JP2010526206A - 亜鉛表面の金属被覆前処理 - Google Patents
亜鉛表面の金属被覆前処理 Download PDFInfo
- Publication number
- JP2010526206A JP2010526206A JP2010504740A JP2010504740A JP2010526206A JP 2010526206 A JP2010526206 A JP 2010526206A JP 2010504740 A JP2010504740 A JP 2010504740A JP 2010504740 A JP2010504740 A JP 2010504740A JP 2010526206 A JP2010526206 A JP 2010526206A
- Authority
- JP
- Japan
- Prior art keywords
- metal
- less
- coating
- treatment agent
- cation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 144
- 239000002184 metal Substances 0.000 title claims abstract description 144
- 239000011248 coating agent Substances 0.000 title claims abstract description 106
- 238000000576 coating method Methods 0.000 title claims abstract description 76
- 239000011701 zinc Substances 0.000 title claims abstract description 71
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 61
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 57
- 238000000034 method Methods 0.000 claims abstract description 140
- 238000011282 treatment Methods 0.000 claims abstract description 99
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 55
- 239000010959 steel Substances 0.000 claims abstract description 55
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 48
- 239000011247 coating layer Substances 0.000 claims abstract description 43
- 239000000463 material Substances 0.000 claims abstract description 29
- 229910052742 iron Inorganic materials 0.000 claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 claims abstract description 22
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 6
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 5
- 239000010941 cobalt Substances 0.000 claims abstract description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 5
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000010276 construction Methods 0.000 claims abstract description 4
- 239000011133 lead Substances 0.000 claims abstract description 4
- 239000011733 molybdenum Substances 0.000 claims abstract description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000010937 tungsten Substances 0.000 claims abstract description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 66
- 150000001875 compounds Chemical class 0.000 claims description 49
- 239000003973 paint Substances 0.000 claims description 42
- 238000006243 chemical reaction Methods 0.000 claims description 40
- 239000010410 layer Substances 0.000 claims description 35
- 150000001768 cations Chemical class 0.000 claims description 31
- 239000000126 substance Substances 0.000 claims description 31
- 229920000642 polymer Polymers 0.000 claims description 20
- 230000008569 process Effects 0.000 claims description 15
- 239000008139 complexing agent Substances 0.000 claims description 14
- -1 tin cation Chemical class 0.000 claims description 14
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 13
- CWYNVVGOOAEACU-UHFFFAOYSA-N iron (II) ion Substances [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 238000012545 processing Methods 0.000 claims description 10
- 238000002161 passivation Methods 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003446 ligand Substances 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 230000001603 reducing effect Effects 0.000 claims description 4
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 3
- 239000012736 aqueous medium Substances 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 2
- IDCPFAYURAQKDZ-UHFFFAOYSA-N 1-nitroguanidine Chemical compound NC(=N)N[N+]([O-])=O IDCPFAYURAQKDZ-UHFFFAOYSA-N 0.000 claims description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 claims description 2
- XNCSCQSQSGDGES-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]propyl-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)C(C)CN(CC(O)=O)CC(O)=O XNCSCQSQSGDGES-UHFFFAOYSA-N 0.000 claims description 2
- DMQQXDPCRUGSQB-UHFFFAOYSA-N 2-[3-[bis(carboxymethyl)amino]propyl-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)CCCN(CC(O)=O)CC(O)=O DMQQXDPCRUGSQB-UHFFFAOYSA-N 0.000 claims description 2
- XLLXMBCBJGATSP-UHFFFAOYSA-N 2-phenylethenol Chemical compound OC=CC1=CC=CC=C1 XLLXMBCBJGATSP-UHFFFAOYSA-N 0.000 claims description 2
- SDOFMBGMRVAJNF-UHFFFAOYSA-N 6-aminohexane-1,2,3,4,5-pentol Chemical compound NCC(O)C(O)C(O)C(O)CO SDOFMBGMRVAJNF-UHFFFAOYSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 2
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 2
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 2
