JP2019504464A - インプリント用インク組成物、インプリント方法、光学エレメント、照明装置、光センサ及び光起電力装置 - Google Patents
インプリント用インク組成物、インプリント方法、光学エレメント、照明装置、光センサ及び光起電力装置 Download PDFInfo
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Abstract
Description
これらのうちの任意の式の少なくとも1つの重合禁止剤と;を有する。
実施例の評価
スピンの結果
硬化後の幾つかの実施例の膜形成品質が、目視で検査され、1〜6の目盛上で分類された。該目盛において、
1=亀裂が入った層
2=はじかれた(dewetted)層
3〜4=中程度の均一性の層
5〜6=高均一性の層
達成することができる。
Claims (21)
- インプリント用インク組成物であって、
溶媒と、
前記溶媒中に溶解及び/又は分散される重合可能な含有物であって、該重合可能な含有物の全重量の少なくとも80重量%を形成する遷移金属酸化物粒子を有すると共に当該インプリント用インク組成物の全重量に対して2〜25重量%を形成する含有物と、
当該インプリント用インク組成物の全重量に対して0.07〜7.00重量%の範囲内で存在する下記の式1〜3:
これらのうちの任意の式の少なくとも1つの重合禁止剤と、
を有する、インプリント用インク組成物。 - 前記遷移金属酸化物粒子は1〜10nmの範囲の下限値から20〜40nmの範囲の上限値までの粒子寸法分布を有し、該粒子寸法分布が好ましくは5〜30nmである、請求項1に記載のインプリント用インク組成物。
- 前記遷移金属酸化物粒子が、TiO2、ZrO2、HfO2、Ta2O3、V2O3、Nb2O3、Y2O3、Fe2O3、BaTiO3及びSrTiO3粒子から選択される、請求項1又は請求項2に記載のインプリント用インク組成物。
- 前記遷移金属酸化物粒子が、アナターゼ又はルチルTi02粒子であり、好ましくはルチルTi02粒子である、請求項3に記載のインプリント用インク組成物。
- 前記重合可能な含有物の全重量に対して20重量%までのポリマ母材前駆物質を更に有する、請求項1ないし4の何れか一項に記載のインプリント用インク組成物。
- 前記ポリマ母材前駆物質がポリシロキサン前駆物質である、請求項5に記載のインプリント用インク組成物。
- アンモニアを有し、1より大きなpHを更に有する、請求項1ないし8の何れか一項に記載のインプリント用インク組成物。
- 前記溶媒は、水及びメタノールの少なくとも一方から選択され、オプションとして当該インプリント用インク組成物の全重量に対して30重量%までのプロポキシエタノールを更に有する、請求項1ないし9の何れか一項に記載のインプリント用インク組成物。
- パターン化された層を形成する方法であって、
パターン化された面を備えた弾性材料を有するスタンプを準備するステップと、
前記パターン化された面により請求項1ないし10の何れか一項に記載のインプリント用インク組成物をインプリントするステップと、
前記インプリント用インク組成物の前記重合可能な含有物を硬化させるステップと、
硬化された前記重合可能な含有物から前記スタンプを解き放して、前記パターン化された層を得るステップと、
を有する、方法。 - 前記弾性材料がポリシロキサン、好ましくはポリジメチルシロキサンである、請求項11に記載の方法。
- 前記インプリントされ硬化されたインプリント用インク組成物を、10〜60分の期間にわたり80〜120℃の範囲の温度まで加熱するステップを更に有する、請求項11又は請求項12に記載の方法。
- 請求項11ないし13の何れか一項に記載の方法により得ることが可能なパターン化された層を有する、光学エレメント。
- 前記パターン化された層が、少なくとも1.7、好ましくは少なくとも1.8、更に好ましくは少なくとも1.9の電磁スペクトルの可視範囲における屈折率を有する、請求項14に記載の光学エレメント。
- 当該光学エレメントが、レンズ、光散乱エレメント、コリメータ、光導入エレメント、導波器、又は、リング共振器、波長フィルタ及び振幅調整器のようなフォトニック装置である、請求項14又は請求項15に記載の光学エレメント。
- 少なくとも1つの固体光源と、該少なくとも1つの固体光源の発光出力の少なくとも一部を再指向させる請求項14ないし16の何れか一項に記載の光学エレメントとを有する、照明装置。
- 請求項14ないし16の何れか一項に記載の光学エレメントを有する、光センサ。
- 光起電力セル及び請求項14ないし16の何れか一項に記載の光学エレメントを有する、光起電力装置。
- 前記光学エレメントが前記光起電力セルのための光導入エレメントとして配置される、請求項19に記載の光起電力装置。
- 当該光起電力装置が太陽電池又は太陽電池パネルである、請求項19又は請求項20に記載の光起電力装置。
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