JP2011510161A - アイオノマーと有機酸塩との組み合わせによって変性されたポリエステル - Google Patents
アイオノマーと有機酸塩との組み合わせによって変性されたポリエステル Download PDFInfo
- Publication number
- JP2011510161A JP2011510161A JP2010544392A JP2010544392A JP2011510161A JP 2011510161 A JP2011510161 A JP 2011510161A JP 2010544392 A JP2010544392 A JP 2010544392A JP 2010544392 A JP2010544392 A JP 2010544392A JP 2011510161 A JP2011510161 A JP 2011510161A
- Authority
- JP
- Japan
- Prior art keywords
- ethylene
- acid
- composition
- weight
- modifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000554 ionomer Polymers 0.000 title claims abstract description 53
- 229920000728 polyester Polymers 0.000 title claims description 47
- -1 organic acid salt Chemical class 0.000 title claims description 32
- 239000000203 mixture Substances 0.000 claims abstract description 116
- 229920001577 copolymer Polymers 0.000 claims abstract description 92
- 239000005977 Ethylene Substances 0.000 claims abstract description 87
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 65
- 239000002253 acid Substances 0.000 claims abstract description 65
- 150000007524 organic acids Chemical class 0.000 claims abstract description 47
- 239000003607 modifier Substances 0.000 claims abstract description 34
- 239000011777 magnesium Substances 0.000 claims abstract description 18
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 17
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 14
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 13
- 229920002215 polytrimethylene terephthalate Polymers 0.000 claims abstract description 11
- 239000011701 zinc Substances 0.000 claims abstract description 11
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 8
- 239000011575 calcium Substances 0.000 claims abstract description 8
- 150000001768 cations Chemical class 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 29
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 28
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 23
- 239000000155 melt Substances 0.000 claims description 22
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 20
- 239000011734 sodium Substances 0.000 claims description 18
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 16
- 229910052708 sodium Inorganic materials 0.000 claims description 16
- 229920001897 terpolymer Polymers 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 150000003839 salts Chemical class 0.000 claims description 15
- 150000002148 esters Chemical class 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 11
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 8
- 239000002667 nucleating agent Substances 0.000 claims description 7
- 229920000874 polytetramethylene terephthalate Polymers 0.000 claims description 7
- 159000000000 sodium salts Chemical class 0.000 claims description 7
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 3
- 125000005907 alkyl ester group Chemical group 0.000 claims description 2
- CGPRUXZTHGTMKW-UHFFFAOYSA-N ethene;ethyl prop-2-enoate Chemical compound C=C.CCOC(=O)C=C CGPRUXZTHGTMKW-UHFFFAOYSA-N 0.000 claims description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 2
- CJHKOVODOPEDJZ-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid;sodium Chemical compound [Na].C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 CJHKOVODOPEDJZ-UHFFFAOYSA-N 0.000 claims description 2
- GJTNGKDEAATFNA-UHFFFAOYSA-M sodium;benzene-1,3-dicarboxylate;hydron Chemical compound [Na+].OC(=O)C1=CC=CC(C([O-])=O)=C1 GJTNGKDEAATFNA-UHFFFAOYSA-M 0.000 claims description 2
