JP2009516102A - 舗装道路路面標識、反射素子およびミクロスフェアを作製する方法 - Google Patents
舗装道路路面標識、反射素子およびミクロスフェアを作製する方法 Download PDFInfo
- Publication number
- JP2009516102A JP2009516102A JP2008540286A JP2008540286A JP2009516102A JP 2009516102 A JP2009516102 A JP 2009516102A JP 2008540286 A JP2008540286 A JP 2008540286A JP 2008540286 A JP2008540286 A JP 2008540286A JP 2009516102 A JP2009516102 A JP 2009516102A
- Authority
- JP
- Japan
- Prior art keywords
- microspheres
- microsphere
- road surface
- tio
- zro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004005 microsphere Substances 0.000 title claims abstract description 165
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 239000000203 mixture Substances 0.000 claims abstract description 71
- 239000011230 binding agent Substances 0.000 claims abstract description 53
- 238000000034 method Methods 0.000 claims abstract description 46
- 239000000463 material Substances 0.000 claims abstract description 30
- 229910052747 lanthanoid Inorganic materials 0.000 claims abstract description 26
- 150000002602 lanthanoids Chemical class 0.000 claims abstract description 26
- 239000002241 glass-ceramic Substances 0.000 claims abstract description 24
- 239000011521 glass Substances 0.000 claims abstract description 17
- 238000010438 heat treatment Methods 0.000 claims description 33
- 239000003550 marker Substances 0.000 claims description 32
- 229910044991 metal oxide Inorganic materials 0.000 claims description 32
- 150000004706 metal oxides Chemical class 0.000 claims description 32
- 230000008018 melting Effects 0.000 claims description 28
- 238000002844 melting Methods 0.000 claims description 28
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 27
- 239000000049 pigment Substances 0.000 claims description 23
- 238000000576 coating method Methods 0.000 claims description 20
- 238000001816 cooling Methods 0.000 claims description 20
- 239000007858 starting material Substances 0.000 claims description 19
- 229910021193 La 2 O 3 Inorganic materials 0.000 claims description 18
- 239000011248 coating agent Substances 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 10
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 4
- 239000011368 organic material Substances 0.000 claims description 4
- 229910010272 inorganic material Inorganic materials 0.000 claims description 3
- 239000011147 inorganic material Substances 0.000 claims description 3
- RUDFQVOCFDJEEF-UHFFFAOYSA-N oxygen(2-);yttrium(3+) Chemical class [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 claims 2
- 229910052727 yttrium Inorganic materials 0.000 claims 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims 2
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 claims 1
- 229910010293 ceramic material Inorganic materials 0.000 claims 1
- 239000002105 nanoparticle Substances 0.000 claims 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 39
- 239000006112 glass ceramic composition Substances 0.000 abstract description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 abstract description 3
- 239000011324 bead Substances 0.000 description 127
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 42
- 239000002245 particle Substances 0.000 description 31
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 28
- 239000011162 core material Substances 0.000 description 21
- 239000013078 crystal Substances 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 239000010410 layer Substances 0.000 description 15
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000002243 precursor Substances 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 238000002441 X-ray diffraction Methods 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 239000004568 cement Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 238000005259 measurement Methods 0.000 description 6
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 5
- 230000003287 optical effect Effects 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 241000588731 Hafnia Species 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 229910001938 gadolinium oxide Inorganic materials 0.000 description 4
- 229940075613 gadolinium oxide Drugs 0.000 description 4
- CMIHHWBVHJVIGI-UHFFFAOYSA-N gadolinium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Gd+3].[Gd+3] CMIHHWBVHJVIGI-UHFFFAOYSA-N 0.000 description 4
- 229910052746 lanthanum Inorganic materials 0.000 description 4
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 3
- 229920000180 alkyd Polymers 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000011049 pearl Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 239000012790 adhesive layer Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 description 2
