JP2010185156A - 人工毛髪用ポリエステル繊維 - Google Patents
人工毛髪用ポリエステル繊維 Download PDFInfo
- Publication number
- JP2010185156A JP2010185156A JP2009031141A JP2009031141A JP2010185156A JP 2010185156 A JP2010185156 A JP 2010185156A JP 2009031141 A JP2009031141 A JP 2009031141A JP 2009031141 A JP2009031141 A JP 2009031141A JP 2010185156 A JP2010185156 A JP 2010185156A
- Authority
- JP
- Japan
- Prior art keywords
- artificial hair
- polyester fiber
- fiber
- hair
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 210000004209 hair Anatomy 0.000 title claims abstract description 81
- 239000000835 fiber Substances 0.000 title claims abstract description 80
- 229920000728 polyester Polymers 0.000 title claims abstract description 54
- 125000003118 aryl group Chemical group 0.000 claims abstract description 26
- 239000010954 inorganic particle Substances 0.000 claims abstract description 17
- 239000000843 powder Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 238000012805 post-processing Methods 0.000 abstract description 10
- -1 polyethylene terephthalate Polymers 0.000 description 19
- 238000000034 method Methods 0.000 description 18
- 238000009987 spinning Methods 0.000 description 11
- 238000004043 dyeing Methods 0.000 description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 description 7
- 239000005020 polyethylene terephthalate Substances 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 239000004594 Masterbatch (MB) Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 229920002050 silicone resin Polymers 0.000 description 3
- 208000016261 weight loss Diseases 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- DOZGRCMRCPSZHG-UHFFFAOYSA-N 2-(4-benzoyl-3-hydroxyphenoxy)ethyl 2-methylprop-2-enoate Chemical compound OC1=CC(OCCOC(=O)C(=C)C)=CC=C1C(=O)C1=CC=CC=C1 DOZGRCMRCPSZHG-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- DCBNMBIOGUANTC-UHFFFAOYSA-N [5-[(5-benzoyl-4-hydroxy-2-methoxyphenyl)methyl]-2-hydroxy-4-methoxyphenyl]-phenylmethanone Chemical compound COC1=CC(O)=C(C(=O)C=2C=CC=CC=2)C=C1CC(C(=CC=1O)OC)=CC=1C(=O)C1=CC=CC=C1 DCBNMBIOGUANTC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000004313 glare Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 238000002074 melt spinning Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 230000001502 supplementing effect Effects 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- IMJYRYAZVATGLW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2,2-dimethylpropyl)phenol Chemical compound CC(C)(C)CC1=CC(CC(C)(C)C)=C(O)C(N2N=C3C=CC=CC3=N2)=C1 IMJYRYAZVATGLW-UHFFFAOYSA-N 0.000 description 1
- WTPYFJNYAMXZJG-UHFFFAOYSA-N 2-[4-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound OCCOC1=CC=C(OCCO)C=C1 WTPYFJNYAMXZJG-UHFFFAOYSA-N 0.000 description 1
- ZAWRQEZIUMGWCE-UHFFFAOYSA-N 2-methyl-2-phenoxypropanedioic acid Chemical compound OC(=O)C(C(O)=O)(C)OC1=CC=CC=C1 ZAWRQEZIUMGWCE-UHFFFAOYSA-N 0.000 description 1
- NEQFBGHQPUXOFH-UHFFFAOYSA-N 4-(4-carboxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C=C1 NEQFBGHQPUXOFH-UHFFFAOYSA-N 0.000 description 1