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 235000010323 ascorbic acid Nutrition 0.000 claims description 2
- 229960005070 ascorbic acid Drugs 0.000 claims description 2
- 239000011668 ascorbic acid Substances 0.000 claims description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 2
- FATUQANACHZLRT-KMRXSBRUSA-L calcium glucoheptonate Chemical compound [Ca+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)C([O-])=O FATUQANACHZLRT-KMRXSBRUSA-L 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 229960001484 edetic acid Drugs 0.000 claims description 2
- 239000000174 gluconic acid Substances 0.000 claims description 2
- 235000012208 gluconic acid Nutrition 0.000 claims description 2
- 239000008103 glucose Substances 0.000 claims description 2
- JESXATFQYMPTNL-UHFFFAOYSA-N mono-hydroxyphenyl-ethylene Natural products OC1=CC=CC=C1C=C JESXATFQYMPTNL-UHFFFAOYSA-N 0.000 claims description 2
- 229940048195 n-(hydroxyethyl)ethylenediaminetriacetic acid Drugs 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- 229960003330 pentetic acid Drugs 0.000 claims description 2
- 125000004437 phosphorous atom Chemical group 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- WSHYKIAQCMIPTB-UHFFFAOYSA-M potassium;2-oxo-3-(3-oxo-1-phenylbutyl)chromen-4-olate Chemical compound [K+].[O-]C=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 WSHYKIAQCMIPTB-UHFFFAOYSA-M 0.000 claims description 2
- 239000000600 sorbitol Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 235000002906 tartaric acid Nutrition 0.000 claims description 2
- 239000011975 tartaric acid Substances 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims 2
- 239000002131 composite material Substances 0.000 claims 1
- 150000004715 keto acids Chemical class 0.000 claims 1
- 238000004381 surface treatment Methods 0.000 abstract description 5
- 239000011135 tin Substances 0.000 abstract description 2
- 239000000049 pigment Substances 0.000 description 55
- 238000005260 corrosion Methods 0.000 description 28
- 230000007797 corrosion Effects 0.000 description 26
- 239000000203 mixture Substances 0.000 description 26
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 22
- 229920001228 polyisocyanate Polymers 0.000 description 19
- 239000005056 polyisocyanate Substances 0.000 description 19
- 239000011347 resin Substances 0.000 description 17
- 229920005989 resin Polymers 0.000 description 17
- 239000000243 solution Substances 0.000 description 17
- 238000001465 metallisation Methods 0.000 description 15
- 125000001931 aliphatic group Chemical group 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- 229910001335 Galvanized steel Inorganic materials 0.000 description 11
- 238000005520 cutting process Methods 0.000 description 11
- 239000008397 galvanized steel Substances 0.000 description 11
- 239000010439 graphite Substances 0.000 description 11
- 229910002804 graphite Inorganic materials 0.000 description 11
- 238000002203 pretreatment Methods 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 239000000758 substrate Substances 0.000 description 10
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 9
- 230000000694 effects Effects 0.000 description 9
- 229920000193 polymethacrylate Polymers 0.000 description 8
- 239000006229 carbon black Substances 0.000 description 7
- 238000007739 conversion coating Methods 0.000 description 7
- 229920000728 polyester Polymers 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 6
- 239000011651 chromium Substances 0.000 description 6
- 230000007547 defect Effects 0.000 description 6
- 238000003618 dip coating Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 230000000536 complexating effect Effects 0.000 description 5
- 230000032798 delamination Effects 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 239000007769 metal material Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 229910052726 zirconium Inorganic materials 0.000 description 5
- 229910021607 Silver chloride Inorganic materials 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 230000004888 barrier function Effects 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- 239000002981 blocking agent Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 238000000151 deposition Methods 0.000 description 4
- 230000001050 lubricating effect Effects 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 238000007747 plating Methods 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229930185605 Bisphenol Natural products 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229920001665 Poly-4-vinylphenol Polymers 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 230000000739 chaotic effect Effects 0.000 description 3
