 2
- 238000012986 modification Methods 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 229940005605 valeric acid Drugs 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- JRHWHSJDIILJAT-UHFFFAOYSA-N 2-hydroxypentanoic acid Chemical compound CCCC(O)C(O)=O JRHWHSJDIILJAT-UHFFFAOYSA-N 0.000 description 1
- PHOJOSOUIAQEDH-UHFFFAOYSA-N 5-hydroxypentanoic acid Chemical compound OCCCCC(O)=O PHOJOSOUIAQEDH-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2001808P | 2008-01-09 | 2008-01-09 | |
| US61/020,018 | 2008-01-09 | ||
| PCT/US2009/030511 WO2009089398A1 (en) | 2008-01-09 | 2009-01-09 | Polyester composition resistant to hydrolysis |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2011523422A JP2011523422A (ja) | 2011-08-11 |
| JP2011523422A5 true JP2011523422A5 (enExample) | 2012-02-23 |
Family
ID=40380025
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010542356A Pending JP2011523422A (ja) | 2008-01-09 | 2009-01-09 | 加水分解抵抗性ポリエステル組成物 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20090176938A1 (enExample) |
| EP (1) | EP2229419A1 (enExample) |
| JP (1) | JP2011523422A (enExample) |
| KR (1) | KR20100112610A (enExample) |
| CN (1) | CN102131868A (enExample) |
| AU (1) | AU2009204056A1 (enExample) |
| WO (1) | WO2009089398A1 (enExample) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100071170A1 (en) * | 2007-12-19 | 2010-03-25 | Burout Charles J | Fastening assembly fabricated from a sustainable material and related method |
| WO2010012688A1 (de) * | 2008-08-01 | 2010-02-04 | Basf Se | Erhöhung der hydrolysebeständigkeit von biologisch abbaubaren polyestern |
| WO2011160053A2 (en) * | 2010-06-18 | 2011-12-22 | Metabolix, Inc. | Melt stable polyesters |
| EP2418250A1 (de) * | 2010-08-11 | 2012-02-15 | Rhein Chemie Rheinau GmbH | Langlebige biobasierte Kunststoffe auf Basis von Polyhydroxyalkanoat, ein Verfahren zu deren Herstellung und deren Verwendung |
| CA2863100C (en) | 2012-02-17 | 2020-07-07 | Andersen Corporation | Polylactic acid containing building component |
| US8754171B2 (en) | 2012-05-10 | 2014-06-17 | E I Du Pont De Nemours And Company | Polyester composition |
| TWI445755B (zh) * | 2012-06-27 | 2014-07-21 | Ind Tech Res Inst | 阻燃性熱可塑性澱粉材料、生質複材及其製備方法 |
| JPWO2014034636A1 (ja) * | 2012-08-27 | 2016-08-08 | ユニチカ株式会社 | ポリ乳酸系樹脂組成物およびそれを成形してなる成形体 |
| EP2980157A4 (en) * | 2013-03-25 | 2016-11-30 | Teijin Ltd | Resin composition |
| KR101632101B1 (ko) * | 2013-06-19 | 2016-06-20 | 주식회사 엘지화학 | 열가소성 폴리에스테르 엘라스토머 수지 조성물 및 이를 포함하는 성형품 |
| CN105579637B (zh) | 2013-09-30 | 2018-04-10 | 3M创新有限公司 | 具有设置于其上的环氧化脂肪酸酯的纤维和擦拭物以及方法 |
| US9982128B2 (en) | 2013-09-30 | 2018-05-29 | 3M Innovative Properties Company | Fibers, wipes, and methods |
| CN104559120B (zh) * | 2015-02-04 | 2017-01-04 | 绵阳市盛宇新材料有限公司 | 一种可降解聚合物复合材料及其制备方法 |
| EP3241865A1 (en) * | 2016-05-04 | 2017-11-08 | Clariant Plastics & Coatings Ltd | Composition for polyester hydrolytic stabilization |
| EP3241866A1 (en) * | 2016-05-04 | 2017-11-08 | Clariant Plastics & Coatings Ltd | Composition for polyester hydrolytic stabilization |
| US11414579B2 (en) * | 2017-06-09 | 2022-08-16 | Toyobo Co., Ltd. | Sealing resin composition |
| FR3073851B1 (fr) | 2017-11-17 | 2019-11-08 | Arkema France | Film imper-respirant souple et etirable a base de copolymere a blocs |
