KR101716507B1 - 두자리 내부 공여체를 가진 자기-제한성 촉매 조성물 - Google Patents
두자리 내부 공여체를 가진 자기-제한성 촉매 조성물 Download PDFInfo
- Publication number
- KR101716507B1 KR101716507B1 KR1020107016163A KR20107016163A KR101716507B1 KR 101716507 B1 KR101716507 B1 KR 101716507B1 KR 1020107016163 A KR1020107016163 A KR 1020107016163A KR 20107016163 A KR20107016163 A KR 20107016163A KR 101716507 B1 KR101716507 B1 KR 101716507B1
- Authority
- KR
- South Korea
- Prior art keywords
- electron donor
- catalyst composition
- external electron
- composition
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
- C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US1597807P | 2007-12-21 | 2007-12-21 | |
| US61/015,978 | 2007-12-21 | ||
| PCT/US2008/086551 WO2009085649A1 (en) | 2007-12-21 | 2008-12-12 | Self-limiting catalyst composition with bidentate internal donor |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020167010561A Division KR101787927B1 (ko) | 2007-12-21 | 2008-12-12 | 두자리 내부 공여체를 가진 자기-제한성 촉매 조성물 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20100105857A KR20100105857A (ko) | 2010-09-30 |
| KR101716507B1 true KR101716507B1 (ko) | 2017-03-14 |
Family
ID=40361758
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020107016163A Expired - Fee Related KR101716507B1 (ko) | 2007-12-21 | 2008-12-12 | 두자리 내부 공여체를 가진 자기-제한성 촉매 조성물 |
| KR1020167010561A Expired - Fee Related KR101787927B1 (ko) | 2007-12-21 | 2008-12-12 | 두자리 내부 공여체를 가진 자기-제한성 촉매 조성물 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020167010561A Expired - Fee Related KR101787927B1 (ko) | 2007-12-21 | 2008-12-12 | 두자리 내부 공여체를 가진 자기-제한성 촉매 조성물 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20100273641A1 (https=) |
| EP (1) | EP2225288B1 (https=) |
| JP (1) | JP5740159B2 (https=) |
| KR (2) | KR101716507B1 (https=) |
| CN (2) | CN101945897B (https=) |
| BR (1) | BRPI0819539B1 (https=) |
| MX (1) | MX2010006895A (https=) |
| PL (1) | PL2225288T3 (https=) |
| RU (1) | RU2489447C2 (https=) |
| WO (1) | WO2009085649A1 (https=) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190050436A (ko) | 2017-11-03 | 2019-05-13 | 롯데케미칼 주식회사 | 고밀도 폴리올레핀의 중합용 촉매 조성물의 제조방법 |
| KR20190052864A (ko) | 2017-11-09 | 2019-05-17 | 롯데케미칼 주식회사 | 고밀도 폴리에틸렌 중합용 촉매의 제조방법 |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL2373702T3 (pl) | 2008-12-31 | 2018-07-31 | W.R. Grace & Co.-Conn. | Kompozycja prekatalizatora z wewnętrznym donorem w postaci podstawionego aromatycznego diestru 1,2-fenylenowego oraz sposób |
| JP5731988B2 (ja) * | 2008-12-31 | 2015-06-10 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | プロピレン系ポリマー、物品およびその製造プロセス |
| CN102803310A (zh) * | 2009-06-19 | 2012-11-28 | 巴塞尔聚烯烃意大利有限责任公司 | 制备抗冲击性丙烯聚合物组合物的方法 |
| US8263520B2 (en) | 2009-12-02 | 2012-09-11 | Dow Global Technologies Llc | Two atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture |
| EP2507269B1 (en) | 2009-12-02 | 2014-10-29 | W.R. Grace & Co.-Conn. | Three and four atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture |
| EP2516489B1 (en) * | 2009-12-21 | 2014-07-02 | W.R. Grace & CO. - CONN. | Gas-phase polymerization process having multiple flow regimes |
| WO2011107371A1 (en) * | 2010-03-04 | 2011-09-09 | Basell Poliolefine Italia Srl | Catalyst components for the polymerization of olefins |