- 239000011162 core material Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 229940043279 diisopropylamine Drugs 0.000 description 3
- 229910052735 hafnium Inorganic materials 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000005554 pickling Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 238000004876 x-ray fluorescence Methods 0.000 description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-REOHCLBHSA-N L-lactic acid Chemical compound C[C@H](O)C(O)=O JVTAAEKCZFNVCJ-REOHCLBHSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 238000007259 addition reaction Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- TVZISJTYELEYPI-UHFFFAOYSA-N hypodiphosphoric acid Chemical compound OP(O)(=O)P(O)(O)=O TVZISJTYELEYPI-UHFFFAOYSA-N 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000003791 organic solvent mixture Substances 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- WHIVNJATOVLWBW-PLNGDYQASA-N (nz)-n-butan-2-ylidenehydroxylamine Chemical compound CC\C(C)=N/O WHIVNJATOVLWBW-PLNGDYQASA-N 0.000 description 1
- MSWZFWKMSRAUBD-IVMDWMLBSA-N 2-amino-2-deoxy-D-glucopyranose Chemical compound N[C@H]1C(O)O[C@H](CO)[C@@H](O)[C@@H]1O MSWZFWKMSRAUBD-IVMDWMLBSA-N 0.000 description 1
- SDXAWLJRERMRKF-UHFFFAOYSA-N 3,5-dimethyl-1h-pyrazole Chemical compound CC=1C=C(C)NN=1 SDXAWLJRERMRKF-UHFFFAOYSA-N 0.000 description 1
- CCTFMNIEFHGTDU-UHFFFAOYSA-N 3-methoxypropyl acetate Chemical compound COCCCOC(C)=O CCTFMNIEFHGTDU-UHFFFAOYSA-N 0.000 description 1
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical class [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 description 1
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 description 1
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- IYXGSMUGOJNHAZ-UHFFFAOYSA-N Ethyl malonate Chemical compound CCOC(=O)CC(=O)OCC IYXGSMUGOJNHAZ-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- DKKCQDROTDCQOR-UHFFFAOYSA-L Ferrous lactate Chemical compound [Fe+2].CC(O)C([O-])=O.CC(O)C([O-])=O DKKCQDROTDCQOR-UHFFFAOYSA-L 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000002156 adsorbate Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- MSWZFWKMSRAUBD-UHFFFAOYSA-N beta-D-galactosamine Natural products NC1C(O)OC(CO)C(O)C1O MSWZFWKMSRAUBD-UHFFFAOYSA-N 0.000 description 1
- QXDMQSPYEZFLGF-UHFFFAOYSA-L calcium oxalate Chemical compound [Ca+2].[O-]C(=O)C([O-])=O QXDMQSPYEZFLGF-UHFFFAOYSA-L 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000004210 cathodic protection Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000002243 cyclohexanonyl group Chemical group *C1(*)C(=O)C(*)(*)C(*)(*)C(*)(*)C1(*)* 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexyloxide Natural products O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000002999 depolarising effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- XTDYIOOONNVFMA-UHFFFAOYSA-N dimethyl pentanedioate Chemical group COC(=O)CCCC(=O)OC XTDYIOOONNVFMA-UHFFFAOYSA-N 0.000 description 1
- 239000001177 diphosphate Substances 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- XQRLCLUYWUNEEH-UHFFFAOYSA-N diphosphonic acid Chemical compound OP(=O)OP(O)=O XQRLCLUYWUNEEH-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000004222 ferrous gluconate Substances 0.000 description 1
- 235000013924 ferrous gluconate Nutrition 0.000 description 1
- 235000013925 ferrous lactate Nutrition 0.000 description 1
- 239000004225 ferrous lactate Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 229960002442 glucosamine Drugs 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 description 1
- NFMHSPWHNQRFNR-UHFFFAOYSA-N hyponitrous acid Chemical compound ON=NO NFMHSPWHNQRFNR-UHFFFAOYSA-N 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- VRIVJOXICYMTAG-IYEMJOQQSA-L iron(ii) gluconate Chemical compound [Fe+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O VRIVJOXICYMTAG-IYEMJOQQSA-L 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N methyl monoether Natural products COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- ICYJJTNLBFMCOZ-UHFFFAOYSA-J molybdenum(4+);disulfate Chemical compound [Mo+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ICYJJTNLBFMCOZ-UHFFFAOYSA-J 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910000349 titanium oxysulfate Inorganic materials 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/54—Contact plating, i.e. electroless electrochemical plating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/021—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material including at least one metal alloy layer