- CFEAAQFZALKQPA-UHFFFAOYSA-N cadmium(2+);oxygen(2-) Chemical compound [O-2].[Cd+2] CFEAAQFZALKQPA-UHFFFAOYSA-N 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 230000005496 eutectics Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000003317 industrial substance Substances 0.000 description 2
- 239000010954 inorganic particle Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000879 optical micrograph Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229910052761 rare earth metal Inorganic materials 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 150000003673 urethanes Chemical class 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- -1 51% Chemical compound 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000004821 Contact adhesive Substances 0.000 description 1
- 229910052691 Erbium Inorganic materials 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 240000002834 Paulownia tomentosa Species 0.000 description 1
- 235000010678 Paulownia tomentosa Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 229910052773 Promethium Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910052775 Thulium Inorganic materials 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- UPEMFLOMQVFMCZ-UHFFFAOYSA-N [O--].[O--].[O--].[Pm+3].[Pm+3] Chemical compound [O--].[O--].[O--].[Pm+3].[Pm+3] UPEMFLOMQVFMCZ-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 150000002603 lanthanum Chemical class 0.000 description 1
- 239000006166 lysate Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000002159 nanocrystal Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000010951 particle size reduction Methods 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- VQMWBBYLQSCNPO-UHFFFAOYSA-N promethium atom Chemical compound [Pm] VQMWBBYLQSCNPO-UHFFFAOYSA-N 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000005563 spheronization Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
- C03C12/02—Reflective beads
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/127—Silica-free oxide glass compositions containing TiO2 as glass former
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
- E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
- E01F9/50—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
- E01F9/506—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users characterised by the road surface marking material, e.g. comprising additives for improving friction or reflectivity; Methods of forming, installing or applying markings in, on or to road surfaces
- E01F9/524—Reflecting elements specially adapted for incorporation in or application to road surface markings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
- Y10T428/2438—Coated
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Optical Elements Other Than Lenses (AREA)
- Glass Compositions (AREA)
- Road Signs Or Road Markings (AREA)
- Road Repair (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/273,513 US7513941B2 (en) | 2005-11-14 | 2005-11-14 | Pavement marking, reflective elements, and methods of making micospheres |
| PCT/US2006/044270 WO2007059175A1 (en) | 2005-11-14 | 2006-11-14 | Pavement marking, reflective elements, and methods of making microspheres |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2009516102A true JP2009516102A (ja) | 2009-04-16 |
| JP2009516102A5 JP2009516102A5 (enExample) | 2009-11-26 |
Family
ID=38041177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008540286A Pending JP2009516102A (ja) | 2005-11-14 | 2006-11-14 | 舗装道路路面標識、反射素子およびミクロスフェアを作製する方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (4) | US7513941B2 (enExample) |
| EP (2) | EP1954640B1 (enExample) |
| JP (1) | JP2009516102A (enExample) |
| KR (1) | KR101365847B1 (enExample) |
| CN (1) | CN101304954B (enExample) |
| AU (1) | AU2006315485B2 (enExample) |
| BR (1) | BRPI0620511A2 (enExample) |
| WO (1) | WO2007059175A1 (enExample) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011065473A1 (ja) * | 2009-11-27 | 2011-06-03 | 丸尾カルシウム株式会社 | 路面標示材用複合反射素子およびそれを含有してなる路面標示材 |
| JP2011253165A (ja) * | 2010-06-04 | 2011-12-15 | Maruo Calcium Co Ltd | 路面標示用複合反射素子およびそれを含有してなる路面標示材 |
| JP2012084670A (ja) * | 2010-10-08 | 2012-04-26 | Keiwa Inc | 太陽電池モジュール用バックシート及び太陽電池モジュール |
| JP2015516311A (ja) * | 2012-02-28 | 2015-06-11 | スリーエム イノベイティブ プロパティズ カンパニー | ポリオルガノシロキサンと親水性成分とを含む剥離コーティングを備えたシーティング物品 |
| JP2016509566A (ja) * | 2013-01-09 | 2016-03-31 | オーシーアイ カンパニー リミテッドOCI Company Ltd. | 再帰反射性に優れた高屈折率のガラスビード及びその製造方法 |
| JP2017132656A (ja) * | 2016-01-28 | 2017-08-03 | 日本電気硝子株式会社 | 光学ガラス及びその製造方法 |
| JP2019044497A (ja) * | 2017-09-04 | 2019-03-22 | 大崎工業株式会社 | 標示シート、標示シートの製造方法、標示体シート、標示体シートの製造方法、及び標示体設置方法 |
