JP2011522772A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2011522772A5 JP2011522772A5 JP2010535049A JP2010535049A JP2011522772A5 JP 2011522772 A5 JP2011522772 A5 JP 2011522772A5 JP 2010535049 A JP2010535049 A JP 2010535049A JP 2010535049 A JP2010535049 A JP 2010535049A JP 2011522772 A5 JP2011522772 A5 JP 2011522772A5
- Authority
- JP
- Japan
- Prior art keywords
- metal
- hydrofluoroalkoxide
- group
- reactive metal
- aldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 claims description 46
- 229910052751 metal Inorganic materials 0.000 claims description 42
- 239000002184 metal Substances 0.000 claims description 42
- 239000007810 chemical reaction solvent Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 8
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 claims description 7
- 239000007795 chemical reaction product Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 230000003472 neutralizing effect Effects 0.000 claims description 3
- 150000004703 alkoxides Chemical class 0.000 claims description 2
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 229910052714 tellurium Inorganic materials 0.000 claims description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 150000001299 aldehydes Chemical class 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 8
- 229910052749 magnesium Inorganic materials 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- -1 perfluoro-n-propyl Chemical group 0.000 description 8
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical group O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- AMIMRNSIRUDHCM-UHFFFAOYSA-N Isopropylaldehyde Chemical compound CC(C)C=O AMIMRNSIRUDHCM-UHFFFAOYSA-N 0.000 description 4
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 229910052738 indium Inorganic materials 0.000 description 4
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Chemical class 0.000 description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 150000003751 zinc Chemical class 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical class CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical group 0.000 description 3
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 3
- PAMIQIKDUOTOBW-UHFFFAOYSA-N 1-methylpiperidine Chemical compound CN1CCCCC1 PAMIQIKDUOTOBW-UHFFFAOYSA-N 0.000 description 2
- JPSKCQCQZUGWNM-UHFFFAOYSA-N 2,7-Oxepanedione Chemical compound O=C1CCCCC(=O)O1 JPSKCQCQZUGWNM-UHFFFAOYSA-N 0.000 description 2
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical class C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 2
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical group [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 2
- YHASWHZGWUONAO-UHFFFAOYSA-N butanoyl butanoate Chemical compound CCCC(=O)OC(=O)CCC YHASWHZGWUONAO-UHFFFAOYSA-N 0.000 description 2
- 239000012024 dehydrating agents Substances 0.000 description 2
- VGGRCVDNFAQIKO-UHFFFAOYSA-N formic anhydride Chemical compound O=COC=O VGGRCVDNFAQIKO-UHFFFAOYSA-N 0.000 description 2
- VANNPISTIUFMLH-UHFFFAOYSA-N glutaric anhydride Chemical compound O=C1CCCC(=O)O1 VANNPISTIUFMLH-UHFFFAOYSA-N 0.000 description 2
- 230000002140 halogenating effect Effects 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 125000005004 perfluoroethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- WYVAMUWZEOHJOQ-UHFFFAOYSA-N propionic anhydride Chemical compound CCC(=O)OC(=O)CC WYVAMUWZEOHJOQ-UHFFFAOYSA-N 0.000 description 2
- 150000003222 pyridines Chemical class 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 229940014800 succinic anhydride Drugs 0.000 description 2
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 2
- 239000004246 zinc acetate Substances 0.000 description 2
