JP2010505977A - フェニルグリオキシレート型の光開始剤を含む光硬化性組成物 - Google Patents
フェニルグリオキシレート型の光開始剤を含む光硬化性組成物 Download PDFInfo
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- JP2010505977A JP2010505977A JP2009530842A JP2009530842A JP2010505977A JP 2010505977 A JP2010505977 A JP 2010505977A JP 2009530842 A JP2009530842 A JP 2009530842A JP 2009530842 A JP2009530842 A JP 2009530842A JP 2010505977 A JP2010505977 A JP 2010505977A
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- JP
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- Prior art keywords
- alkyl
- phenyl
- substituted
- optionally
- optionally substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000203 mixture Substances 0.000 title claims abstract description 131
- FAQJJMHZNSSFSM-UHFFFAOYSA-N phenylglyoxylic acid Chemical compound OC(=O)C(=O)C1=CC=CC=C1 FAQJJMHZNSSFSM-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 150000001875 compounds Chemical class 0.000 claims abstract description 80
- 239000003086 colorant Substances 0.000 claims abstract description 35
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 125000000217 alkyl group Chemical group 0.000 claims description 122
- -1 printing plate Substances 0.000 claims description 114
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 109
- 238000000576 coating method Methods 0.000 claims description 75
- 239000000049 pigment Substances 0.000 claims description 63
- 239000001257 hydrogen Substances 0.000 claims description 46
- 229910052739 hydrogen Inorganic materials 0.000 claims description 46
- 239000000463 material Substances 0.000 claims description 45
- 239000011248 coating agent Substances 0.000 claims description 44
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 42
- 239000000976 ink Substances 0.000 claims description 29
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- 238000000034 method Methods 0.000 claims description 24
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- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 21
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 21
- 125000002947 alkylene group Chemical group 0.000 claims description 19
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 15
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- 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims description 9
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- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 8
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- 125000001424 substituent group Chemical group 0.000 claims description 8
- 125000002993 cycloalkylene group Chemical group 0.000 claims description 7
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- 238000009472 formulation Methods 0.000 description 25
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- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 18
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- 229920001577 copolymer Polymers 0.000 description 16
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- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 15
- 239000000178 monomer Substances 0.000 description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
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- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 10
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 10
- 150000003077 polyols Chemical class 0.000 description 10
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- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
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- 239000011230 binding agent Substances 0.000 description 9
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
