JP2011115961A - 感熱記録体 - Google Patents
感熱記録体 Download PDFInfo
- Publication number
- JP2011115961A JP2011115961A JP2009273136A JP2009273136A JP2011115961A JP 2011115961 A JP2011115961 A JP 2011115961A JP 2009273136 A JP2009273136 A JP 2009273136A JP 2009273136 A JP2009273136 A JP 2009273136A JP 2011115961 A JP2011115961 A JP 2011115961A
- Authority
- JP
- Japan
- Prior art keywords
- heat
- diisocyanate
- sensitive recording
- composite fine
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 isocyanate compound Chemical class 0.000 claims abstract description 76
- 239000002243 precursor Substances 0.000 claims abstract description 55
- 239000002131 composite material Substances 0.000 claims abstract description 50
- 239000010419 fine particle Substances 0.000 claims abstract description 47
- 239000012948 isocyanate Substances 0.000 claims abstract description 31
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims abstract description 20
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 claims abstract description 20
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002904 solvent Substances 0.000 claims abstract description 12
- 229920002873 Polyethylenimine Polymers 0.000 claims abstract description 9
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 9
- 230000001804 emulsifying effect Effects 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 48
- 150000001875 compounds Chemical class 0.000 claims description 35
- 238000006116 polymerization reaction Methods 0.000 claims description 35
- 239000005056 polyisocyanate Substances 0.000 claims description 19
- 229920001228 polyisocyanate Polymers 0.000 claims description 19
- 239000012736 aqueous medium Substances 0.000 claims description 11
- 239000002609 medium Substances 0.000 claims description 5
- 230000035945 sensitivity Effects 0.000 abstract description 23
- 239000000975 dye Substances 0.000 description 51
- 239000010410 layer Substances 0.000 description 37
- 239000002245 particle Substances 0.000 description 31
- 239000007788 liquid Substances 0.000 description 22
- 239000000123 paper Substances 0.000 description 22
- 238000002360 preparation method Methods 0.000 description 18
- 239000000243 solution Substances 0.000 description 18
- 238000000576 coating method Methods 0.000 description 15
- 239000011248 coating agent Substances 0.000 description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 description 14
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 13
- 239000004372 Polyvinyl alcohol Substances 0.000 description 12
- 239000007787 solid Substances 0.000 description 12
- 239000000853 adhesive Substances 0.000 description 10
- 230000001070 adhesive effect Effects 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- 239000011241 protective layer Substances 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 9