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
- C23C28/025—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only with at least one zinc-based layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12785—Group IIB metal-base component
- Y10T428/12792—Zn-base component
- Y10T428/12799—Next to Fe-base component [e.g., galvanized]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemical Treatment Of Metals (AREA)
- Paints Or Removers (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Coating With Molten Metal (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Chemically Coating (AREA)
Abstract
【選択図】図1
Description
Eredox(単位:ボルト(V)):Ag/AgCl/1M KCl//metal(A)/M(1)
上記式中 Ag/AgCl/1M KCl=0.2368V
但し、標準水素電極(SHE)に対比
M(1)は金属(A)カチオン及び/又は化合物を含む本発明の処理剤
(A)を示す。
EZn(単位:ボルト):Ag/AgCl/1M KCl//Zn/M(2)
Zn/M(2)//金属(A)/M(1)
上記式においてM(1)は金属(A)のカチオン及び/又は化合物を含む初期剤(1)を表し、M(2)は、金属(A)のカチオン及び/又は化合物を含まないということのみでM(1)と異なる処理剤(2)を表す。
Me0→Men++ne-
に基づくものである。
x−(N−R1−N−R2−アミノメチル)−4−ヒドロキシスチレンモノマー単位
を含む水溶性及び/又は水分散性重合体錯化剤であり、この錯化剤において、芳香族環上における置換位置xは、x=2,3,5又は6でありR1は炭素原子数が4以下のアルキル基であり、またR2は一般実験式:H(HOH)mCH2−の置換基を表し、前記式中の、ヒドロキシメチレン基の数mは3以上5以下である。このような錯化性重合体化合物としては、ポリ(5−ビニル−2−ヒドロキシ−N−ベンジル−N−グルカミン)が、その顕著な錯化性により特に好まれている。
i)必要により前記金属の表面を清浄化/グリース除去し、
ii)本発明方法に従って水性処理剤(1)をもって前処理して金属被覆し、
iii)必要によりすすぎ洗い及び/又は乾燥工程を施し、
iv)6価クロム不含有化成処理を施す。但し、この化成処理において、表面積m2当り0.05乃至3.5mmolの金属Mを含む化成被膜層を形成し、前記金属Mは、前記化成溶液の不可欠成分を構成するものであって、前記金属MはCr(III),B,Si,Ti,Zr及びHfから選ばれる。
を含む方法(IIa)に係るものである。
a)ヒドロキシル基含有ポリエーテルとして、ビスフェノール−エピクロロヒドリン重縮合生成物を主成分として含むエポキシ樹脂、
b)ブロックされた脂肪族ポリイソシアネート、
c)ブロックされていない脂肪族ポリイソシアネート、及び
d)ヒドロキシル基含有ポリエステル及びヒドロキシル基含有ポリ(メタ)アクリレートから選ばれた少なくとも1種の反応成分、
を含むものである。
a):b)=1:08乃至1:1.3
及び
c):d)=1:1.4乃至1:2.3
で含有する。
a):d)=1:2乃至1:6(好ましくは1:3乃至1:5)
及び
b):c)=1:0.5乃至1:5(好ましくは1:1乃至1:3)
をなして用いられる。
前記被覆剤(1)は、好ましくは成分a)乃至b)に添加された1種の導電性顔料又は複数種の導電性顔料の混合物を含有する。これらの顔料はカーボンブラック及び黒鉛と同様の、比較的低い密度を有するものであってもよく、或は金属鎖と同様の比較的高い密度を有するものであってもよい。前記被覆剤(1)中の前記導電性顔料の絶対含有率はその密度に依存する。その理由は、導電性顔料の効果は、硬化された被覆層内における導電性顔料の質量含有率の方に、導電性顔料の体積含有率よりも低く依存するということにある。
i)必要により原料材の表面を清浄化/油脂分除去し、
ii)本発明に従う水性処理剤(1)によって、金属被覆前処理し
iii)必要によりすすぎ洗い及び/又は乾燥工程を施し、
iv)クロム(VI)非含有化成処理を施して、表面積m2当り0.01乃至0.7mmolの金属Mを含む化成被膜層を形成し、但し金属Mは、化成処理液の不可欠成分を構成し、この金属MはCr(III),B,Si,Ti,Zr及びHfから選ばれ、
v)必要によりすすぎ洗い及び/又は乾燥工程を施し、
vi)前述の記載事項に従う被覆剤(1)を、被覆し、そして、120乃至260℃との好ましくは150乃至170℃の温度範囲において硬化する。
ことから構成される。
実施態様
0.15モル/リットル H3PO2
0.033モル/リットル 乳酸
#: Fe(II)はFeSO4・7H2Oを表す
本発明方法(III)を、下記に詳述するように実施する。
(i)電気亜鉛めっきされた鋼板(ZE)を、アルカリ性洗浄剤(Ridoline(商標)C72,Ridoline(商標)B40;本願の出願人による浸漬及びスプレー洗浄製品)を用いて脱脂する。
(ii)金属被覆(鉄被覆)前処理を、50℃の水性媒体温度及び2.5のpH値において、t=2秒間(B1)及びt=5秒間(B2)の接触時間で施す。但し、この場合処理剤(1)は下記の構成を有している。
B1: 27.8g/リットルのFeSO4・7H2O
B2: 13.9g/リットルのFeSO4・7H2O
9.9g/リットルのH3PO2
3.0g/リットルの乳酸
(iii)前記前処理された鋼板を水道水中に浸漬することによってすすぎ洗いする工程。
(iv)主成分としてリン酸、リン酸マンガン、H2TiF6及びアミノメチル−置換ポリビニルフェノール(本願の出願人が3年販のGranodin(商標)1445T)を含む市販の前処理溶液を、ケムコーター(ローラー塗布法)を用いて前記金属表面に塗布する。これに80℃において乾燥を施し、得られたチタン含有被覆層をX−線蛍光分析法により測定したところその含有量は10乃至15mg/m2の間にあった。
(v)前記前処理された鋼板を水道水中に浸漬して、すすぎ洗いする工程。
(vi)ドイツ特許出願DE102007001654D(その実施例1参照)の実施例部に記載された組成に基いて、導電性顔料とに、黒鉛を含む市販の被覆剤(1)を、ケムコーターを用いて、前記前処理された鋼板に塗布し、乾燥器内において、160℃の基材温度に加熱して硬化させる。この被覆剤の塗布によって、1.8μmの厚さを有する乾燥被膜層が得られる。
本発明方法(III)を改変して、実施例B1の工程(ii)、すなわち、金属被覆前処理を省略した。
本発明方法(III)を変更して、実施例B1の工程(ii)の代りに、本出願人の市販製品(Granodine(商標)1303)によるアルカリ性不動態化前処理を、未審査ドイツ特許出願DE19733972(その表1、実施例1参照)に記載されている硝酸鉄(III)を主成分とする組成に従って施した。
実施例B1において、本出願人による市販のアルカリ性洗浄系(Ridoline(商標)1565/Ridosol(商標)1237)を用いて脱脂した後、得られた鋼板を市販活性化処理溶液(Fixodine(商標)9112)中において活性化し、工程(vi)に類似の塗料系により被覆される前に三室構造リン酸塩処理浴中において、本出願人市販のgranodine(商標)958Aを用いて不動態化する。
750ppmZnを含む量のH2ZrF6、
20ppmCuを含む量のCu(NO3)2、
10ppmSiを含む量のSiO2、及び
200ppmZnを含むZn(NO3)2
を含む酸性水性組成物中において、pH値4、接触時間90秒間、温度20℃に於て実施される(図1、方法IIa)。脱イオン水による別のすすぎ洗いの後に、電着被膜剤(CathoGuard500)を層厚さ20μmに塗布し、このようにして被覆された鋼板を、空気循環オーブン中において180℃において30分間硬化処理し、その後に、Clemenによる引っかきテスト用具を使用して、鋼基材の、鋼表面の中央部分に引っかききずをつける。表3は、本実験において測定されたように、VDA気象変更テストによるひっかききず上において得られた腐食値(塗料の真下において測定)を示す。
# pH値をアンモニア溶液又は硫酸により調整した。
Z 溶融浸漬亜鉛めっき鋼材
ZE 電気亜鉛めっき鋼材
Claims (25)
- 亜鉛めっき又は亜鉛合金めっきされた鋼材の表面を、金属(A)のカチオン及び/又は化合物を含有する、pH9以下の水性処理剤(1)に接触させることを含む、亜鉛めっき又は亜鉛合金めっき鋼材表面を金属被覆前処理する方法であって、
所定の処理温度で、かつ所定濃度の金属(A)のカチオン及び/又は化合物を含有する前記水性処理剤(1)中において、前記金属(A)の金属電極で、測定された酸化還元電位Eredoxが、金属(A)のいかなるカチオン及び/又は化合物も含まない点のみにおいて、前記水性処理剤(1)とは異なる水性処理剤(2)に接触している前記亜鉛めっき又は亜鉛合金めっき鋼材表面の電極電位Eznよりも貴な値を示すことを特徴とする、亜鉛めっき又は亜鉛合金めっき鋼材表面を金属被覆前処理する方法。 - 前記水性処理剤(1)中の前記金属(A)のカチオン及び/又は化合物の酸化還元電位Eredoxが、前記水性処理剤(2)と接触している亜鉛めっき又は亜鉛合金めっきされた鋼材表面の電極電位Eznに対して、少なくとも+50mVだけ、好ましくは少なくとも+100mVだけ、より好ましくは、少なくとも+300mVだけ、但し、最高+800mVまで、より貴な値を示す、請求項1に記載の方法。
