JP2010528126A - 担持メタロセン触媒 - Google Patents

担持メタロセン触媒 Download PDF

Info

Publication number
JP2010528126A
JP2010528126A JP2010508535A JP2010508535A JP2010528126A JP 2010528126 A JP2010528126 A JP 2010528126A JP 2010508535 A JP2010508535 A JP 2010508535A JP 2010508535 A JP2010508535 A JP 2010508535A JP 2010528126 A JP2010528126 A JP 2010528126A
Authority
JP
Japan
Prior art keywords
group
ethylene
substituent
catalyst
propylene copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2010508535A
Other languages
English (en)
Japanese (ja)
Other versions
JP2010528126A5 (enExample
Inventor
ゴーテイアー，ウイリアム
ローシヤー，デイビツド
テイアン，ジユン
ウイリアムズ，ネイサン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fina Technology Inc
Original Assignee
Fina Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Technology Inc filed Critical Fina Technology Inc
Publication of JP2010528126A publication Critical patent/JP2010528126A/ja
Publication of JP2010528126A5 publication Critical patent/JP2010528126A5/ja
Pending legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP2010508535A 2007-05-18 2008-05-13 担持メタロセン触媒 Pending JP2010528126A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/804,483 US20080287619A1 (en) 2007-05-18 2007-05-18 Supported metallocene catalysts
PCT/US2008/063513 WO2008144303A1 (en) 2007-05-18 2008-05-13 Supported metallocene catalysts

Publications (2)

Publication Number Publication Date
JP2010528126A true JP2010528126A (ja) 2010-08-19
JP2010528126A5 JP2010528126A5 (enExample) 2011-06-30

Family

ID=40028164

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2010508535A Pending JP2010528126A (ja) 2007-05-18 2008-05-13 担持メタロセン触媒

Country Status (8)

Country Link
US (1) US20080287619A1 (enExample)
EP (1) EP2155389A4 (enExample)
JP (1) JP2010528126A (enExample)
KR (1) KR20100016614A (enExample)
CN (1) CN101568383B (enExample)
CA (1) CA2677773A1 (enExample)
MX (1) MX2009005467A (enExample)
WO (1) WO2008144303A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8299188B2 (en) * 2007-05-18 2012-10-30 Fina Technology, Inc. Supported metallocene catalysts
TWI555574B (zh) * 2011-03-09 2016-11-01 亞比馬利股份有限公司 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途
CN105658686A (zh) * 2013-06-24 2016-06-08 沙特基础工业公司 基于钛酸化的铬的催化剂以制备高密度聚乙烯

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001027124A1 (en) * 1999-10-08 2001-04-19 Mitsui Chemicals, Inc. Metallocene compound, process for producing metallocene compound, olefin polymerization catalyst, process for producing polyolefin, and polyolefin
WO2004087775A1 (ja) * 2003-03-28 2004-10-14 Mitsui Chemicals, Inc. プロピレン系共重合体、ポリプロピレン組成物およびその用途、ならびに遷移金属化合物、オレフィン重合用触媒
JP2006008983A (ja) * 2004-05-28 2006-01-12 Mitsui Chemicals Inc プロピレン系重合体
JP2006052313A (ja) * 2004-08-11 2006-02-23 Mitsui Chemicals Inc プロピレン系重合体およびシュリンクフィルムへの応用
JP2006057010A (ja) * 2003-08-22 2006-03-02 Mitsui Chemicals Inc プロピレン系ランダム共重合体及びその用途
WO2006025540A1 (ja) * 2004-08-30 2006-03-09 Mitsui Chemicals, Inc. プロピレン系重合体の製造方法
US20060160967A1 (en) * 2004-12-16 2006-07-20 Voskoboynikov Alexander Z Halogen substituted metallocene compounds for olefin polymerization
JP2007524721A (ja) * 2003-04-11 2007-08-30 フイナ・テクノロジー・インコーポレーテツド 担持メタロセン触媒
WO2008014217A2 (en) * 2006-07-25 2008-01-31 Fina Technology, Inc. Fluorenyl catalyst compositions and olefin polymerization process

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5643847A (en) * 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
EP0818475A1 (en) * 1996-07-11 1998-01-14 Fina Research S.A. Syndiotactic/atactic block polyolefins, catalysts and processes for producing the same
US5847059A (en) * 1996-12-20 1998-12-08 Fina Technology, Inc. Catalyst yield from supported metallocene catalysts
EP0881237A1 (en) * 1997-05-26 1998-12-02 Fina Research S.A. Process to produce bimodal polyolefins with metallocene catalysts using two reaction zones
US6090325A (en) * 1997-09-24 2000-07-18 Fina Technology, Inc. Biaxially-oriented metallocene-based polypropylene films
EP0967234A1 (en) * 1998-06-24 1999-12-29 Fina Research S.A. Production of polyethylene
US6515086B1 (en) * 1999-02-19 2003-02-04 Fina Research, S.A. Polyolefin production
US6443095B1 (en) * 2000-12-07 2002-09-03 Mcmahon Linda Live insect bird feeder and method
US6984698B2 (en) * 2001-01-31 2006-01-10 Fina Technology, Inc. Polyethylene films for barrier applications
US6777367B2 (en) * 2001-02-13 2004-08-17 Fina Technology, Inc. Method for the preparation of metallocene catalysts
US6777366B2 (en) * 2001-02-13 2004-08-17 Fina Technology, Inc. Method for the preparation of metallocene catalysts
US20030236365A1 (en) * 2002-06-24 2003-12-25 Fina Technology, Inc. Polyolefin production with a high performance support for a metallocene catalyst system
US6716936B1 (en) * 2002-12-16 2004-04-06 Equistar Chemicals L.P. Cascaded boiling pool slurry reactors for producing bimodal low to medium density polyethylene polymers
EP1493759A1 (en) * 2003-07-04 2005-01-05 Total Petrochemicals Research Feluy Polymerisation process
US7034157B2 (en) * 2003-10-23 2006-04-25 Fina Technology, Inc. Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins
US20050234198A1 (en) * 2004-04-20 2005-10-20 Fina Technology, Inc. Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system
US7220806B2 (en) * 2005-04-29 2007-05-22 Fina Technology, Inc. Process for increasing ethylene incorporation into random copolymers
CN101511591B (zh) * 2006-09-05 2012-07-25 普瑞曼聚合物株式会社 多层拉伸中空体
JP5967856B2 (ja) * 2006-09-12 2016-08-10 三井化学株式会社 ポリプロピレン樹脂およびブロー容器

