JP2010508163A - 凹凸層及び凹凸層を作製する刻印方法 - Google Patents
凹凸層及び凹凸層を作製する刻印方法 Download PDFInfo
- Publication number
- JP2010508163A JP2010508163A JP2009534036A JP2009534036A JP2010508163A JP 2010508163 A JP2010508163 A JP 2010508163A JP 2009534036 A JP2009534036 A JP 2009534036A JP 2009534036 A JP2009534036 A JP 2009534036A JP 2010508163 A JP2010508163 A JP 2010508163A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- silicon oxide
- oxide compound
- concavo
- silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 147
- -1 siliconoxide compound Chemical class 0.000 claims abstract description 119
- 238000000034 method Methods 0.000 claims abstract description 77
- 239000000758 substrate Substances 0.000 claims abstract description 14
- 230000003287 optical effect Effects 0.000 claims abstract description 11
- 239000004065 semiconductor Substances 0.000 claims abstract description 5
- 239000010410 layer Substances 0.000 claims description 171
- 239000000243 solution Substances 0.000 claims description 60
- 239000002904 solvent Substances 0.000 claims description 53
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 40
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 34
- 238000004049 embossing Methods 0.000 claims description 34
- 229910052710 silicon Inorganic materials 0.000 claims description 33
- 230000008569 process Effects 0.000 claims description 23
- 239000002243 precursor Substances 0.000 claims description 22
- 238000001035 drying Methods 0.000 claims description 20
- 239000000126 substance Chemical group 0.000 claims description 17
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 16
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 125000003545 alkoxy group Chemical group 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 10
- 239000002105 nanoparticle Substances 0.000 claims description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- 125000000962 organic group Chemical group 0.000 claims description 8
- 125000004429 atom Chemical group 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 239000002346 layers by function Substances 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 239000000470 constituent Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 230000000295 complement effect Effects 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 description 22
- 238000004132 cross linking Methods 0.000 description 19
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 12
- 229910002808 Si–O–Si Inorganic materials 0.000 description 11
- 150000003377 silicon compounds Chemical class 0.000 description 11
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 10
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 230000008901 benefit Effects 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000010586 diagram Methods 0.000 description 8
- 238000006460 hydrolysis reaction Methods 0.000 description 8
- 229910018540 Si C Inorganic materials 0.000 description 7
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 7
- 229910010271 silicon carbide Inorganic materials 0.000 description 7
- 238000004528 spin coating Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000007711 solidification Methods 0.000 description 6