| US20230270091A1 (en) * | 2022-02-25 | 2023-08-31 | Globeride, Inc. | Fishing worm |
| JP2024133342A (ja) * | 2019-04-05 | 2024-10-01 | 日本電気硝子株式会社 | 装飾用ガラス物品 |
Families Citing this family (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004030984A2 (en) * | 2002-09-30 | 2004-04-15 | Next Safety, Inc. | Roadway and vehicular-mounted reflectors incorporating a field of discrete crystal reflectors and retroreflectors |
| US9732481B2 (en) | 2004-04-02 | 2017-08-15 | Flint Trading, Inc. | Preformed thermoplastic pavement marking and method utilizing large aggregate for improved long term skid resistance and reduced tire tracking |
| US7513941B2 (en) * | 2005-11-14 | 2009-04-07 | 3M Innovative Properties Company | Pavement marking, reflective elements, and methods of making micospheres |
| JP4953234B2 (ja) * | 2006-09-14 | 2012-06-13 | 独立行政法人 宇宙航空研究開発機構 | チタン系酸化物ガラスおよびその製造方法 |
| US9207373B2 (en) | 2007-04-10 | 2015-12-08 | Stoncor Group, Inc. | Methods for fabrication and highway marking usage of agglomerated retroreflective beads |
| US8292539B2 (en) * | 2007-04-10 | 2012-10-23 | Stoncor Group, Inc. | Agglomerated retroreflective beads for highway marking and methods for fabrication and use thereof |
| US20080280034A1 (en) * | 2007-05-11 | 2008-11-13 | 3M Innovative Properties Company | Pavement marking and reflective elements having microspheres comprising lanthanum oxide and aluminum oxide with zirconia, titania, or mixtures thereof |
| EP2235266A1 (en) * | 2007-12-21 | 2010-10-06 | 3M Innovative Properties Company | Retroreflective pavement markings |
| EP2238486A1 (en) * | 2007-12-21 | 2010-10-13 | 3M Innovative Properties Company | Retroreflective articles and retroreflective elements comprising a spherical core and two concentric optical interference layers |
| JP5681104B2 (ja) | 2008-07-10 | 2015-03-04 | スリーエム イノベイティブ プロパティズ カンパニー | 粘弾性導光体を有する再帰反射物品及びデバイス |
| WO2010006102A2 (en) | 2008-07-10 | 2010-01-14 | 3M Innovative Properties Company | Retroreflective articles and devices having viscoelastic lightguide |
| CN102124384B (zh) | 2008-07-10 | 2016-10-12 | 3M创新有限公司 | 粘弹性光导 |
| JP2011530718A (ja) | 2008-08-08 | 2011-12-22 | スリーエム イノベイティブ プロパティズ カンパニー | 光を管理するための粘弾性層を有する光ガイド |
| US9133318B2 (en) * | 2008-09-02 | 2015-09-15 | Flint Trading, Inc. | Taggants for thermoplastic marking materials |
| US8840956B2 (en) * | 2008-10-31 | 2014-09-23 | Potters Industries, Llc | Retroreflective coating and method for applying a retroreflective coating on a structure |
| US7955858B2 (en) * | 2008-12-16 | 2011-06-07 | The Boeing Company | Quantum dot-based environmental indicators |
| US20100272962A1 (en) * | 2009-04-22 | 2010-10-28 | Potters Industries Inc. | Reflective substrate surface system, reflective assembly, and methods of improving the visibility of a substrate surface |
| US8591045B2 (en) | 2009-08-21 | 2013-11-26 | 3M Innovative Properties Company | Pavement markings, reflective elements, and methods of making microspheres |
| BR112012003663A2 (pt) * | 2009-08-21 | 2016-03-29 | 3M Innovative Properties Co | demarcações de pavimentos, elementos refletivos, e métodos de preparo de microesferas. |
| CA2730631C (en) * | 2010-02-09 | 2015-03-31 | Potters Industries, Inc. | Reflective substrate surface system, reflective assembly, and methods of improving the visibility of a substrate surface |
| US9239417B2 (en) | 2010-02-10 | 2016-01-19 | 3M Innovative Properties Company | Illumination device having viscoelastic layer |
| CN101857368B (zh) * | 2010-06-30 | 2011-09-28 | 张学军 | 一种用于道路标线的矿石玻璃珠 |
| US8622555B2 (en) | 2010-08-31 | 2014-01-07 | 3M Innovative Properties Company | Security article having a switching feature |
| US8503610B1 (en) | 2010-11-23 | 2013-08-06 | The Boeing Company | X-ray inspection tool |
| US8396187B2 (en) | 2010-12-10 | 2013-03-12 | The Boeing Company | X-ray inspection tool |
| US8764202B1 (en) | 2011-04-11 | 2014-07-01 | The United States Of America As Represented By The Secretary Of The Army | Retro-reflective article |
| CN102226042B (zh) * | 2011-04-20 | 2013-05-22 | 天津恒实通工程技术发展有限公司 | 氧化钛-镧包覆中空微珠的方法 |
| EP2751338A4 (en) | 2011-09-01 | 2015-07-01 | 3M Innovative Properties Co | RAIL MARKING MATERIALS AND METHODS |
| US8588262B1 (en) | 2011-09-07 | 2013-11-19 | The Boeing Company | Quantum dot detection |
| JP2014528099A (ja) | 2011-09-20 | 2014-10-23 | スリーエム イノベイティブ プロパティズ カンパニー | 再帰反射素子 |
| WO2013181325A2 (en) | 2012-05-30 | 2013-12-05 | 3M Innovative Properties Company | Marking tape, method of applying and method of manufacturing the marking tape |
| US9932476B2 (en) | 2012-10-29 | 2018-04-03 | 3M Innovative Properties Company | Pavement marking compositions |