- 前記金属(A)の、カチオン及び/又は化合物の前記濃度が、少なくとも0.001M、好ましくは、少なくとも0.01M、但し、0.2M以下、好ましくは0.1M以下である、請求項1又は2に記載の方法。
- 前記金属(A)のカチオン及び/又は化合物が鉄、モリブデン、タングステン、コバルト、ニッケル、鉛、及び/又は錫のカチオン及び/又は化合物から選ばれる、請求項1乃至3のいずれか1項に記載の方法。
- 前記金属(A)のカチオン及び/又は化合物として、鉄(II)イオン及び/又は鉄(II)化合物が用いられる、請求項4に記載の方法。
- 前記水性処理剤のpH値が、2以上かつ6以下、好ましくは4以下である、請求項5に記載の方法。
- 前記水性処理剤(1)が、さらに、酸素及び/又は窒素配位子を有するキレート性錯体生成剤を含む、請求項5又は6に記載の方法。
- 前記キレート性錯体生成剤がトリエタノールアミン、ジエタノールアミン、モノエタノールアミン、モノイソプロパノールアミン、アミノエチルエタノールアミン、1−アミノ−2,3,4,5,6−ペンタヒドロキシヘキサン、N−(ヒドロキシエチル)エチレンジアミン−三酢酸、エチレンジアミン−四酢酸、ジエチレントリアミン−五酢酸、1,2−ジアミノプロパン−四酢酸、1,3−ジアミノプロパン−四酢酸、酒石酸、乳酸、ムチン酸、グルコン酸及び/又はグルコヘプトン酸、並びに前記酸の塩及び立体異性体と、さらにまた、ソルビトール、グルコース及びグルカミン、並びにこれらの立体異性体から選ばれる、請求項7に記載の方法。
- 前記キレート性錯体生成剤として、x−(N−R1−N−R2−アミノメチル)−4−ヒドロキシスチレンモノマー単位を含む水溶性及び/又は水分散性ポリマー化合物が用いられ、前記モノマー単位の化学式において、その芳香族環上の置換基位置xは、2,3,5又は6位であり、R1は4個以下の炭素原子を有するアルキル基を表し、R2は一般実験式:H(CHOH)mCH2−の置換基を表し、mは3以上5以下のヒドロキシメチレン基数を表し、前記ポリマー化合物は好ましくはポリ(5−ビニル−2−ヒドロキシ−N−ベンジル−N−グルカミン)である、請求項7に記載の方法。
- 前記キレート性錯体生成剤のモル量の、前記金属(A)のカチオン及び/又は化合物の濃度に対するモル比が5:1以下、好ましくは2:1以下で、しかし1:5以上である、請求項8に記載の方法。
- 前記水溶性及び/又は水分散性ポリマー化合物のモノマー単位の濃度として定義された前記キレート性錯体生成剤のモル量の、前記金属(A)のカチオン及び/又は化合物の濃度に対するモル比が、5:1以下、好ましくは2:1以下で、しかし、1:5以上である、請求項9に記載の方法。
- 前記金属(A)のカチオン及び/又は化合物として、酸化段階+II及び/又は+IVにある錫のカチオン及び/又は化合物が用いられる、請求項4に記載の方法。
- 前記水性処理剤のpH値が4以上でかつ8以下、好ましくは6以下である、請求項12に記載の方法。
- 前記水性処理剤がさらに、りん又は窒素のオキソ酸及びその塩から選ばれた促進剤を含み、但し前記オキソ酸において少なくとも1個のりん原子又は窒素原子が、中間酸化段階にある、請求項1乃至13のいずれか1項に記載の方法。
- 前記水性処理剤が、ヒドラジン、ヒドロキシルアミン、ニトログアニジン、N−メチルモルホリンN−オキサイド、グルコヘプトナート、アスコルビン酸及び還元糖から選ばれた促進剤をさらに含む、請求項1乃至13のいずれか1項に記載の方法。
- 前記促進剤の、前記金属(A)のカチオン及び/又は化合物の濃度に対するモル比が、2:1以下であり、好ましくは1:1以下で、しかし、1:5以上である、請求項14又は15に記載の方法。
- 前記水性処理剤が、50ppm以下の、好ましくは10ppm以下で、しかし、0.1ppm以上の銅(II)カチオンをさらに含む、請求項1乃至16のいずれか1項に記載の方法。
- 前記水性処理剤が、界面活性剤をさらに含む、請求項1乃至17のいずれか1項に記載の方法。
- 前記亜鉛めっき又は亜鉛合金めっきされた鋼材表面を、前記水性処理剤に、1秒間以上、しかし、30秒間以下、好ましくは10秒間以下接触させる、請求項1乃至18のいずれか1項に記載の方法。
- 前記亜鉛めっき又は亜鉛合金めっきされた鋼材表面を、前記水性処理剤に接触させることにより、金属(A)による金属被覆層が、1mg/m2以上、但し100mg/m2以下の、好ましくは50mg/m2以下の被覆層量をもって得られる、請求項19に記載の方法。
- 前記亜鉛めっき又は亜鉛合金めっき鋼材表面に、中間洗浄及び/又は乾燥工程を施し、又は施さずに、これを水性媒体に接触させた後、金属被覆前処理された亜鉛めっき又は亜鉛合金めっき鋼材表面に、不動態化処理を施す、請求項1乃至19のいずれか1項に記載の方法。
- 追加の層、特に有機塗料層又は塗料複合層を塗布するための追加加工工程が施される、請求項21に記載の方法。
- 請求項1乃至20のいずれか1項に記載の方法に従って金属被覆された亜鉛めっき又は亜鉛合金めっき鋼材表面を、少なくとも部分的に含む金属構造部材。
- 追加被覆層、特に化成処理層及び/又は塗料層が塗布されている、請求項23に記載の金属構造部材。
- 自動車製造における車体の製造、船舶製造、建設工業、及び、白物家電製品の製造における、請求項23又は24に記載の金属構造部材の使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007021364.8 | 2007-05-04 | ||
DE102007021364A DE102007021364A1 (de) | 2007-05-04 | 2007-05-04 | Metallisierende Vorbehandlung von Zinkoberflächen |
PCT/EP2008/055308 WO2008135478A2 (de) | 2007-05-04 | 2008-04-30 | Metallisierende vorbehandlung von zinkoberflächen |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015224587A Division JP2016074985A (ja) | 2007-05-04 | 2015-11-17 | 亜鉛表面の金属被覆前処理 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2010526206A true JP2010526206A (ja) | 2010-07-29 |
JP5917802B2 JP5917802B2 (ja) | 2016-05-18 |
Family
ID=39791281
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010504740A Expired - Fee Related JP5917802B2 (ja) | 2007-05-04 | 2008-04-30 | 亜鉛表面の金属被覆前処理 |
JP2015224587A Pending JP2016074985A (ja) | 2007-05-04 | 2015-11-17 | 亜鉛表面の金属被覆前処理 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015224587A Pending JP2016074985A (ja) | 2007-05-04 | 2015-11-17 | 亜鉛表面の金属被覆前処理 |
Country Status (17)
Country | Link |
---|---|
US (1) | US8293334B2 (ja) |
EP (2) | EP2292808B1 (ja) |
JP (2) | JP5917802B2 (ja) |
KR (1) | KR20100028542A (ja) |
CN (1) | CN101675181B (ja) |
AU (1) | AU2008248694B2 (ja) |
BR (1) | BRPI0811537A2 (ja) |
CA (1) | CA2686380C (ja) |
DE (1) | DE102007021364A1 (ja) |
ES (2) | ES2589380T3 (ja) |
HU (2) | HUE030515T2 (ja) |
MX (1) | MX2009011876A (ja) |
PL (2) | PL2292808T3 (ja) |
PT (2) | PT2145031E (ja) |
RU (1) | RU2482220C2 (ja) |
WO (1) | WO2008135478A2 (ja) |
ZA (1) | ZA200907724B (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015510550A (ja) * | 2012-02-24 | 2015-04-09 | 日本パーカライジング株式会社 | 不動態化工程前の亜鉛表面の前処理 |
US11987887B2 (en) | 2019-07-29 | 2024-05-21 | Ewald Dörken Ag | Method for passivating metallic substances |
KR102690190B1 (ko) * | 2019-07-29 | 2024-08-01 | 에발트 되르켄 아.게. | 금속성 기재의 부동태화 방법 |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007021364A1 (de) * | 2007-05-04 | 2008-11-06 | Henkel Ag & Co. Kgaa | Metallisierende Vorbehandlung von Zinkoberflächen |