- 230000008023 solidification Effects 0.000 description 6
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 5
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- 235000019253 formic acid Nutrition 0.000 description 5
- 230000007062 hydrolysis Effects 0.000 description 5
- 230000005855 radiation Effects 0.000 description 5
- 238000005245 sintering Methods 0.000 description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 239000011368 organic material Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000003636 chemical group Chemical group 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 230000001788 irregular Effects 0.000 description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229960004063 propylene glycol Drugs 0.000 description 3
- 235000013772 propylene glycol Nutrition 0.000 description 3
- 229920002379 silicone rubber Polymers 0.000 description 3
- 239000004945 silicone rubber Substances 0.000 description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Natural products CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000635 electron micrograph Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000001459 lithography Methods 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 239000012686 silicon precursor Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 1
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 1
- MARUHZGHZWCEQU-UHFFFAOYSA-N 5-phenyl-2h-tetrazole Chemical compound C1=CC=CC=C1C1=NNN=N1 MARUHZGHZWCEQU-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000006552 photochemical reaction Methods 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 1
- 238000001020 plasma etching Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000003340 retarding agent Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0002—Lithographic processes using patterning methods other than those involving the exposure to radiation, e.g. by stamping
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
- B29C59/022—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing characterised by the disposition or the configuration, e.g. dimensions, of the embossments or the shaping tools therefor
- B29C2059/023—Microembossing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
Landscapes
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mathematical Physics (AREA)
- Theoretical Computer Science (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Manufacturing & Machinery (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
- Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
- Silicon Compounds (AREA)
- Micromachines (AREA)
Abstract
Description
Claims (22)
- テンプレート凹凸パターンを含む型押面を持つ押型を用いて凹凸層を形成する方法において、
− 基板面を設けるステップと、
− 前記基板面及び前記型押面の少なくとも一方に、酸化ケイ素化合物及び溶媒を有する酸化ケイ素化合物溶液を供給するステップと、
− 前記溶媒を少なくとも部分的に除去して、部分的に乾燥された酸化ケイ素化合物層を残存させるステップと、
− 前記部分的に乾燥された酸化ケイ素化合物層を前記基板面と前記型押面との間に挟み、これにより前記部分的に乾燥された酸化ケイ素化合物層が前記テンプレート凹凸パターンに従って型形成されるようにするステップと、
− 前記部分的に乾燥された酸化ケイ素化合物層を、挟まれている間に更に乾燥し、これにより固化された酸化ケイ素層を形成するステップと、
− 前記型押面を前記固化された酸化ケイ素層から分離し、これにより前記凹凸層を出現させるステップと、
を有し、
− 前記酸化ケイ素化合物溶液は前記酸化ケイ素の凹凸層を形成するための酸化ケイ素化合物を有し、該酸化ケイ素化合物のケイ素原子は4つの酸素原子と化学的に結合されたケイ素原子又は3つの酸素原子及び酸素とは異なる1つの原子と化学的に結合されたケイ素原子の何れかであり、前記ケイ素原子と前記酸素とは異なる1つの原子との間の化学的結合が当該方法の間において化学的に不活性である方法。 - 前記酸化ケイ素化合物がナノ粒子を有する請求項1に記載の方法。