| WO2014190017A1 (en) | 2013-05-24 | 2014-11-27 | 3M Innovative Properties Company | Bead-coated sheet |
| EP3126414B1 (en) | 2014-04-04 | 2018-06-06 | 3M Innovative Properties Company | Primer composition for wet or damp surface preparation |
| US10138367B2 (en) | 2014-04-29 | 2018-11-27 | 3M Innovative Properties Company | Copolymers of poly(ethylene-co-acrylic acid) and polydiorganosiloxanes |
| EP3177576B1 (en) | 2014-08-08 | 2023-09-27 | 3M Innovative Properties Company | Retroreflective elements including particles |
| WO2016081078A1 (en) * | 2014-10-03 | 2016-05-26 | Flint Trading, Inc. | Preformed thermoplastic pavement marking and method for high skid resistance with maintained high retroreflectivity |
| CN104354352A (zh) * | 2014-10-14 | 2015-02-18 | 陈国顺 | 一种带彩色印花型反光织物及制作方法 |
| EP3227732A1 (en) * | 2014-12-05 | 2017-10-11 | 3M Innovative Properties Company | Retroreflective elements with a monolayer-forming compound |
| US20170022676A1 (en) * | 2015-04-29 | 2017-01-26 | Michael L. Milano | Luminescent raised road marker |
| WO2016205443A1 (en) | 2015-06-18 | 2016-12-22 | 3M Innovative Properties Company | Thermoplastic pavement marking tapes |
| CN105016621A (zh) * | 2015-07-01 | 2015-11-04 | 合肥鼎亮光学科技有限公司 | 一种反光膜用耐高温低膨胀玻璃微珠及其制备方法 |
| CN105036560A (zh) * | 2015-07-13 | 2015-11-11 | 安徽天堂唯高塑业科技有限公司 | 一种微棱镜型反光膜用玻璃微珠及其制备方法 |
| KR101594869B1 (ko) * | 2015-08-26 | 2016-02-17 | (주) 지비테크 | 유리조각을 매용제로 활용한 굴절률을 가지는 유리알 조성물 및 유리 조성물을 조분화한 유리가루를 이용한 굴절률을 가지는 유리알 |
| CN108025958B (zh) | 2015-09-11 | 2021-04-09 | 3M创新有限公司 | 具有小珠共混物的耐用回射元件 |
| CN108027463B (zh) | 2015-09-11 | 2021-12-07 | 3M创新有限公司 | 具有离子共聚物芯的耐用回射元件 |
| CN108496098B (zh) | 2016-01-21 | 2021-12-07 | 3M创新有限公司 | 光学掩蔽滤光器 |
| CN110402310B (zh) | 2017-03-15 | 2022-01-28 | 3M创新有限公司 | 用于车道识别的道路标记系统 |
| US20200024813A1 (en) | 2017-03-20 | 2020-01-23 | 3M Innovative Properties Company | White pavement marking |
| WO2019021130A1 (en) | 2017-07-28 | 2019-01-31 | 3M Innovative Properties Company | NANOCRYSTALLINE CERAMIC OXIDE BALLS |
| CN107324660B (zh) * | 2017-09-01 | 2020-04-24 | 长飞光纤光缆股份有限公司 | 一种无色高折射率玻璃及其制备方法 |
| EP3724400A1 (en) | 2017-12-14 | 2020-10-21 | 3M Innovative Properties Company | Pavement markings and pavement marking system for lane identification |
| US10969600B2 (en) | 2018-03-08 | 2021-04-06 | Apple Inc. | Electronic devices with optical markers |
| US11001979B2 (en) | 2018-08-13 | 2021-05-11 | Vergence Automation, Inc. | Methods and apparatus for ultrawide entrance angle reflective articles for use with autonomous vehicle machine vision systems |
| CN108919396B (zh) * | 2018-08-24 | 2024-07-23 | 福建跃发光新材料股份有限公司 | 一种幻影多变反光布及其制作方法 |
| US11762133B1 (en) | 2018-09-13 | 2023-09-19 | Vergence Automation, Inc. | Retroreflective materials and articles incorporating near-ideal total internal retroreflective elements |
| US11467324B2 (en) * | 2018-10-26 | 2022-10-11 | Tundra Composits, LLC | Complex retroreflective bead |
| CN109680597B (zh) * | 2018-12-20 | 2021-03-05 | 安徽择正公路工程有限责任公司 | 道路标线装置及标线方法 |
| CN110256897B (zh) * | 2019-07-19 | 2021-12-07 | 安米微纳新材料(广州)有限公司 | 一种无机油墨、光伏背板玻璃及其制备方法 |
| CN111170645A (zh) * | 2020-01-15 | 2020-05-19 | 浙江工业大学 | 一种含纳米颗粒的玻璃微粉及其制备方法 |
| WO2022069967A1 (en) | 2020-10-01 | 2022-04-07 | 3M Innovative Properties Company | Dielectric material for a high voltage capacitor |
| US12152354B2 (en) | 2020-12-08 | 2024-11-26 | Vergence Automation, Inc. | Anisotropic retroreflective mesh for longitudinal pavement marking articles and methods |
| US12196987B2 (en) | 2021-01-12 | 2025-01-14 | Tundra COmpoistes, LLC | Retroreflective composite reflective microspheres and reflective inorganic material |
| CN119528445B (zh) * | 2024-12-12 | 2025-09-19 | 四川增量新材料科技有限公司 | 一种用于道路标线的高折射率大粒径玻璃微珠及其球化成型制备方法 |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3493403A (en) * | 1963-02-14 | 1970-02-03 | Minnesota Mining & Mfg | High titania glass articles and process |
| US3946130A (en) * | 1974-04-01 | 1976-03-23 | Minnesota Mining And Manufacturing Company | Transparent glass microspheres and products made therefrom |
| US4657595A (en) * | 1985-09-16 | 1987-04-14 | The Procter & Gamble Company | Quick setting anionic bituminous emulsions |
| US4921754A (en) * | 1984-01-13 | 1990-05-01 | Seibu Polymer Kasei Kabushiki Kaisha | High-durability pavement marking sheet material |
| WO1996033139A1 (en) * | 1995-04-18 | 1996-10-24 | Minnesota Mining And Manufacturing Company | Acid-resistant glass |
| US5759928A (en) * | 1994-05-20 | 1998-06-02 | Minneota Mining And Manufacturing Company | Retroreflective article with non-continuous top coat |
| JP2001500992A (ja) * | 1997-07-16 | 2001-01-23 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 隆起した突起部を有する方向指示性舗装道路用マーキング及び製造方法 |