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- 238000005516 engineering process Methods 0.000 description 8
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- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 7
- 150000003254 radicals Chemical class 0.000 description 7
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- 239000000126 substance Substances 0.000 description 7
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 6
- 239000012965 benzophenone Substances 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 239000004611 light stabiliser Substances 0.000 description 6
- 239000012860 organic pigment Substances 0.000 description 6
- 229920000647 polyepoxide Polymers 0.000 description 6
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- 239000011541 reaction mixture Substances 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- 238000003848 UV Light-Curing Methods 0.000 description 5
- 239000006096 absorbing agent Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
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- 0 *CC(CC[S+](CCC(C*)=*)c(cc1)ccc1Sc1ccccc1)=* Chemical compound *CC(CC[S+](CCC(C*)=*)c(cc1)ccc1Sc1ccccc1)=* 0.000 description 4
- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 description 4
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 description 4
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 4
- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 4
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
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- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 4
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- 229910052744 lithium Inorganic materials 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
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- MYYLFDRHMOSOJJ-UHFFFAOYSA-N (3-methylphenyl)-(4-phenylphenyl)methanone Chemical compound CC1=CC=CC(C(=O)C=2C=CC(=CC=2)C=2C=CC=CC=2)=C1 MYYLFDRHMOSOJJ-UHFFFAOYSA-N 0.000 description 2
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- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/031—Organic compounds not covered by group G03F7/029
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/40—Unsaturated compounds
- C07C59/76—Unsaturated compounds containing keto groups
- C07C59/90—Unsaturated compounds containing keto groups containing singly bound oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
- C07C69/738—Esters of keto-carboxylic acids or aldehydo-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/0045—Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
- C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06121655 | 2006-10-03 | ||
| PCT/EP2007/060093 WO2008040650A2 (en) | 2006-10-03 | 2007-09-24 | Photocurable compositions comprising a photoinitiator of the phenylglyoxylate type |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2010505977A true JP2010505977A (ja) | 2010-02-25 |
| JP2010505977A5 JP2010505977A5 (enExample) | 2010-11-11 |
Family
ID=37642478
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009530842A Pending JP2010505977A (ja) | 2006-10-03 | 2007-09-24 | フェニルグリオキシレート型の光開始剤を含む光硬化性組成物 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20100022676A1 (enExample) |
| EP (1) | EP2069866A2 (enExample) |
| JP (1) | JP2010505977A (enExample) |
| CN (1) | CN101523289A (enExample) |
| WO (1) | WO2008040650A2 (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013014534A (ja) * | 2011-07-04 | 2013-01-24 | Daicel Corp | ベンゾイルギ酸化合物、及びその製造方法 |
| JP2013241006A (ja) * | 2012-05-17 | 2013-12-05 | Xerox Corp | デジタルオフセット印刷適用のためのインク |
| KR20200107879A (ko) * | 2019-03-08 | 2020-09-16 | 조병묵 | 낚시용 축광 도료 조성물 |