- 前記酸化ケイ素化合物溶液が酸化ケイ素化合物前駆体と少なくとも1つの単官能化トリアルコキシシランとを混合することにより作製され、該混合物が酸の水溶液と反応されて前記酸化ケイ素化合物を形成する請求項1に記載の方法。
- 前記酸化ケイ素化合物前駆体がテトラアルコキシシランである請求項3に記載の方法。
- 前記テトラアルコキシシランにおけるアルコキシ基の少なくとも1つが、前記少なくとも1つの単官能化トリアルコキシシランにおけるアルコキシ基の少なくとも1つと同一である請求項4に記載の方法。
- 前記単官能化トリアルコキシシランの単官能は、該単官能が前記ケイ素原子と化学的に結合される炭素原子を含む請求項3ないし5の何れか一項に記載の方法。
- 前記炭素原子が4未満の炭素原子を持つアルキル基の一部である請求項6に記載の方法。
- 4つの酸素原子に化学的に結合されたケイ素/3つの酸素原子及び酸素とは異なる1つの原子と化学的に結合されたケイ素のモル比が、前記酸化ケイ素化合物溶液及び/又は前記部分的に乾燥された酸化ケイ素化合物層内で3/2より小さい請求項1に記載の方法。
- 前記溶媒が第1溶媒及び第2溶媒を有し、前記第1溶媒が前記第2溶媒よりも高い蒸気圧を有する請求項1に記載の方法。
- 前記押型が前記部分的に乾燥された酸化ケイ素化合物層の構成物質に対して透過的であり、これにより前記挟むステップの間において更なる乾燥を達成する請求項1に記載の方法。
- 前記凹凸層に加熱ステップが施こされる請求項1に記載の方法。
- 請求項1ないし11の何れか一項に記載の方法により得られる凹凸層。
- 酸化ケイ素を有する凹凸層において、該凹凸層が4つの酸素原子に化学的に結合されたケイ素原子と3つの酸素原子及び1つの炭素原子に化学的に結合されたケイ素原子とを有することを特徴とする凹凸層。
- 4つの酸素原子に化学的に結合されたケイ素原子/3つの酸素原子及び1つの炭素原子に化学的に結合されたケイ素原子のモル比が少なくとも2/3である請求項13に記載の凹凸層。
- 前記炭素原子は前記ケイ素原子が前記酸化ケイ素化合物の少なくとも1つの他のケイ素原子に接続される有機基の一部であり、該有機基が前記少なくとも1つの他のケイ素原子に化学的に結合される請求項12又は13に記載の凹凸層。
- 前記炭素原子がメチル基、エチル基又はプロピル基のうちの何れか1つの一部である請求項13又は14に記載の凹凸層。
- 前記凹凸層の凹凸がテンプレート凹凸面内の対応する相補的凹凸に従う形状を有する請求項13に記載の凹凸層。
- 前記凹凸層が1マイクロメートルより小さな寸法の凹凸を有する請求項13に記載の凹凸層。
- 請求項12又は13に記載の凹凸層のエッチマスクとしての使用。
- 請求項12又は13に記載の凹凸層の、該凹凸層を含む機能層を有する半導体デバイスの製造のための使用。
- 請求項12又は13に記載の凹凸層の、該凹凸層を含む機能層を有する光学デバイスの製造のための使用。
- 請求項12又は13に記載の凹凸層の、該凹凸層を含む機能層を有する微細機械デバイスの製造のための使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06123325.0 | 2006-11-01 | ||
EP06123325 | 2006-11-01 | ||
PCT/IB2007/054361 WO2008053418A2 (en) | 2006-11-01 | 2007-10-26 | Relief layer and imprint method for making the same |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014191048A Division JP5916825B2 (ja) | 2006-11-01 | 2014-09-19 | 凹凸層及び凹凸層を作製する刻印方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2010508163A true JP2010508163A (ja) | 2010-03-18 |
JP5936806B2 JP5936806B2 (ja) | 2016-06-22 |
Family
ID=39166818
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009534036A Active JP5936806B2 (ja) | 2006-11-01 | 2007-10-26 | 凹凸層及び凹凸層を作製する刻印方法 |
JP2014191048A Active JP5916825B2 (ja) | 2006-11-01 | 2014-09-19 | 凹凸層及び凹凸層を作製する刻印方法 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014191048A Active JP5916825B2 (ja) | 2006-11-01 | 2014-09-19 | 凹凸層及び凹凸層を作製する刻印方法 |
Country Status (7)
Country | Link |
---|---|
US (3) | US9298086B2 (ja) |
EP (1) | EP2087403B1 (ja) |
JP (2) | JP5936806B2 (ja) |
CN (3) | CN101535892A (ja) |
AT (1) | ATE544093T1 (ja) |
ES (1) | ES2381621T3 (ja) |
WO (1) | WO2008053418A2 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013154637A (ja) * | 2012-01-06 | 2013-08-15 | Nippon Shokubai Co Ltd | 樹脂製ナノ構造体の製造方法 |
JPWO2015115128A1 (ja) * | 2014-01-29 | 2017-03-23 | 株式会社ダイセル | ナノインプリント用光硬化性組成物、及びそれを使用した微細パターンの形成方法 |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9440254B2 (en) | 2006-12-04 | 2016-09-13 | Koninklijke Philips N.V. | Method and apparatus for applying a sheet to a substrate |
US8172968B2 (en) | 2007-01-16 | 2012-05-08 | Koninklijke Philips Electronics N.V. | Method and system for contacting of a flexible sheet and a substrate |
US7791096B2 (en) * | 2007-06-08 | 2010-09-07 | Koninklijke Philips Electronics N.V. | Mount for a semiconductor light emitting device |