| JP2001174610A (ja) * | 1999-12-16 | 2001-06-29 | Fuji Photo Film Co Ltd | 光コリメータシートの製造方法 |
| JP2002522676A (ja) * | 1998-08-11 | 2002-07-23 | スリーエム イノベイティブ プロパティズ カンパニー | 耐磨耗性輸送表面マーカー形成方法および材料 |
| JP2005104768A (ja) * | 2003-09-30 | 2005-04-21 | Nippon Electric Glass Co Ltd | 再帰反射用ガラスビーズ及びその製造方法 |
Family Cites Families (99)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2354018A (en) | 1940-08-03 | 1944-07-18 | Minnesota Mining & Mfg | Light reflector sheet |
| US2713286A (en) | 1949-10-22 | 1955-07-19 | Minnesota Mining & Mfg | Reflex light reflectors and glass bead elements thereof |
| US2853393A (en) | 1951-07-05 | 1958-09-23 | Minnesota Mining & Mfg | High-index glass elements |
| DE1065580B (de) | 1953-08-12 | 1959-09-17 | Minnesota Mining and Manufacturing Company, Saint Paul, Minn. (V. St. A.) | Durchsichtiges Glaselement mit einer Stärke von nicht mehr 2 mm |
| US2726161A (en) | 1953-09-21 | 1955-12-06 | Minnesota Mining & Mfg | High-index glass elements |
| US2842446A (en) | 1954-12-27 | 1958-07-08 | Minnesota Mining & Mfg | High-index glass elements |
| US2873197A (en) | 1955-01-21 | 1959-02-10 | Carborundum Co | Refractory fibrous material |
| US2963378A (en) | 1955-04-25 | 1960-12-06 | Minnesota Mining & Mfg | Ass beads hemispherically reflectorled with metallic coating and compositions thereof |
| US2870030A (en) | 1955-07-18 | 1959-01-20 | Minnesota Mining & Mfg | High-index glass elements |
| US2924533A (en) | 1956-05-28 | 1960-02-09 | Carborundum Co | Spheroidal refractory material and method of making |
| US2960594A (en) | 1958-06-30 | 1960-11-15 | Plasma Flame Corp | Plasma flame generator |
| US3145114A (en) | 1960-10-24 | 1964-08-18 | Prismo Safety Corp | Process for increasing the index of refraction of glass and an article made thereby |
| US3228897A (en) | 1961-10-26 | 1966-01-11 | Minnesota Mining & Mfg | Reflective coating compositions containing glass beads, metal flake pigment and binder |
| US3149016A (en) | 1962-04-02 | 1964-09-15 | Minnesota Mining & Mfg | Nucleated glass particle and process for making it |
| GB1018773A (en) * | 1962-09-13 | 1966-02-02 | Bellon Labor Sa Roger | ª‡-phenyl-ª‰-2-furyl-propionitrile derivatives |
| US3419403A (en) | 1963-03-18 | 1968-12-31 | Cataphote Corp | High index of refraction glass compositions |
| DE1250977B (enExample) | 1963-04-22 | 1967-09-28 | ||
| US3294558A (en) | 1963-04-22 | 1966-12-27 | Cataphote Corp | Colorless high index glass compositions |
| US3293051A (en) | 1963-08-22 | 1966-12-20 | Cataphote Corp | High titanate glass beads |
| US3254563A (en) * | 1963-11-12 | 1966-06-07 | Prismo Safety Corp | Retro-reflective particles and reflective markers and compositions containing such particles |
| US3323888A (en) | 1964-03-17 | 1967-06-06 | Cataphote Corp | Method for manufacturing glass beads |
| BE661293A (enExample) | 1964-04-21 | 1900-01-01 | ||
| US3493404A (en) * | 1964-06-22 | 1970-02-03 | Physical Sciences Corp | Ceramic material |
| FR1404190A (fr) | 1964-08-10 | 1965-06-25 | Minnesota Mining & Mfg | Perles transparentes |
| US3416936A (en) | 1965-03-01 | 1968-12-17 | Gen Steel Ind Inc | Abrasion resistant glass bead with sharp softening range and process for making the same |
| US3432314A (en) | 1966-08-02 | 1969-03-11 | Us Air Force | Transparent zirconia composition and process for making same |
| US3410185A (en) | 1966-08-08 | 1968-11-12 | Minnesota Mining & Mfg | Marking |
| US3418896A (en) * | 1967-02-03 | 1968-12-31 | Prismo Safety Corp | Reflective markers and reflective elements therefor |
| US3499857A (en) | 1967-04-17 | 1970-03-10 | Cataphote Corp | Thermoplastic resinous compositions,particularly using unsaturated triglycerides |
| US3523029A (en) | 1967-08-21 | 1970-08-04 | Cataphote Corp | Hot melt highway marking composition |
| DE1771079B1 (de) | 1968-03-30 | 1971-12-30 | Jenaer Glaswerk Schott & Gen | Gegenreduktion und verfaerbung stabile glaeser fuer reflex perlen mit brechwerten mindestens gleich groesser od gleich 2,2 |
| US3560074A (en) | 1968-10-21 | 1971-02-02 | Cataphote Corp | 95% titanium dioxide glass spheroids |
| US3709706A (en) | 1969-05-16 | 1973-01-09 | Minnesota Mining & Mfg | Refractory fibers and other articles of zirconia and silica mixtures |
| US3645933A (en) | 1969-11-12 | 1972-02-29 | Sherwin Williams Co | Coating composition including isocyanate-modified polyester and chlorinated rubber |
| US3684536A (en) | 1970-11-04 | 1972-08-15 | Du Pont | Bismuthate glass-ceramic precursor compositions |
| US3795524A (en) | 1971-03-01 | 1974-03-05 | Minnesota Mining & Mfg | Aluminum borate and aluminum borosilicate articles |
| US3749763A (en) | 1971-08-03 | 1973-07-31 | Humphreys Corp | Processing of silicate ores and product thereof |
| IT1045437B (it) | 1972-12-28 | 1980-05-10 | Eigenmann Ludwig | Perfezionamento ai materiali cata rifrangenti a doppia focalizzazione in particolare per segnaletica strdale |
| US3864113A (en) | 1973-10-19 | 1975-02-04 | Corning Glass Works | Method of Producing Glass by Flame Hydrolysis |
| US3915771A (en) | 1974-03-04 | 1975-10-28 | Minnesota Mining & Mfg | Pavement-marking tape |
| US3923051A (en) | 1974-03-18 | 1975-12-02 | Samuel Soichet | Inflatable intrauterine contraceptive device for postpartum use |
| US4082427A (en) | 1974-07-02 | 1978-04-04 | Fukuoka Tokushu Garasu Kabushiki Kaisha | High refractive index glass compositions |
| US4137086A (en) | 1975-05-13 | 1979-01-30 | Pilkington Brothers Limited | Glass compositions for use in curable compositions |
| FR2320276A1 (fr) | 1975-08-06 | 1977-03-04 | Prod Refractaires Europ | Billes ameliorees en matiere ceramique |
| US4056602A (en) | 1975-08-20 | 1977-11-01 | Thagard Technology Company | High temperature chemical reaction processes utilizing fluid-wall reactors |
| US4095974A (en) | 1975-09-24 | 1978-06-20 | Thagard Technology Company | High temperature chemical reaction processes utilizing fluid-wall reactors |
| AT364475B (de) | 1975-12-10 | 1981-10-27 | Minnesota Mining & Mfg | Transparente glasmikrokugeln |
| JPS5415919A (en) | 1977-06-07 | 1979-02-06 | Fukuoka Tokushiyu Garasu Kk | Glass having high refractive index |
| US4367919A (en) * | 1977-08-01 | 1983-01-11 | Minnesota Mining And Manufacturing Company | Durable glass elements |
| US4192576A (en) | 1978-11-20 | 1980-03-11 | Minnesota Mining And Manufacturing Company | Ultra-high-index glass microspheres and products made therefrom |
| US4248932A (en) * | 1979-06-14 | 1981-02-03 | Minnesota Mining And Manufacturing Company | Extended-life pavement-marking sheet material |
| FR2493910A1 (fr) | 1980-11-13 | 1982-05-14 | Produits Refractaires | Agent de soutenement a base de zircone et de silice pour fractures geologiques profondes |
| DE3216451C2 (de) | 1982-05-03 | 1984-04-19 | Schott Glaswerke, 6500 Mainz | Optisches Leichtgewichtglas mit einem Brechwert ≥ 1.70, einer Abbezahl ≥ 22 und einer Dichte ≦ 3,5 g/cm↑3↑ |
| JPS6033229A (ja) | 1983-07-28 | 1985-02-20 | Minolta Camera Co Ltd | 高屈折率光学ガラス |
| US4621936A (en) | 1983-10-14 | 1986-11-11 | Corning Glass Works | Zirconia pen balls |
| US4564556A (en) | 1984-09-24 | 1986-01-14 | Minnesota Mining And Manufacturing Company | Transparent non-vitreous ceramic particulate |
| DE3504625C1 (de) | 1985-02-11 | 1986-07-03 | Schott Glaswerke, 6500 Mainz | Hochbrechendes optisches Glas im System SiO2-TiO2-Nb2O5-BaO-Alkalioxid mit Brechwerten ? 1,83 und Abbezahlen ? 25,und mit sehr guter chemischer Bestaendigkeit |
| US4721743A (en) | 1985-03-25 | 1988-01-26 | The Dow Chemical Company | Non-thermoset thermally stable capped epoxy resin compositions |
| US4772511A (en) | 1985-11-22 | 1988-09-20 | Minnesota Mining And Manufacturing Company | Transparent non-vitreous zirconia microspheres |
| CA1308845C (en) * | 1986-01-13 | 1992-10-13 | Roger W. Lange | Pavement markings containing transparent non-vitreous ceramic microspheres |
| US4837069A (en) | 1987-01-07 | 1989-06-06 | Minnesota Mining And Manufacturing Company | Transparent alumina microspheres |
| JP2610004B2 (ja) | 1988-04-28 | 1997-05-14 | 東芝硝子株式会社 | ガラスビーズ |
| US4988541A (en) * | 1988-06-09 | 1991-01-29 | Minnesota Mining And Manufacturing Company | Process for making retroreflector sheet |
| US5227221A (en) * | 1988-06-09 | 1993-07-13 | Minnesota Mining And Manufacturing Company | Patterned skid preventative sheet |
| US4988555A (en) * | 1988-06-09 | 1991-01-29 | Minnesota Mining And Manufacturing Company | Patterned pavement marking |
| US5262595A (en) | 1990-07-25 | 1993-11-16 | Ngk Insulators, Ltd. | Dielectric ceramic body including TiO2 dispersion in crystallized cordierite matrix phase, method of producing the same, and circuit board using the same |
| AU658871B2 (en) | 1991-02-28 | 1995-05-04 | Minnesota Mining And Manufacturing Company | Pavement markers with silicone adhesive |
| US5268789A (en) | 1992-02-18 | 1993-12-07 | Minnesota Mining And Manufacturing Company | Retroreflective assembly and process for making same |
| US5286682A (en) * | 1992-02-19 | 1994-02-15 | Minnesota Mining And Manufacturing Company | Yellow retroreflective pavement markings |
| DE4210011C1 (enExample) | 1992-03-27 | 1993-07-15 | Schott Glaswerke, 6500 Mainz, De | |
| FR2714905B1 (fr) | 1994-01-11 | 1996-03-01 | Produits Refractaires | Billes en matière céramique fondue. |
