JP2010503638A - 殺虫剤組成物 - Google Patents
殺虫剤組成物 Download PDFInfo
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- JP2010503638A JP2010503638A JP2009527825A JP2009527825A JP2010503638A JP 2010503638 A JP2010503638 A JP 2010503638A JP 2009527825 A JP2009527825 A JP 2009527825A JP 2009527825 A JP2009527825 A JP 2009527825A JP 2010503638 A JP2010503638 A JP 2010503638A
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- 229920000620 organic polymer Polymers 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- 210000001672 ovary Anatomy 0.000 description 1
- KZAUOCCYDRDERY-UHFFFAOYSA-N oxamyl Chemical compound CNC(=O)ON=C(SC)C(=O)N(C)C KZAUOCCYDRDERY-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- PMCVMORKVPSKHZ-UHFFFAOYSA-N oxydemeton-methyl Chemical compound CCS(=O)CCSP(=O)(OC)OC PMCVMORKVPSKHZ-UHFFFAOYSA-N 0.000 description 1
- LCCNCVORNKJIRZ-UHFFFAOYSA-N parathion Chemical compound CCOP(=S)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 LCCNCVORNKJIRZ-UHFFFAOYSA-N 0.000 description 1
- RLBIQVVOMOPOHC-UHFFFAOYSA-N parathion-methyl Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C=C1 RLBIQVVOMOPOHC-UHFFFAOYSA-N 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- XAMUDJHXFNRLCY-UHFFFAOYSA-N phenthoate Chemical compound CCOC(=O)C(SP(=S)(OC)OC)C1=CC=CC=C1 XAMUDJHXFNRLCY-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 150000008048 phenylpyrazoles Chemical class 0.000 description 1
- LMNZTLDVJIUSHT-UHFFFAOYSA-N phosmet Chemical compound C1=CC=C2C(=O)N(CSP(=S)(OC)OC)C(=O)C2=C1 LMNZTLDVJIUSHT-UHFFFAOYSA-N 0.000 description 1
- RGCLLPNLLBQHPF-HJWRWDBZSA-N phosphamidon Chemical compound CCN(CC)C(=O)C(\Cl)=C(/C)OP(=O)(OC)OC RGCLLPNLLBQHPF-HJWRWDBZSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- FSDNTQSJGHSJBG-UHFFFAOYSA-N piperidine-4-carbonitrile Chemical compound N#CC1CCNCC1 FSDNTQSJGHSJBG-UHFFFAOYSA-N 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- YFGYUFNIOHWBOB-UHFFFAOYSA-N pirimicarb Chemical compound CN(C)C(=O)OC1=NC(N(C)C)=NC(C)=C1C YFGYUFNIOHWBOB-UHFFFAOYSA-N 0.000 description 1
- QHOQHJPRIBSPCY-UHFFFAOYSA-N pirimiphos-methyl Chemical group CCN(CC)C1=NC(C)=CC(OP(=S)(OC)OC)=N1 QHOQHJPRIBSPCY-UHFFFAOYSA-N 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 235000021118 plant-derived protein Nutrition 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229940116317 potato starch Drugs 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- QYMMJNLHFKGANY-UHFFFAOYSA-N profenofos Chemical compound CCCSP(=O)(OCC)OC1=CC=C(Br)C=C1Cl QYMMJNLHFKGANY-UHFFFAOYSA-N 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- RZKYDQNMAUSEDZ-UHFFFAOYSA-N prop-2-enylphosphonic acid Chemical compound OP(O)(=O)CC=C RZKYDQNMAUSEDZ-UHFFFAOYSA-N 0.000 description 1