US9574093B2 (en) | 2007-09-28 | 2017-02-21 | Ppg Industries Ohio, Inc. | Methods for coating a metal substrate and related coated metal substrates |
US9234292B2 (en) * | 2009-11-18 | 2016-01-12 | Jx Nippon Mining & Metals Corporation | Nickel-iron alloy plating solution |
DE102009047522A1 (de) * | 2009-12-04 | 2011-06-09 | Henkel Ag & Co. Kgaa | Mehrstufiges Vorbehandlungsverfahren für metallische Bauteile mit Zink- und Eisenoberflächen |
DE102010001686A1 (de) * | 2010-02-09 | 2011-08-11 | Henkel AG & Co. KGaA, 40589 | Zusammensetzung für die alkalische Passivierung von Zinkoberflächen |
KR101262497B1 (ko) * | 2011-03-28 | 2013-05-08 | 주식회사 노루코일코팅 | 강판의 흑변 방지용 피막 형성 조성물 및 상기 조성물에 의해 피막이 형성된 강판 및 피막 형성방법 |
DE102011078258A1 (de) | 2011-06-29 | 2013-01-03 | Henkel Ag & Co. Kgaa | Elektrolytische Vereisenung von Zinkoberflächen |
WO2013160567A1 (fr) | 2012-04-25 | 2013-10-31 | Arcelormittal Investigacion Y Desarrollo, S.L. | Procédé de réalisation d'une tôle prélaquée à revêtements znalmg et tôle correspondante. |
DE102012212598A1 (de) | 2012-07-18 | 2014-02-20 | Henkel Ag & Co. Kgaa | Verzinnende Vorbehandlung von verzinktem Stahl in Gegenwart von Pyrophosphat |
DE102012111066A1 (de) | 2012-11-16 | 2014-06-05 | Salzgitter Flachstahl Gmbh | Beschichtetes Stahlblech mit verbesserten Korrosionseigenschaften und Verfahren zur Herstellung eines solchen Bleches |
CN104338668A (zh) * | 2013-07-30 | 2015-02-11 | 比亚迪股份有限公司 | 一种基材表面自泳涂装的方法以及电子产品外壳 |
RU2591919C1 (ru) * | 2015-04-01 | 2016-07-20 | Российская Федерация, от имени которой выступает Государственная корпорация по атомной энергии "Росатом" | Установка диффузионного цинкования металлических деталей |
DE102015206812A1 (de) | 2015-04-15 | 2016-10-20 | Henkel Ag & Co. Kgaa | Polymerhaltige Vorspüle vor einer Konversionsbehandlung |
DE102015209910A1 (de) | 2015-05-29 | 2016-12-01 | Henkel Ag & Co. Kgaa | Vorspüle enthaltend ein quartäres Amin zur Konditionierung vor einer Konversionsbehandlung |
DE102015209909A1 (de) | 2015-05-29 | 2016-12-01 | Henkel Ag & Co. Kgaa | Konditionierung vor einer Konversionsbehandlung von Metalloberflächen |
CN105063696A (zh) * | 2015-08-07 | 2015-11-18 | 昆山—邦泰汽车零部件制造有限公司 | 一种耐磨的汽车五金件制造方法 |
JP7035021B2 (ja) | 2016-08-23 | 2022-03-14 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | ジ-又はポリアミンとα,β-不飽和カルボン酸誘導体との反応生成物として得られる接着促進剤の金属表面処理のための使用 |
EP3591092B1 (en) * | 2017-03-03 | 2024-05-01 | Nissan Motor Co., Ltd. | High-design sliding member |
EP3569734A1 (en) | 2018-05-18 | 2019-11-20 | Henkel AG & Co. KGaA | Passivation composition based on trivalent chromium |
CN109267079A (zh) * | 2018-11-15 | 2019-01-25 | 济南大学 | 一种中性金属表面除锈清洗剂的制备方法 |
FI3663435T3 (fi) | 2018-12-05 | 2024-05-24 | Henkel Ag & Co Kgaa | Fosfori- ja fosfonihappojen seoksiin perustuva passivointikoostumus |
WO2021114015A1 (en) * | 2019-12-09 | 2021-06-17 | Hewlett-Packard Development Company, L.P. | Coated metal alloy substrate and process for production thereof |
CN110923768B (zh) * | 2019-12-19 | 2022-01-25 | 漳州市福美鑫新材料科技有限公司 | 一种用于三价铬电镀工件后处理工艺的设备 |
CN110983220B (zh) * | 2019-12-30 | 2023-08-18 | 江苏圣大中远电气有限公司 | 核电产品抗磨耐腐蚀表面处理系统 |
WO2021139955A1 (en) | 2020-01-06 | 2021-07-15 | Henkel Ag & Co. Kgaa | Passivation composition suitable for inner surfaces of zinc coated steel tanks storing hydrocarbons |
EP3872231A1 (de) * | 2020-02-28 | 2021-09-01 | voestalpine Stahl GmbH | Verfahren zum konditionieren der oberfläche eines mit einer zinklegierungs-korrosionsschutzschicht beschichteten metallbandes |
CN116670236A (zh) | 2021-01-06 | 2023-08-29 | 汉高股份有限及两合公司 | 用于涂锌铝钢的基于Cr(III)的改善钝化 |
GB2603194A (en) | 2021-02-01 | 2022-08-03 | Henkel Ag & Co Kgaa | Improved cr(iii) based dry-in-place coating composition for zinc coated steel |
EP4174211A1 (de) | 2021-11-02 | 2023-05-03 | Henkel AG & Co. KGaA | Mehrstufige behandlung zur aktivierten zinkphosphatierung metallischer bauteile mit zinkoberflächen |
CN114108043B (zh) * | 2021-11-19 | 2023-08-11 | 山东省路桥集团有限公司 | 钢结构桥梁锈蚀区域的修复再生预处理方法 |
CN115627465B (zh) * | 2022-10-26 | 2024-05-24 | 国网湖北省电力有限公司电力科学研究院 | 一种耐盐穴高压气氛防腐镀层的施镀工艺及应用 |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5243171B2 (ja) * | 1973-01-11 | 1977-10-28 | ||
JPH0450387B2 (ja) * | 1984-09-12 | 1992-08-14 | Nisshin Steel Co Ltd | |
JPH06293973A (ja) * | 1993-04-07 | 1994-10-21 | Nippon Parkerizing Co Ltd | 亜鉛含有金属めっき鋼板用酸性置換めっき液組成物 |
JPH07286285A (ja) * | 1994-04-20 | 1995-10-31 | Nippon Paint Co Ltd | 金属表面用化成処理水溶液 |
JPH09502768A (ja) * | 1993-09-17 | 1997-03-18 | ブレント インターナショナル パブリック リミティド カンパニー | 金属表面をリン酸塩処理するための予備洗浄 |