| DE4423794C1 (de) | 1994-07-01 | 1996-02-08 | Ivoclar Ag | Zr0¶2¶-haltige Glaskeramik, Verfahren zu deren Herstellung sowie deren Verwendung |
| US5516227A (en) * | 1994-07-07 | 1996-05-14 | Iit Research Institute | Spherodized fluorescent beads for improved roadway pavement marker visibility |
| IT1268814B1 (it) | 1994-12-13 | 1997-03-06 | Calp Spa | Miscela vetrificabile per vetri di qualita' |
| ATE176919T1 (de) | 1995-01-18 | 1999-03-15 | Dow Chemical Co | Schnellhärtende wässrige beschichtungszusammensetzung und farbe |
| US5674616A (en) | 1995-02-06 | 1997-10-07 | Conversion Technologies International, Inc. | Glass beads having improved fracture toughness |
| US5576097A (en) | 1995-04-24 | 1996-11-19 | Brite-Line Industries, Inc. | High brightness durable retro-reflecting microspheres and method of making the same |
| WO1997028471A1 (en) | 1996-02-05 | 1997-08-07 | Minnesota Mining And Manufacturing Company | Durable retroreflective elements |
| US5917652A (en) | 1996-02-05 | 1999-06-29 | Minnesota Mining And Manufacturing Company | Durable retroreflective elements |
| US5777791A (en) | 1996-11-26 | 1998-07-07 | Minnesota Mining And Manufacturing Company | Wet retroreflective pavement marking articles |
| US6153127A (en) | 1996-12-25 | 2000-11-28 | Nippon Sheet Glass Co., Ltd. | Optical thin film, forming composition thereof, and ultraviolet ray absorbing and thermic ray reflecting glass using the same |
| US6132132A (en) | 1997-02-26 | 2000-10-17 | Rohm And Haas Company | Water-based road marking paint |
| JP3993269B2 (ja) | 1997-04-18 | 2007-10-17 | スリーエム カンパニー | 透明ビーズおよびその製造方法 |
| WO1998047830A1 (en) * | 1997-04-18 | 1998-10-29 | Minnesota Mining And Manufacturing Company | Transparent beads and their production method |
| US6166106A (en) | 1997-06-13 | 2000-12-26 | 3M Innovative Properties Company | Liquid pavement marking compositions |
| US6365262B1 (en) | 1998-10-20 | 2002-04-02 | 3M Innovative Properties Company | Pavement marking articles having enhanced retroreflectivity under dry or wet conditions and method for making same |
| JP4530443B2 (ja) * | 1999-03-26 | 2010-08-25 | スリーエム カンパニー | 路面標示体の製造方法 |
| US6245700B1 (en) | 1999-07-27 | 2001-06-12 | 3M Innovative Properties Company | Transparent microspheres |
| WO2003011781A2 (en) * | 2001-08-02 | 2003-02-13 | 3M Innovative Properties Company | al2O3-RARE EARTH OXIDE-ZrO2/HfO2 MATERIALS, AND METHODS OF MAKING AND USING THE SAME |
| ATE378293T1 (de) * | 2001-08-02 | 2007-11-15 | 3M Innovative Properties Co | Verfahren zur herstellung von gegenständen aus glas sowie so hergestellte glaskeramikgegenstände |
| AU2002367931A1 (en) * | 2001-08-02 | 2003-12-22 | 3M Innovative Properties Company | Alumina-yttria-zirconium oxide/hafnium oxide materials, and methods of making and using the same |
| US20040259713A1 (en) | 2003-06-11 | 2004-12-23 | 3M Innovative Properties Company | Microspheres comprising titania and bismuth oxide |
| US7141522B2 (en) | 2003-09-18 | 2006-11-28 | 3M Innovative Properties Company | Ceramics comprising Al2O3, Y2O3, ZrO2 and/or HfO2, and Nb2O5 and/or Ta2O5 and methods of making the same |
| WO2005047604A1 (en) * | 2003-11-06 | 2005-05-26 | 3M Innovative Properties Company | Retroreflective elements comprising a bonded resin core and pavement markings |
| US20050158461A1 (en) * | 2004-01-21 | 2005-07-21 | 3M Innovative Properties Company | Methods of making reflective elements |
| US7332453B2 (en) | 2004-07-29 | 2008-02-19 | 3M Innovative Properties Company | Ceramics, and methods of making and using the same |
| US7513941B2 (en) * | 2005-11-14 | 2009-04-07 | 3M Innovative Properties Company | Pavement marking, reflective elements, and methods of making micospheres |
| US20080010208A1 (en) * | 2006-07-06 | 2008-01-10 | Motorola, Inc. | Method and apparatus for communication by a secondary user of spectrum |
| US8145134B2 (en) * | 2008-07-22 | 2012-03-27 | At&T Intellectual Property I, L.P. | Wireless microphone beacon |
-
2005
- 2005-11-14 US US11/273,513 patent/US7513941B2/en active Active
-
2006
- 2006-11-14 BR BRPI0620511-9A patent/BRPI0620511A2/pt not_active IP Right Cessation
- 2006-11-14 KR KR1020087012948A patent/KR101365847B1/ko active Active
- 2006-11-14 EP EP06837616.9A patent/EP1954640B1/en active Active
- 2006-11-14 JP JP2008540286A patent/JP2009516102A/ja active Pending
- 2006-11-14 CN CN2006800420105A patent/CN101304954B/zh not_active Expired - Fee Related
- 2006-11-14 EP EP14165447.5A patent/EP2759523A1/en not_active Withdrawn
- 2006-11-14 AU AU2006315485A patent/AU2006315485B2/en not_active Ceased
- 2006-11-14 WO PCT/US2006/044270 patent/WO2007059175A1/en not_active Ceased
-
2008