- AVFZOVWCLRSYKC-UHFFFAOYSA-N 1-methylpyrrolidine Chemical compound CN1CCCC1 AVFZOVWCLRSYKC-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- AHVYPIQETPWLSZ-UHFFFAOYSA-N N-methyl-pyrrolidine Natural products CN1CC=CC1 AHVYPIQETPWLSZ-UHFFFAOYSA-N 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Chemical class C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical class C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| UA2007012916 | 2007-11-20 | ||
| UAA200712916 | 2007-11-20 | ||
| US10433408P | 2008-10-10 | 2008-10-10 | |
| UA2008012034 | 2008-10-10 | ||
| UAA200812034 | 2008-10-10 | ||
| US61/104,334 | 2008-10-10 | ||
| PCT/US2008/084107 WO2009067571A1 (en) | 2007-11-20 | 2008-11-20 | Synthesis of hydrofluoroalkanols and hydrofluoroalkenes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2011522772A JP2011522772A (ja) | 2011-08-04 |
| JP2011522772A5 true JP2011522772A5 (enExample) | 2012-01-12 |
Family
ID=40114060
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010535049A Abandoned JP2011522772A (ja) | 2007-11-20 | 2008-11-20 | ヒドロフルオロアルカノールおよびヒドロフルオロアルケンの合成 |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP2215097A1 (enExample) |
| JP (1) | JP2011522772A (enExample) |
| KR (1) | KR20100099182A (enExample) |
| CN (1) | CN101861322B (enExample) |
| BR (1) | BRPI0818958A2 (enExample) |
| RU (1) | RU2010125261A (enExample) |
| WO (1) | WO2009067571A1 (enExample) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102177118A (zh) | 2008-10-10 | 2011-09-07 | 纳幕尔杜邦公司 | 包含2,3,3,3-四氟丙烯、2-氯-2,3,3,3-四氟丙醇、乙酸2-氯-2,3,3,3-四氟丙酯或(2-氯-2,3,3,3-四氟丙氧基)氯化锌的组合物 |
| EP2349961B1 (en) | 2008-10-13 | 2016-11-23 | Blue Cube IP LLC | Process for the production of chlorinated and/or fluorinated propenes |
| CN101851146B (zh) * | 2009-04-02 | 2013-09-25 | 中化蓝天集团有限公司 | 一种制备三氟乙烯的方法 |
| WO2011044447A2 (en) | 2009-10-09 | 2011-04-14 | Dow Global Technologies, Inc | Process for the production of chlorinated and/or fluorinated propenes |
| KR20120091192A (ko) | 2009-10-09 | 2012-08-17 | 다우 글로벌 테크놀로지스 엘엘씨 | 등온 다중튜브 반응기 및 이를 도입한 방법 |
| EP2485997B1 (en) | 2009-10-09 | 2015-09-09 | Dow Global Technologies LLC | Process for the production of chlorinated and/or fluorinated propenes and higher alkenes |
| RU2009149445A (ru) * | 2009-12-29 | 2011-07-10 | Е.И.Дюпон де Немур энд Компани (US) | Синтез фторированных олефинов из фторированных спиртов |
| JP5881725B2 (ja) | 2010-11-25 | 2016-03-09 | アルケマ フランス | クロロトリフルオロプロペンとヘキサフルオロブテンとの組成物 |
| JP6212035B2 (ja) | 2011-05-31 | 2017-10-11 | ブルー キューブ アイピー エルエルシー | 塩素化プロペンの製造方法 |
| CN103562163B (zh) | 2011-05-31 | 2015-12-23 | 陶氏环球技术有限责任公司 | 生产氯化丙烯类的方法 |
| ES2721451T3 (es) | 2011-06-08 | 2019-07-31 | Dow Agrosciences Llc | Procedimiento para la producción de propenos clorados y/o fluorados |
| CN103717559A (zh) | 2011-08-07 | 2014-04-09 | 陶氏环球技术有限责任公司 | 生产氯化的丙烯的方法 |
| CN109438173A (zh) | 2011-08-07 | 2019-03-08 | 蓝立方知识产权有限责任公司 | 生产氯化的丙烯的方法 |
| CN102351651A (zh) * | 2011-08-25 | 2012-02-15 | 西安近代化学研究所 | 3,3,3-三氟丙醇的制备方法 |
| CN104039744B (zh) | 2011-11-21 | 2016-04-20 | 陶氏环球技术有限责任公司 | 制备氯化烷烃的方法 |
| EP2785670B1 (en) | 2011-12-02 | 2017-10-25 | Blue Cube IP LLC | Process for the production of chlorinated alkanes |
| US9284239B2 (en) | 2011-12-02 | 2016-03-15 | Blue Cube Ip Llc | Process for the production of chlorinated alkanes |
| JP6170068B2 (ja) | 2011-12-13 | 2017-07-26 | ブルー キューブ アイピー エルエルシー | 塩素化プロパン及びプロペンの製造方法 |
| IN2014CN04418A (enExample) | 2011-12-22 | 2015-09-04 | Dow Global Technologies Llc | |
| WO2013096706A1 (en) | 2011-12-23 | 2013-06-27 | Dow Global Technologies, Llc | Process for the production of alkenes and/or aromatic compounds |
| FR2989084B1 (fr) * | 2012-04-04 | 2015-04-10 | Arkema France | Compositions a base de 2,3,3,4,4,4-hexafluorobut-1-ene |
| WO2014046970A1 (en) | 2012-09-20 | 2014-03-27 | Dow Global Technologies, Llc | Process for the production of chlorinated propenes |
| US9598334B2 (en) | 2012-09-20 | 2017-03-21 | Blue Cube Ip Llc | Process for the production of chlorinated propenes |