JP2001523769A (ja) * | 1997-11-19 | 2001-11-27 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン | クロムを含んでいない有機系被覆用重合性組成物 |
US6346295B1 (en) * | 1997-08-06 | 2002-02-12 | Henkel Kommanditgesellschaft Auf Aktien | Alkaline strip passivation |
WO2004101850A1 (de) * | 2003-05-19 | 2004-11-25 | Henkel Kommanditgesellschaft Auf Aktien | Vorbehandlung von metallloberflächen vor einer lackierung |
JP2007023353A (ja) * | 2005-07-19 | 2007-02-01 | Yuken Industry Co Ltd | 亜鉛系めっき部材のノンクロム反応型化成処理 |
JP2008510603A (ja) * | 2004-08-24 | 2008-04-10 | ビーエーエスエフ ソシエタス・ヨーロピア | イタコン酸単独重合体又は共重合体を用いた金属表面の不動態化方法 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE171455C (ja) | ||||
CH361954A (de) | 1953-08-27 | 1962-05-15 | Gen Am Transport | Verfahren zur chemischen Vernickelung |
NL282799A (ja) * | 1961-09-13 | |||
DE2103086C3 (de) * | 1971-01-23 | 1979-11-15 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Oberflächenbehandlung von Werkstücken aus Eisen und Stahl |
JPS51135840A (en) * | 1975-05-21 | 1976-11-25 | Nippon Packaging Kk | Surface treatment process for zinc or zinc alloy |
JPS5817254B2 (ja) * | 1981-05-13 | 1983-04-06 | 工業技術院長 | 亜鉛めつきの耐食性の改良方法 |
JPS62127479A (ja) * | 1985-11-26 | 1987-06-09 | Nisshin Steel Co Ltd | 亜鉛めつき鋼板の表面処理方法 |
US5298289A (en) | 1987-12-04 | 1994-03-29 | Henkel Corporation | Polyphenol compounds and treatment and after-treatment of metal, plastic and painted surfaces therewith |
JPH0331484A (ja) * | 1989-06-27 | 1991-02-12 | Nippon Parkerizing Co Ltd | 亜鉛または亜鉛系メッキ材料の黒色化処理法 |
JPH0448095A (ja) * | 1990-06-15 | 1992-02-18 | Nippon Steel Corp | 缶外面の耐錆性と外観に優れた容器用表面処理鋼板の製造法 |
JP2904592B2 (ja) * | 1991-01-14 | 1999-06-14 | 日本鋼管株式会社 | 亜鉛又は亜鉛合金のクロメート処理の前処理方法 |
US5449415A (en) * | 1993-07-30 | 1995-09-12 | Henkel Corporation | Composition and process for treating metals |
DE19923084A1 (de) | 1999-05-20 | 2000-11-23 | Henkel Kgaa | Chromfreies Korrosionsschutzmittel und Korrosionsschutzverfahren |
DE10010758A1 (de) * | 2000-03-04 | 2001-09-06 | Henkel Kgaa | Korrosionsschutzverfahren für Metalloberflächen |
US6530999B2 (en) * | 2000-10-10 | 2003-03-11 | Henkel Corporation | Phosphate conversion coating |
DE102007001654A1 (de) | 2007-01-04 | 2008-07-10 | Henkel Kgaa | Leitfähige, organische Beschichtungen mit optimiertem Polymersystem |
DE102007021364A1 (de) * | 2007-05-04 | 2008-11-06 | Henkel Ag & Co. Kgaa | Metallisierende Vorbehandlung von Zinkoberflächen |
EP2206802B1 (en) * | 2007-09-27 | 2013-02-27 | Chemetall GmbH | Method for producing surface-treated metal material and method for producing metal coated article |
-
2007
- 2007-05-04 DE DE102007021364A patent/DE102007021364A1/de not_active Ceased
-
2008
- 2008-04-30 HU HUE10187987A patent/HUE030515T2/en unknown
- 2008-04-30 ES ES10187987.2T patent/ES2589380T3/es active Active
- 2008-04-30 EP EP10187987.2A patent/EP2292808B1/de active Active
- 2008-04-30 WO PCT/EP2008/055308 patent/WO2008135478A2/de active Application Filing
- 2008-04-30 RU RU2009144881/02A patent/RU2482220C2/ru not_active IP Right Cessation
- 2008-04-30 PL PL10187987.2T patent/PL2292808T3/pl unknown
- 2008-04-30 HU HUE08749904A patent/HUE028450T2/en unknown
- 2008-04-30 EP EP08749904.2A patent/EP2145031B1/de active Active
- 2008-04-30 BR BRPI0811537-0A2A patent/BRPI0811537A2/pt not_active Application Discontinuation
- 2008-04-30 MX MX2009011876A patent/MX2009011876A/es active IP Right Grant
- 2008-04-30 JP JP2010504740A patent/JP5917802B2/ja not_active Expired - Fee Related
- 2008-04-30 KR KR1020097025157A patent/KR20100028542A/ko not_active Application Discontinuation
- 2008-04-30 CN CN2008800147916A patent/CN101675181B/zh active Active
- 2008-04-30 CA CA2686380A patent/CA2686380C/en not_active Expired - Fee Related
- 2008-04-30 PT PT08749904T patent/PT2145031E/pt unknown
- 2008-04-30 PT PT101879872T patent/PT2292808T/pt unknown
- 2008-04-30 ES ES08749904.2T patent/ES2575993T3/es active Active
- 2008-04-30 PL PL08749904.2T patent/PL2145031T3/pl unknown
- 2008-04-30 AU AU2008248694A patent/AU2008248694B2/en not_active Ceased
-
2009
- 2009-11-03 ZA ZA2009/07724A patent/ZA200907724B/en unknown
- 2009-11-18 US US12/621,206 patent/US8293334B2/en active Active
-
2015
- 2015-11-17 JP JP2015224587A patent/JP2016074985A/ja active Pending
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5243171B2 (ja) * | 1973-01-11 | 1977-10-28 | ||
JPH0450387B2 (ja) * | 1984-09-12 | 1992-08-14 | Nisshin Steel Co Ltd | |
JPH06293973A (ja) * | 1993-04-07 | 1994-10-21 | Nippon Parkerizing Co Ltd | 亜鉛含有金属めっき鋼板用酸性置換めっき液組成物 |