| CN102781971B (zh) * | 2010-03-04 | 2015-03-11 | 巴塞尔聚烯烃意大利有限责任公司 | 用于烯烃聚合的催化剂组分 |
| CN102234337B (zh) * | 2010-04-22 | 2013-08-14 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的催化剂组分及其催化剂 |
| BR112012033011B1 (pt) * | 2010-06-24 | 2020-05-26 | Basell Poliolefine Italia S.R.L. | Sistema catalisador e processo para polimerizar olefinas utilizando tal sistema |
| BR112013008900A2 (pt) | 2010-10-19 | 2016-06-28 | Basell Poliolefine Srl | "sistema da catalisação para a polimerização de olefinas" |
| WO2012052386A1 (en) | 2010-10-19 | 2012-04-26 | Basell Poliolefine Italia S.R.L. | Process for the polymerization of olefins |
| JP2014500384A (ja) * | 2010-12-21 | 2014-01-09 | ダウ グローバル テクノロジーズ エルエルシー | アルコキシアルキルエステル内部電子供与体を有するプロ触媒組成物の製造方法および製品 |
| US20120157295A1 (en) | 2010-12-21 | 2012-06-21 | Linfeng Chen | Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product |
| EP2610274A1 (en) * | 2011-12-30 | 2013-07-03 | Borealis AG | Propylene random copolymer |
| EP3653631A1 (en) * | 2012-09-24 | 2020-05-20 | INDIAN OIL CORPORATION Ltd. | Processes for the preparation of an olefin polymerization catalyst based on treating solid organomagnesium compounds with titanium moieties |
| SG11201501883UA (en) | 2013-02-27 | 2015-05-28 | Toho Titanium Co Ltd | Production method for solid catalyst component for polymerizing olefins, catalyst for polymerizing olefins, and production method for polymerized olefins |
| US9790291B2 (en) * | 2013-03-14 | 2017-10-17 | Formosa Plastics Corporation, Usa | Non-phthalate compounds as electron donors for polyolefin catalysts |
| CZ2013676A3 (cs) * | 2013-09-03 | 2015-03-11 | Polymer Institute Brno, Spol. S R. O. | Polyolefinový prášek, způsob jeho výroby a použití |
| CN104558282B (zh) * | 2013-10-18 | 2017-02-15 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法和用于烯烃聚合的催化剂与应用 |
| US9714302B2 (en) * | 2014-10-10 | 2017-07-25 | W. R. Grace & Co.—Conn. | Process for preparing spherical polymerization catalyst components for use in olefin polymerizations |
| KR101699590B1 (ko) * | 2014-11-28 | 2017-01-24 | 한화토탈 주식회사 | 프로필렌 중합용 고체촉매 및 이를 이용한 폴리프로필렌 제조 방법 |
| CN107207646A (zh) * | 2015-01-30 | 2017-09-26 | 东邦钛株式会社 | 烯烃类聚合用固体催化剂成分、烯烃类聚合催化剂的制造方法和烯烃类聚合物的制造方法 |
| US10392453B2 (en) * | 2015-01-30 | 2019-08-27 | Toho Titanium Co., Ltd. | Production method for olefin-polymerization catalyst and production method for olefin polymer |
| CN110023351B (zh) * | 2016-10-06 | 2022-04-26 | 格雷斯公司 | 采用内给电子体的组合制得的主催化剂组合物 |
| EP3309183A1 (en) * | 2016-10-14 | 2018-04-18 | SABIC Global Technologies B.V. | Polypropylene for use in bopp applications |
| US10124324B1 (en) * | 2017-05-09 | 2018-11-13 | Formosa Plastics Corporation, Usa | Olefin polymerization catalyst components and process for the production of olefin polymers therewith |
| CN109517099B (zh) * | 2018-11-27 | 2021-07-30 | 山东鲁晶化工科技有限公司 | 一种外给电子体、烯烃聚合催化剂体系及其应用 |
| CN110003367B (zh) * | 2019-04-26 | 2020-07-17 | 营口市向阳催化剂有限责任公司 | 一种具有双功能的外给电子体的齐格勒-纳塔催化剂及其应用 |
| JP7539785B2 (ja) * | 2020-03-31 | 2024-08-26 | 住友化学株式会社 | オレフィン重合用固体触媒成分 |
| JP2023531256A (ja) * | 2020-06-26 | 2023-07-21 | リライアンス、インダストリーズ、リミテッド | チーグラー・ナッタ触媒システムおよびこれを用いる重合プロセス |
| WO2023144126A1 (en) | 2022-01-27 | 2023-08-03 | Ineos Europe Ag | Catalyst composition |