US9778562B2 (en) | 2007-11-21 | 2017-10-03 | Canon Nanotechnologies, Inc. | Porous template and imprinting stack for nano-imprint lithography |
WO2009141774A1 (en) | 2008-05-20 | 2009-11-26 | Koninklijke Philips Electronics N.V. | Aqueous curable imprintable medium and patterned layer forming method |
US8470188B2 (en) | 2008-10-02 | 2013-06-25 | Molecular Imprints, Inc. | Nano-imprint lithography templates |
WO2010121064A2 (en) | 2009-04-15 | 2010-10-21 | Cornell Research Foundation, Inc. | Improved fluorescent silica nanoparticles through silica densification |
NL2005263A (en) * | 2009-09-29 | 2011-03-30 | Asml Netherlands Bv | Imprint lithography. |
US8616873B2 (en) | 2010-01-26 | 2013-12-31 | Molecular Imprints, Inc. | Micro-conformal templates for nanoimprint lithography |
DE102012112030A1 (de) | 2012-12-10 | 2014-06-12 | Ev Group E. Thallner Gmbh | Verfahren zum Mikrokontaktprägen |
JP5897234B1 (ja) * | 2012-12-21 | 2016-03-30 | コーニンクレッカ フィリップス エヌ ヴェKoninklijke Philips N.V. | 組成物、インプリンティング・インクおよびインプリンティング方法 |
CN105818556A (zh) * | 2016-03-25 | 2016-08-03 | 南京京晶光电科技有限公司 | 一种采用纳米压印工艺在基材表面加工cd纹的方法 |
EP3440509B1 (en) | 2016-04-06 | 2020-06-17 | Koninklijke Philips N.V. | Imprint lithography stamp, method of making and using the same |
US20190384167A1 (en) * | 2017-01-27 | 2019-12-19 | Arizona Board Of Regents On Behalf Of Arizona State University | Electrochemical imprinting of micro- and nano-structures in porous silicon, silicon, and other semiconductors |
CN107473177B (zh) * | 2017-07-14 | 2020-07-14 | 华中科技大学 | 一种3d立体微纳结构的制作方法 |
EP3582004A1 (en) | 2018-06-13 | 2019-12-18 | Koninklijke Philips N.V. | Imprinting composition and method of forming a patterned layer using the same |
CN112993106B (zh) * | 2020-09-16 | 2022-07-22 | 重庆康佳光电技术研究院有限公司 | 蓝宝石基底图案化方法及蓝宝石基底 |
CN115008669A (zh) * | 2022-05-23 | 2022-09-06 | 如皋易塑复合新材料有限公司 | 一种瓦楞板模压成型设备及其模压工艺 |
CN115284696B (zh) * | 2022-08-11 | 2023-07-25 | 业成科技(成都)有限公司 | 复合光学膜结构及其制造方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005053006A (ja) * | 2003-08-06 | 2005-03-03 | Nippon Sheet Glass Co Ltd | 微小成形体の製造方法 |
WO2006044690A2 (en) * | 2004-10-18 | 2006-04-27 | Molecular Imprints, Inc. | Low-k dielectric functional imprinting materials |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2758415A1 (de) * | 1977-12-28 | 1979-07-12 | Fraunhofer Ges Forschung | Kieselsaeureheteropolykondensate, verfahren zu deren herstellung und deren verwendung als membranen und adsorbentien |
DE2758414A1 (de) * | 1977-12-28 | 1979-07-12 | Fraunhofer Ges Forschung | Kieselsaeureheteropolykondensate, verfahren zu deren herstellung und deren verwendung bei der zuechtung lebender zellen |
FR2692274A1 (fr) | 1992-06-10 | 1993-12-17 | Du Pont | Nouvelle laque à base de silicium, son emploi en tant que revêtement de substrat et les substrats ainsi obtenus. |
DE4417405A1 (de) | 1994-05-18 | 1995-11-23 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung von strukturierten anorganischen Schichten |
KR100272785B1 (ko) * | 1995-06-27 | 2000-11-15 | 우찌가사끼 이사오 | 인쇄배선판용프리프래그,수지니스,수지조성물및상기물질을사용하여제조된인쇄배선판용적층판 |
JP3750393B2 (ja) * | 1998-02-05 | 2006-03-01 | 日本板硝子株式会社 | 凹凸表面を有する物品の製造方法 |
JP2000191966A (ja) * | 1998-12-25 | 2000-07-11 | Central Glass Co Ltd | 酸化物膜形成用インキおよび金属酸化物膜の形成方法 |
