JP2011518930A - ガス化プロセスに由来するガス中のタール含有量を減少させるための貴金属系触媒の使用 - Google Patents

ガス化プロセスに由来するガス中のタール含有量を減少させるための貴金属系触媒の使用 Download PDF

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Publication number
JP2011518930A
JP2011518930A JP2011506645A JP2011506645A JP2011518930A JP 2011518930 A JP2011518930 A JP 2011518930A JP 2011506645 A JP2011506645 A JP 2011506645A JP 2011506645 A JP2011506645 A JP 2011506645A JP 2011518930 A JP2011518930 A JP 2011518930A
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Prior art keywords
catalyst
noble metal
gas
tar
gasification
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JP2011506645A
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Japanese (ja)
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JP2011518930A5 (enExample
Inventor
アンファング，ゲオルグ
モードゥル，ノルベート
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ズュート‐ヒェミー アクチェンゲゼルシャフト
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Publication of JP2011518930A5 publication Critical patent/JP2011518930A5/ja
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892—Nickel and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0242—Coating followed by impregnation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/34—Purifying combustible gases containing carbon monoxide by catalytic conversion of impurities to more readily removable materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/023—Reducing the tar content
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Industrial Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2011506645A 2008-04-28 2009-04-15 ガス化プロセスに由来するガス中のタール含有量を減少させるための貴金属系触媒の使用 Pending JP2011518930A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102008021084.6 2008-04-28
DE102008021084A DE102008021084A1 (de) 2008-04-28 2008-04-28 Verwendung eines Katalysators auf Edelmetallbasis zur Verringerung des Teergehalts in Gasen aus Vergasungsprozessen
PCT/EP2009/054429 WO2009132959A2 (de) 2008-04-28 2009-04-15 Verwendung eines katalysators auf edelmetallbasis zur verringerung des teergehalts in gasen aus vergasungsprozessen

Publications (2)

Publication Number Publication Date
JP2011518930A true JP2011518930A (ja) 2011-06-30
JP2011518930A5 JP2011518930A5 (enExample) 2013-08-01

Family

ID=41111855

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2011506645A Pending JP2011518930A (ja) 2008-04-28 2009-04-15 ガス化プロセスに由来するガス中のタール含有量を減少させるための貴金属系触媒の使用

Country Status (5)

Country Link
US (1) US20110101278A1 (enExample)
EP (1) EP2274094B1 (enExample)
JP (1) JP2011518930A (enExample)
DE (1) DE102008021084A1 (enExample)
WO (1) WO2009132959A2 (enExample)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010007588A1 (de) * 2010-02-05 2011-08-11 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V., 80686 Herstellungsverfahren für ein Synthesegas aus einer Biomasse
FI123686B (fi) 2010-03-03 2013-09-30 Neste Oil Oyj Menetelmä kaasutuskaasun reformoimiseksi
DE102011105353A1 (de) 2011-06-22 2012-12-27 Süd-Chemie AG Multifunktionaler Katalysator zur simultanen Entfernung/Umwandlung von teerartigen und schwefelhaltigen Kohlenwasserstoffen
DE102012111900A1 (de) 2012-12-06 2014-06-26 Krones Ag Vorrichtung und Verfahren zum Cracken von Gasen

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005112956A (ja) * 2003-10-06 2005-04-28 Nippon Steel Corp バイオマスのガス化方法
JP2007506856A (ja) * 2004-08-05 2007-03-22 コリア インスティテュート オブ エナジー リサーチ バイオマス精製燃料の低温触媒ガス化装置および方法
WO2007075476A2 (en) * 2005-12-21 2007-07-05 Virent Energy Systems Inc. Catalysts and methods for reforming oxygenated compounds
WO2007116121A1 (en) * 2006-04-10 2007-10-18 Valtion Teknillinen Tutkimuskeskus Multiple stage method of reforming a gas containing tarry impurities employing a zirconium-based catalyst

Family Cites Families (5)

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Publication number Priority date Publication date Assignee Title
US7449424B2 (en) * 2004-05-14 2008-11-11 Gas Technology Institute Method for producing catalytically-active materials
DE102004024672B4 (de) 2004-05-18 2007-06-14 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Vorrichtung und Verfahren zur Erzeugung eines teerfreien Schwachgases durch Vergasung von Biomasse
US7704486B2 (en) * 2005-02-16 2010-04-27 Basf Corporation Precious metal water-gas shift catalyst with oxide support modified with rare earth elements
US7915196B2 (en) * 2005-10-07 2011-03-29 Alliance For Sustainable Energy, Llc Attrition resistant fluidizable reforming catalyst
DE102008021081A1 (de) * 2008-04-28 2009-10-29 Süd-Chemie AG Verfahren zur katalytischen Verringerung des Teergehalts in Gasen aus Vergasungsprozessen unter Verwendung eines Katalysators auf Edelmetallbasis

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005112956A (ja) * 2003-10-06 2005-04-28 Nippon Steel Corp バイオマスのガス化方法
JP2007506856A (ja) * 2004-08-05 2007-03-22 コリア インスティテュート オブ エナジー リサーチ バイオマス精製燃料の低温触媒ガス化装置および方法
WO2007075476A2 (en) * 2005-12-21 2007-07-05 Virent Energy Systems Inc. Catalysts and methods for reforming oxygenated compounds
WO2007116121A1 (en) * 2006-04-10 2007-10-18 Valtion Teknillinen Tutkimuskeskus Multiple stage method of reforming a gas containing tarry impurities employing a zirconium-based catalyst

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
K TOMISHIGE: "CATALYST PERFORMANCE IN REFORMING OF TAR DERIVED FROM BIOMASS OVER NOBLE METAL CATALYSTS", GREEN CHEMISTRY, vol. V5, JPN5011002859, 2003, pages 399 - 403, ISSN: 0002452761 *
M A GERBER: "REVIEW OF NOVEL CATALYSTS FOR BIOMASS TAR CRACKING AND METHANE REFORMING", PACIFIC NORTHWEST NATIONAL LABORATORY [ONLINE], JPN5011002858, October 2007 (2007-10-01), ISSN: 0002452760 *

Also Published As

Publication number Publication date
WO2009132959A3 (de) 2010-08-05
WO2009132959A2 (de) 2009-11-05
DE102008021084A1 (de) 2009-10-29
EP2274094B1 (de) 2018-10-03
US20110101278A1 (en) 2011-05-05
EP2274094A2 (de) 2011-01-19

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