- UUAGPGQUHZVJBQ-UHFFFAOYSA-N Bisphenol A bis(2-hydroxyethyl)ether Chemical compound C=1C=C(OCCO)C=CC=1C(C)(C)C1=CC=C(OCCO)C=C1 UUAGPGQUHZVJBQ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920001283 Polyalkylene terephthalate Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- SCMSRHIBVBIECI-UHFFFAOYSA-N [2-hydroxy-4-(2-hydroxyethoxy)phenyl]-phenylmethanone Chemical compound OC1=CC(OCCO)=CC=C1C(=O)C1=CC=CC=C1 SCMSRHIBVBIECI-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- BWVAOONFBYYRHY-UHFFFAOYSA-N [4-(hydroxymethyl)phenyl]methanol Chemical compound OCC1=CC=C(CO)C=C1 BWVAOONFBYYRHY-UHFFFAOYSA-N 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- WXNRYSGJLQFHBR-UHFFFAOYSA-N bis(2,4-dihydroxyphenyl)methanone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=C(O)C=C1O WXNRYSGJLQFHBR-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- CCQPAEQGAVNNIA-UHFFFAOYSA-N cyclobutane-1,1-dicarboxylic acid Chemical compound OC(=O)C1(C(O)=O)CCC1 CCQPAEQGAVNNIA-UHFFFAOYSA-N 0.000 description 1
- FDKLLWKMYAMLIF-UHFFFAOYSA-N cyclopropane-1,1-dicarboxylic acid Chemical compound OC(=O)C1(C(O)=O)CC1 FDKLLWKMYAMLIF-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 239000012796 inorganic flame retardant Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- WPUMVKJOWWJPRK-UHFFFAOYSA-N naphthalene-2,7-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=CC2=CC(C(=O)O)=CC=C21 WPUMVKJOWWJPRK-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- CGEXUOTXYSGBLV-UHFFFAOYSA-N phenyl benzenesulfonate Chemical compound C=1C=CC=CC=1S(=O)(=O)OC1=CC=CC=C1 CGEXUOTXYSGBLV-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920000874 polytetramethylene terephthalate Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- YXTFRJVQOWZDPP-UHFFFAOYSA-M sodium;3,5-dicarboxybenzenesulfonate Chemical compound [Na+].OC(=O)C1=CC(C(O)=O)=CC(S([O-])(=O)=O)=C1 YXTFRJVQOWZDPP-UHFFFAOYSA-M 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
Images
Abstract
【解決手段】上記の本発明の目的は、芳香族ポリエステル繊維と無機粒子からなる人工毛髪用ポリエステル繊維であって、該無機粒子によって人工毛髪用ポリエステル繊維の表面に突起が形成されている人工毛髪用ポリエステル繊維によって達成することができる。
【選択図】図1
Description
(1)極限粘度
ポリマーサンプル0.12gを10mLのテトラクロロエタン/フェノール(容量比1/1)に溶解し、35℃における還元粘度(mL/g)を測定した。
(2)単糸繊度
JIS L 1015:2005 8.5.1 A法に記載の方法により測定した。
(3)人工毛髪用繊維の表面光沢の評価
自然光下において視覚で確認し、人毛に近い表面光沢を有するものを適当(○)、表面反射が大きく、ギラツキ感のあるものを不適当(×)と判断した。
(4)人工毛髪用繊維の風合いの評価
繊維サンプル束に直に触れて、その触感を評価し、風合いを判定した。人毛に近い触感を有するものを適当(○)、平滑で人毛から隔たった触感のものは不適当(×)と判断した。
(5)製糸性の評価
本発明の人工毛髪用の芳香族ポリエステル繊維を紡糸、延伸処理を行い、紡糸・延伸工程において著しい断糸の発生や、紡糸口金に異物が溜まるなどして口金ろ過圧が異常に増加しなかった製造例を製糸性良好(○)と判定し、そのような製造工程上の問題が発生した製造例を製糸性不良(×)と判定した。
極限粘度0.62dL/gのポリエチレンテレフタレートチップ85質量%と該ポリエチレンテレフタレートをベースとし、シリコーンレジンパウダー(信越化学株式会社製)を20%含むマスターバッチ15質量%をタンブラーにて混合した後、真空下160℃で8時間乾燥した。該混合チップを、290℃でエクストルーダ型混練機、計量ギヤポンプ及び80メッシュのメタルサンドと300メッシュの金網よりなる濾過層を有する紡糸機を用い、図1の形状の紡出孔を30ホール有する紡糸口金より溶融吐出し、紡糸口金下5cmの所で50℃温水で冷却後巻き取り紡糸原糸を得た。次いで70℃の温水中で4.4倍に延伸し、さらに150℃で緊張熱処理を施した後に3000dtex/30filの延伸糸として巻取った。該繊維中に含まれるシリコーンパウダーの含率は3質量%である。得られた繊維に対し、表面光沢及び風合いを評価した結果を表1に示した。
極限粘度0.62dL/gのポリエチレンテレフタレートチップ70質量%とシリコーンレジンパウダーを20質量%含むマスターバッチ30質量%としたこと以外は実施例1と同様にして人工毛髪用繊維を得た。該繊維中に含まれるシリコーンパウダーの含率は6質量%である。得られた繊維に対し、表面光沢及び風合いを評価した結果を表1に示した。
極限粘度0.62dL/gのポリエチレンテレフタレートチップを、真空下160℃で8時間乾燥した。該チップを、290℃でエクストルーダ型混練機、計量ギヤポンプ及び80メッシュのメタルサンドと300メッシュの金網よりなる濾過層を有する紡糸機を用い、図1の形状の紡出孔を30ホール有する紡糸口金より溶融吐出し、紡糸口金下5cmの所で50℃温水で冷却後巻き取り紡糸原糸を得た。次いで70℃の温水中で4.4倍に延伸し、さらに150℃で緊張熱処理を施した後に3000dtex/30filの延伸糸として巻取った。得られた繊維に対し、表面光沢及び風合いを評価した結果を表1に示した。
実施例1において、ポリエチレンテレフタレートチップ70質量%と、シリコーンレジンパウダー30質量%含有するマスターバッチ30質量%を混合し、実施例1と同様の条件で製糸したが、延伸倍率を4.4倍とすると単糸切れが発生し、製糸性が不良であった。
b 短軸径
Claims (4)