DE10001135A1 (de) * | 2000-01-13 | 2001-07-19 | Inst Neue Mat Gemein Gmbh | Verfahren zur Herstellung eines mikrostrukturierten Oberflächenreliefs durch Prägen thixotroper Schichten |
US6723198B1 (en) * | 2001-05-24 | 2004-04-20 | Seagate Technology Llc | Servo pattern formation via transfer of sol-gel layer and magnetic media obtained thereby |
US6757116B1 (en) | 2001-08-16 | 2004-06-29 | Seagate Technology Llc | Disk biasing for manufacture of servo patterned media |
WO2004044960A2 (en) * | 2002-11-13 | 2004-05-27 | Surface Logix, Inc. | Thermal interface composite structure and method of making same |
AU2003276558A1 (en) * | 2002-12-13 | 2004-07-09 | Koninklijke Philips Electronics N.V. | Field emission device, and method of manufacturing such a device |
WO2004090058A1 (en) * | 2003-04-09 | 2004-10-21 | Lg Chem, Ltd. | Coating composition for insulating film production, preparation method of insulation film by using the same, insulation film for semi-conductor device prepared therefrom, and semi-conductor device comprising the same |
JP2004314238A (ja) | 2003-04-16 | 2004-11-11 | Canon Inc | ナノ構造体の製造方法及びナノ構造体 |
WO2005101466A2 (en) | 2003-12-19 | 2005-10-27 | The University Of North Carolina At Chapel Hill | Methods for fabricating isolated micro- and nano- structures using soft or imprint lithography |
US20050230882A1 (en) * | 2004-04-19 | 2005-10-20 | Molecular Imprints, Inc. | Method of forming a deep-featured template employed in imprint lithography |
CN1752165A (zh) * | 2004-09-23 | 2006-03-29 | 张崇照 | 一种有机硅透明耐磨增硬涂料及其制作方法 |
DE102004054238A1 (de) | 2004-11-10 | 2006-05-11 | Robert Bosch Gmbh | Dosiersystem sowie Verfahren zum Betreiben eines Dosiersystems |
DE102005012694A1 (de) * | 2005-03-18 | 2006-10-05 | Wacker Chemie Ag | Grundiermittel für hitzehärtbare Siliconelastomere |
KR100843392B1 (ko) | 2005-03-31 | 2008-07-03 | 삼성전기주식회사 | 우수한 내구성을 갖는 인쇄회로기판용 임프린트 몰드 및이를 이용한 인쇄회로기판의 제조방법 |
US7452957B2 (en) | 2005-08-31 | 2008-11-18 | Kimberly-Clark Worldwide, Inc. | Hydrophilic silicone elastomers |
JP5000112B2 (ja) * | 2005-09-09 | 2012-08-15 | 東京応化工業株式会社 | ナノインプリントリソグラフィによるパターン形成方法 |
-
2007
- 2007-10-26 CN CNA2007800409878A patent/CN101535892A/zh active Pending
- 2007-10-26 JP JP2009534036A patent/JP5936806B2/ja active Active
- 2007-10-26 ES ES07826880T patent/ES2381621T3/es active Active
- 2007-10-26 US US12/447,536 patent/US9298086B2/en active Active
- 2007-10-26 AT AT07826880T patent/ATE544093T1/de active
- 2007-10-26 CN CN2012104179596A patent/CN102967993A/zh active Pending
- 2007-10-26 CN CN201510994629.7A patent/CN105372934B/zh active Active
- 2007-10-26 WO PCT/IB2007/054361 patent/WO2008053418A2/en active Application Filing
- 2007-10-26 EP EP07826880A patent/EP2087403B1/en active Active
-
2014
- 2014-09-19 JP JP2014191048A patent/JP5916825B2/ja active Active
-
2015
- 2015-12-14 US US14/968,127 patent/US20160246169A1/en not_active Abandoned
-
2020
- 2020-09-15 US US17/020,896 patent/US11619878B2/en active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005053006A (ja) * | 2003-08-06 | 2005-03-03 | Nippon Sheet Glass Co Ltd | 微小成形体の製造方法 |