- ZYHMJXZULPZUED-UHFFFAOYSA-N propargite Chemical compound C1=CC(C(C)(C)C)=CC=C1OC1C(OS(=O)OCC#C)CCCC1 ZYHMJXZULPZUED-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- FITIWKDOCAUBQD-UHFFFAOYSA-N prothiofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(Cl)C=C1Cl FITIWKDOCAUBQD-UHFFFAOYSA-N 0.000 description 1
- DDIQWGKUSJOETH-UHFFFAOYSA-N pyrafluprole Chemical compound ClC=1C=C(C(F)(F)F)C=C(Cl)C=1N1N=C(C#N)C(SCF)=C1NCC1=CN=CC=N1 DDIQWGKUSJOETH-UHFFFAOYSA-N 0.000 description 1
- ROVGZAWFACYCSP-VUMXUWRFSA-N pyrethrin I Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-VUMXUWRFSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 description 1
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 229940100486 rice starch Drugs 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 150000003385 sodium Chemical class 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 239000001589 sorbitan tristearate Substances 0.000 description 1
- 235000011078 sorbitan tristearate Nutrition 0.000 description 1
- 229960004129 sorbitan tristearate Drugs 0.000 description 1
- 229940014213 spinosad Drugs 0.000 description 1
- DTDSAWVUFPGDMX-UHFFFAOYSA-N spirodiclofen Chemical compound CCC(C)(C)C(=O)OC1=C(C=2C(=CC(Cl)=CC=2)Cl)C(=O)OC11CCCCC1 DTDSAWVUFPGDMX-UHFFFAOYSA-N 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- CLSVJBIHYWPGQY-GGYDESQDSA-N spirotetramat Chemical compound CCOC(=O)OC1=C(C=2C(=CC=C(C)C=2)C)C(=O)N[C@@]11CC[C@H](OC)CC1 CLSVJBIHYWPGQY-GGYDESQDSA-N 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- JXHJNEJVUNHLKO-UHFFFAOYSA-N sulprofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(SC)C=C1 JXHJNEJVUNHLKO-UHFFFAOYSA-N 0.000 description 1
- 239000004546 suspension concentrate Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 description 1
- 235000012756 tartrazine Nutrition 0.000 description 1
- 239000004149 tartrazine Substances 0.000 description 1
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 description 1
- ZZYSLNWGKKDOML-UHFFFAOYSA-N tebufenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(=CC=2)C(C)(C)C)=C1Cl ZZYSLNWGKKDOML-UHFFFAOYSA-N 0.000 description 1
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- BAKXBZPQTXCKRR-UHFFFAOYSA-N thiodicarb Chemical compound CSC(C)=NOC(=O)NSNC(=O)ON=C(C)SC BAKXBZPQTXCKRR-UHFFFAOYSA-N 0.000 description 1
- 235000010215 titanium dioxide Nutrition 0.000 description 1
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- 229940074410 trehalose Drugs 0.000 description 1
- VPYJNCGUESNPMV-UHFFFAOYSA-N triallylamine Chemical compound C=CCN(CC=C)CC=C VPYJNCGUESNPMV-UHFFFAOYSA-N 0.000 description 1
- NKNFWVNSBIXGLL-UHFFFAOYSA-N triazamate Chemical compound CCOC(=O)CSC1=NC(C(C)(C)C)=NN1C(=O)N(C)C NKNFWVNSBIXGLL-UHFFFAOYSA-N 0.000 description 1
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 230000002485 urinary effect Effects 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 229960000834 vinyl ether Drugs 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 239000012138 yeast extract Substances 0.000 description 1
- 239000005943 zeta-Cypermethrin Substances 0.000 description 1
- FYGDTMLNYKFZSV-BYLHFPJWSA-N β-1,4-galactotrioside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@H](CO)O[C@@H](O[C@@H]2[C@@H](O[C@@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-BYLHFPJWSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
- A01N25/006—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Insects & Arthropods (AREA)
- Food Science & Technology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Abstract
【選択図】なし
Description
(i)0.001〜50重量%の、節足動物害虫に対して活性を有する少なくとも1種の殺虫性化合物、
(ii)0.5〜20重量%の、ポリマーPの1g当たり少なくとも100gの脱イオン水に対する吸収能力を有する少なくとも1種の超吸収性ポリマーP、及び
(iii)5〜94.5重量%の、水と異なる少なくとも1種の賦形剤物質、及び
(iv)5〜94.5重量%の水
[ここで、重量%は組成物の総重量に基づく]
を含有する、ゲル又は固体の形態の殺虫剤組成物に関する。
A.1. 有機(チオ)ホスフェート系:
例えば、アセフェート、アザメチホス、アジンホス-メチル、クロルピリホス、クロルピリホス-メチル、クロルフェンビンホス、ジアジノン、ジクロルボス、ジクロトホス、ジメトエート、ジスルホトン、エチオン、フェニトロチオン、フェンチオン、イソキサチオン、マラチオン、メタミドホス、メチダチオン、メチル-パラチオン、メビンホス、モノクロトホス、オキシデメトン-メチル、パラオキソン、パラチオン、フェントエート、ホサロン、ホスメット、ホスファミドン、ホレート、ホキシム、ピリミホス-メチル、プロフェノホス、プロチオホス、スルプロホス、テトラクロルビンホス、テルブホス、トリアゾホス、トリクロルホン;
例えば、アラニカルブ、アルジカルブ、ベンジオカルブ、ベンフラカルブ、カルバリル、カルボフラン、カルボスルファン、フェノキシカルブ、フラチオカルブ、メチオカルブ、メトミル、オキサミル、ピリミカルブ、プロポクスル、チオジカルブ、トリアザメート;
例えば、アレトリン、ビフェントリン、シフルトリン、シハロトリン、シフェノトリン、シペルメトリン、アルファ-シペルメトリン、ベータ-シペルメトリン、ゼータ-シペルメトリン、デルタメトリン、エスフェンバレレート、エトフェンプロクス、フェンプロパトリン、フェンバレレート、イミプロトリン、ラムダ-シハロトリン、ペルメトリン、プラレトリン、ピレトリンI及びII、レスメトリン、シラフルオフェン、タウ-フルバリネート、テフルトリン、テトラメトリン、トラロメトリン、トランスフルトリン、プロフルトリン、ジメフルトリン;
a) キチン合成インヒビター:
例えば、ベンゾイル尿素:クロルフルアズロン、ジフルベンズロン、フルシクロクスロン、フルフェノクスロン、ヘキサフルムロン、ルフェヌロン、ノバルロン、テフルベンズロン、トリフルムロン;ブプロフェジン、ジオフェノラン、ヘキシチアゾクス、エトキサゾール、クロフェンタジン;
b) エクジソン拮抗物質:
例えば、ハロフェノジド、メトキシフェノジド、テブフェノジド、アザジラクチン;
c) ジュベノイド:
例えば、ピリプロキシフェン、メトプレン、フェノキシカルブ;
d) 脂質生合成インヒビター:
例えば、スピロジクロフェン、スピロメシフェン又はスピロテトラマト;
例えば、クロチアニジン、ジノテフラン、イミダクロプリド、チアメトキサム、ニテンピラム、アセタミプリド、チアクロプリド、又は式P1のトリアゾール化合物:
例えば、アセトプロール、エンドスルファン、エチプロール、フィプロニル、バニリプロール、ピラフルプロール、ピリプロール、又は式P2のフェニルピラゾール化合物(5-アミノ-3-(アミノチオカルボニル)-1-(2,6-ジクロロ-4-トリフルオロメチルフェニル)-4-(トリフルオロメチルスルフィニル)-ピラゾール):
例えばフェナザキン、ピリダベン、テブフェンピラド、トルフェンピラド、フルフェネリム;
A.9. ミトコンドリア複合体II及び/又は複合体III電子伝達インヒビター(METI II及びIII化合物):
例えばアセキノシル、フルアシプリム、ヒドラメチルノン;
A.10. 脱共役化合物:
例えばクロルフェナピル;
シヘキサチン、ジアフェンチウロン、酸化フェンブタスズ、プロパルギット;
A.12. 脱皮阻害化合物:
例えばシロマジン;
A.13. 混合機能オキシダーゼインヒビター化合物:
例えばピペロニルブトキシド;
A.14. ナトリウムチャネルブロッカー化合物:
例えばインドキサカルブ、メタフルミゾン;
ベンクロチアズ、ビフェナゼート、カルタップ、フロニカミド、ピリダリル、ピメトロジン、硫黄、チオシクラム、フルベンジアミド、シエノピラフェン、フルピラゾホス、シフルメトフェン、アミドフルメト、式P4のアミノキナゾリノン化合物(1-アセチル-2-オキソ-3-(ピリジン-3-イルメチル)アミノ-6-ヘプタフルオロプロピル-1,2,3,4-テトラヒドロキナゾリン):
X及びYは各々独立してハロゲン(特に、塩素)であり、
Wはハロゲン又はC1-C2-ハロアルキル(特に、チオフルオロメチル)であり、
R1は各々が1、2、3、4又は5個のハロゲン原子で置換されていてもよいC1-C6-アルキル、C2-C6-アルケニル、C2-C6-アルキニル、C1-C4-アルコキシ-C1-C4-アルキル又はC3-C6-シクロアルキル(特に、R1はメチル又はエチル)であり、
R2及びR3はC1-C6-アルキル(特に、メチル)であるか、又は隣接炭素原子と一緒になって1、2若しくは3個のハロゲン原子を有していてもよいC3-C6-シクロアルキル部分(特に、2,2-ジクロロシクロプロピル及び2,2-ジブロモシクロプロピルを含めたシクロプロピル部分)を形成していてもよく、
R4は水素又はC1-C6-アルキル(特に水素、メチル又はエチル)である。];
例えば、下記の式P5a及びP5bの化合物:
A1はCH3、Cl、Br、Iであり、
XはC-H、C-Cl、C-F又はNであり、
Y’はF、Cl又はBrであり、
Y”はF、Cl又はCF3であり、
B1は水素、Cl、Br、I、CNであり、
B2はCl、Br、CF3、OCH2CF3、OCF2Hであり、
RBは水素、CH3又はCH(CH3)2である。];
並びに、JP 2002 284608号、WO 02/89579号、WO 02/90320号、WO 02/90321号、WO 04/06677号、WO 04/20399号、又はJP 2004 99597号に記載されているマロノニトリル化合物。
鱗翅類(鱗翅目)、例えば、タマナヤガ(アグロチス・イプシロン(Agrotis ypsilon))、カブラヤガ(アグロチス・セゲツム(Agrotis segetum))、アラバマ・アルギラセア(Alabama argillacea)、アンチカルシア・ゲンマタリス(Anticarsia gemmatalis)、リンゴヒメシンクイ(アルギレスチア・コンジュゲラ(Argyresthia conjugella))、ガマキンウワバ(オートグラファ・ガンマ(Autographa gamma))、ブパルス・ピニアリウス(Bupalus piniarius)、カコエシア・ムリナナ(Cacoecia murinana)、カプア・レチクラナ(Capua reticulana)、ケイマトビア・ブルマタ(Cheimatobia brumata)、トウヒノシントメハマキ(コリストネウラ・フミフェラナ(Choristoneura fumiferana))、コリストネウラ・オクシデンタリス(Choristoneura occidentalis)、アワヨトウ(シルフィス・ウニプンクタ(Cirphis unipuncta))、コドリンガ(シジア・ポモネラ(Cydia pomonella))、デンドロリムス・ピニ(Dendrolimus pini)、アメリカウリノメイガ(ジアファニア・ニチダリス(Diaphania nitidalis))、サウスウエスタンコーンボーラー(ジアトラエア・グランジオセラ(Diatraea grandiosella))、エアリアス・インスラナ(Earias insulana)、エラスモパルプス・リグノセルス(Elasmopalpus lignosellus)、ユーポエシリア・アンビグエラ(Eupoecilia ambiguella)、エベトリア・ボウリアナ(Evetria bouliana)、フェルチア・スブテラネア(Feltia subterranea)、ガレリア・メロネラ(Galleria mellonella)、グラホリタ・フネブラナ(Grapholitha funebrana)、グラホリタ・モレスタ(Grapholitha molesta)、ヘリオチス・アルミゲラ(Heliothis armigera)、ヘリオチス・ビレセンス(Heliothis virescens)、ヘリオチス・ゼア(Heliothis zea)、ヘルラ・ウンダリス(Hellula undalis)、ヒベルニア・デホリアリア(Hibernia defoliaria)、ヒファントリア・クネア(Hyphantria cunea)、ヒポノメウタ・マリネルス(Hyponomeuta malinellus)、ケイフェリア・リコペルシセラ(Keiferia lycopersicella)、ランブジナ・フィセラリア(Lambdina fiscellaria)、ラフィグマ・エキシグア(Laphygma exigua)、ロイコプテラ・コフェエラ(Leucoptera coffeella)、ロイコプテラ・シテラ(Leucoptera scitella)、リトコレチス・ブランカルデラ(Lithocolletis blancardella)、ロベシア・ボトラナ(Lobesia botrana)、ロキソステージ・スチクチカリス(Loxostege sticticalis)、リマントリア・ジスパル(Lymantria dispar)、リマントリア・モナカ(Lymantria monacha)、リオネチア・クレルケラ(Lyonetia clerkella)、マラコソマ・ネウストリア(Malacosoma neustria)、マメストラ・ブラッシカエ(Mamestra brassicae)、オルギイア・プソイドツガタ(Orgyia pseudotsugata)、オストリニア・ヌビラリス(Ostrinia nubilalis)、パノリス・フランメア(Panolis flammea)、ペクチノホラ・ゴッシピエラ(Pectinophora gossypiella)、ペリドロマ・サウシア(Peridroma saucia)、ファレラ・ブセファラ(Phalera bucephala)、フトリマエア・オペルクレラ(Phthorimaea operculella)、フィロクニスチス・シトレラ(Phyllocnistis citrella)、ピエリス・ブラッシカ(Pieris brassicae)、プラチペナ・スカブラ(Plathypena scabra)、プルテラ・キシロステラ(Plutella xylostella)、プソイドプルシア・インクルデンス(Pseudoplusia includens)、リアシオニア・フルストラナ(Rhyacionia frustrana)、スクロビパルプラ・アブソルタ(Scrobipalpula absoluta)、シトトロガ・セレアレラ(Sitotroga cerealella)、スパルガノチス・ピレリアナ(Sparganothis pilleriana)、スポドプテラ・フルギペルダ(Spodoptera frugiperda)、スポドプテラ・リットラリス(Spodoptera littoralis)、スポドプテラ・リツラ(Spodoptera litura)、タウマトポエア・ピチオカンパ(Thaumatopoea pityocampa)、トルトリキス・ビリダナ(Tortrix viridana)、トリコプルシアニ(Trichoplusiani)、及びゼイラフェラ・カナデンシス(Zeiraphera canadensis)、
ノミ(隠翅目)、例えば、クテノセファリデス・フェリス(Ctenocephalides felis)、クテノセファリデス・カニス(Ctenocephalides canis)、ゼノプシラ・ケオピス(Xenopsylla cheopis)、プレックス・イリタンス(Pulex irritans)、ツンガ・ペネトランス(Tunga penetrans)、及びノソフィルス・ファスキアツス(Nosopsyllus fasciatus)。
−(酸性形態で計算して)15〜89.9重量%、特に20〜79.8重量%の少なくとも1種のカルボン酸CA又はその塩、好ましくはアクリル酸又はその塩(特に、そのアルカリ金属塩)、より好ましくはアクリル酸のカリウム塩、
−10〜84.9重量%、特に20〜79.8重量%の少なくとも1種のアミドAM、好ましくは3〜8個の炭素原子を有するモノエチレン性不飽和モノカルボン酸のアミド、特にアクリルアミド、及び
−0.1〜10重量%、特に0.2〜5重量%の少なくとも1種の架橋剤モノマー
を重合形態で含み、重量%は酸性形態の超吸収性ポリマーを基準とし、モノマーAM及びCAの量は超吸収性ポリマーを形成するモノマーの少なくとも90%(例えば、90〜99.9%)を占めているか、あるいはモノマーAM及びCAの合計量が、酸性形態の超吸収性ポリマーを基準として少なくとも80重量%、より好ましくは少なくとも90重量%、特には90〜99.9%を構成する。
−15〜89.9重量%、特に20〜79.8重量%の少なくとも1種のカルボン酸CA、好ましくはアクリル酸、
−(酸性形態で計算して)10〜84.9重量%、特に20〜79.8重量%の少なくとも1種の又はその塩(特に、そのアルカリ金属塩)、より好ましくはアクリル酸のカリウム塩、及び
−0.1〜10重量%、特に0.2〜5重量%の少なくとも1つの架橋剤モノマー
を重合形態で含み、重量%は酸性形態の超吸収性ポリマーを基準とし、カルボン酸CA及びCAの塩の量は、超吸収性ポリマーを形成するモノマーの少なくとも90%(例えば、90〜99.9%)を占めているか、あるいはカルボン酸CA及びCAの塩の合計量が、酸性形態の超吸収性ポリマーを基準として少なくとも80重量%、より好ましくは少なくとも90重量%、特には90〜99.9%を構成する。
・生物信号化学物質(セミオケミカル)、例えばフェロモン、特に性フェロモン及び集合フェロモン、カイロモン、並びに
・天然又は合成起源の香味料。
・動物タンパク質及び植物タンパク質を含むタンパク質、例えば、肉粉、魚粉、魚エキス、魚介、魚介エキス、又は血粉、昆虫部分、コオロギ粉、酵母エキス、卵黄、タンパク質加水分解物、酵母自己消化物、グルテン加水分解物などの形態のもの;
・炭水化物及び水素化炭水化物、特に単糖及び二糖、例えばグルコース、アラビノース、フルクトース、マンノース、スクロース(ショ糖)、ラクトース、ガラクトース、マルトース、マルトトリオース、マルトテトロース、マルトペントース、又はこれらの混合物、例えば糖蜜、コーンシロップ、メープルシロップ、転化糖及びハチミツ;多糖、例えばデンプン、例としてジャガイモデンプン、コーンスターチ、及びデンプンベースの物質、例えば穀粉(例:小麦粉、トウモロコシ粉、麦芽粉、米粉、米糠)、ペクチン、及びグリセロール、水素化単糖及びオリゴ糖(糖アルコール)、例えばキシリトール、ソルビトール、マンニトール、イソマルトロース、トレハロース及びマルチトール、並びにマルチトール含有シロップ;
・脂肪及び油、例えば植物油、例としてトウモロコシ油、オリーブ油、カラウェー油、亜麻仁油、キャノーラ油、ピーナッツ油、菜種油、ゴマ油、ダイズ油、ヒマワリ油、動物起源の脂肪及び油、例えば魚ベースの油、そしてまた上記の脂肪及び油から誘導される脂肪酸。
a)分散剤、湿潤剤及び乳化剤などの界面活性剤、
b)有機溶媒、
c)脱泡剤(消泡剤)、
d)増粘剤、
e)保存剤、
f)染料又は顔料、並びに
g)忌避剤
が含まれる。
(a1)アニオン性界面活性剤、例えば通常アルカリ金属塩、アルカリ土類金属塩又はアンモニウム塩の形態、特にナトリウム、カリウム、カルシウム又はアンモニウム塩の形態の、
−アルキルスルホネート(例えば、ラウリルスルホネート又はイソトリデシルスルホネート)、
−アルキルスルフェート、特に脂肪アルコールスルフェート(例えば、ラウリルスルフェート、イソトリデシルスルフェート、セチルスルフェート、ステアリルスルフェート)、
−アリール-及びアルキルアリールスルホネート(例えば、ナフチルスルホネート、ジブチルナフチルスルホネート、ドデシルジフェニルエーテルスルホネート、クミルスルホネート、ノニルベンゼンスルホネート、ドデシルベンゼンスルホネート)、
−脂肪酸及び脂肪酸エステルのスルホネート、
−脂肪酸及び脂肪酸エステルのスルフェート、
−アルコキシル化アルカノールのスルフェート(例えば、エトキシル化ラウリルアルコールのスルフェート)、
−アルコキシル化アルキルフェノールのスルフェート、
−アルキルホスフェート、C8-C16アルキルホスフェート、
−ジアルキルホスフェート、C8-C16ジアルキルホスフェート、
−スルホコハク酸のジアルキルエステル(例えば、ジオクチルスルホスクシネート)、
−アシルサルコシネート、
−脂肪酸(例えば、ステアレート)、
−アシルグルタメート、及び
−リグニンスルホネート;
(a2)非イオン性界面活性剤、例えば
−アルコキシル化アルカノール、特にエトキシル化脂肪アルコール及びエトキシル化オキソアルコール(例えば、エトキシル化ラウリルアルコール、エトキシル化イソトリデカノール、エトキシル化セチルアルコール、エトキシル化ステアリルアルコール)及びそのエステル(例えば、アセテート)、
−アルコキシル化アルキルフェノール(例えば、エトキシル化ノニルフェニル、エトキシル化ドデシルフェニル、エトキシル化イソトリデシルフェノール)及びそのエステル(例えば、アセテート)、
−アルキルグルコシド及びアルキルポリグルコシド、
−コポリマー、特にエチレンオキシドとプロピレンオキシドのブロックコポリマー、
−エトキシル化アルキルグルコシド及びアルキルポリグルコシド、
−エトキシル化脂肪アミン、
−エトキシル化脂肪酸、
−部分エステル、例えば脂肪酸とグリセリン又はソルビタンのモノ-、ジ-及びトリエステル(例えば、グリセリンモノステアレート、ソルビタンモノオレエート、ソルビタントリステアレート)、
−脂肪酸とグリセリン又はソルビタンのエトキシル化部分エステル(例えば、エトキシル化グリセリンモノステアレート)、
−植物油又は獣脂のエトキシレート(例えば、コーン油エトキシレート、ヒマシ油エトキシレート、獣油エトキシレート)、
−脂肪アミン、脂肪アミド又は脂肪酸ジエタノールアミドのエトキシレート;
(a3)カチオン性界面活性剤、例えば
−第4級アンモニウム化合物、特にアルキルトリメチルアンモニウム塩及びジアルキルジメチルアンモニウム塩(例えば、ハライド、スルフェート及びアルキルスルフェート)、
−ピリジニウム塩、特にアルキルピリジニウム塩(例えば、ハライド、スルフェート及びC1-C4-アルキルスルフェート)、並びに
−イミダゾリニウム塩、特にN,N’-ジアルキルイミダゾリニウム塩(例えば、ハライド、スルフェート及びメトキシスルフェート)
が含まれる。
超吸収性ポリマーSAP1:400g/gのDI(脱イオン)水を吸水する能力及び0.3mm未満の粒径を有する、アクリル酸カリウムとアクリルアミドの架橋コポリマーの粉末(Aquasorb 3005 S、SNF FLOERGER, Andrezieux, France)。
超吸収性ポリマーSAP2:240g/gのDI水を吸水する能力及び0.1mm未満の粒径を有する、アクリル酸カリウムとアクリル酸の架橋コポリマーの粉末(Luqasorb(登録商標)1010、BASF Aktiengesellschaft, Germany)。
殺虫剤製剤P2:240g/Lのメタフルミゾン、10.8g/Lの(エチレンオキシド/プロピレンオキシド)コポリマー(EO/POポリマー)、97.4gの界面活性剤混合物、54.1g/Lのプロピレングリコール、5.4g/Lの消泡剤、1.1g/lの殺生物剤、1.7g/Lのキサンタンガム及び水(1Lまで加える)を含有する、水性懸濁液濃縮物。
殺虫剤製剤P3:化合物P5a、界面活性剤混合物、増粘剤、殺生物剤、消泡剤及び水(1Lまで加える)を含有する、水性懸濁液濃縮物。
殺虫剤製剤P4:約75重量%の化合物P5a、11重量%の界面活性剤混合物及び24重量%のカオリン粘土を含有する、粉末。
殺虫剤製剤P5:約25重量%の化合物P5a、45重量%のプロピレンカーボネート及び30重量%のEO/PO-ブロックコポリマーを含有する、希釈可能な濃縮物。
殺虫剤製剤P6:化合物P5、界面活性剤混合物、炭化水素の混合物及び水を含有する、マイクロエマルジョン濃縮物。
162g/Lの単糖及び二糖を含有する市販の赤ブドウ果汁。
誘引剤組成物AtC 2:醸造酵母由来の食品グレード酵母自己消化物:酵母自己消化物SPA400(販売元:Halcyons Proteins Pty Ltd. Australia)。
誘引剤組成物AtC 3:タンパク質加水分解物:Buminal(販売元:Bayer AG)。
誘引剤組成物AtC 4:tert-ブチル4-(又は5-)クロロ-2-メチルシクロヘキサンカルボキシレート:Capilure(販売元:Oecos Herfordshire UK Company)。
誘引剤組成物AtC 5:メチルユージノール、純度>95%(販売元:Bronson & Jacobs Pty Ltd. Australia)。
ゲル化剤:ポリアクリレート増粘剤(Carbopol EZ-2、Novenon Ohio USA)。
1.1 即時使用ゲルの調製(製剤1.a〜1.eについての一般配合)
a)約22〜32gの脱イオン水を混合容器に充填した。次いで、順に、0.75gのゲル化剤1、17.0gの三温糖及び8.0gのグルコ-マンニトールとグルコ-ソルビトールの市販混合物(イソマルト)を徐々に加え、その混合物を諸成分が溶解するまで攪拌した。次いで、17.8gのコーンスターチ、0.5gのピーナッツバターフレーバー、2.5gの凍結乾燥したニワトリ肝粉及び2.5gの凍結乾燥したコオロギ粉を加え、その混合物を固体材料が液体媒体中で均一に分散するまで攪拌した。次いで、0.2gの市販保存剤(Proxel GXL)及び超吸収性ポリマー粉(SAP)を加え、その混合物を材料が液体媒体中で均一に分散するまで攪拌した。次いで、プロピレングリコール又は油を加え(表1に掲げた量)、その混合物を、実質的に均一なゲルが得られるまで攪拌した。
比較製剤を製剤1.a〜1.eに記載の通り調製した。しかし超吸収性ポリマーは加えなかった。その代わり、殺生物剤を加えた後にNaOH水溶液を加えた。さらにイソマルトを加えた後にカラギナンを加えた。
製剤1.f〜1.mは、殺虫剤製剤P3〜P6と超吸収性ポリマーSAP1を用いて、製剤1.a〜1.eに対して記載したように調製した。ゲル製剤の組成を次の表1a〜1dに示す(全ての量は重量%として示す)。
一般配合A
50〜60gの脱イオン水を混合容器中に充填した。次いで0.2gの市販保存剤(Proxel GXL)、5gのサトウキビ糖、5gの赤ブドウ果汁及び10gのグリセリンを加え、その混合物を、成分が完全に溶解するまで攪拌した。次いで、殺虫剤製剤P1を加え、その混合物を再び、実質的に均質な分散液が得られるまで攪拌した。次いで、2種の異なる誘引剤組成物を逐次加え、その混合物を再び、実質的に均質な分散液が得られるまで攪拌した。超吸収性ポリマーを徐々に加え、その混合物を、実質的に均質なゲルが得られるまで攪拌した。
30〜40gの脱イオン水を混合容器中に充填した。次いで0.2gの市販保存剤(Proxel GXL)、5gのサトウキビ糖、5gの赤ブドウ果汁及び10gのグリセリンを加え、その混合物を、成分が完全に溶解するまで攪拌した。次いで、殺虫剤製剤P2を加え、その混合物を再び、実質的に均質な分散液が得られるまで攪拌した。次いで、2種の異なる誘引剤組成物を逐次加え、その混合物を再び、実質的に均質な分散液が得られるまで攪拌した。超吸収性ポリマーを徐々に加え、その混合物を、実質的に均質なゲルが得られるまで攪拌した。
混合容器中に68gのククルビタシン含有組成物(メロン果汁エキス、Invite、前記参照)を攪拌しながら加えた。次いで、超吸収性ポリマーとクエン酸を順に加え、その混合物を、実質的に均質なゲルが得られるまで混合した。そのゲルに、9.7若しくは4.9gの殺虫剤製剤P1(又は13.6若しくは6.8gの殺虫剤製剤P2)及び5gのプロピレングリコールを加え、その混合物を、実質的に均質なゲルが得られるまで攪拌した。
1.ゴキブリに対する活性(組成物1.a〜1.e)
研究室実験を実施し、代わりの食餌源の存在(選択試験)のもとでの、II.1に記載した即時使用ゲルの、成虫雄チャバネゴキブリ(Blattella germanica)を駆除する効力を比較した。
水希釈液を噴霧した、切除されたオリーブ小枝に対する成虫オリーブミバエ(B. oleae)の嗅覚応答を、風洞型オルファクトメーターを用いて測定した。噴霧した小枝を風洞型オルファクトメーター中に移し、これらに対する成虫オリーブミバエの応答を評価した。
試験する組成物を10倍の水で(体積基準で)希釈した。得られた希釈液の1mlを25%の濃度で円型濾紙(直径9cm)に塗布した(C及びD試験では0.5mlを塗布した)。処理した円型濾紙をペトリ皿上に置いた。Ceratitis capitataの5個体をそれぞれに置いた。ペトリ皿を閉じて、死滅率をT+1、T+6、T+24及びT+48時間で4回の試験で登録した。この試験を4回行った。ハエの齢は、4日齢であった試験Aを除くと、2日齢であった。結果を表7a〜7dに示す。
適当な数のトウモロコシ植物を有する別々の12m×200mの菜園(1ヘクタール当たり約80,000〜90,000植物を密植)において圃場試験として試験を行った。植物はコーンルートワーム成虫による平均的な侵襲を示した。各製剤1Lを水34Lで希釈することにより、水性噴霧液を調製した。植物に水性噴霧液を用いて35 l/haの施用率で噴霧した。施用はトウモロコシ植物のVT段階(出穂段階)に行った。生存コーンルートワーム個体の数を、2 DAT(処理後日数)及び7 DATで数え、無処理対照菜園の同じ時間におけるコーンルートワーム個体数と比較した。これらの数から効力を、Abbotの式:
E = 100×(1 - x/y)
x = 処理した菜園における昆虫個体数
y = 無処理の菜園における昆虫個体数
により計算した。
研究室実験を実施して、代わりの食餌源の存在(選択試験)のもとで、II.1.2に記載した即時使用ゲルの、成虫雄チャバネゴキブリ(Blattella germanica)を駆除する効力を比較した。
Claims (26)
- (i)0.001〜50重量%の、節足動物害虫に対して活性を有する少なくとも1種の殺虫性化合物、
(ii)0.5〜20重量%の、ポリマーPの1g当たり少なくとも100gの脱イオン水に対する吸収能力を有する少なくとも1種の超吸収性ポリマーP、及び
(iii)5〜94.5重量%の、水と異なる少なくとも1種の賦形剤物質、及び
(iv)5〜94.5重量%の水
[ここで、重量%は組成物の総重量に基づく]
を含有する、ゲル又は固体の形態の殺虫剤組成物。 - 賦形剤物質が誘引剤を含む、先行する請求項のいずれか1項に記載の組成物。
- 賦形剤物質が摂食刺激剤を含む、請求項2に記載の組成物。
- 摂食刺激剤が少なくとも1種の食用炭水化物及び/又は少なくとも1種の食用水素化炭水化物を含む、請求項3に記載の組成物。
- 賦形剤物質が天然の油及び脂肪、脂肪酸、脂肪アルコール並びにそれらの混合物から選択される疎水性成分を含む、先行する請求項のいずれか1項に記載の組成物。
- 超吸収性ポリマーPがエチレン性不飽和モノマーMの架橋コポリマーであって、前記モノマーMが少なくとも90重量%(モノマーMの総重量基準で)の少なくとも1種のモノエチレン性不飽和カルボン酸CAを含む、先行する請求項のいずれか1項に記載の組成物。
- モノマーMが、少なくとも90重量%(モノマーMの総重量基準で)の少なくとも1種のモノエチレン性不飽和カルボン酸CA、又は、少なくとも1種のモノエチレン性不飽和カルボン酸CA若しくはその塩と少なくとも1種のモノエチレン性不飽和酸のアミドAMとの混合物を含む、請求項6に記載の組成物。
- モノマーMが少なくとも90重量%(モノマーMの総重量基準で)のアクリル酸又はそのアルカリ金属塩とアクリルアミドとの混合物を含む、請求項7に記載の組成物。
- モノマーMが少なくとも90重量%(モノマーMの総重量基準で)のアクリル酸とアクリル酸のアルカリ金属塩との混合物を含む、請求項6に記載の組成物。
- 少なくとも1種の殺虫性化合物が、
・成長調節物質、
・ニコチノイド殺虫剤、
・有機(チオ)ホスフェート系、
・カルバメート系、
・ピレスロイド系、
・GABA拮抗化合物、
・大環状ラクトン殺虫剤、
・ミトコンドリア複合体I電子伝達インヒビター、
・ミトコンドリア複合体III電子伝達インヒビター、
・脱共役化合物、
・酸化的リン酸化インヒビター化合物、
・脱皮阻害化合物、
・混合機能オキシダーゼインヒビター化合物、
・ナトリウムチャネルブロッカー化合物、
・式P5の化合物:
X及びYはそれぞれ独立してハロゲンであり、
Wはハロゲン又はC1〜C2-ハロアルキルであり、
R1はC1〜C6-アルキル、C2〜C6-アルケニル、C2〜C6-アルキニル、C1〜C4-アルコキシ-C1〜C4-アルキル又はC3〜C6-シクロアルキルであって、それぞれが1、2、3、4又は5個のハロゲン原子により置換されていてもよく、
R2及びR3はC1〜C6-アルキルであるか、又は隣接する炭素原子と一緒に1、2若しくは3個のハロゲン原子を保持してもよいC3〜C6-シクロアルキル部分を形成してもよく、
R4は水素又はC1〜C6-アルキルである。]、
及びその農学的に許容される塩;
・式P6のアントラニルアミド化合物:
A1はCH3、Cl、Br、Iであり、
XはC-H、C-Cl、C-F又はNであり、
Y'はF、Cl、又はBrであり、
Y''はF、Cl、又はCF3であり、
B1は水素、Cl、Br、I、CNであり、
B2はCl、Br、CF3、OCH2CF3、OCF2Hであり、
RBは水素、CH3又はCH(CH3)2である。];
ベンクロチアズ、ビフェナゼート、カルタップ、フロニカミド、ピリダリル、ピメトロジン、硫黄、チオシクラム、フルベンジアミド、シエノピラフェン、フルピラゾホス、シフルメトフェン、アミドフルメト、1-アセチル-2-オキソ-3-(ピリジン-3-イルメチル)アミノ-6-ヘプタフルオロプロピル-1,2,3,4-テトラヒドロキナゾリン及びマロジニトリル化合物
からなる群より選択される、先行する請求項のいずれか1項に記載の組成物。 - 水希釈可能なゲル又は固体の形態の、先行する請求項のいずれか1項に記載の組成物。
- 殺虫性化合物と異なる酸を含む、請求項11に記載の組成物。
- 少なくとも1種の界面活性剤を含む、請求項11に記載の組成物。
- 即時使用ゲルの形態の、先行する請求項のいずれか1項に記載の組成物。
- 節足動物害虫を駆除するための、先行する請求項のいずれか1項に記載の組成物の使用。
- 請求項1〜14のいずれか1項に記載の組成物を、直接に又は水希釈液の形態で、節足動物害虫が前記組成物と接触する場所に施用することを含む、節足動物害虫を駆除する方法。
- 組成物を直接に、即時使用ゲルの形態で施用する、請求項16に記載の方法。
- 節足動物害虫が膜翅目、ゴキブリ目、等翅目、双翅目及び鱗翅目から選択される昆虫である、請求項17に記載の方法。
- 組成物を施用する場所が建物の一部分である、請求項17又は18のいずれか1項に記載の方法。
- 請求項14に記載の即時使用ゲル組成物を含有するデバイス。
- 希釈した水性噴霧可能殺虫剤組成物を調製するための、請求項11に記載の殺虫剤組成物の使用。
- 請求項11〜13のいずれか1項に記載の組成物を水で希釈することにより得られる希釈した水性噴霧可能殺虫剤組成物を、節足動物害虫が前記組成物と接触する場所に施用することを含む、請求項16に記載の方法。
- 組成物を施用する場所が植物若しくは植物の一部分又は植物周囲の土壌である、請求項22に記載の方法。
- 節足動物害虫が植物に害を与える昆虫である、請求項22又は23に記載の方法。
- 昆虫が膜翅目、等翅目、双翅目、鞘翅目及び鱗翅目から選択される、請求項24に記載の方法。
- 昆虫が刺咬昆虫(piercing and chewing insect)から選択される、請求項24に記載の方法。
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JP2016117712A (ja) * | 2014-12-19 | 2016-06-30 | ライオン株式会社 | 殺虫剤 |
JP2018090709A (ja) * | 2016-12-05 | 2018-06-14 | エステー株式会社 | 貼付用ゲル状薬剤含有体およびその製造方法 |
JP2019210224A (ja) * | 2018-05-31 | 2019-12-12 | アース製薬株式会社 | 害虫誘引剤 |
JP7409764B2 (ja) | 2018-05-31 | 2024-01-09 | アース製薬株式会社 | 害虫誘引剤 |
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