| CN104718020A (zh) | 2012-09-30 | 2015-06-17 | 陶氏环球技术有限公司 | 堰式骤冷器和并入所述堰式骤冷器的工艺 |
| WO2014066083A1 (en) | 2012-10-26 | 2014-05-01 | Dow Global Technologies, Llc | Mixer and reactor and process incorporating the same |
| JP6247311B2 (ja) | 2012-12-18 | 2017-12-13 | ブルー キューブ アイピー エルエルシー | 塩素化プロペンを生成するための方法 |
| CA2894168C (en) | 2012-12-19 | 2018-04-24 | Dow Global Technologies Llc | Process for the production of chlorinated propenes |
| EP2961722A2 (en) | 2013-02-27 | 2016-01-06 | Blue Cube IP LLC | Process for the production of chlorinated propenes |
| EP2966141A4 (en) * | 2013-03-06 | 2017-01-25 | Unimatec Co., Ltd. | Fluorine-containing calcium composite particles, preparation method therefor, and surface treatment agent using same as active component |
| EP2964597B1 (en) | 2013-03-09 | 2017-10-04 | Blue Cube IP LLC | Process for the production of chlorinated alkanes |
| MY178665A (en) * | 2014-02-20 | 2020-10-20 | Asahi Glass Co Ltd | Composition for heat cycle system, and heat cycle system |
| WO2015125874A1 (ja) * | 2014-02-20 | 2015-08-27 | 旭硝子株式会社 | 熱サイクル用作動媒体 |
| CN106255736B (zh) * | 2014-03-17 | 2019-11-26 | Ａｇｃ株式会社 | 热循环用工作介质、热循环系统用组合物以及热循环系统 |
| KR101892880B1 (ko) * | 2014-10-16 | 2018-08-28 | 미쓰비시덴키 가부시키가이샤 | 냉동 사이클 장치 |
| AU2014408863B2 (en) * | 2014-10-16 | 2019-01-03 | Mitsubishi Electric Corporation | Refrigeration cycle apparatus |
| CN105037401B (zh) * | 2015-07-23 | 2018-12-14 | 暨南大学 | 一种格氏反应用镁屑的处理方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1496633A (fr) * | 1966-02-07 | 1967-09-29 | Ici Ltd | Procédé de fabrication de composés organiques fluorés oxygénés |
| US7951982B2 (en) * | 2004-04-29 | 2011-05-31 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| US7026520B1 (en) * | 2004-12-09 | 2006-04-11 | Honeywell International Inc. | Catalytic conversion of hydrofluoroalkanol to hydrofluoroalkene |
-
2008
- 2008-11-20 CN CN2008801165517A patent/CN101861322B/zh not_active Expired - Fee Related
- 2008-11-20 KR KR1020107013445A patent/KR20100099182A/ko not_active Withdrawn
- 2008-11-20 BR BRPI0818958A patent/BRPI0818958A2/pt not_active IP Right Cessation
- 2008-11-20 RU RU2010125261/04A patent/RU2010125261A/ru not_active Application Discontinuation
- 2008-11-20 WO PCT/US2008/084107 patent/WO2009067571A1/en not_active Ceased
- 2008-11-20 JP JP2010535049A patent/JP2011522772A/ja not_active Abandoned
- 2008-11-20 EP EP08851477A patent/EP2215097A1/en not_active Withdrawn
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2011522772A5 (enExample) | ||
| RU2010125261A (ru) | Синтез гидрофторалканолов и гидрофторалкенов | |
| Dhungana et al. | Transition metal‐catalyzed dicarbofunctionalization of unactivated olefins | |
| CN103691451B (zh) | 一种气相甲醇羰基化合成甲酸甲酯的催化剂及其制备方法和应用 | |
| WO2013125020A1 (ja) | 脱水素用触媒、該触媒を用いたカルボニル化合物および水素の製造方法 | |
| KR101459599B1 (ko) | 신규한 Ｃｕ-ＭＯＦ 화합물, 이를 포함하는 선택적 ＣＯ2 흡착체 및 불균일 에스터 교환 반응 촉매 | |
| TW201035008A (en) | Method of hydrodechlorination to produce dihydrofluorinated olefins | |
| JP2011528687A5 (enExample) | ||
| JP6474794B2 (ja) | アルカン酸アルキルの気相生成 | |
| JP2008517865A (ja) | 合成ガス及び水素リッチなガス混合物の調製への、ナノ構造の金属触媒の使用 | |
| TW201238937A (en) | Selective catalytic dehydrochlorination of hydrochlorofluorocarbons | |
| JPWO2013125020A1 (ja) | 脱水素用触媒、該触媒を用いたカルボニル化合物および水素の製造方法 | |
| JP2017047377A (ja) | 固体触媒、及びアルデヒド類の製造方法 | |
| JP2011503018A5 (enExample) | ||
| JP5305279B2 (ja) | 多孔性金属錯体及びその製造方法 | |
| CN109195937A (zh) | 通过有机/无机催化剂由乙醇和乙醛在含水介质中产生乙酸和氢气 | |
| CN111808023B (zh) | 一种制备3-芳基异喹啉衍生物的方法 | |
| JP2010194517A (ja) | アンモニア分解触媒 | |
| JP2010194518A (ja) | アンモニア分解触媒 | |
| JP6871802B2 (ja) | 不均一系パラジウム触媒存在下でアルデヒドを一酸化炭素源として用いるハロゲン化合物のカルボニル化反応によりカルボニル化合物を得る方法 | |
| JP6553093B2 (ja) | エチレンのジクロロエタンへのオキシ塩素化のための触媒及び方法 | |
| JP2010194519A (ja) | アンモニア分解触媒 | |
| CN102941121A (zh) | 一种用于芳基烷烃氧化反应的催化体系及其应用 | |
| WO2010098245A1 (ja) | アンモニア分解触媒 | |
| CN102050711A (zh) | 一种丙烯醛的制备方法 |