| FR3073848B1 (fr) | 2017-11-17 | 2020-11-13 | Arkema France | Copolymere a blocs presentant des resistances ameliorees a l'abrasion et a la dechirure |
| FR3073852B1 (fr) | 2017-11-17 | 2019-10-11 | Arkema France | Mousse de copolymere a blocs |
| FR3073867B1 (fr) | 2017-11-17 | 2019-11-08 | Arkema France | Materiau textile souple etirable et anti-bouloches a base de copolymere a blocs |
| CN108303348B (zh) * | 2017-12-20 | 2020-07-14 | 中国石油化工股份有限公司 | 聚合物在油藏孔喉中拉伸降解特性模拟装置及系统 |
| KR102519456B1 (ko) | 2018-03-15 | 2023-04-06 | 주식회사 엘지화학 | 미생물을 이용한 폴리(3-하이드록시프로피오네이트-b-락테이트) 블록공중합체 |
| CN108559238B (zh) * | 2018-05-02 | 2020-11-13 | 张家港绿洲新材料科技有限公司 | 一种生物基可降解的聚羟基羧酸合金材料及其制备方法和应用 |
| CN108641265A (zh) * | 2018-05-24 | 2018-10-12 | 中北大学 | 弹性体接枝共聚物改性废旧hips/pp复合材料及制备方法 |
| CN109593247A (zh) * | 2018-11-02 | 2019-04-09 | 浙江耀隆塑业有限公司 | 一种适用于道路设施的热塑性弹性体及其制备方法 |
| CN111876058B (zh) * | 2020-07-17 | 2022-02-18 | 擎天材料科技有限公司 | 一种Primid体系低温固化超耐候粉末涂料用聚酯树脂及其制备方法 |
| CN115960447A (zh) * | 2022-12-30 | 2023-04-14 | 中广核高新核材科技（苏州）有限公司 | 一种高韧结晶耐热生物降解吸管料及其制备方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL272088A (enExample) * | 1960-12-02 | |||
| US4965302A (en) * | 1988-03-29 | 1990-10-23 | Mitsubishi Kasei Corporation | Thermoplastic polyester resin composition and molded articles produced therefrom |
| US5302694A (en) * | 1990-02-21 | 1994-04-12 | Boehringer Ingelheim Gmbh | Process for preparing polyesters based on hydroxycarboxylic acids |
| US5973024A (en) * | 1997-07-09 | 1999-10-26 | Nisshinbo Industries, Inc. | Method for control of biodegradation rate of biodegradable plastic |
| JP4703402B2 (ja) * | 2003-06-27 | 2011-06-15 | ユニチカ株式会社 | 脂肪族ポリエステル樹脂組成物、その製造方法、前記樹脂組成物からなる成形体及び発泡体 |
| RU2312871C2 (ru) * | 2003-08-12 | 2007-12-20 | Мицуи Кемикалз, Инк. | Смола на основе сложного полиэфира и формованный продукт из ламината на основе смолы из сложного полиэфира |
| JP4512381B2 (ja) * | 2004-02-12 | 2010-07-28 | 日清紡ホールディングス株式会社 | 生分解性プラスチックを含む繊維製品 |
| JP4983079B2 (ja) * | 2005-04-20 | 2012-07-25 | 東レ株式会社 | 樹脂組成物およびそれからなる成形品 |
| TWI432517B (zh) * | 2005-07-08 | 2014-04-01 | Toray Industries | 樹脂組成物及其成形品 |
| JP5245229B2 (ja) * | 2005-09-30 | 2013-07-24 | 東レ株式会社 | 樹脂組成物およびそれからなる成形品 |
| JP2007131795A (ja) * | 2005-11-14 | 2007-05-31 | Mitsui Chemicals Inc | 乳酸系ポリマー組成物 |
| CN101326218A (zh) * | 2005-12-26 | 2008-12-17 | 日清纺织株式会社 | 聚烯烃·聚酯系薄膜 |
| EP1975195A4 (en) * | 2006-01-19 | 2009-04-08 | Asahi Kasei Chemicals Corp | FOAM |
| JP2007284495A (ja) * | 2006-04-13 | 2007-11-01 | Sharp Corp | 熱可塑性樹脂の再資源化方法、ならびに熱可塑性樹脂原料、熱可塑性樹脂部材およびそれらの製造方法 |
| JP2007326940A (ja) * | 2006-06-07 | 2007-12-20 | Sharp Corp | 熱可塑性樹脂組成物、熱可塑性樹脂成形体および熱可塑性樹脂成形体の製造方法、ならびに熱可塑性樹脂の再資源化方法 |
-
2009
- 2009-01-09 CN CN2009801019318A patent/CN102131868A/zh active Pending
- 2009-01-09 EP EP09701276A patent/EP2229419A1/en not_active Withdrawn
- 2009-01-09 KR KR1020107017500A patent/KR20100112610A/ko not_active Ceased
- 2009-01-09 AU AU2009204056A patent/AU2009204056A1/en not_active Abandoned
- 2009-01-09 WO PCT/US2009/030511 patent/WO2009089398A1/en not_active Ceased
- 2009-01-09 JP JP2010542356A patent/JP2011523422A/ja active Pending
- 2009-01-09 US US12/351,388 patent/US20090176938A1/en not_active Abandoned
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