- VIQSRHWJEKERKR-UHFFFAOYSA-L disodium;terephthalate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=C(C([O-])=O)C=C1 VIQSRHWJEKERKR-UHFFFAOYSA-L 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 33
- 238000002425 crystallisation Methods 0.000 description 17
- 230000008025 crystallization Effects 0.000 description 17
- 238000002156 mixing Methods 0.000 description 17
- 235000005985 organic acids Nutrition 0.000 description 17
- 239000008188 pellet Substances 0.000 description 17
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 13
- 150000007514 bases Chemical class 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 9
- 239000000654 additive Substances 0.000 description 9
- 238000001125 extrusion Methods 0.000 description 9
- 238000001746 injection moulding Methods 0.000 description 9
- 238000006386 neutralization reaction Methods 0.000 description 9
- 229920000058 polyacrylate Polymers 0.000 description 9
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 8
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 8
- 229920001519 homopolymer Polymers 0.000 description 8
- 238000005482 strain hardening Methods 0.000 description 8
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 7
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 7
- 239000001993 wax Substances 0.000 description 7
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 6
- 229920000800 acrylic rubber Polymers 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 230000003078 antioxidant effect Effects 0.000 description 5
- 238000000113 differential scanning calorimetry Methods 0.000 description 5
- 229920006228 ethylene acrylate copolymer Polymers 0.000 description 5
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 238000003856 thermoforming Methods 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- NMYFVWYGKGVPIW-UHFFFAOYSA-N 3,7-dioxabicyclo[7.2.2]trideca-1(11),9,12-triene-2,8-dione Chemical group O=C1OCCCOC(=O)C2=CC=C1C=C2 NMYFVWYGKGVPIW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- 235000021357 Behenic acid Nutrition 0.000 description 3
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 229940116226 behenic acid Drugs 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 3
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 101150015886 nuc-1 gene Proteins 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 150000002924 oxiranes Chemical class 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- DJYPJBAHKUBLSS-UHFFFAOYSA-M sodium;hydron;terephthalate Chemical compound [Na+].OC(=O)C1=CC=C(C([O-])=O)C=C1 DJYPJBAHKUBLSS-UHFFFAOYSA-M 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- 229920013627 Sorona Polymers 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000004703 alkoxides Chemical class 0.000 description 2
- 235000013361 beverage Nutrition 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 235000019359 magnesium stearate Nutrition 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 238000000518 rheometry Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 2
- CVYDEWKUJFCYJO-UHFFFAOYSA-M sodium;docosanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O CVYDEWKUJFCYJO-UHFFFAOYSA-M 0.000 description 2
- YKIBJOMJPMLJTB-UHFFFAOYSA-M sodium;octacosanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O YKIBJOMJPMLJTB-UHFFFAOYSA-M 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 239000012745 toughening agent Substances 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- QXJSBBXBKPUZAA-CMDGGOBGSA-N (e)-octadec-10-enoic acid Chemical compound CCCCCCC\C=C\CCCCCCCCC(O)=O QXJSBBXBKPUZAA-CMDGGOBGSA-N 0.000 description 1
- RGASRBUYZODJTG-UHFFFAOYSA-N 1,1-bis(2,4-ditert-butylphenyl)-2,2-bis(hydroxymethyl)propane-1,3-diol dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C RGASRBUYZODJTG-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 1
- WTPYFJNYAMXZJG-UHFFFAOYSA-N 2-[4-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound OCCOC1=CC=C(OCCO)C=C1 WTPYFJNYAMXZJG-UHFFFAOYSA-N 0.000 description 1
- AIBRSVLEQRWAEG-UHFFFAOYSA-N 3,9-bis(2,4-ditert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP1OCC2(COP(OC=3C(=CC(=CC=3)C(C)(C)C)C(C)(C)C)OC2)CO1 AIBRSVLEQRWAEG-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- 101100457042 Dictyostelium discoideum mgst gene Proteins 0.000 description 1
- 229920003314 Elvaloy® Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- HPFXACZRFJDURI-KTKRTIGZSA-N N-oleoylglycine Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCC(O)=O HPFXACZRFJDURI-KTKRTIGZSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229920003298 Nucrel® Polymers 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical class [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229920003182 Surlyn® Polymers 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229960000250 adipic acid Drugs 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- WQZGKKKJIJFFOK-DVKNGEFBSA-N alpha-D-glucose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-DVKNGEFBSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000003819 basic metal compounds Chemical class 0.000 description 1
- XMEXYUIRYSLNKT-UHFFFAOYSA-N benzene-1,3-dicarboxylic acid;sodium Chemical compound [Na].OC(=O)C1=CC=CC(C(O)=O)=C1 XMEXYUIRYSLNKT-UHFFFAOYSA-N 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 239000006085 branching agent Substances 0.000 description 1
- INDXRDWMTVLQID-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO.OCCCCO INDXRDWMTVLQID-UHFFFAOYSA-N 0.000 description 1
- 239000004281 calcium formate Substances 0.000 description 1
- 229940044172 calcium formate Drugs 0.000 description 1
- 235000019255 calcium formate Nutrition 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 235000012174 carbonated soft drink Nutrition 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- PMMYEEVYMWASQN-IMJSIDKUSA-N cis-4-Hydroxy-L-proline Chemical compound O[C@@H]1CN[C@H](C(O)=O)C1 PMMYEEVYMWASQN-IMJSIDKUSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004440 column chromatography Methods 0.000 description 1
- 210000001520 comb Anatomy 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 231100001010 corrosive Toxicity 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000003398 denaturant Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229940044170 formate Drugs 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000003845 household chemical Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 238000010102 injection blow moulding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229940096405 magnesium cation Drugs 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 235000010746 mayonnaise Nutrition 0.000 description 1
- 239000008268 mayonnaise Substances 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 235000021400 peanut butter Nutrition 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 239000007870 radical polymerization initiator Substances 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 150000003385 sodium Chemical class 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- POZWVHISDXHZLV-KVVVOXFISA-M sodium;(z)-docos-13-enoate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCCCCCC([O-])=O POZWVHISDXHZLV-KVVVOXFISA-M 0.000 description 1
- WQOMVNPUJAWPFR-UHFFFAOYSA-M sodium;2-carboxynaphthalene-1-carboxylate Chemical compound [Na+].C1=CC=CC2=C(C([O-])=O)C(C(=O)O)=CC=C21 WQOMVNPUJAWPFR-UHFFFAOYSA-M 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- IISLNQNUYOZKNE-UHFFFAOYSA-N sodium;terephthalic acid Chemical compound [Na].OC(=O)C1=CC=C(C(O)=O)C=C1 IISLNQNUYOZKNE-UHFFFAOYSA-N 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229960005137 succinic acid Drugs 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000009823 thermal lamination Methods 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0869—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with unsaturated acids, e.g. [meth]acrylic acid; with unsaturated esters, e.g. [meth]acrylic acid esters
- C08L23/0876—Salts thereof, i.e. ionomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2322008P | 2008-01-24 | 2008-01-24 | |
| PCT/US2009/031509 WO2009094359A1 (en) | 2008-01-24 | 2009-01-21 | Polyesters modified by a combination of ionomer and organic acid salts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2011510161A true JP2011510161A (ja) | 2011-03-31 |
| JP2011510161A5 JP2011510161A5 (enExample) | 2012-03-01 |
Family
ID=40512595
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010544392A Pending JP2011510161A (ja) | 2008-01-24 | 2009-01-21 | アイオノマーと有機酸塩との組み合わせによって変性されたポリエステル |
| JP2010544394A Pending JP2011510162A (ja) | 2008-01-24 | 2009-01-21 | 溶融粘度が低下した強靭化ポリ（トリメチレンテレフタレート）組成物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010544394A Pending JP2011510162A (ja) | 2008-01-24 | 2009-01-21 | 溶融粘度が低下した強靭化ポリ（トリメチレンテレフタレート）組成物 |
Country Status (6)
| Country | Link |
|---|---|
| US (3) | US20090192269A1 (enExample) |
| EP (2) | EP2235108B1 (enExample) |
| JP (2) | JP2011510161A (enExample) |
| KR (2) | KR20100115772A (enExample) |
| CN (2) | CN101925654A (enExample) |
| WO (2) | WO2009094362A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012519754A (ja) * | 2009-03-03 | 2012-08-30 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ポリ（トリメチレンテレフタレート）成形用樹脂およびその成形品 |
| JP2013509493A (ja) * | 2009-11-02 | 2013-03-14 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 強化されたポリ（トリメチレンテレフタレート）組成物およびその成形品 |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2911329B1 (fr) * | 2007-01-12 | 2009-04-17 | Rexam Pharma Soc Par Actions S | Ensemble de conditionnement et de distribution d'un liquide medical |
| CN101987913A (zh) * | 2009-07-31 | 2011-03-23 | E.I.内穆尔杜邦公司 | 增韧的聚苯二甲酸丙二醇酯树脂组合物 |
| US8389604B2 (en) | 2009-11-02 | 2013-03-05 | E I Du Pont De Nemours And Company | Method for providing toughened poly(trimethylene terephthalate) molding resins |
| US20110294961A1 (en) * | 2010-05-28 | 2011-12-01 | E. I. Du Pont De Nemours And Company | Thermoplastic polyester elastomer compositions |
| US20110294955A1 (en) * | 2010-05-28 | 2011-12-01 | E. I. Du Pont De Nemours And Company | Thermoplastic polyester elastomer composition including ionomer |
| EP2612824B1 (en) * | 2010-09-01 | 2020-05-20 | Kyodo Printing Co., Ltd. | Laminate, packaging container, and packaging body |
| US8931696B2 (en) | 2011-08-17 | 2015-01-13 | Darden Gwaltney Hood | Counterfeit detection system and method |
| US20130149930A1 (en) * | 2011-12-12 | 2013-06-13 | E I Du Pont De Nemours And Company | Methods to form an ionomer coating on a substrate |
| US9732021B2 (en) | 2012-02-24 | 2017-08-15 | Biochemtex S.P.A. | Continuous process for conversion of lignin to useful compounds |
| EP2817515A2 (en) | 2012-02-24 | 2014-12-31 | Chemtex Italia S.p.A. | Continuous process for conversion of lignin to useful compounds |
| WO2014185890A1 (en) * | 2013-05-14 | 2014-11-20 | Hood Darden Gwaltney | Counterfeit detection system and method |
| CN105440593A (zh) * | 2014-08-29 | 2016-03-30 | 杜邦公司 | 包含聚对苯二甲酸丙二醇酯的增韧组合物 |
| CN109370175B (zh) * | 2018-11-27 | 2021-03-23 | 江苏万纳普新材料科技有限公司 | 一种pbt直接注射成型用高效增强型无卤阻燃功能母粒及其制备方法 |
| KR102236412B1 (ko) * | 2018-11-29 | 2021-04-05 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이로부터 제조된 성형품 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004300376A (ja) * | 2003-04-01 | 2004-10-28 | Asahi Kasei Chemicals Corp | 高温物性に優れたポリトリメチレンテレフタレート樹脂組成物 |
| JP2007119781A (ja) * | 2005-10-25 | 2007-05-17 | Lanxess Deutschland Gmbh | 改良された流動性を有する熱可塑性ポリエステルをベースとする成形用組成物 |
Family Cites Families (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB578097A (en) | 1943-06-01 | 1946-06-14 | Deloro Smelting & Refining Co | Surgical and dental alloys |
| JPS4975661A (enExample) * | 1972-11-24 | 1974-07-22 | ||
| US4010222A (en) * | 1975-05-23 | 1977-03-01 | E. I. Du Pont De Nemours And Company | Blends of copolyesters and ethylene/carboxylic acid copolymers which are at least ten percent neutralized |
| JPS52151346A (en) * | 1976-06-11 | 1977-12-15 | Teijin Ltd | Flame-retardant polyester compositions |
| JPS5493043A (en) * | 1977-12-29 | 1979-07-23 | Unitika Ltd | Resin composition and its production |
| US4891406A (en) * | 1983-08-08 | 1990-01-02 | Huels Aktiengesellschaft | High impact strength molding compositions based on polyalkylene terephthalates |
| EP0174343B1 (en) | 1984-02-24 | 1992-04-29 | E.I. Du Pont De Nemours And Company | Toughened thermoplastic polyester compositions |
| US4551485A (en) * | 1984-09-04 | 1985-11-05 | Ethyl Corporation | Poly(ethylene terephthalate) blends |
| JPS62280227A (ja) * | 1986-05-29 | 1987-12-05 | Mitsui Petrochem Ind Ltd | 成形物品の製造方法 |
| US5091478A (en) | 1986-11-14 | 1992-02-25 | E. I. Du Pont De Nemours And Company | Partially grafted thermoplastic compositions |
| US4871810A (en) * | 1987-11-13 | 1989-10-03 | E. I. Du Pont De Nemours And Company | Composition comprising melt blended product of thermoplastic resin and two ethylene copolymers containing coreactive groups |
| US4912167A (en) * | 1987-12-14 | 1990-03-27 | E. I. Du Pont De Nemours And Company | Polyester compositions for blow molding |
| JP2614200B2 (ja) | 1989-03-29 | 1997-05-28 | 鐘紡株式会社 | 熱成形ポリエステル容器 |
| US5115012A (en) * | 1990-06-18 | 1992-05-19 | E. I. Du Pont De Nemours And Company | Thermoplastic blow moldable polyester compositions |
| US5128404A (en) * | 1990-06-18 | 1992-07-07 | E. I. Du Pont De Nemours And Company | Thermoplastic blow moldable polybutylene terephthalate compositions |
| JP3112938B2 (ja) * | 1990-08-27 | 2000-11-27 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | 強化熱可塑性ポリエステル組成物 |
| US5344912A (en) * | 1992-02-03 | 1994-09-06 | Therma-Plate Corporation | Elevated temperature dimensionally stable polyester with low gas permeability |
| US5554120A (en) * | 1994-07-25 | 1996-09-10 | Advanced Cardiovascular Systems, Inc. | Polymer blends for use in making medical devices including catheters and balloons for dilatation catheters |
| US5498650A (en) * | 1995-02-24 | 1996-03-12 | Ecological Chemical Products | Poly(lactic acid) composition having improved physical properties |
| EP0822963B1 (en) * | 1995-04-26 | 2001-08-22 | Honeywell International, Inc. | Process for the production of polyester molding compositions |
| US6020414A (en) * | 1996-10-23 | 2000-02-01 | Hoechst Celanese Corporation | Method and compositions for toughening polyester resins |
| US6232400B1 (en) * | 1998-04-20 | 2001-05-15 | Acushnet Company | Golf balls formed of compositions comprising poly(trimethylene terephthalate) and method of making such balls |
| US6245844B1 (en) | 1998-09-18 | 2001-06-12 | E. I. Du Pont De Nemours And Company | Nucleating agent for polyesters |
| JP2001011292A (ja) * | 1999-06-30 | 2001-01-16 | Kanegafuchi Chem Ind Co Ltd | 淡色系耐光性ポリエステル樹脂組成物およびそれから成形された照明器具部品 |
| JP2002356608A (ja) * | 2001-05-30 | 2002-12-13 | Bridgestone Sports Co Ltd | ゴルフボール用樹脂組成物及びゴルフボール |
| KR100840219B1 (ko) * | 2001-08-03 | 2008-06-23 | 도레이 가부시끼가이샤 | 수지 조성물 및 그것으로 이루어진 성형품, 필름 및 섬유 |
| CN1296432C (zh) * | 2002-03-29 | 2007-01-24 | 三井化学株式会社 | 乳酸基树脂组合物 |
| JP2004083656A (ja) * | 2002-08-23 | 2004-03-18 | Asahi Kasei Chemicals Corp | 成形性に優れた樹脂組成物 |
| JP2004189977A (ja) * | 2002-12-13 | 2004-07-08 | Mitsubishi Engineering Plastics Corp | ポリトリメチレンテレフタレート系樹脂組成物および成形品 |
| KR101043137B1 (ko) | 2003-05-13 | 2011-06-20 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 강화된 폴리옥시메틸렌-폴리(락트산) 조성물 |
| US6943214B2 (en) * | 2003-05-13 | 2005-09-13 | E. I. Du Pont De Nemours And Company | Toughened polyoxymethylene-poly(lactic acid) compositions |
| EP1685188A1 (en) * | 2003-10-21 | 2006-08-02 | E.I. Dupont De Nemours And Company | Ethylene copolymer modified oriented polyester films, tapes, fibers and nonwoven textiles |
| US7381772B2 (en) * | 2003-12-12 | 2008-06-03 | E. I. Du Pont De Nemours And Company | Toughened poly(lactic acid) compositions |
| US7354973B2 (en) * | 2003-12-12 | 2008-04-08 | E.I. Du Pont De Nemours And Company | Toughened poly(lactic acid) compositions |
| JP4526865B2 (ja) * | 2004-04-30 | 2010-08-18 | Ｓａｂｉｃイノベーティブプラスチックスジャパン合同会社 | ポリエステル樹脂製光反射体 |
| JP4732457B2 (ja) * | 2004-06-08 | 2011-07-27 | ランクセス・ドイチュランド・ゲーエムベーハー | 熱可塑性ポリエステルをベースとする改良された流動性を有する成形用組成物 |
| US20060009556A1 (en) | 2004-07-08 | 2006-01-12 | Mengshi Lu | High gloss PET molding composition and articles made therefrom |
| US20060030678A1 (en) * | 2004-08-04 | 2006-02-09 | Brown Michael J | Polyester-containing multilayer coextruded articles |
| US20060223923A1 (en) * | 2005-02-07 | 2006-10-05 | Serge Cavalli | Thermoplastic vulcanisate blend |
| JP2006290952A (ja) | 2005-04-07 | 2006-10-26 | Asahi Kasei Chemicals Corp | 良外観強化ｐｔｔ樹脂組成物 |
| US20070049690A1 (en) * | 2005-08-29 | 2007-03-01 | Pravin Borade | Impact modified poly(arylene ether)/polyester blends and method |
| JP2007119594A (ja) | 2005-10-28 | 2007-05-17 | Asahi Kasei Chemicals Corp | 耐衝撃性に優れたポリトリメチレンテレフタレート樹脂組成物 |
| KR20080094807A (ko) | 2006-02-01 | 2008-10-24 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 폴리에스테르 및 에틸렌 공중합체를 포함하는 물품 |
-
2009
- 2009-01-21 CN CN2009801029733A patent/CN101925654A/zh active Pending
- 2009-01-21 JP JP2010544392A patent/JP2011510161A/ja active Pending
- 2009-01-21 EP EP09704155A patent/EP2235108B1/en not_active Not-in-force
- 2009-01-21 CN CN2009801104077A patent/CN101977990A/zh active Pending
- 2009-01-21 KR KR1020107018761A patent/KR20100115772A/ko not_active Withdrawn
- 2009-01-21 WO PCT/US2009/031514 patent/WO2009094362A1/en not_active Ceased
- 2009-01-21 KR KR1020107018759A patent/KR20100126702A/ko not_active Withdrawn
- 2009-01-21 JP JP2010544394A patent/JP2011510162A/ja active Pending