- 239000004816 latex Substances 0.000 description 9
- 229920000126 latex Polymers 0.000 description 9
- 239000000049 pigment Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- WNZQDUSMALZDQF-UHFFFAOYSA-N 2-benzofuran-1(3H)-one Chemical compound C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000003086 colorant Substances 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000001993 wax Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000084 colloidal system Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 229920002635 polyurethane Polymers 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 5
- 230000001681 protective effect Effects 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 4
- ZXFKEMLZEHXAHH-UHFFFAOYSA-N 1,4-dihydrochromeno[2,3-c]pyrazole Chemical compound O1C2=CC=CC=C2CC2=C1NN=C2 ZXFKEMLZEHXAHH-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 238000003745 diagnosis Methods 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 238000009499 grossing Methods 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920000609 methyl cellulose Polymers 0.000 description 3
- 239000001923 methylcellulose Substances 0.000 description 3
- 235000010981 methylcellulose Nutrition 0.000 description 3
- 239000003094 microcapsule Substances 0.000 description 3
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 3
- 229920000768 polyamine Polymers 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- OAGNKYSIOSDNIG-UHFFFAOYSA-N 1-methyl-3-[2-(3-methylphenoxy)ethoxy]benzene Chemical compound CC1=CC=CC(OCCOC=2C=C(C)C=CC=2)=C1 OAGNKYSIOSDNIG-UHFFFAOYSA-N 0.000 description 2
- YFJKDTUNMQIYCV-UHFFFAOYSA-N 2-ethoxy-1-(4-methylphenoxy)naphthalene Chemical compound CCOC1=CC=C2C=CC=CC2=C1OC1=CC=C(C)C=C1 YFJKDTUNMQIYCV-UHFFFAOYSA-N 0.000 description 2
- HEZFLHDITQDUKF-UHFFFAOYSA-N 2-ethoxy-1-phenoxynaphthalene Chemical compound CCOC1=CC=C2C=CC=CC2=C1OC1=CC=CC=C1 HEZFLHDITQDUKF-UHFFFAOYSA-N 0.000 description 2
- XCSGHNKDXGYELG-UHFFFAOYSA-N 2-phenoxyethoxybenzene Chemical compound C=1C=CC=CC=1OCCOC1=CC=CC=C1 XCSGHNKDXGYELG-UHFFFAOYSA-N 0.000 description 2
- IYVGEXHNZJTTTF-UHFFFAOYSA-N 3-(1-butyl-2-methylindol-3-yl)-3h-2-benzofuran-1-one Chemical compound C12=CC=CC=C2N(CCCC)C(C)=C1C1C2=CC=CC=C2C(=O)O1 IYVGEXHNZJTTTF-UHFFFAOYSA-N 0.000 description 2
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 2
- GNZQDEXHTZDQRB-UHFFFAOYSA-N 3-[4-(diethylamino)-2-methylphenyl]-6-(dimethylamino)-3-[4-(dimethylamino)phenyl]-2-benzofuran-1-one Chemical compound CC1=CC(N(CC)CC)=CC=C1C1(C=2C=CC(=CC=2)N(C)C)C2=CC=C(N(C)C)C=C2C(=O)O1 GNZQDEXHTZDQRB-UHFFFAOYSA-N 0.000 description 2
- XQXPVVBIMDBYFF-UHFFFAOYSA-N 4-hydroxyphenylacetic acid Chemical compound OC(=O)CC1=CC=C(O)C=C1 XQXPVVBIMDBYFF-UHFFFAOYSA-N 0.000 description 2
- HNQMMWIWFNZYRX-UHFFFAOYSA-N 7-[4-(diethylamino)-2-ethoxyphenyl]-7h-furo[3,4-b]pyridin-5-one Chemical compound CCOC1=CC(N(CC)CC)=CC=C1C1C2=NC=CC=C2C(=O)O1 HNQMMWIWFNZYRX-UHFFFAOYSA-N 0.000 description 2
- RNIHAPSVIGPAFF-UHFFFAOYSA-N Acrylamide-acrylic acid resin Chemical compound NC(=O)C=C.OC(=O)C=C RNIHAPSVIGPAFF-UHFFFAOYSA-N 0.000 description 2
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 229920002396 Polyurea Polymers 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- KLIYQWXIWMRMGR-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate Chemical compound C=CC=C.COC(=O)C(C)=C KLIYQWXIWMRMGR-UHFFFAOYSA-N 0.000 description 2
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 2
- 239000002612 dispersion medium Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- FWQHNLCNFPYBCA-UHFFFAOYSA-N fluoran Chemical compound C12=CC=CC=C2OC2=CC=CC=C2C11OC(=O)C2=CC=CC=C21 FWQHNLCNFPYBCA-UHFFFAOYSA-N 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 2
- 229920000554 ionomer Polymers 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000011115 styrene butadiene Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- AZYRZNIYJDKRHO-UHFFFAOYSA-N 1,3-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC(C(C)(C)N=C=O)=C1 AZYRZNIYJDKRHO-UHFFFAOYSA-N 0.000 description 1
- RTTZISZSHSCFRH-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC(CN=C=O)=C1 RTTZISZSHSCFRH-UHFFFAOYSA-N 0.000 description 1
- BZMWYTDVUYRVEI-UHFFFAOYSA-N 1,4-bis(4-methylphenoxy)benzene Chemical compound C1=CC(C)=CC=C1OC(C=C1)=CC=C1OC1=CC=C(C)C=C1 BZMWYTDVUYRVEI-UHFFFAOYSA-N 0.000 description 1
- AGPLQTQFIZBOLI-UHFFFAOYSA-N 1-benzyl-4-phenylbenzene Chemical group C=1C=C(C=2C=CC=CC=2)C=CC=1CC1=CC=CC=C1 AGPLQTQFIZBOLI-UHFFFAOYSA-N 0.000 description 1
- XMOWAIVXKJWQBJ-UHFFFAOYSA-N 1-ethyl-2-methylindole Chemical compound C1=CC=C2N(CC)C(C)=CC2=C1 XMOWAIVXKJWQBJ-UHFFFAOYSA-N 0.000 description 1
- ANGBYYLFRXLPRD-UHFFFAOYSA-N 1-methyl-2-(2-phenoxyethoxy)benzene Chemical compound CC1=CC=CC=C1OCCOC1=CC=CC=C1 ANGBYYLFRXLPRD-UHFFFAOYSA-N 0.000 description 1
- UIFAEJQCFLEWCF-UHFFFAOYSA-N 1-methyl-4-[2-(4-methylphenoxy)ethoxy]benzene Chemical compound C1=CC(C)=CC=C1OCCOC1=CC=C(C)C=C1 UIFAEJQCFLEWCF-UHFFFAOYSA-N 0.000 description 1
- CEGHCPGGKKWOKF-UHFFFAOYSA-N 2'-anilino-6'-[cyclohexyl(methyl)amino]-3'-methylspiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound C=1C=C(C2(C3=CC=CC=C3C(=O)O2)C2=CC(NC=3C=CC=CC=3)=C(C)C=C2O2)C2=CC=1N(C)C1CCCCC1 CEGHCPGGKKWOKF-UHFFFAOYSA-N 0.000 description 1
- VQWGCFKMUFNLIK-UHFFFAOYSA-N 2-[2-(4-dodecoxy-3-methoxyphenyl)ethenyl]quinoline Chemical group C1=C(OC)C(OCCCCCCCCCCCC)=CC=C1C=CC1=CC=C(C=CC=C2)C2=N1 VQWGCFKMUFNLIK-UHFFFAOYSA-N 0.000 description 1
- CHEQGIKXBJKRHY-UHFFFAOYSA-N 2-hydroxy-4-[2-(4-methoxyphenoxy)ethoxy]benzoic acid;zinc Chemical compound [Zn].C1=CC(OC)=CC=C1OCCOC1=CC=C(C(O)=O)C(O)=C1 CHEQGIKXBJKRHY-UHFFFAOYSA-N 0.000 description 1
- VGAQXHYJWADXQV-UHFFFAOYSA-N 2-hydroxy-4-[3-(4-methylphenyl)sulfonylpropoxy]benzoic acid zinc Chemical compound [Zn].C1=CC(C)=CC=C1S(=O)(=O)CCCOC1=CC=C(C(O)=O)C(O)=C1 VGAQXHYJWADXQV-UHFFFAOYSA-N 0.000 description 1
- JQXYBDVZAUEPDL-UHFFFAOYSA-N 2-methylidene-5-phenylpent-4-enoic acid Chemical compound OC(=O)C(=C)CC=CC1=CC=CC=C1 JQXYBDVZAUEPDL-UHFFFAOYSA-N 0.000 description 1
- WLTCCDHHWYAMCG-UHFFFAOYSA-N 2-phenylmethoxynaphthalene Chemical compound C=1C=C2C=CC=CC2=CC=1OCC1=CC=CC=C1 WLTCCDHHWYAMCG-UHFFFAOYSA-N 0.000 description 1
- PFANXOISJYKQRP-UHFFFAOYSA-N 2-tert-butyl-4-[1-(5-tert-butyl-4-hydroxy-2-methylphenyl)butyl]-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(CCC)C1=CC(C(C)(C)C)=C(O)C=C1C PFANXOISJYKQRP-UHFFFAOYSA-N 0.000 description 1
- AGIJRRREJXSQJR-UHFFFAOYSA-N 2h-thiazine Chemical compound N1SC=CC=C1 AGIJRRREJXSQJR-UHFFFAOYSA-N 0.000 description 1
- GRIKUIPJBHJPPN-UHFFFAOYSA-N 3',6'-dimethoxyspiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(OC)C=C1OC1=CC(OC)=CC=C21 GRIKUIPJBHJPPN-UHFFFAOYSA-N 0.000 description 1
- XOEUNIAGBKGZLU-UHFFFAOYSA-N 3,3-bis(2-methyl-1-octylindol-3-yl)-2-benzofuran-1-one Chemical compound C1=CC=C2C(C3(C4=CC=CC=C4C(=O)O3)C3=C(C)N(C4=CC=CC=C43)CCCCCCCC)=C(C)N(CCCCCCCC)C2=C1 XOEUNIAGBKGZLU-UHFFFAOYSA-N 0.000 description 1
- GPBLVTFWNRNYKR-UHFFFAOYSA-N 3-(1-ethyl-2-methylindol-3-yl)-3h-2-benzofuran-1-one Chemical compound C12=CC=CC=C2N(CC)C(C)=C1C1C2=CC=CC=C2C(=O)O1 GPBLVTFWNRNYKR-UHFFFAOYSA-N 0.000 description 1
- VIUDTWATMPPKEL-UHFFFAOYSA-N 3-(trifluoromethyl)aniline Chemical compound NC1=CC=CC(C(F)(F)F)=C1 VIUDTWATMPPKEL-UHFFFAOYSA-N 0.000 description 1
- KMGZNVWFFYYSLP-UHFFFAOYSA-N 3-[2,2-bis(1-ethyl-2-methylindol-3-yl)ethenyl]-3-[4-(diethylamino)phenyl]-2-benzofuran-1-one Chemical compound C1=CC(N(CC)CC)=CC=C1C1(C=C(C=2C3=CC=CC=C3N(CC)C=2C)C=2C3=CC=CC=C3N(CC)C=2C)C2=CC=CC=C2C(=O)O1 KMGZNVWFFYYSLP-UHFFFAOYSA-N 0.000 description 1
- HOUWRQXIBSGOHF-UHFFFAOYSA-N 3-[4-(diethylamino)phenyl]-3-(1-ethyl-2-methylindol-3-yl)-2-benzofuran-1-one Chemical compound C1=CC(N(CC)CC)=CC=C1C1(C=2C3=CC=CC=C3N(CC)C=2C)C2=CC=CC=C2C(=O)O1 HOUWRQXIBSGOHF-UHFFFAOYSA-N 0.000 description 1
- MTMKZABGIQJAEX-UHFFFAOYSA-N 4,4'-sulfonylbis[2-(prop-2-en-1-yl)phenol] Chemical compound C1=C(CC=C)C(O)=CC=C1S(=O)(=O)C1=CC=C(O)C(CC=C)=C1 MTMKZABGIQJAEX-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- ZTILAOCGFRDHBH-UHFFFAOYSA-N 4-(4-propan-2-yloxyphenyl)sulfonylphenol Chemical compound C1=CC(OC(C)C)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 ZTILAOCGFRDHBH-UHFFFAOYSA-N 0.000 description 1
- MOPBWASVAUDDTC-UHFFFAOYSA-N 4-[2-(3,4-dimethylphenyl)ethyl]-1,2-dimethylbenzene Chemical compound C1=C(C)C(C)=CC=C1CCC1=CC=C(C)C(C)=C1 MOPBWASVAUDDTC-UHFFFAOYSA-N 0.000 description 1
- VHLLJTHDWPAQEM-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)-4-methylpentan-2-yl]phenol Chemical compound C=1C=C(O)C=CC=1C(C)(CC(C)C)C1=CC=C(O)C=C1 VHLLJTHDWPAQEM-UHFFFAOYSA-N 0.000 description 1
- PVFQHGDIOXNKIC-UHFFFAOYSA-N 4-[2-[3-[2-(4-hydroxyphenyl)propan-2-yl]phenyl]propan-2-yl]phenol Chemical compound C=1C=CC(C(C)(C)C=2C=CC(O)=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 PVFQHGDIOXNKIC-UHFFFAOYSA-N 0.000 description 1
- PRMDDINQJXOMDC-UHFFFAOYSA-N 4-[4,4-bis(5-cyclohexyl-4-hydroxy-2-methylphenyl)butan-2-yl]-2-cyclohexyl-5-methylphenol Chemical compound C=1C(C2CCCCC2)=C(O)C=C(C)C=1C(C)CC(C=1C(=CC(O)=C(C2CCCCC2)C=1)C)C(C(=CC=1O)C)=CC=1C1CCCCC1 PRMDDINQJXOMDC-UHFFFAOYSA-N 0.000 description 1
- SKVLHBJJOXTLKQ-UHFFFAOYSA-N 7,7-bis[4-(diethylamino)-2-ethoxyphenyl]furo[3,4-b]pyridin-5-one Chemical compound CCOC1=CC(N(CC)CC)=CC=C1C1(C=2C(=CC(=CC=2)N(CC)CC)OCC)C2=NC=CC=C2C(=O)O1 SKVLHBJJOXTLKQ-UHFFFAOYSA-N 0.000 description 1
- VOWWYDCFAISREI-UHFFFAOYSA-N Bisphenol AP Chemical compound C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)C1=CC=CC=C1 VOWWYDCFAISREI-UHFFFAOYSA-N 0.000 description 1
- GIXXQTYGFOHYPT-UHFFFAOYSA-N Bisphenol P Chemical compound C=1C=C(C(C)(C)C=2C=CC(O)=CC=2)C=CC=1C(C)(C)C1=CC=C(O)C=C1 GIXXQTYGFOHYPT-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- IPAJDLMMTVZVPP-UHFFFAOYSA-N Crystal violet lactone Chemical compound C1=CC(N(C)C)=CC=C1C1(C=2C=CC(=CC=2)N(C)C)C2=CC=C(N(C)C)C=C2C(=O)O1 IPAJDLMMTVZVPP-UHFFFAOYSA-N 0.000 description 1
- ORAWFNKFUWGRJG-UHFFFAOYSA-N Docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(N)=O ORAWFNKFUWGRJG-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- CWHJHUCTNPFJAK-UHFFFAOYSA-N [N+](#[C-])N1C(=O)NC=2NC(=O)NC2C1=O.[N+](#[C-])N1C(=O)NC=2NC(=O)NC2C1=O Chemical class [N+](#[C-])N1C(=O)NC=2NC(=O)NC2C1=O.[N+](#[C-])N1C(=O)NC=2NC(=O)NC2C1=O CWHJHUCTNPFJAK-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 150000001541 aziridines Chemical class 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- IWGFEQWCMAADJZ-UHFFFAOYSA-N dibenzyl benzene-1,4-dicarboxylate Chemical compound C=1C=C(C(=O)OCC=2C=CC=CC=2)C=CC=1C(=O)OCC1=CC=CC=C1 IWGFEQWCMAADJZ-UHFFFAOYSA-N 0.000 description 1
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002296 dynamic light scattering Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- MFGZXPGKKJMZIY-UHFFFAOYSA-N ethyl 5-amino-1-(4-sulfamoylphenyl)pyrazole-4-carboxylate Chemical compound NC1=C(C(=O)OCC)C=NN1C1=CC=C(S(N)(=O)=O)C=C1 MFGZXPGKKJMZIY-UHFFFAOYSA-N 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical class CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- JHOKTNSTUVKGJC-UHFFFAOYSA-N n-(hydroxymethyl)octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCO JHOKTNSTUVKGJC-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- WGOROJDSDNILMB-UHFFFAOYSA-N octatriacontanediamide Chemical compound NC(=O)CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC(N)=O WGOROJDSDNILMB-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical class OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- QHDYIMWKSCJTIM-UHFFFAOYSA-N phenyl 1-hydroxynaphthalene-2-carboxylate Chemical compound C1=CC2=CC=CC=C2C(O)=C1C(=O)OC1=CC=CC=C1 QHDYIMWKSCJTIM-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000120 polyethyl acrylate Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 125000003003 spiro group Chemical group 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229940037312 stearamide Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LPEBYPDZMWMCLZ-CVBJKYQLSA-L zinc;(z)-octadec-9-enoate Chemical compound [Zn+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O LPEBYPDZMWMCLZ-CVBJKYQLSA-L 0.000 description 1
Landscapes
- Heat Sensitive Colour Forming Recording (AREA)
Abstract
【解決手段】支持体上に、染料前駆体含有複合微粒子と顕色剤を含有する感熱記録層を有する感熱記録体において、染料前駆体含有複合微粒子が、多価イソシアネート化合物含有重合成分を溶媒とし、染料前駆体を溶質とする溶液を、水性媒体中に乳化分散した後、ポリエチレンイミンの存在下で多価イソシアネート化合物含有重合成分の高分子化反応により得られた複合微粒子であり、多価イソシアネート化合物含有重合成分が、ジシクロヘキシルメタン−4,4’−ジイソシアネート、m−テトラメチルキシリレンジイソシアネート及びヘキサメチレンジイソシアネートのイソシアヌレート体を含むことを特徴とする感熱記録体。
【選択図】 なし
Description
また、各層を形成し終えた後、また全ての層を形成し終えた後の任意の過程でスーパーカレンダーによる平滑化処理を施すこともできる。
〔染料前駆体含有複合微粒子分散液(A液)の調製〕
染料前駆体として3−(N−エチル−N−イソアミルアミノ)−6−メチル−7−アニリノフルオラン13部、3−ジエチルアミノ−6,8−ジメチルフルオラン5部、及び3,3’−ビス(4−ジエチルアミノ−2−エトキシフェニル)−4−アザフタリド5部を、150℃に加熱した多価イソシアネート化合物としてm−テトラメチルキシリレンジイソシアネート〔商品名:TMXDI(登録商標)[META]、日本サイテックインダストリーズ社製〕8部、ヘキサメチレンジイソシアネートのイソシアヌレート体〔商品名:タケネートD−170HN(登録商標)、三井化学ポリウレタン社製〕5部、ジシクロヘキシルメタン−4,4’−ジイソシアネート〔商品名:デスモジュール(登録商標)W、住化バイエルウレタン社製〕6部に溶解し、この溶液をポリビニルアルコール〔商品名:ポバール(登録商標)PVA217EE、クラレ社製〕の10%水溶液90部に徐々に添加し、ホモジナイザー(商品名:T.K.ROBO MICS、特殊機化工業社製)を用いて、回転数8500rpmの攪拌によって8分間乳化分散した。この乳化分散液を50℃に昇温し、硬化促進剤としてポリエチレンイミン〔商品名:エポミン(登録商標)SP−006、日本触媒社製〕の10%水溶液10部を添加し、80℃まで加熱後、6時間の硬化反応を行わせて、平均粒子径0.7μmの染料前駆体含有複合微粒子の分散液(A液)を調製した。なお、前記複合微粒子分散液の固形分濃度は30%であった。
4,4’―シクロヘキシリデンジフェノール20部、部分鹸化ポリビニルアルコールの10%水溶液20部、及び水40部からなる組成物をウルトラビスコミルにて平均粒子径が0.3μmとなるまで粉砕して顕色剤分散液(B液)を得た。
A液30部、B液60部、ポリウレタンアイオノマーを含有する水性媒体中でスチレンモノマー及びブタジエンモノマーを重合して得られたラテックス〔商品名:パテラコール(登録商標)H2020A、DIC社製、固形分濃度41%〕20部、及び水30部からなる組成物を混合して感熱記録層用塗液を得た。
アイオノマー型ウレタン系樹脂ラテックス〔商品名:ハイドラン(登録商標)AP−30F、大日本インキ化学工業社製、固形分濃度20%〕100部、アセトアセチル変性ポリビニルアルコール〔商品名:ゴーセファイマー(登録商標)Z−410、重合度:約2300、鹸化度:約98モル%、日本合成化学工業社製〕の8%水溶液500部、カオリン〔商品名:ULTRA WHITE(登録商標)90、BASF社製〕を平均粒子径が1.6μmとなるように微粒化した60%スラリー50部、平均粒子径2.5μmの焼成カオリン〔商品名:ANSILEX(登録商標)93、BASF社製〕の40%スラリー2部、ステアリン酸アミド(商品名:ハイミクロンL−271、中京油脂社製、固形分濃度25%)26部、ステアリルリン酸エステルカリウム塩(商品名:ウーポール1800、松本油脂製薬社製、固形濃度35%)4部、パーフルオロアルキルエチレンオキシド付加物〔商品名:サーフロン(登録商標)S−145、セイミケミカル社製〕の10%水溶液15部、及び水300部からなる組成物を混合して保護層用塗液を得た。
青色透明なポリエチレンテレフタレートフィルム〔商品名:スカイロール(登録商標)ST96B、厚さ175μm、SKC社製〕の片面上に、支持体側から感熱記録層用塗液、保護層用塗液の順にそれぞれ乾燥後の塗布量が20g/m2、3.5g/m2となるようにメイヤーバーを用いて1層毎に塗布乾燥して感熱記録体を得た。
実施例1のA液調製において、多価イソシアネート化合物の量をm−テトラメチルキシリレンジイソシアネート6部、ヘキサメチレンジイソシアネートのイソシアヌレート体6.5部、ジシクロヘキシルメタン−4,4’−ジイソシアネート6.5部とした以外は、実施例1と同様にして感熱記録体を得た。なお、この時の複合微粒子の平均粒子径は0.7μmであった。
実施例1のA液調製において、多価イソシアネート化合物の量をm−テトラメチルキシリレンジイソシアネート12部、ヘキサメチレンジイソシアネートのイソシアヌレート体1部、ジシクロヘキシルメタン−4,4’−ジイソシアネート6部とした以外は、実施例1と同様にして感熱記録体を得た。なお、この時の複合微粒子の平均粒子径は0.7μmであった。
実施例1のA液調製において、多価イソシアネート化合物の量をm−テトラメチルキシリレンジイソシアネート13部、ヘキサメチレンジイソシアネートのイソシアヌレート体5部、ジシクロヘキシルメタン−4,4’−ジイソシアネート1部とした以外は、実施例1と同様にして感熱記録体を得た。なお、この時の複合微粒子の平均粒子径は0.7μmであった。
実施例1のA液調製において、多価イソシアネート化合物の量をm−テトラメチルキシリレンジイソシアネート19部とし、ヘキサメチレンジイソシアネートのイソシアヌレート体及びジシクロヘキシルメタン−4,4’−ジイソシアネートを用いなかった以外は、実施例1と同様にして感熱記録体を得た。なお、この時の複合微粒子の平均粒子径は0.7μmであった。
実施例1のA液調製において、多価イソシアネート化合物の量をヘキサメチレンジイソシアネートのイソシアヌレート体19部とし、m−テトラメチルキシリレンジイソシアネート及びジシクロヘキシルメタン−4,4’−ジイソシアネートを用いなかった以外は、実施例1と同様にして感熱記録体を得た。なお、この時の複合微粒子の平均粒子径は0.7μmであった。
実施例1のA液調製において、多価イソシアネート化合物の量をジシクロヘキシルメタン−4,4’−ジイソシアネート19部とし、m−テトラメチルキシリレンジイソシアネート及びヘキサメチレンジイソシアネートのイソシアヌレート体を用いなかった以外は、実施例1と同様にして感熱記録体を得た。なお、この時の複合微粒子の平均粒子径は0.7μmであった。
実施例1のA液調製において、多価イソシアネート化合物の量をm−テトラメチルキシリレンジイソシアネート9.5部、ジシクロヘキシルメタン−4,4’−ジイソシアネート9.5部とし、ヘキサメチレンジイソシアネートのイソシアヌレート体を用いなかった以外は、実施例1と同様にして感熱記録体を得た。なお、この時の複合微粒子の平均粒子径は0.7μmであった。
実施例1のA液調製において、多価イソシアネート化合物の量をヘキサメチレンジイソシアネートのイソシアヌレート体9.5部、ジシクロヘキシルメタン−4,4’−ジイソシアネート9.5部とし、m−テトラメチルキシリレンジイソシアネートを用いなかった以外は、実施例1と同様にして感熱記録体を得た。なお、この時の複合微粒子の平均粒子径は0.7μmであった。
デジタルフィルムイメージャー(機種名:UP−DF500、SONY社製)を用いて階調(Step)印字を行い、得られた記録部及び未記録部の濃度をX−Rite濃度計Model301(X−Rite社製)にて測定した。
前記の記録濃度の測定において得られた記録部について、低階調における濃度が高く、高階調との濃度差が十分に保たれているものを、階調再現性を有して記録感度に優れたものと判定した。具体的には、9Stepの濃度が2.0以上のものを○とし、1.0以上2.0未満のものを△とし、1.0未満のものを×とした。また、9Stepと16Stepとの濃度差が1.0以上のものを○とし、0.5以上1.0未満のものを△とし、0.5未満のものを×とした。
各感熱記録体を白紙状態で70℃の環境下で2時間処理した後、未記録部の濃度をマクベス濃度計にて測定し、高温環境下に曝された時の地肌カブリを評価した。同時に目視にて地肌カブリの程度を評価し、問題ないレベルを○と判定し、地肌カブリを認識できるが許容範囲内を△とし、単品で評価した場合でも地肌カブリを認識できるレベルを×とした。
A液の調製において、硬化反応を行なわせた後の発泡量が、硬化促進剤添加前の体積の1.5倍以下を良好と判定して○とし、1.5倍より大きく2倍以下を△とし、2倍より大きいものを×とした。
Claims (3)
- 支持体上に、染料前駆体含有複合微粒子と顕色剤を含有する感熱記録層を有する感熱記録体において、前記染料前駆体含有複合微粒子が、多価イソシアネート化合物含有重合成分を溶媒とし、染料前駆体を溶質とする溶液を、水性媒体中に乳化分散した後、ポリエチレンイミンの存在下で多価イソシアネート化合物含有重合成分の高分子化反応により得られた複合微粒子であり、前記多価イソシアネート化合物含有重合成分が、ジシクロヘキシルメタン−4,4’−ジイソシアネート、m−テトラメチルキシリレンジイソシアネート及びヘキサメチレンジイソシアネートのイソシアヌレート体を含むことを特徴とする感熱記録体。
- 前記多価イソシアネート化合物含有重合成分の合計量に対して、ジシクロヘキシルメタン−4,4’−ジイソシアネートを5〜40質量%、m−テトラメチルキシリレンジイソシアネートを20〜90質量%、及びヘキサメチレンジイソシアネートのイソシアヌレート体を5〜40質量%の割合で含む、請求項1に記載の感熱記録体。
- 前記多価イソシアネート化合物含有重合成分の合計量に対して、ジシクロヘキシルメタン−4,4’−ジイソシアネートを10〜40質量%、m−テトラメチルキシリレンジイソシアネートを20〜80質量%、及びヘキサメチレンジイソシアネートのイソシアヌレート体を10〜40質量%の割合で含む、請求項1に記載の感熱記録体。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009273136A JP5278293B2 (ja) | 2009-12-01 | 2009-12-01 | 感熱記録体 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009273136A JP5278293B2 (ja) | 2009-12-01 | 2009-12-01 | 感熱記録体 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2011115961A true JP2011115961A (ja) | 2011-06-16 |
JP5278293B2 JP5278293B2 (ja) | 2013-09-04 |
Family
ID=44281888
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009273136A Expired - Fee Related JP5278293B2 (ja) | 2009-12-01 | 2009-12-01 | 感熱記録体 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP5278293B2 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2017014927A (ja) * | 2015-06-29 | 2017-01-19 | 株式会社神戸製鋼所 | 圧縮機ユニット |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP7045055B2 (ja) | 2018-03-23 | 2022-03-31 | 株式会社サンセイアールアンドディ | 遊技機 |
JP7045056B2 (ja) | 2018-03-23 | 2022-03-31 | 株式会社サンセイアールアンドディ | 遊技機 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008120740A1 (ja) * | 2007-03-30 | 2008-10-09 | Oji Paper Co., Ltd. | 感熱記録体 |
JP2009255359A (ja) * | 2008-04-16 | 2009-11-05 | Oji Paper Co Ltd | 感熱記録体およびその製造方法 |
-
2009
- 2009-12-01 JP JP2009273136A patent/JP5278293B2/ja not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008120740A1 (ja) * | 2007-03-30 | 2008-10-09 | Oji Paper Co., Ltd. | 感熱記録体 |
JP2009255359A (ja) * | 2008-04-16 | 2009-11-05 | Oji Paper Co Ltd | 感熱記録体およびその製造方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2017014927A (ja) * | 2015-06-29 | 2017-01-19 | 株式会社神戸製鋼所 | 圧縮機ユニット |
Also Published As
Publication number | Publication date |
---|---|
JP5278293B2 (ja) | 2013-09-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5278293B2 (ja) | 感熱記録体 | |
JP5051219B2 (ja) | 感熱記録体及びその製造方法 | |
JP2015121738A (ja) | 偽造判定用封緘ラベル | |
JP4492453B2 (ja) | 多色感熱記録体 | |
JPH09263057A (ja) | 染料前駆体含有樹脂複合微粒子およびこの複合微粒子を含む感熱記録材料 | |
JP6589720B2 (ja) | 感熱記録体 | |
JP5272622B2 (ja) | 多色感熱記録材料 | |
JP2008265114A (ja) | 多色感熱記録体 | |
JP4497016B2 (ja) | 多色感熱記録体 | |
JP5029208B2 (ja) | 感熱記録体 | |
JP2003266951A (ja) | 感熱記録体 | |
JP2005225222A (ja) | 多色感熱記録体 | |
JP2009255359A (ja) | 感熱記録体およびその製造方法 | |
JP5772679B2 (ja) | 多色感熱記録材料 | |
JP6718149B2 (ja) | 感熱記録体 | |
JP4683299B2 (ja) | 2色感熱記録体 | |
JPH1178246A (ja) | 染料前駆体を含有する複合微粒子およびその複合微粒子を用いた感熱記録材料 | |
JP2010149291A (ja) | 感熱記録材料 | |
JP4127181B2 (ja) | 多色感熱記録体 | |
JPH10217617A (ja) | 多色感熱記録材料 | |
JP2000079766A (ja) | 感熱記録材料 | |
JP2004001376A (ja) | 多色感熱記録材料 | |
JPH10100535A (ja) | 感熱記録材料 | |
JP2003094809A (ja) | 感熱記録体 | |
JP2009056643A (ja) | 透明感熱記録体 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20120110 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130411 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20130423 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20130506 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 Ref document number: 5278293 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |