JP2010254942A - プリント基板樹脂組成物及びこれを用いたプリント基板 - Google Patents
プリント基板樹脂組成物及びこれを用いたプリント基板 Download PDFInfo
- Publication number
- JP2010254942A JP2010254942A JP2009168214A JP2009168214A JP2010254942A JP 2010254942 A JP2010254942 A JP 2010254942A JP 2009168214 A JP2009168214 A JP 2009168214A JP 2009168214 A JP2009168214 A JP 2009168214A JP 2010254942 A JP2010254942 A JP 2010254942A
- Authority
- JP
- Japan
- Prior art keywords
- epoxy resin
- printed circuit
- circuit board
- resin composition
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011342 resin composition Substances 0.000 title claims abstract description 32
- 239000003822 epoxy resin Substances 0.000 claims abstract description 84
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 84
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000002245 particle Substances 0.000 claims abstract description 26
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 239000002131 composite material Substances 0.000 claims abstract description 19
- 239000011258 core-shell material Substances 0.000 claims abstract description 18
- 239000011256 inorganic filler Substances 0.000 claims abstract description 14
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 14
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229930003836 cresol Natural products 0.000 claims abstract description 10
- 239000000758 substrate Substances 0.000 claims description 16
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 239000004843 novolac epoxy resin Substances 0.000 claims description 8
- 125000003700 epoxy group Chemical group 0.000 claims description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 6
- ULKLGIFJWFIQFF-UHFFFAOYSA-N 5K8XI641G3 Chemical compound CCC1=NC=C(C)N1 ULKLGIFJWFIQFF-UHFFFAOYSA-N 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 230000001788 irregular Effects 0.000 claims description 4
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 3
- ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 2-phenyl-1h-imidazole Chemical compound C1=CNC(C=2C=CC=CC=2)=N1 ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- -1 imidazole compound Chemical class 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- 230000032798 delamination Effects 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 229920003986 novolac Polymers 0.000 abstract description 5
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 24
- 229940106691 bisphenol a Drugs 0.000 description 13
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 12
- 239000011810 insulating material Substances 0.000 description 11
- 230000000704 physical effect Effects 0.000 description 10
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 9
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 9
- 239000010410 layer Substances 0.000 description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 8
- 239000003063 flame retardant Substances 0.000 description 8
- 229910052698 phosphorus Inorganic materials 0.000 description 8
- 239000011574 phosphorus Substances 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000011229 interlayer Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000035939 shock Effects 0.000 description 5
- 239000004593 Epoxy Substances 0.000 description 4
- 239000012046 mixed solvent Substances 0.000 description 4
- 238000007747 plating Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 229910000679 solder Inorganic materials 0.000 description 3
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000001555 benzenes Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical compound N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/30—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen
- C08G59/304—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen containing phosphorus
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
- H05K1/0373—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement containing additives, e.g. fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/01—Dielectrics
- H05K2201/0104—Properties and characteristics in general
- H05K2201/0133—Elastomeric or compliant polymer
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/02—Fillers; Particles; Fibers; Reinforcement materials
- H05K2201/0203—Fillers and particles
- H05K2201/0206—Materials
- H05K2201/0212—Resin particles
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Epoxy Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
【解決手段】樹脂組成物は、DGEBA型エポキシ樹脂にコア−シェル構造のシリコンエラストマー粒子10が分散されているビスフェノールA型エポキシ樹脂、クレゾールノボラックエポキシ樹脂、及びリン系エポキシ樹脂を含む複合エポキシ樹脂と;ビスフェノールA系硬化剤と;硬化促進剤と;無機充填剤とを含む。
【選択図】図1
Description
平均粒径が約1μm、平均エポキシ樹脂当量が302のDGEBA型エポキシ樹脂にコア−シェル構造のシリコンエラストマー粒子が40重量%分散されているビスフェノールA型エポキシ樹脂375g、平均エポキシ樹脂当量が206のクレゾールノボラックエポキシ樹脂750g、平均エポキシ樹脂当量が590の難燃性エポキシ樹脂375g、66.7重量%(溶媒:2−メトキシエタノール)BPA(Bisphenol−A)ノボラック樹脂硬化剤992.76gを添加した後、MEK(Methyl Ethyl Ketone)239.54gと2−メトキシエタノール501gの混合溶媒に常温で300rpmで撹拌した後、2.53μmの粒度分布を持つ不規則な形状の無機充填剤を442.85g添加した後、400rpmで3時間撹拌した。最後に、2−エチル−4−メチルイミダゾール0.25重量部を添加した後、1時間撹拌して絶縁材料組成物を製造した。このように製造された絶縁材料組成物をPETフィルムにフィルムキャスティングしてロール状の製品に製造した。製造された製品を405mm×510mmの大きさに切断し、通常の基板製造工程によって多層プリント基板を製造し、ソルダディップテスト(solder dip test)(260℃、20秒)によって外部デラミネーションの有無を確認し、横断面切断の後に内部クラック発生の有無を確認して、その結果を下記表1に示した。
85重量%(溶媒:2−メトキシエタノール)のビスフェノールA型エポキシ樹脂14.99g、85重量%(溶媒:2−メトキシエタノール)のクレゾールノボラックエポキシ樹脂73.33g、ゴム変性型エポキシ樹脂10g、85重量%(溶媒:2−メトキシエタノール)のリン系難燃性エポキシ樹脂37.48g、及び66.7重量%(溶媒:2−メトキシエタノール)アミノトリアジン系ノボラック硬化剤56.50gを添加した後、この混合物を90℃で1時間300rpmで撹拌した。続いて、0.6〜1.2μmの粒度分布を持つ球形のシリカを70.93g添加した後、400rpmで3時間撹拌した。温度を常温に低めた後、2−エチル−4−メチルイミダゾール0.25重量部を添加し、1時間撹拌して絶縁材料組成物を製造した。このように製造された絶縁材料組成物をPETフィルムにフィルムキャスティングしてロール状の製品に製造した。製造された製品を405mm×510mmの大きさに切断し、通常の基板製造工程によって多層プリント基板を製造し、ソルダディップテスト(260℃、20秒)によって外部デラミネーションの有無を確認し、横断面切断後の内部クラック発生の有無を確認し、その結果を下記表1に示した。
11 コア
12 シェル
13 反応性基
Claims (10)
- (a)平均エポキシ樹脂当量200〜400のDGEBA(diglycidyl ether of bisphenol A)型エポキシ樹脂にコア−シェル構造のシリコンエラストマー粒子が分散されているビスフェノールA型エポキシ樹脂20〜50重量%、平均エポキシ樹脂当量100〜300のクレゾールノボラックエポキシ樹脂20〜60重量%、及び平均エポキシ樹脂当量400〜800のリン系エポキシ樹脂20〜30重量%を含む複合エポキシ樹脂;
(b)前記複合エポキシ樹脂のエポキシ基の総混合当量に対して0.3〜1.5当量のビスフェノールA系硬化剤;
(c)前記複合エポキシ樹脂100重量部に対して0.1〜1重量部の硬化促進剤;及び
(d)前記複合エポキシ樹脂100重量部に対して10〜30重量部の無機充填剤;を含むことを特徴とする、プリント基板用樹脂組成物。 - 前記DGEBA型エポキシ樹脂に分散されたコア−シェル構造のシリコンエラストマー粒子の含量は、20〜60重量%であることを特徴とする、請求項1に記載のプリント基板用樹脂組成物。
- 前記コア−シェル構造のシリコンエラストマー粒子は、0.1〜3μmの平均粒径を持つことを特徴とする、請求項1に記載のプリント基板用樹脂組成物。
- 前記硬化剤は、軟化点が100〜140℃、水酸基当量が100〜150であることを特徴とする、請求項1に記載のプリント基板用樹脂組成物。
- 前記硬化剤は、前記複合エポキシ樹脂のエポキシ基と前記硬化剤のフェノール性水酸基の割合が、1:0.7〜1:1.3であることを特徴とする、請求項1に記載のプリント基板用樹脂組成物。
- 前記硬化促進剤は、イミダゾール系化合物であることを特徴とする、請求項1に記載のプリント基板用樹脂組成物。
- 前記硬化促進剤は、2−エチル−4−メチルイミダゾール、1−(2−シアノエチル)−2−アルキルイミダゾール、2−フェニルイミダゾール及びこれらの混合物よりなる群から選ばれる1種以上の化合物であることを特徴とする、請求項6に記載のプリント基板用樹脂組成物。
- 前記無機充填剤は、シランカップリング剤で表面処理されたものであることを特徴とする、請求項1に記載のプリント基板用樹脂組成物。
- 前記無機充填剤は、不規則な外形を持つことを特徴とする、請求項1に記載のプリント基板用樹脂組成物。
- 請求項1による樹脂組成物を利用して製造されたプリント基板。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020090035541A KR101095136B1 (ko) | 2009-04-23 | 2009-04-23 | 인쇄회로기판용 수지 조성물 및 이를 이용한 인쇄회로기판 |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2010254942A true JP2010254942A (ja) | 2010-11-11 |
Family
ID=42991106
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009168214A Pending JP2010254942A (ja) | 2009-04-23 | 2009-07-16 | プリント基板樹脂組成物及びこれを用いたプリント基板 |
Country Status (4)
Country | Link |
---|---|
US (1) | US20100270065A1 (ja) |
JP (1) | JP2010254942A (ja) |
KR (1) | KR101095136B1 (ja) |
CN (1) | CN101870763B (ja) |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10511426A (ja) * | 1995-12-27 | 1998-11-04 | ヘクセル・コーポレーション | 硬化剤と強化剤とを含むエポキシ樹脂 |
JP2004537165A (ja) * | 2001-07-10 | 2004-12-09 | スリーエム イノベイティブ プロパティズ カンパニー | アミノフェニルフルオレンで硬化したエポキシ誘電体層を有するコンデンサ |
JP2005255822A (ja) * | 2004-03-11 | 2005-09-22 | Kaneka Corp | ゴム強化エポキシ樹脂製品 |
WO2006019041A1 (ja) * | 2004-08-18 | 2006-02-23 | Kaneka Corporation | 半導体封止剤用エポキシ樹脂組成物およびエポキシ樹脂成形材料 |
JP2006143973A (ja) * | 2004-11-24 | 2006-06-08 | Matsushita Electric Works Ltd | エポキシ樹脂組成物、並びにプリプレグ、積層板、プリント配線板 |
WO2006118091A1 (ja) * | 2005-04-28 | 2006-11-09 | San Nopco Ltd. | 電子基板充填用樹脂 |
JP2008095105A (ja) * | 2006-10-11 | 2008-04-24 | Samsung Electro Mech Co Ltd | 印刷回路基板用難燃性樹脂組成物及びそれを用いた印刷回路基板 |
JP2008150555A (ja) * | 2006-12-20 | 2008-07-03 | Hitachi Chem Co Ltd | 封止用液状エポキシ樹脂組成物、電子部品装置及びウエハーレベルチップサイズパッケージ |
JP2008291154A (ja) * | 2007-05-25 | 2008-12-04 | Hitachi Chem Co Ltd | 熱硬化性樹脂組成物、コアシェルポリマ、硬化物 |
JP2009067987A (ja) * | 2007-09-13 | 2009-04-02 | Samsung Electro Mech Co Ltd | 印刷回路基板用難燃性樹脂組成物とそれを用いた印刷回路基板及びその製造方法 |
JP2009074036A (ja) * | 2007-02-23 | 2009-04-09 | Panasonic Electric Works Co Ltd | エポキシ樹脂組成物、プリプレグ、積層板、及びプリント配線板 |
JP2009073933A (ja) * | 2007-09-20 | 2009-04-09 | Toto Kasei Co Ltd | 耐熱劣化性を有するエポキシ樹脂組成物 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5300402A (en) * | 1988-12-30 | 1994-04-05 | International Business Machines Corporation | Composition for photo imaging |
EP0850973B1 (en) * | 1996-07-04 | 2004-09-15 | Tohto Kasei Co., Ltd. | Phenolic hydroxyl-containing modified resin, curable composition thereof, epoxidation product of said modified resin, and curable composition thereof |
US6117536A (en) * | 1998-09-10 | 2000-09-12 | Ga-Tek Inc. | Adhesion promoting layer for use with epoxy prepregs |
ES2367838T3 (es) * | 1998-09-10 | 2011-11-10 | JX Nippon Mining & Metals Corp. | Laminado que comprende una hoja de cobre tratada y procedimiento para su fabricación. |
DE60214093T2 (de) * | 2001-07-12 | 2007-10-04 | Dainippon Ink And Chemicals, Inc. | Epoxidharzzusammensetzung, daraus hergestellter gehärteter Gegenstand, neues Epoxidharz, neue Phenolverbindung, und Verfahren zu deren Herstellung |
ATE363506T1 (de) * | 2001-12-06 | 2007-06-15 | Huntsman Adv Mat Switzerland | Harzzusammensetzung |
CN100384903C (zh) * | 2002-05-29 | 2008-04-30 | 日本化学工业株式会社 | 含磷环氧树脂和树脂组合物及其制造方法,以及密封材料和层积板 |
US20050267286A1 (en) * | 2003-10-20 | 2005-12-01 | Shinya Nakamura | Curing accelerator for curing resin, curing resin composition, electronic component device and method for producing phosphine derivative |
CN101942182B (zh) * | 2004-09-17 | 2012-05-23 | 东丽株式会社 | 树脂组合物和由其形成的成型品 |
TW200643100A (en) * | 2005-04-15 | 2006-12-16 | Hitachi Chemical Co Ltd | Curing accelerating compound-silica composite material, method for producing curing accelerating compound-silica composite material, curing accelerator, curable resin composition, and electronic component |
KR100648463B1 (ko) | 2005-09-26 | 2006-11-27 | 삼성전기주식회사 | 난연성 수지 조성물 |
TWI410442B (zh) * | 2005-11-29 | 2013-10-01 | Ajinomoto Kk | A resin composition for an insulating layer of a multilayer printed circuit board |
KR101019738B1 (ko) * | 2006-02-24 | 2011-03-08 | 미쯔비시 가스 케미칼 컴파니, 인코포레이티드 | 수지 조성물, 프리프레그 및 금속-호일-클래드 라미네이트 |
KR100771331B1 (ko) | 2006-05-16 | 2007-10-29 | 삼성전기주식회사 | 에폭시 수지 조성물 및 이를 이용한 인쇄회로기판 |
CN101517029B (zh) * | 2006-07-31 | 2013-10-16 | 汉高股份及两合公司 | 可固化的环氧树脂-基粘合剂组合物 |
US8288266B2 (en) * | 2006-08-08 | 2012-10-16 | Endicott Interconnect Technologies, Inc. | Circuitized substrate assembly |
EP2076578A4 (en) * | 2006-10-06 | 2011-01-19 | Henkel Ag & Co Kgaa | POWDER-RESISTANT EPOXY-BASED PUMP-BASED ADHESIVES |
JP5175509B2 (ja) | 2007-09-07 | 2013-04-03 | 日鉄住金ドラム株式会社 | 粉体塗料組成物 |
-
2009
- 2009-04-23 KR KR1020090035541A patent/KR101095136B1/ko not_active IP Right Cessation
- 2009-07-16 JP JP2009168214A patent/JP2010254942A/ja active Pending
- 2009-07-22 US US12/507,627 patent/US20100270065A1/en not_active Abandoned
- 2009-07-31 CN CN200910160891.6A patent/CN101870763B/zh not_active Expired - Fee Related
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10511426A (ja) * | 1995-12-27 | 1998-11-04 | ヘクセル・コーポレーション | 硬化剤と強化剤とを含むエポキシ樹脂 |
JP2004537165A (ja) * | 2001-07-10 | 2004-12-09 | スリーエム イノベイティブ プロパティズ カンパニー | アミノフェニルフルオレンで硬化したエポキシ誘電体層を有するコンデンサ |
JP2005255822A (ja) * | 2004-03-11 | 2005-09-22 | Kaneka Corp | ゴム強化エポキシ樹脂製品 |
WO2006019041A1 (ja) * | 2004-08-18 | 2006-02-23 | Kaneka Corporation | 半導体封止剤用エポキシ樹脂組成物およびエポキシ樹脂成形材料 |
JP2006143973A (ja) * | 2004-11-24 | 2006-06-08 | Matsushita Electric Works Ltd | エポキシ樹脂組成物、並びにプリプレグ、積層板、プリント配線板 |
WO2006118091A1 (ja) * | 2005-04-28 | 2006-11-09 | San Nopco Ltd. | 電子基板充填用樹脂 |
JP2008095105A (ja) * | 2006-10-11 | 2008-04-24 | Samsung Electro Mech Co Ltd | 印刷回路基板用難燃性樹脂組成物及びそれを用いた印刷回路基板 |
JP2008150555A (ja) * | 2006-12-20 | 2008-07-03 | Hitachi Chem Co Ltd | 封止用液状エポキシ樹脂組成物、電子部品装置及びウエハーレベルチップサイズパッケージ |
JP2009074036A (ja) * | 2007-02-23 | 2009-04-09 | Panasonic Electric Works Co Ltd | エポキシ樹脂組成物、プリプレグ、積層板、及びプリント配線板 |
JP2008291154A (ja) * | 2007-05-25 | 2008-12-04 | Hitachi Chem Co Ltd | 熱硬化性樹脂組成物、コアシェルポリマ、硬化物 |
JP2009067987A (ja) * | 2007-09-13 | 2009-04-02 | Samsung Electro Mech Co Ltd | 印刷回路基板用難燃性樹脂組成物とそれを用いた印刷回路基板及びその製造方法 |
JP2009073933A (ja) * | 2007-09-20 | 2009-04-09 | Toto Kasei Co Ltd | 耐熱劣化性を有するエポキシ樹脂組成物 |
Also Published As
Publication number | Publication date |
---|---|
CN101870763A (zh) | 2010-10-27 |
CN101870763B (zh) | 2014-01-15 |
KR101095136B1 (ko) | 2011-12-16 |
KR20100116889A (ko) | 2010-11-02 |
US20100270065A1 (en) | 2010-10-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TWI410442B (zh) | A resin composition for an insulating layer of a multilayer printed circuit board | |
JP5192259B2 (ja) | エポキシ樹脂組成物、プリプレグ、積層板、及びプリント配線板 | |
JP4983228B2 (ja) | 多層プリント配線板の絶縁層用樹脂組成物 | |
JP4992396B2 (ja) | 多層プリント配線板の層間絶縁層用樹脂組成物 | |
JP5573869B2 (ja) | 多層プリント配線板の層間絶縁層用樹脂組成物 | |
JP5039707B2 (ja) | プリント配線板用エポキシ樹脂組成物、樹脂組成物ワニス、プリプレグ、金属張積層体、プリント配線板及び多層プリント配線板 | |
KR101560518B1 (ko) | 절연 수지 재료 및 다층 기판 | |
CN101864151B (zh) | 用于高剥离强化印刷电路板的阻燃树脂组合物、利用其的印刷电路板及其制造方法 | |
JP2016166347A (ja) | 樹脂組成物、低誘電率樹脂シート、プリプレグ、金属箔張り積層板、高周波回路基板および多層配線基板 | |
KR101044114B1 (ko) | 인쇄회로기판용 수지 조성물 및 이를 이용한 인쇄회로기판 | |
JP2008037957A (ja) | 熱硬化性樹脂組成物、bステージ化した樹脂フィルムおよび多層ビルドアップ基板 | |
KR20180063034A (ko) | 수지 조성물 및 다층 기판 | |
KR20070089053A (ko) | 열경화성 수지조성물, b-스테이지화된 수지필름 및 다층빌드업 기판 | |
KR102422859B1 (ko) | 수지 시트 | |
JPWO2007097209A1 (ja) | エポキシ樹脂組成物 | |
CN110382589A (zh) | 树脂材料、叠层膜以及多层印刷布线板 | |
JP5345656B2 (ja) | 多層配線基板用難燃性樹脂組成物及びこれを含む多層配線基板 | |
KR102393446B1 (ko) | 전자 재료용 몰리브덴산아연암모늄 수화물, 전자 재료용 수지 조성물, 프리프레그, 수지 시트, 적층판, 금속박 피복 적층판, 및 프린트 배선판 | |
JP4915549B2 (ja) | 印刷配線板用樹脂組成物、プリプレグおよびこれを用いた積層板 | |
WO2014045625A1 (ja) | 絶縁樹脂フィルム、予備硬化物、積層体及び多層基板 | |
JP4765975B2 (ja) | 積層板とそれを用いたプリント配線板 | |
JP5384233B2 (ja) | プリント基板用樹脂組成物及びこれを用いたプリント基板 | |
JP2019006980A (ja) | 絶縁フィルム用樹脂組成物、絶縁フィルム及び多層プリント配線板 | |
JP2013075440A (ja) | 積層体の製造方法及び積層構造体 | |
JP2010254942A (ja) | プリント基板樹脂組成物及びこれを用いたプリント基板 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20120130 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120207 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20120507 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20120510 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20120604 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20120607 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20120704 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20120709 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20130129 |