| JP2020532567A (ja) * | 2017-09-06 | 2020-11-12 | 常州強力電子新材料股▲分▼有限公司CHANGZHOU TRONLY NEW ELECTRONIC MATERIALS Co., Ltd. | スルホニウム塩光開始剤、その製造方法、それを含む光硬化性組成物及びその適用 |
| JP2023502311A (ja) * | 2019-10-11 | 2023-01-24 | アイジーエム レシンス イタリア ソチエタ レスポンサビリタ リミタータ | Led光硬化用のクマリングリオキシレート |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7943080B2 (en) * | 2005-12-23 | 2011-05-17 | Asml Netherlands B.V. | Alignment for imprint lithography |
| WO2010077132A1 (en) | 2008-12-31 | 2010-07-08 | Draka Comteq B.V. | Uvled apparatus for curing glass-fiber coatings |
| DK2388239T3 (da) | 2010-05-20 | 2017-04-24 | Draka Comteq Bv | Hærdningsapparat, der anvender vinklede UV-LED'er |
| US8871311B2 (en) | 2010-06-03 | 2014-10-28 | Draka Comteq, B.V. | Curing method employing UV sources that emit differing ranges of UV radiation |
| WO2011160262A1 (zh) * | 2010-06-25 | 2011-12-29 | 北京英力科技发展有限公司 | 低挥发性苯甲酰基甲酸酯 |
| CN102442909B (zh) * | 2010-06-25 | 2013-10-30 | 北京英力科技发展有限公司 | 低挥发低迁移性苯甲酰基甲酸酯 |
| EP2418183B1 (en) | 2010-08-10 | 2018-07-25 | Draka Comteq B.V. | Method for curing coated glass fibres providing increased UVLED intensitiy |
| CN102002022B (zh) * | 2010-10-29 | 2013-05-08 | 苏州凯康化工科技有限公司 | 一种月桂酸改性环氧丙烯酸酯及其制备方法和应用 |
| CN102746785B (zh) * | 2011-04-19 | 2014-12-17 | 比亚迪股份有限公司 | 一种双重固化涂料组合物及其固化方法 |
| ITVA20120010A1 (it) * | 2012-05-03 | 2013-11-04 | Lamberti Spa | Alfa-dichetoni per fotopolimerizzazioni tramite led |
| ITVA20120041A1 (it) * | 2012-10-22 | 2014-04-23 | Lamberti Spa | 3-chetocumarine per fotopolimerizzazioni tramite led |
| US8916334B2 (en) | 2013-01-28 | 2014-12-23 | Hewlett-Packard Development Company, L.P. | Micro-composite material for three-dimensional printing |
| DE102014103923A1 (de) * | 2013-04-05 | 2014-10-09 | Fischerwerke Gmbh & Co. Kg | Kunstharz-Verklebungsmittel mit biogenen reaktiven Verdünnern und Harzen |
| KR101391225B1 (ko) * | 2013-09-05 | 2014-05-07 | 동우 화인켐 주식회사 | 비표시부 차광 패턴 형성용 감광성 수지 조성물 |
| US9422436B2 (en) * | 2014-01-13 | 2016-08-23 | Xerox Corporation | Methods for producing inks |
| MX2016016633A (es) | 2014-06-23 | 2017-06-06 | Carbon Inc | Resinas de poliuretano que tienen multiples mecanismos de endurecimiento para usarse en la produccion de objetos tridimensionales. |
| CN105517648B (zh) | 2014-12-10 | 2017-06-20 | 互应化学工业株式会社 | 液体阻焊剂组合物和被覆印刷线路板 |
| DE102015121562B4 (de) * | 2015-12-10 | 2021-05-06 | Coroplast Fritz Müller Gmbh & Co. Kg | Hochtemperaturbeständiges farbiges, insbesondere orangefarbiges, Klebeband, Verfahren zu seiner Herstellung, Verwendung eines Trägers zu seiner Herstellung sowie Verwendung des Klebebandes zur Herstellung von Kabelbäumen |
| US10316213B1 (en) | 2017-05-01 | 2019-06-11 | Formlabs, Inc. | Dual-cure resins and related methods |
| CN107239002B (zh) * | 2017-07-07 | 2019-12-06 | 深圳市华星光电技术有限公司 | Uv固化粉末光阻组合物及其制作方法、彩膜基板的制作方法 |
| CN109503735A (zh) * | 2017-09-15 | 2019-03-22 | 常州强力先端电子材料有限公司 | 光引发剂、包含其的光固化组合物及其应用 |
| CN111433268B (zh) | 2017-11-29 | 2022-07-05 | 康宁股份有限公司 | 高度负载的无机填充的水性树脂体系 |
| EP3597669A1 (en) | 2018-07-20 | 2020-01-22 | Clariant International Ltd | Photo-curable resin composition for 3d printing |
| EP3597668A1 (en) | 2018-07-20 | 2020-01-22 | Clariant International Ltd | Photo-curable resin composition for 3d printing |
| CN110804337A (zh) * | 2019-11-06 | 2020-02-18 | 甘肃天后光学科技有限公司 | 隐形眼镜彩色油墨、所用光亮剂及其制备方法 |
| DE102022000134A1 (de) | 2022-01-15 | 2023-07-20 | Polystal Composites Gmbh | Verfahren zur Härtung eines Glasfasercompositmaterials |
| CN117865923A (zh) * | 2024-01-08 | 2024-04-12 | 湖北固润科技股份有限公司 | 甲酰甲酸香豆素化合物、其制备方法和用途以及包含其的光引发剂组合物和可光固化组合物 |
| CN120865455A (zh) * | 2024-04-30 | 2025-10-31 | 常州强力先端电子材料有限公司 | 一种光固化组合物及其应用 |
| CN120865125A (zh) * | 2024-04-30 | 2025-10-31 | 常州强力先端电子材料有限公司 | 一种光引发剂及其制备方法和应用 |
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| WO2006067061A2 (en) * | 2004-12-22 | 2006-06-29 | Ciba Specialty Chemicals Holding Inc. | Process for the production of strongly adherent coatings |
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| US3856529A (en) * | 1967-05-26 | 1974-12-24 | Kalle Ag | Method and materials for making half tone prints |
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| US4038164A (en) * | 1975-09-18 | 1977-07-26 | Stauffer Chemical Company | Photopolymerizable aryl and heterocyclic glyoxylate compositions and process |
| US4024296A (en) * | 1976-02-02 | 1977-05-17 | Ppg Industries, Inc. | Photocatalyst system and pigmented actinic light polymerizable coating compositions containing the same |
| US4475999A (en) * | 1983-06-06 | 1984-10-09 | Stauffer Chemical Company | Sensitization of glyoxylate photoinitiators |
| JP2588330B2 (ja) * | 1991-09-25 | 1997-03-05 | 積水化学工業株式会社 | 光硬化型樹脂組成物の硬化方法 |
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| DE19913353A1 (de) * | 1999-03-24 | 2000-09-28 | Basf Ag | Verwendung von Phenylglyoxalsäureestern als Photoinitiatoren |
| TWI244495B (en) * | 2000-08-14 | 2005-12-01 | Ciba Sc Holding Ag | Process for producing coatings siloxane photoinitiators |
| CA2483004A1 (en) * | 2002-04-26 | 2003-11-06 | Ciba Specialty Chemicals Holding Inc. | Incorporable photoinitiator |
-
2007
- 2007-09-24 US US12/442,779 patent/US20100022676A1/en not_active Abandoned
- 2007-09-24 JP JP2009530842A patent/JP2010505977A/ja active Pending
- 2007-09-24 WO PCT/EP2007/060093 patent/WO2008040650A2/en not_active Ceased
- 2007-09-24 EP EP07820500A patent/EP2069866A2/en not_active Withdrawn
- 2007-09-24 CN CNA2007800368558A patent/CN101523289A/zh active Pending
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| JPS5523186A (en) * | 1978-07-13 | 1980-02-19 | Ciba Geigy Ag | Photoohardening composition |
| JP2001511137A (ja) * | 1997-01-30 | 2001-08-07 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | 不揮発性フェニルグリオキシル酸エステル |
| WO2006067061A2 (en) * | 2004-12-22 | 2006-06-29 | Ciba Specialty Chemicals Holding Inc. | Process for the production of strongly adherent coatings |
| JP2008523987A (ja) * | 2004-12-22 | 2008-07-10 | チバ ホールディング インコーポレーテッド | 強接着性コーティングの製造方法 |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013014534A (ja) * | 2011-07-04 | 2013-01-24 | Daicel Corp | ベンゾイルギ酸化合物、及びその製造方法 |
| JP2013241006A (ja) * | 2012-05-17 | 2013-12-05 | Xerox Corp | デジタルオフセット印刷適用のためのインク |
| JP2020532567A (ja) * | 2017-09-06 | 2020-11-12 | 常州強力電子新材料股▲分▼有限公司CHANGZHOU TRONLY NEW ELECTRONIC MATERIALS Co., Ltd. | スルホニウム塩光開始剤、その製造方法、それを含む光硬化性組成物及びその適用 |
| JP7025531B2 (ja) | 2017-09-06 | 2022-02-24 | 常州強力電子新材料股▲分▼有限公司 | スルホニウム塩光開始剤、その製造方法、それを含む光硬化性組成物及びその適用 |
| US11535590B2 (en) | 2017-09-06 | 2022-12-27 | Changzhou Tronly New Electronic Materials Co., Ltd. | Sulfonium salt photoinitiator, preparation method therefor, photocurable composition comprising sulfonium salt photoinitiator, and use thereof |
| KR20200107879A (ko) * | 2019-03-08 | 2020-09-16 | 조병묵 | 낚시용 축광 도료 조성물 |
| KR102406534B1 (ko) * | 2019-03-08 | 2022-06-07 | 조병묵 | 낚시용 축광 도료 조성물 |
| JP2023502311A (ja) * | 2019-10-11 | 2023-01-24 | アイジーエム レシンス イタリア ソチエタ レスポンサビリタ リミタータ | Led光硬化用のクマリングリオキシレート |
| JP7697458B2 (ja) | 2019-10-11 | 2025-06-24 | アイジーエム レシンス イタリア ソチエタ レスポンサビリタ リミタータ | Led光硬化用のクマリングリオキシレート |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101523289A (zh) | 2009-09-02 |
| EP2069866A2 (en) | 2009-06-17 |
| US20100022676A1 (en) | 2010-01-28 |
| WO2008040650A2 (en) | 2008-04-10 |
| WO2008040650A3 (en) | 2009-01-08 |
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