- 2008-12-17 US US12/337,524 patent/US7579293B2/en not_active Expired - Lifetime
- 2008-12-17 US US12/337,506 patent/US7745360B2/en not_active Expired - Lifetime
-
2010
- 2010-05-12 US US12/778,782 patent/US7947616B2/en not_active Expired - Lifetime
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3493403A (en) * | 1963-02-14 | 1970-02-03 | Minnesota Mining & Mfg | High titania glass articles and process |
| US3946130A (en) * | 1974-04-01 | 1976-03-23 | Minnesota Mining And Manufacturing Company | Transparent glass microspheres and products made therefrom |
| US4921754A (en) * | 1984-01-13 | 1990-05-01 | Seibu Polymer Kasei Kabushiki Kaisha | High-durability pavement marking sheet material |
| US4657595A (en) * | 1985-09-16 | 1987-04-14 | The Procter & Gamble Company | Quick setting anionic bituminous emulsions |
| US5759928A (en) * | 1994-05-20 | 1998-06-02 | Minneota Mining And Manufacturing Company | Retroreflective article with non-continuous top coat |
| WO1996033139A1 (en) * | 1995-04-18 | 1996-10-24 | Minnesota Mining And Manufacturing Company | Acid-resistant glass |
| JP2001500992A (ja) * | 1997-07-16 | 2001-01-23 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | 隆起した突起部を有する方向指示性舗装道路用マーキング及び製造方法 |
| JP2002522676A (ja) * | 1998-08-11 | 2002-07-23 | スリーエム イノベイティブ プロパティズ カンパニー | 耐磨耗性輸送表面マーカー形成方法および材料 |
| JP2001174610A (ja) * | 1999-12-16 | 2001-06-29 | Fuji Photo Film Co Ltd | 光コリメータシートの製造方法 |
| JP2005104768A (ja) * | 2003-09-30 | 2005-04-21 | Nippon Electric Glass Co Ltd | 再帰反射用ガラスビーズ及びその製造方法 |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011065473A1 (ja) * | 2009-11-27 | 2011-06-03 | 丸尾カルシウム株式会社 | 路面標示材用複合反射素子およびそれを含有してなる路面標示材 |
| JP5719310B2 (ja) * | 2009-11-27 | 2015-05-13 | 丸尾カルシウム株式会社 | 路面標示材用複合反射素子の製造方法および路面標示材用複合反射素子を含有してなる路面標示材 |
| JP2011253165A (ja) * | 2010-06-04 | 2011-12-15 | Maruo Calcium Co Ltd | 路面標示用複合反射素子およびそれを含有してなる路面標示材 |
| JP2012084670A (ja) * | 2010-10-08 | 2012-04-26 | Keiwa Inc | 太陽電池モジュール用バックシート及び太陽電池モジュール |
| JP2015516311A (ja) * | 2012-02-28 | 2015-06-11 | スリーエム イノベイティブ プロパティズ カンパニー | ポリオルガノシロキサンと親水性成分とを含む剥離コーティングを備えたシーティング物品 |
| JP2016509566A (ja) * | 2013-01-09 | 2016-03-31 | オーシーアイ カンパニー リミテッドOCI Company Ltd. | 再帰反射性に優れた高屈折率のガラスビード及びその製造方法 |
| US9670091B2 (en) | 2013-01-09 | 2017-06-06 | Oci Company Ltd. | High refractive index glass bead with high retroreflectivity, and method of preparing the same |
| JP2017132656A (ja) * | 2016-01-28 | 2017-08-03 | 日本電気硝子株式会社 | 光学ガラス及びその製造方法 |
| JP2019044497A (ja) * | 2017-09-04 | 2019-03-22 | 大崎工業株式会社 | 標示シート、標示シートの製造方法、標示体シート、標示体シートの製造方法、及び標示体設置方法 |
| JP2024133342A (ja) * | 2019-04-05 | 2024-10-01 | 日本電気硝子株式会社 | 装飾用ガラス物品 |
| JP7769311B2 (ja) | 2019-04-05 | 2025-11-13 | 日本電気硝子株式会社 | 装飾用ガラス物品 |
| US20230270091A1 (en) * | 2022-02-25 | 2023-08-31 | Globeride, Inc. | Fishing worm |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1954640B1 (en) | 2018-08-01 |
| AU2006315485B2 (en) | 2013-01-10 |
| US7745360B2 (en) | 2010-06-29 |
| EP1954640A4 (en) | 2009-05-06 |
| EP1954640A1 (en) | 2008-08-13 |
| US20090098338A1 (en) | 2009-04-16 |
| US7513941B2 (en) | 2009-04-07 |
| US20090098999A1 (en) | 2009-04-16 |
| US7947616B2 (en) | 2011-05-24 |
| KR101365847B1 (ko) | 2014-02-21 |
| US7579293B2 (en) | 2009-08-25 |
| CN101304954B (zh) | 2011-09-07 |
| BRPI0620511A2 (pt) | 2011-11-16 |
| WO2007059175A1 (en) | 2007-05-24 |
| US20100221419A1 (en) | 2010-09-02 |
| EP2759523A1 (en) | 2014-07-30 |
| CN101304954A (zh) | 2008-11-12 |
| US20070110960A1 (en) | 2007-05-17 |
| KR20080066063A (ko) | 2008-07-15 |
| AU2006315485A1 (en) | 2007-05-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US7947616B2 (en) | Pavement marking, reflective elements, and methods of making microspheres | |
| US8591044B2 (en) | Pavement markings, reflective elements, and methods of making microspheres | |
| EP2360128B1 (en) | Pavement marking and reflective elements having microspheres comprising lanthanum oxide and aluminum oxide with zirconia, titania, or mixtures thereof | |
| US8591045B2 (en) | Pavement markings, reflective elements, and methods of making microspheres | |
| US7524779B2 (en) | Microspheres having a high index of refraction | |
| EP4490554A1 (en) | Microspheres comprising zirconia and alumina suitable for retroreflective articles |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20091006 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20091006 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20101005 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20110105 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20110113 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110405 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20110426 |