WO2006044690A2 (en) * | 2004-10-18 | 2006-04-27 | Molecular Imprints, Inc. | Low-k dielectric functional imprinting materials |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013154637A (ja) * | 2012-01-06 | 2013-08-15 | Nippon Shokubai Co Ltd | 樹脂製ナノ構造体の製造方法 |
JPWO2015115128A1 (ja) * | 2014-01-29 | 2017-03-23 | 株式会社ダイセル | ナノインプリント用光硬化性組成物、及びそれを使用した微細パターンの形成方法 |
Also Published As
Publication number | Publication date |
---|---|
CN105372934B (zh) | 2020-11-10 |
JP5916825B2 (ja) | 2016-05-11 |
US20100075108A1 (en) | 2010-03-25 |
EP2087403B1 (en) | 2012-02-01 |
ATE544093T1 (de) | 2012-02-15 |
US20160246169A1 (en) | 2016-08-25 |
US20200409257A1 (en) | 2020-12-31 |
US11619878B2 (en) | 2023-04-04 |
JP5936806B2 (ja) | 2016-06-22 |
ES2381621T3 (es) | 2012-05-30 |
CN105372934A (zh) | 2016-03-02 |
CN101535892A (zh) | 2009-09-16 |
EP2087403A2 (en) | 2009-08-12 |
JP2015053487A (ja) | 2015-03-19 |
CN102967993A (zh) | 2013-03-13 |
WO2008053418A2 (en) | 2008-05-08 |
WO2008053418A3 (en) | 2008-11-13 |
US9298086B2 (en) | 2016-03-29 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5916825B2 (ja) | 凹凸層及び凹凸層を作製する刻印方法 | |
JP4381825B2 (ja) | ナノインプリントレジスト | |
KR101293093B1 (ko) | 나노패턴화 방법, 내부에 사용하기 위한 경화된 레지스트필름, 및 이 레지스트 필름을 포함하는 물품 | |
JP5007416B2 (ja) | 多孔質シリカ膜の製造方法 | |
CN109414726A (zh) | 使用压印光刻的纳米结构图案化 | |
TW201005036A (en) | Aqueous curable imprintable medium and patterned layer forming method | |
KR20070083711A (ko) | 낮은-k 유전 기능 임프린팅 재료 | |
KR101145867B1 (ko) | SOG(Spin-on glass)를 이용하여 기판에 나노패턴을 형성하는 방법 | |
JPH0792695A (ja) | 薄膜パターン形成法 | |
JP2006151800A (ja) | シリカエアロゲル膜の製造方法 | |
CN110651226B (zh) | 纳米压印光刻方法及由其获得的图案化基底 | |
JP2019504464A (ja) | インプリント用インク組成物、インプリント方法、光学エレメント、照明装置、光センサ及び光起電力装置 | |
CN1562731A (zh) | 基于旋涂的纳米复制方法 | |
JP4808385B2 (ja) | ナノ材料の製造方法 | |
JP2010500629A (ja) | 現像溶媒によるパターン化フィルムの調製方法 | |
KR100700435B1 (ko) | 패턴 복제에 사용되는 몰드 제조용 불화 유기규소 화합물,그를 이용하여 제조된 패턴 복제용 유기-무기 혼성 몰드,그 몰드를 이용한 패턴 복제 방법 및 그 방법에 의하여복제된 패턴 | |
KR100586175B1 (ko) | 나노임프린트용 스탬퍼 및 그 제조방법 | |
Binderup et al. | Large area nanoscale patterning of functional materials using organosilicate ink based nanotransfer printing | |
KR20230109688A (ko) | 패시베이션된 나노입자들을 갖는 임프린트 조성물들 및 이를 제조하기 위한 재료들 및 프로세스들 | |
Savegnago | New organic-inorganic sol-gel resists for micro and nanoimprinting | |
Pina | Novel organosilicone materials and patterning techniques for nanoimprint lithography |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20101022 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130207 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20130424 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20130502 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130801 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20140520 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140919 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20141006 |
|
A912 | Re-examination (zenchi) completed and case transferred to appeal board |
Free format text: JAPANESE INTERMEDIATE CODE: A912 Effective date: 20141031 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160128 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160225 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20160511 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5936806 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |