JP2011508013A5 - - Google Patents
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- Publication number
- JP2011508013A5 JP2011508013A5 JP2010539658A JP2010539658A JP2011508013A5 JP 2011508013 A5 JP2011508013 A5 JP 2011508013A5 JP 2010539658 A JP2010539658 A JP 2010539658A JP 2010539658 A JP2010539658 A JP 2010539658A JP 2011508013 A5 JP2011508013 A5 JP 2011508013A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst composition
- electron donor
- external electron
- group
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 claims 48
- 239000003054 catalyst Substances 0.000 claims 38
- 239000003795 chemical substances by application Substances 0.000 claims 9
- -1 diol esters Chemical class 0.000 claims 9
- 230000000694 effects Effects 0.000 claims 8
- 239000012035 limiting reagent Substances 0.000 claims 8
- 238000006116 polymerization reaction Methods 0.000 claims 8
- 229910052782 aluminium Inorganic materials 0.000 claims 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 7
- HRAQMGWTPNOILP-UHFFFAOYSA-N 4-Ethoxy ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(OCC)C=C1 HRAQMGWTPNOILP-UHFFFAOYSA-N 0.000 claims 5
- 150000001875 compounds Chemical class 0.000 claims 5
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 claims 4
- 150000001733 carboxylic acid esters Chemical group 0.000 claims 4
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 claims 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 4
- BEDHCUAJOBASSZ-UHFFFAOYSA-N (2-cyclopentyl-1,3-dimethoxypropan-2-yl)cyclopentane Chemical compound C1CCCC1C(COC)(COC)C1CCCC1 BEDHCUAJOBASSZ-UHFFFAOYSA-N 0.000 claims 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims 3
- 229930195729 fatty acid Natural products 0.000 claims 3
- 239000000194 fatty acid Substances 0.000 claims 3
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 claims 2
- 150000001412 amines Chemical group 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 2
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 claims 2
- 125000000524 functional group Chemical group 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 229930195734 saturated hydrocarbon Natural products 0.000 claims 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims 2
- 150000003900 succinic acid esters Chemical class 0.000 claims 2
- 150000003623 transition metal compounds Chemical class 0.000 claims 2
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 claims 2
- IVVMILZHRRFSQR-UHFFFAOYSA-N 1,2-bis(methoxymethyl)-9h-fluorene Chemical compound C1=CC=C2C3=CC=C(COC)C(COC)=C3CC2=C1 IVVMILZHRRFSQR-UHFFFAOYSA-N 0.000 claims 1
- GLVIMRBXUNCALJ-UHFFFAOYSA-N 1-ethoxy-2-pentoxybenzene Chemical group CCCCCOC1=CC=CC=C1OCC GLVIMRBXUNCALJ-UHFFFAOYSA-N 0.000 claims 1
- RGHIYOCUMCUWAQ-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,5-dimethylhexane Chemical compound COCC(COC)(CC(C)C)C(C)C RGHIYOCUMCUWAQ-UHFFFAOYSA-N 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 125000005036 alkoxyphenyl group Chemical group 0.000 claims 1
- WGFNXLQURMLAGC-UHFFFAOYSA-N diethyl 2,3-di(propan-2-yl)butanedioate Chemical group CCOC(=O)C(C(C)C)C(C(C)C)C(=O)OCC WGFNXLQURMLAGC-UHFFFAOYSA-N 0.000 claims 1
- 229920001038 ethylene copolymer Polymers 0.000 claims 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical class OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims 1
- 150000002430 hydrocarbons Chemical group 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- GTCCGKPBSJZVRZ-UHFFFAOYSA-N pentane-2,4-diol Chemical group CC(O)CC(C)O GTCCGKPBSJZVRZ-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US1597807P | 2007-12-21 | 2007-12-21 | |
| US61/015,978 | 2007-12-21 | ||
| PCT/US2008/086551 WO2009085649A1 (en) | 2007-12-21 | 2008-12-12 | Self-limiting catalyst composition with bidentate internal donor |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011508013A JP2011508013A (ja) | 2011-03-10 |
| JP2011508013A5 true JP2011508013A5 (https=) | 2012-01-19 |
| JP5740159B2 JP5740159B2 (ja) | 2015-06-24 |
Family
ID=40361758
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010539658A Expired - Fee Related JP5740159B2 (ja) | 2007-12-21 | 2008-12-12 | 二座内部供与体を有する自己制限性触媒組成物 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20100273641A1 (https=) |
| EP (1) | EP2225288B1 (https=) |
| JP (1) | JP5740159B2 (https=) |
| KR (2) | KR101716507B1 (https=) |
| CN (2) | CN101945897B (https=) |
| BR (1) | BRPI0819539B1 (https=) |
| MX (1) | MX2010006895A (https=) |
| PL (1) | PL2225288T3 (https=) |
| RU (1) | RU2489447C2 (https=) |
| WO (1) | WO2009085649A1 (https=) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102325808B (zh) | 2008-12-31 | 2014-03-12 | 陶氏环球技术有限责任公司 | 包含取代的1,2-亚苯基芳族二酯内给体的前催化剂组合物及方法 |
| CN102333749B (zh) * | 2008-12-31 | 2015-04-22 | 陶氏环球技术有限责任公司 | 取代的亚苯基芳族二酯的生产方法 |
| KR101769275B1 (ko) | 2009-06-19 | 2017-08-18 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 내충격성 프로필렌 중합체 조성물의 제조 방법 |
| MY158466A (en) | 2009-12-02 | 2016-10-14 | Grace W R & Co | Three and four atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture |
| JP5878473B2 (ja) | 2009-12-02 | 2016-03-08 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | ポリプロピレン製造のための触媒における内部供与体としての二原子架橋ジカーボネート化合物 |
| EP2516489B1 (en) * | 2009-12-21 | 2014-07-02 | W.R. Grace & CO. - CONN. | Gas-phase polymerization process having multiple flow regimes |
| CN102781971B (zh) * | 2010-03-04 | 2015-03-11 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂组分 |
| EP2542592B1 (en) | 2010-03-04 | 2014-03-19 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| CN102234337B (zh) * | 2010-04-22 | 2013-08-14 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的催化剂组分及其催化剂 |
| CN102958953B (zh) * | 2010-06-24 | 2015-08-05 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂体系 |
| BR112013008507A2 (pt) | 2010-10-19 | 2017-10-31 | Basell Poliolefine Italia Srl | processo para a polimerização de olefinas |
| WO2012052387A1 (en) | 2010-10-19 | 2012-04-26 | Basell Poliolefine Italia S.R.L. | Catalyst system for the polymerization of olefins |
| US20120157295A1 (en) | 2010-12-21 | 2012-06-21 | Linfeng Chen | Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product |
| JP2014500384A (ja) * | 2010-12-21 | 2014-01-09 | ダウ グローバル テクノロジーズ エルエルシー | アルコキシアルキルエステル内部電子供与体を有するプロ触媒組成物の製造方法および製品 |
| EP2610274A1 (en) * | 2011-12-30 | 2013-07-03 | Borealis AG | Propylene random copolymer |
| CN104583219B (zh) * | 2012-09-24 | 2018-03-16 | 印度石油有限公司 | 固体形式的有机金属化合物，其制造方法，及其用途 |
| WO2014132806A1 (ja) * | 2013-02-27 | 2014-09-04 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分の製造方法、オレフィン類重合用触媒およびオレフィン類重合体の製造方法 |
| US9790291B2 (en) * | 2013-03-14 | 2017-10-17 | Formosa Plastics Corporation, Usa | Non-phthalate compounds as electron donors for polyolefin catalysts |
| CZ2013676A3 (cs) * | 2013-09-03 | 2015-03-11 | Polymer Institute Brno, Spol. S R. O. | Polyolefinový prášek, způsob jeho výroby a použití |
| CN104558282B (zh) * | 2013-10-18 | 2017-02-15 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法和用于烯烃聚合的催化剂与应用 |
| US9714302B2 (en) * | 2014-10-10 | 2017-07-25 | W. R. Grace & Co.—Conn. | Process for preparing spherical polymerization catalyst components for use in olefin polymerizations |
| KR101699590B1 (ko) * | 2014-11-28 | 2017-01-24 | 한화토탈 주식회사 | 프로필렌 중합용 고체촉매 및 이를 이용한 폴리프로필렌 제조 방법 |
| EP3255067B1 (en) * | 2015-01-30 | 2021-02-24 | Toho Titanium Co., Ltd. | Production method for olefin-polymerization catalyst and production method for olefin polymer |
| KR20170110077A (ko) * | 2015-01-30 | 2017-10-10 | 도호 티타늄 가부시키가이샤 | 올레핀류 중합용 고체 촉매 성분, 올레핀류 중합 촉매의 제조 방법 및 올레핀류 중합체의 제조 방법 |
| RU2752084C2 (ru) | 2016-10-06 | 2021-07-22 | У. Р. Грейс Энд Ко.-Конн. | Композиция прокатализатора, полученная с комбинацией внутренних доноров электронов |
| EP3309183A1 (en) * | 2016-10-14 | 2018-04-18 | SABIC Global Technologies B.V. | Polypropylene for use in bopp applications |
| US10124324B1 (en) * | 2017-05-09 | 2018-11-13 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| KR102287922B1 (ko) | 2017-11-03 | 2021-08-06 | 롯데케미칼 주식회사 | 고밀도 폴리올레핀의 중합용 촉매 조성물의 제조방법 |
| KR102287924B1 (ko) | 2017-11-09 | 2021-08-06 | 롯데케미칼 주식회사 | 고밀도 폴리에틸렌 중합용 촉매의 제조방법 |
| CN109517099B (zh) * | 2018-11-27 | 2021-07-30 | 山东鲁晶化工科技有限公司 | 一种外给电子体、烯烃聚合催化剂体系及其应用 |
| CN110003367B (zh) * | 2019-04-26 | 2020-07-17 | 营口市向阳催化剂有限责任公司 | 一种具有双功能的外给电子体的齐格勒-纳塔催化剂及其应用 |
| JP7539785B2 (ja) * | 2020-03-31 | 2024-08-26 | 住友化学株式会社 | オレフィン重合用固体触媒成分 |
| KR20230029899A (ko) * | 2020-06-26 | 2023-03-03 | 릴라이언스 인더스트리즈 리미티드 | 치글러나타(ziegler-natta) 촉매 시스템 및 이를 이용한 중합 공정 |
| CN118591567A (zh) | 2022-01-27 | 2024-09-03 | 英尼奥斯欧洲股份公司 | 催化剂组合物 |
| US20250154299A1 (en) | 2022-02-09 | 2025-05-15 | Ineos Europe Ag | Catalyst component |
| JP2025538763A (ja) | 2022-12-09 | 2025-11-28 | イネオス ユーロープ アクチェンゲゼルシャフト | 触媒成分 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5077357A (en) * | 1990-10-22 | 1991-12-31 | Shell Oil Company | Olefin polymerization catalyst |
| US4866022A (en) | 1984-03-23 | 1989-09-12 | Amoco Corporation | Olefin polymerization catalyst |
| IT1227258B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1227260B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta |
| DE3936856A1 (de) | 1989-11-06 | 1991-05-08 | Basf Ag | Katalysatorsysteme vom typ der ziegler-natta-katalysatoren |
| US4983562A (en) | 1989-11-17 | 1991-01-08 | Union Carbide Chemicals And Plastics Company Inc. | High activity catalyst system for the production of propylene polymers |
| US5432244A (en) * | 1990-12-12 | 1995-07-11 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of polypropylene |
| US5218052A (en) | 1991-02-04 | 1993-06-08 | Amoco Corporation | Olefin polymerization and copolymerization process |
| IT1252205B (it) * | 1991-12-13 | 1995-06-05 | Himont Inc | Processo per la preparazione di poliolefine stabilizzate e prodotti cosi` ottenuti. |
| IT1262933B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Processo per la polimerizzazione in fase gas di alfa-olefine |
| CN1115988A (zh) | 1993-09-16 | 1996-01-31 | 壳牌石油公司 | 聚合物的制备 |
| US7049377B1 (en) * | 1995-02-21 | 2006-05-23 | Basell Poliolefine Italia S.R.L. | 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers |
| KR100218048B1 (ko) | 1996-04-25 | 1999-09-01 | 유현식 | α-올레핀 중합용 촉매 및 이를 이용하는 α-올레핀 중합방법 |
| US6124507A (en) * | 1997-12-10 | 2000-09-26 | Union Carbide Chemicals & Plastics Technology Corporation | Electron donors |
| CN1115349C (zh) * | 1998-04-03 | 2003-07-23 | 中国石油化工集团公司 | 一种制备稳定聚烯烃的方法 |
| KR20010043615A (ko) | 1999-03-15 | 2001-05-25 | 바셀 테크놀로지 컴퍼니 비.브이. | 올레핀 중합용 촉매성분 및 촉매 |
| CA2334743C (en) * | 1999-04-15 | 2010-01-12 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| CN1137155C (zh) * | 1999-12-06 | 2004-02-04 | 中国石油化工集团公司 | 用于烯烃聚合或共聚合的催化剂体系 |
| FR2812642B1 (fr) * | 2000-08-03 | 2003-08-01 | Atofina | Procede de preparation d'un support de catalyseur pour la poymerisation de l'ethylene et des alpha-olefines, le support ainsi obtenu et le catalyseur correspondant |
| US6825146B2 (en) * | 2001-05-29 | 2004-11-30 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst compositions and method of preparation |
| CN1169845C (zh) * | 2002-02-07 | 2004-10-06 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用 |
| KR100615936B1 (ko) | 2002-04-04 | 2006-08-28 | 미쓰이 가가쿠 가부시키가이샤 | 올레핀 중합용 고체상 티탄 촉매, 올레핀 중합용 촉매, 및올레핀 중합 방법 |
| US7202314B2 (en) | 2002-09-16 | 2007-04-10 | Basell Poliolefine Italia S.P.A. | Components and catalysts for the polymerization of olefins |
| CN1681853A (zh) * | 2002-09-16 | 2005-10-12 | 巴塞尔聚烯烃意大利有限公司 | 烯烃聚合用组分和催化剂 |
| EP1668044B1 (en) * | 2003-09-23 | 2014-05-07 | W.R. Grace & CO. - CONN. | Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process |
| US7393806B2 (en) * | 2003-09-23 | 2008-07-01 | Dow Global Technologies Inc. | Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process |
| US7491670B2 (en) * | 2003-09-23 | 2009-02-17 | Dow Global Technologies Inc. | Self limiting catalyst composition and propylene polymerization process |
| US7351778B2 (en) * | 2004-04-30 | 2008-04-01 | China Petroleum & Chemical Corporation | Catalyst component for olefin polymerization and catalyst comprising the same |
| JP4688135B2 (ja) * | 2005-01-18 | 2011-05-25 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分および触媒 |
| KR100918546B1 (ko) | 2005-01-19 | 2009-09-21 | 미쓰이 가가쿠 가부시키가이샤 | 올레핀 중합체의 제조방법 및 고체상 티탄 촉매성분 |
| US7491781B2 (en) | 2005-03-08 | 2009-02-17 | Ineos Usa Llc | Propylene polymer catalyst donor component |
| ES2703366T3 (es) | 2007-08-24 | 2019-03-08 | Grace W R & Co | Composición de catalizador auto-limitante sin silano |
-
2008
- 2008-12-12 JP JP2010539658A patent/JP5740159B2/ja not_active Expired - Fee Related
- 2008-12-12 PL PL08866579T patent/PL2225288T3/pl unknown
- 2008-12-12 KR KR1020107016163A patent/KR101716507B1/ko not_active Expired - Fee Related
- 2008-12-12 CN CN200880127351.1A patent/CN101945897B/zh not_active Expired - Fee Related
- 2008-12-12 KR KR1020167010561A patent/KR101787927B1/ko not_active Expired - Fee Related
- 2008-12-12 RU RU2010130415/04A patent/RU2489447C2/ru active
- 2008-12-12 US US12/809,663 patent/US20100273641A1/en not_active Abandoned
- 2008-12-12 BR BRPI0819539A patent/BRPI0819539B1/pt not_active IP Right Cessation
- 2008-12-12 CN CN201410344155.7A patent/CN104193857B/zh not_active Expired - Fee Related
- 2008-12-12 MX MX2010006895A patent/MX2010006895A/es active IP Right Grant
- 2008-12-12 EP EP08866579.9A patent/EP2225288B1/en not_active Revoked
- 2008-12-12 WO PCT/US2008/086551 patent/WO2009085649A1/en not_active Ceased
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