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001027124A1 (en) * 1999-10-08 2001-04-19 Mitsui Chemicals, Inc. Metallocene compound, process for producing metallocene compound, olefin polymerization catalyst, process for producing polyolefin, and polyolefin
WO2004087775A1 (ja) * 2003-03-28 2004-10-14 Mitsui Chemicals, Inc. プロピレン系共重合体、ポリプロピレン組成物およびその用途、ならびに遷移金属化合物、オレフィン重合用触媒
JP2007524721A (ja) * 2003-04-11 2007-08-30 フイナ・テクノロジー・インコーポレーテツド 担持メタロセン触媒
JP2006057010A (ja) * 2003-08-22 2006-03-02 Mitsui Chemicals Inc プロピレン系ランダム共重合体及びその用途
JP2006008983A (ja) * 2004-05-28 2006-01-12 Mitsui Chemicals Inc プロピレン系重合体
JP2006052313A (ja) * 2004-08-11 2006-02-23 Mitsui Chemicals Inc プロピレン系重合体およびシュリンクフィルムへの応用
WO2006025540A1 (ja) * 2004-08-30 2006-03-09 Mitsui Chemicals, Inc. プロピレン系重合体の製造方法
US20060160967A1 (en) * 2004-12-16 2006-07-20 Voskoboynikov Alexander Z Halogen substituted metallocene compounds for olefin polymerization
WO2008014217A2 (en) * 2006-07-25 2008-01-31 Fina Technology, Inc. Fluorenyl catalyst compositions and olefin polymerization process

Also Published As

Publication number Publication date
US20080287619A1 (en) 2008-11-20
KR20100016614A (ko) 2010-02-12
CA2677773A1 (en) 2008-11-27
CN101568383A (zh) 2009-10-28
MX2009005467A (es) 2009-06-02
CN101568383B (zh) 2013-03-20
EP2155389A4 (en) 2012-06-27
EP2155389A1 (en) 2010-02-24
WO2008144303A1 (en) 2008-11-27

Similar Documents

Publication Publication Date Title
US8299188B2 (en) Supported metallocene catalysts
JP5622841B2 (ja) オレフィン系重合体およびそれを含む繊維
US6730751B2 (en) Polymerization of polyethylene having high molecular weight
JP2007524721A (ja) 担持メタロセン触媒
JPH06510801A (ja) アミド遷移金属化合物及びアイソタクチックポリプロピレン製造用触媒系
CN103842394B (zh) 用于制备超高分子量聚乙烯(uhmwpe)的催化剂
JPWO1999009076A1 (ja) 多分散性プロピレン重合体およびその製造方法
EP0979247B1 (en) Process for producing isotactic polypropylenes in condensed phase using titanocenes
CN116438211A (zh) 生产卤基或叔胺官能化聚烯烃的溶液法
US8524627B2 (en) Activating supports with controlled distribution of OH groups
JP2010528126A (ja) 担持メタロセン触媒
WO2017111513A1 (ko) 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조방법
CN111556878B (zh) 负载型茂金属催化剂和使用该催化剂制备聚丙烯的方法
EP1574525A1 (en) Catalyst composition for polymerization of olefins and polymerization process using the same
JP6174682B2 (ja) ポリオレフィン重合方法、それによって製造した半結晶性エチレン系ポリマー、およびそのポリマーから製造した物品
CN111212845B (zh) 聚烯烃催化剂及利用它的聚烯烃制造方法
US6878787B2 (en) Polyamide supported metallocene catalysts
JP5129129B2 (ja) フルオレニルリガンドをベースにしたエチレンとα−オレフィンとの重合触媒系
US7125937B2 (en) Polyorganosilsesquioxane supported metallocene catalysts
JP2005524742A (ja) ポリオレフィンを製造するための混合触媒組成物
JP2008121030A (ja) 多分散性プロピレン重合体およびその製造方法
Hanson New catalysts for olefin polymerization

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110506

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20110506

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20130605

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130618

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20130912

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20131008

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20140206

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20140214

A912 Re-examination (zenchi) completed and case transferred to appeal board

Free format text: JAPANESE INTERMEDIATE CODE: A912

Effective date: 20140314