- 芳香族ポリエステル繊維と無機粒子からなる人工毛髪用ポリエステル繊維であって、該無機粒子の人工毛髪用ポリエステル繊維中の配合率が0.1〜8.0質量%であって、該無機粒子によって芳香族ポリエステル繊維の表面に突起が形成されている人工毛髪用ポリエステル繊維。
- 繊維の横断面形状がメガネ型で、そのメガネ型が有するクビレ度が2.5〜8.0である請求項1記載の人工毛髪用ポリエステル繊維。
- 耐熱粒子がシリコーンパウダーである請求項1又は2記載の人工毛髪用ポリエステル繊維。
- 芳香族ポリエステル繊維の単繊維繊度が20〜110dtexである請求項1〜3のいずれか1項記載の人工毛髪用ポリエステル繊維。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009031141A JP2010185156A (ja) | 2009-02-13 | 2009-02-13 | 人工毛髪用ポリエステル繊維 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009031141A JP2010185156A (ja) | 2009-02-13 | 2009-02-13 | 人工毛髪用ポリエステル繊維 |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2010185156A true JP2010185156A (ja) | 2010-08-26 |
Family
ID=42765979
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2009031141A Pending JP2010185156A (ja) | 2009-02-13 | 2009-02-13 | 人工毛髪用ポリエステル繊維 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2010185156A (ja) |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0543420A (ja) * | 1991-08-16 | 1993-02-23 | Kao Corp | 化粧料 |
JP2007146306A (ja) * | 2005-11-24 | 2007-06-14 | Teijin Fibers Ltd | 人工毛髪用繊維 |
JP2008088585A (ja) * | 2006-09-29 | 2008-04-17 | Kaneka Corp | 難燃性ポリエステル系人工毛髪 |
-
2009
- 2009-02-13 JP JP2009031141A patent/JP2010185156A/ja active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0543420A (ja) * | 1991-08-16 | 1993-02-23 | Kao Corp | 化粧料 |
JP2007146306A (ja) * | 2005-11-24 | 2007-06-14 | Teijin Fibers Ltd | 人工毛髪用繊維 |
JP2008088585A (ja) * | 2006-09-29 | 2008-04-17 | Kaneka Corp | 難燃性ポリエステル系人工毛髪 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR100861061B1 (ko) | 난연성 폴리에스테르계 인공 모발용 섬유 | |
US7759430B2 (en) | Flame retardant polyester fiber for artificial hair | |
JP2003293234A (ja) | 伸縮性芯鞘型複合糸及び伸縮性織編物 | |
EP0910688A1 (en) | Fibers with optical function | |
JP2008088585A (ja) | 難燃性ポリエステル系人工毛髪 | |
JP5651270B2 (ja) | ポリエステル系人工毛髪用繊維及びそれを含む頭飾製品、並びにその製造方法 | |
JP2007146306A (ja) | 人工毛髪用繊維 | |
JP4859916B2 (ja) | 導電性複合繊維及びその製造方法 | |
JPWO2006121054A1 (ja) | 人工毛髪用ポリエステル系繊維 | |
JPH05140817A (ja) | 人工毛髪用ポリエステルモノフイラメント集束体 | |
JP5065576B2 (ja) | 人工毛髪用繊維 | |
JP2010185156A (ja) | 人工毛髪用ポリエステル繊維 | |
KR100309693B1 (ko) | 인조가발사용폴리에스테르수지조성물및이를함유하는인조가발사 | |
JP2015094050A (ja) | 人工毛髪用ポリエステル系繊維及びそれを含む頭飾製品 | |
JP2013237956A (ja) | 冷感に優れた遮熱性複合繊維 | |
JP3175222B2 (ja) | 人工毛髪 | |
JP2017078245A (ja) | 人工毛髪用合成繊維 | |
JPH11181630A (ja) | 複合繊維 | |
JP2018154930A (ja) | 人工毛髪用繊維及びその製造方法 | |
JP2010100962A (ja) | 人工毛髪用繊維 | |
JPS61102415A (ja) | ポリエステル繊維およびその製造法 | |
JP2008274453A (ja) | 光沢の改良された人工毛髪用ポリエステル系繊維及びその製造方法 | |
JPH05140807A (ja) | 人工毛髪 | |
JPS60162811A (ja) | 微細凹部形成性ポリエステル繊維 | |
JP2010150700A (ja) | 人工毛髪用繊維および人工毛髪製品 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
RD02 | Notification of acceptance of power of attorney |
Effective date: 20110705 Free format text: JAPANESE INTERMEDIATE CODE: A7422 |
|
RD04 | Notification of resignation of power of attorney |
Effective date: 20110705 Free format text: JAPANESE INTERMEDIATE CODE: A7424 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20111201 |
|
A711 | Notification of change in applicant |
Effective date: 20130208 Free format text: JAPANESE INTERMEDIATE CODE: A712 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130521 |
|
A977 | Report on retrieval |
Effective date: 20130523 Free format text: JAPANESE INTERMEDIATE CODE: A971007 |
|
A02 | Decision of refusal |
Effective date: 20130924 Free format text: JAPANESE INTERMEDIATE CODE: A02 |