JPH09502768A (ja) * | 1993-09-17 | 1997-03-18 | ブレント インターナショナル パブリック リミティド カンパニー | 金属表面をリン酸塩処理するための予備洗浄 |
JPH07286285A (ja) * | 1994-04-20 | 1995-10-31 | Nippon Paint Co Ltd | 金属表面用化成処理水溶液 |
US6346295B1 (en) * | 1997-08-06 | 2002-02-12 | Henkel Kommanditgesellschaft Auf Aktien | Alkaline strip passivation |
JP2001523769A (ja) * | 1997-11-19 | 2001-11-27 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン | クロムを含んでいない有機系被覆用重合性組成物 |
WO2004101850A1 (de) * | 2003-05-19 | 2004-11-25 | Henkel Kommanditgesellschaft Auf Aktien | Vorbehandlung von metallloberflächen vor einer lackierung |
JP2008510603A (ja) * | 2004-08-24 | 2008-04-10 | ビーエーエスエフ ソシエタス・ヨーロピア | イタコン酸単独重合体又は共重合体を用いた金属表面の不動態化方法 |
JP2007023353A (ja) * | 2005-07-19 | 2007-02-01 | Yuken Industry Co Ltd | 亜鉛系めっき部材のノンクロム反応型化成処理 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015510550A (ja) * | 2012-02-24 | 2015-04-09 | 日本パーカライジング株式会社 | 不動態化工程前の亜鉛表面の前処理 |
US11987887B2 (en) | 2019-07-29 | 2024-05-21 | Ewald Dörken Ag | Method for passivating metallic substances |
KR102690190B1 (ko) * | 2019-07-29 | 2024-08-01 | 에발트 되르켄 아.게. | 금속성 기재의 부동태화 방법 |
Also Published As
Publication number | Publication date |
---|---|
MX2009011876A (es) | 2010-02-24 |
RU2482220C2 (ru) | 2013-05-20 |
EP2145031A2 (de) | 2010-01-20 |
WO2008135478A3 (de) | 2009-01-08 |
CN101675181B (zh) | 2012-10-24 |
AU2008248694A1 (en) | 2008-11-13 |
ZA200907724B (en) | 2011-04-28 |
RU2009144881A (ru) | 2011-06-10 |
ES2589380T3 (es) | 2016-11-14 |
HUE028450T2 (en) | 2016-12-28 |
DE102007021364A1 (de) | 2008-11-06 |
EP2145031B1 (de) | 2016-03-16 |
CA2686380C (en) | 2016-04-05 |
PL2145031T3 (pl) | 2016-09-30 |
JP2016074985A (ja) | 2016-05-12 |
US8293334B2 (en) | 2012-10-23 |
KR20100028542A (ko) | 2010-03-12 |
PT2145031E (pt) | 2016-06-16 |
ES2575993T3 (es) | 2016-07-04 |
AU2008248694B2 (en) | 2012-10-04 |
PT2292808T (pt) | 2016-09-08 |
CA2686380A1 (en) | 2008-11-13 |
US20100209732A1 (en) | 2010-08-19 |
WO2008135478A2 (de) | 2008-11-13 |
JP5917802B2 (ja) | 2016-05-18 |
EP2292808B1 (de) | 2016-06-08 |
BRPI0811537A2 (pt) | 2014-11-18 |
PL2292808T3 (pl) | 2016-12-30 |
EP2292808A1 (de) | 2011-03-09 |
HUE030515T2 (en) | 2017-05-29 |
CN101675181A (zh) | 2010-03-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5917802B2 (ja) | 亜鉛表面の金属被覆前処理 | |
JP6526968B2 (ja) | 不動態化工程前の亜鉛表面の前処理 | |
CA2883180C (en) | Zirconium pretreatment compositions containing molybdenum, associated methods for treating metal substrates, and related coated metal substrates | |
CA2905744C (en) | Method for preparing and treating a steel substrate | |
EP2890829B1 (en) | Zirconium pretreatment compositions containing lithium, associated methods for treating metal substrates, and related coated metal substrates | |
US4537837A (en) | Corrosion resistant metal composite with metallic undercoat and chromium topcoat | |
JP2003505590A (ja) | 金属表面の防食処理あるいは後処理のプロセス | |
AU2012290704A1 (en) | Zirconium pretreatment compositions containing a rare earth metal, associated methods for treating metal substrates, and related coated metal substrates | |
CA2840117C (en) | Electrolytic plating of iron on zinc surfaces |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20110218 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130423 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130618 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20140318 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140610 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140618 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20140701 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140902 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20141023 |
|
A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20141023 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20141023 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20141117 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150202 |
|
A912 | Re-examination (zenchi) completed and case transferred to appeal board |
Free format text: JAPANESE INTERMEDIATE CODE: A912 Effective date: 20150327 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150825 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20151117 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160202 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20160407 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5917802 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
LAPS | Cancellation because of no payment of annual fees |