| WO2023152111A1 (en) | 2022-02-09 | 2023-08-17 | Ineos Europe Ag | Catalyst component |
| EP4630463A1 (en) | 2022-12-09 | 2025-10-15 | Ineos Europe AG | Catalyst component |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000055215A1 (en) | 1999-03-15 | 2000-09-21 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| JP2005539108A (ja) | 2002-09-16 | 2005-12-22 | バセル ポリオレフィン イタリア エス.アール.エス. | オレフィン類の重合用の成分と触媒 |
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| US5077357A (en) * | 1990-10-22 | 1991-12-31 | Shell Oil Company | Olefin polymerization catalyst |
| US4866022A (en) | 1984-03-23 | 1989-09-12 | Amoco Corporation | Olefin polymerization catalyst |
| IT1227260B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta |
| IT1227258B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| DE3936856A1 (de) | 1989-11-06 | 1991-05-08 | Basf Ag | Katalysatorsysteme vom typ der ziegler-natta-katalysatoren |
| US4983562A (en) | 1989-11-17 | 1991-01-08 | Union Carbide Chemicals And Plastics Company Inc. | High activity catalyst system for the production of propylene polymers |
| US5432244A (en) * | 1990-12-12 | 1995-07-11 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of polypropylene |
| US5218052A (en) | 1991-02-04 | 1993-06-08 | Amoco Corporation | Olefin polymerization and copolymerization process |
| IT1252205B (it) * | 1991-12-13 | 1995-06-05 | Himont Inc | Processo per la preparazione di poliolefine stabilizzate e prodotti cosi` ottenuti. |
| IT1262933B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Processo per la polimerizzazione in fase gas di alfa-olefine |
| EP0669946B2 (en) | 1993-09-16 | 2001-12-19 | Union Carbide Chemicals & Plastics Technology Corporation | Polymer production |
| US7049377B1 (en) * | 1995-02-21 | 2006-05-23 | Basell Poliolefine Italia S.R.L. | 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers |
| KR100218048B1 (ko) | 1996-04-25 | 1999-09-01 | 유현식 | α-올레핀 중합용 촉매 및 이를 이용하는 α-올레핀 중합방법 |
| US6124507A (en) * | 1997-12-10 | 2000-09-26 | Union Carbide Chemicals & Plastics Technology Corporation | Electron donors |
| CN1115349C (zh) * | 1998-04-03 | 2003-07-23 | 中国石油化工集团公司 | 一种制备稳定聚烯烃的方法 |
| CN1240729C (zh) * | 1999-04-15 | 2006-02-08 | 巴塞尔聚烯烃意大利有限公司 | 用于烯烃聚合的组分和催化剂 |
| CN1137155C (zh) * | 1999-12-06 | 2004-02-04 | 中国石油化工集团公司 | 用于烯烃聚合或共聚合的催化剂体系 |
| FR2812642B1 (fr) * | 2000-08-03 | 2003-08-01 | Atofina | Procede de preparation d'un support de catalyseur pour la poymerisation de l'ethylene et des alpha-olefines, le support ainsi obtenu et le catalyseur correspondant |
| US6825146B2 (en) * | 2001-05-29 | 2004-11-30 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst compositions and method of preparation |
| CN1169845C (zh) * | 2002-02-07 | 2004-10-06 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用 |
| WO2003085006A1 (en) | 2002-04-04 | 2003-10-16 | Mitsui Chemicals, Inc | Solid titanium catalyst component for olefin polymerization, catalyst for olefin polymerization, and process for olefin polymerization |
| US7202314B2 (en) | 2002-09-16 | 2007-04-10 | Basell Poliolefine Italia S.P.A. | Components and catalysts for the polymerization of olefins |
| EP1668044B1 (en) * | 2003-09-23 | 2014-05-07 | W.R. Grace & CO. - CONN. | Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process |
| US7393806B2 (en) * | 2003-09-23 | 2008-07-01 | Dow Global Technologies Inc. | Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process |
| EP1668046B8 (en) * | 2003-09-23 | 2021-04-21 | W.R. Grace & CO. - CONN. | Self limiting catalyst composition and propylene polymerization process |
| US7351778B2 (en) * | 2004-04-30 | 2008-04-01 | China Petroleum & Chemical Corporation | Catalyst component for olefin polymerization and catalyst comprising the same |
| JP4688135B2 (ja) * | 2005-01-18 | 2011-05-25 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分および触媒 |
| JP5530054B2 (ja) | 2005-01-19 | 2014-06-25 | 三井化学株式会社 | オレフィン重合体製造用固体状チタン触媒成分、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| US7491781B2 (en) | 2005-03-08 | 2009-02-17 | Ineos Usa Llc | Propylene polymer catalyst donor component |
| PL2185600T3 (pl) | 2007-08-24 | 2019-07-31 | W.R. Grace & Co. - Conn. | Samohamująca kompozycja katalityczna bez silanu |
-
2008
- 2008-12-12 JP JP2010539658A patent/JP5740159B2/ja not_active Expired - Fee Related
- 2008-12-12 KR KR1020107016163A patent/KR101716507B1/ko not_active Expired - Fee Related
- 2008-12-12 KR KR1020167010561A patent/KR101787927B1/ko not_active Expired - Fee Related
- 2008-12-12 CN CN200880127351.1A patent/CN101945897B/zh not_active Expired - Fee Related
- 2008-12-12 EP EP08866579.9A patent/EP2225288B1/en not_active Revoked
- 2008-12-12 CN CN201410344155.7A patent/CN104193857B/zh not_active Expired - Fee Related
- 2008-12-12 WO PCT/US2008/086551 patent/WO2009085649A1/en not_active Ceased
- 2008-12-12 BR BRPI0819539A patent/BRPI0819539B1/pt not_active IP Right Cessation
- 2008-12-12 PL PL08866579T patent/PL2225288T3/pl unknown
- 2008-12-12 US US12/809,663 patent/US20100273641A1/en not_active Abandoned
- 2008-12-12 RU RU2010130415/04A patent/RU2489447C2/ru active
- 2008-12-12 MX MX2010006895A patent/MX2010006895A/es active IP Right Grant
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000055215A1 (en) | 1999-03-15 | 2000-09-21 | Basell Technology Company B.V. | Components and catalysts for the polymerization of olefins |
| JP2005539108A (ja) | 2002-09-16 | 2005-12-22 | バセル ポリオレフィン イタリア エス.アール.エス. | オレフィン類の重合用の成分と触媒 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190050436A (ko) | 2017-11-03 | 2019-05-13 | 롯데케미칼 주식회사 | 고밀도 폴리올레핀의 중합용 촉매 조성물의 제조방법 |
| KR102287922B1 (ko) * | 2017-11-03 | 2021-08-06 | 롯데케미칼 주식회사 | 고밀도 폴리올레핀의 중합용 촉매 조성물의 제조방법 |
| KR20190052864A (ko) | 2017-11-09 | 2019-05-17 | 롯데케미칼 주식회사 | 고밀도 폴리에틸렌 중합용 촉매의 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2011508013A (ja) | 2011-03-10 |
| BRPI0819539A2 (pt) | 2015-05-26 |
| EP2225288B1 (en) | 2018-08-29 |
| RU2010130415A (ru) | 2012-01-27 |
| CN104193857A (zh) | 2014-12-10 |
| BRPI0819539B1 (pt) | 2019-09-10 |
| KR101787927B1 (ko) | 2017-10-18 |
| US20100273641A1 (en) | 2010-10-28 |
| EP2225288A1 (en) | 2010-09-08 |
| JP5740159B2 (ja) | 2015-06-24 |
| KR20100105857A (ko) | 2010-09-30 |
| CN101945897A (zh) | 2011-01-12 |
| PL2225288T3 (pl) | 2019-01-31 |
| KR20160049050A (ko) | 2016-05-04 |
| MX2010006895A (es) | 2010-09-30 |
| CN101945897B (zh) | 2014-08-20 |
| CN104193857B (zh) | 2017-05-24 |
| RU2489447C2 (ru) | 2013-08-10 |
| WO2009085649A1 (en) | 2009-07-09 |
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