- 2009-01-21 WO PCT/US2009/031509 patent/WO2009094359A1/en not_active Ceased
- 2009-01-21 EP EP09703388A patent/EP2235107B1/en not_active Not-in-force
- 2009-01-23 US US12/358,718 patent/US20090192269A1/en not_active Abandoned
- 2009-01-23 US US12/358,835 patent/US8609770B2/en active Active
- 2009-01-23 US US12/358,944 patent/US8242209B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004300376A (ja) * | 2003-04-01 | 2004-10-28 | Asahi Kasei Chemicals Corp | 高温物性に優れたポリトリメチレンテレフタレート樹脂組成物 |
| JP2007119781A (ja) * | 2005-10-25 | 2007-05-17 | Lanxess Deutschland Gmbh | 改良された流動性を有する熱可塑性ポリエステルをベースとする成形用組成物 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012519754A (ja) * | 2009-03-03 | 2012-08-30 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ポリ（トリメチレンテレフタレート）成形用樹脂およびその成形品 |
| JP2013509493A (ja) * | 2009-11-02 | 2013-03-14 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 強化されたポリ（トリメチレンテレフタレート）組成物およびその成形品 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20090192266A1 (en) | 2009-07-30 |
| CN101925654A (zh) | 2010-12-22 |
| EP2235108B1 (en) | 2013-02-27 |
| US20090192269A1 (en) | 2009-07-30 |
| KR20100126702A (ko) | 2010-12-02 |
| JP2011510162A (ja) | 2011-03-31 |
| WO2009094359A1 (en) | 2009-07-30 |
| WO2009094362A1 (en) | 2009-07-30 |
| EP2235107A1 (en) | 2010-10-06 |
| US8609770B2 (en) | 2013-12-17 |
| EP2235107B1 (en) | 2012-09-26 |
| EP2235108A1 (en) | 2010-10-06 |
| CN101977990A (zh) | 2011-02-16 |
| US20090192268A1 (en) | 2009-07-30 |
| KR20100115772A (ko) | 2010-10-28 |
| US8242209B2 (en) | 2012-08-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2235108B1 (en) | Polyesters modified by a combination of ionomer and organic acid salts | |
| JPWO2011004885A1 (ja) | ポリ乳酸系樹脂組成物及び成形体 | |
| US5115012A (en) | Thermoplastic blow moldable polyester compositions | |
| US20090005514A1 (en) | Toughened polyester and articles therefrom | |
| US20120196064A1 (en) | Toughened polytrimethylene benzenedicarboxylate resin composition | |
| EP2403906B1 (en) | Poly(trimethylene terephthalate) molding resins and molded articles therefrom | |
| WO2006051640A1 (ja) | 難燃性生分解性ポリエステル樹脂組成物、その製造方法、及びそれより得られる成形体 | |
| JP5856970B2 (ja) | 強化されたポリ（トリメチレンテレフタレート）樹脂の供給方法 | |
| US8048959B2 (en) | Ethylene alkyl acrylate toughened poly(hydroxyalkanoic acid) compositions | |
| US20070299212A1 (en) | Polymer impact modifier blend concentrate | |
| KR20130000407A (ko) | 재생가능한 자원에서 유래하는 중합체의 조성물 | |
| US8716404B1 (en) | Polyesters modified by a combination of ionomer and fatty acid salts | |
| CN101410455A (zh) | 含有衍生自聚对苯二甲酸乙二醇酯(pet)的改性的聚对苯二甲酸丁二醇酯(pbt)无规共聚物的模塑组合物 | |
| EP3218436B1 (en) | Polyester composition and article prepared therefrom | |
| EP4291610B1 (en) | Thermoplastic composition of polycarbonate and polyester | |
| JPS63245427A (ja) | 耐衝撃性ポリエステル樹脂組成物 | |
| US8697804B1 (en) | Nucleated poly(trimethylene terephthalate) | |
| KR20230125822A (ko) | 내열성 방향족 폴리카르보네이트-폴리에스테르 조성물 | |
| WO1997013807A1 (en) | Polyester molding composition with improved flow and improved molded part surface | |
| JPS63130655A (ja) | 衝撃強度の優れたポリエステル樹脂組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120113 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20120113 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20120802 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120816 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20121116 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20121126 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20130307 |