JP2009502458A - 漂白触媒顆粒物の製造方法 - Google Patents
漂白触媒顆粒物の製造方法 Download PDFInfo
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- JP2009502458A JP2009502458A JP2008523211A JP2008523211A JP2009502458A JP 2009502458 A JP2009502458 A JP 2009502458A JP 2008523211 A JP2008523211 A JP 2008523211A JP 2008523211 A JP2008523211 A JP 2008523211A JP 2009502458 A JP2009502458 A JP 2009502458A
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- Prior art keywords
- iii
- alkyl
- bleach catalyst
- carrier material
- acid
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract description 43
- 239000008187 granular material Substances 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 37
- 230000002378 acidificating effect Effects 0.000 claims abstract description 34
- 229920000642 polymer Polymers 0.000 claims abstract description 31
- 239000007844 bleaching agent Substances 0.000 claims abstract description 27
- 239000000654 additive Substances 0.000 claims abstract description 21
- 239000012876 carrier material Substances 0.000 claims abstract description 20
- 239000007864 aqueous solution Substances 0.000 claims abstract description 12
- 238000004061 bleaching Methods 0.000 claims abstract description 12
- 239000007900 aqueous suspension Substances 0.000 claims abstract description 9
- 239000012530 fluid Substances 0.000 claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- -1 pyridin-1-yl-methyl Chemical group 0.000 claims description 27
- 150000001875 compounds Chemical class 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- 235000011152 sodium sulphate Nutrition 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 239000003446 ligand Substances 0.000 claims description 6
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- ZTQXXOJWTGPDML-UHFFFAOYSA-N 2-(4-oxobutyl)heptanedioic acid Chemical compound OC(=O)CCCCC(C(O)=O)CCCC=O ZTQXXOJWTGPDML-UHFFFAOYSA-N 0.000 claims description 3
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 claims description 3
- 150000004696 coordination complex Chemical class 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical group FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052794 bromium Inorganic materials 0.000 claims description 2
- 239000000460 chlorine Chemical group 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 239000011737 fluorine Chemical group 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims description 2
- 125000006514 pyridin-2-ylmethyl group Chemical group [H]C1=C([H])C([H])=C([H])C(=N1)C([H])([H])* 0.000 claims description 2
- 125000004076 pyridyl group Chemical group 0.000 claims description 2
- 150000002431 hydrogen Chemical group 0.000 claims 2
- 239000011247 coating layer Substances 0.000 claims 1
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- 229930195729 fatty acid Natural products 0.000 description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
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- 238000003860 storage Methods 0.000 description 6
- 229920002341 Sokalan® CP 13 S Polymers 0.000 description 5
- 229920005646 polycarboxylate Polymers 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 description 4
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- 239000001993 wax Substances 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
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- 125000000129 anionic group Chemical group 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
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- 239000007787 solid Substances 0.000 description 3
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- 239000010457 zeolite Substances 0.000 description 3
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- LCTONWCANYUPML-UHFFFAOYSA-N Pyruvic acid Chemical compound CC(=O)C(O)=O LCTONWCANYUPML-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
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- 235000021355 Stearic acid Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
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- 150000007513 acids Chemical class 0.000 description 2
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- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
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- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 2
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- 239000000645 desinfectant Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000001177 diphosphate Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- CSVGEMRSDNSWRF-UHFFFAOYSA-L disodium;dihydrogen phosphate Chemical compound [Na+].[Na+].OP(O)([O-])=O.OP(O)([O-])=O CSVGEMRSDNSWRF-UHFFFAOYSA-L 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 238000009477 fluid bed granulation Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 229960002598 fumaric acid Drugs 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- VANNPISTIUFMLH-UHFFFAOYSA-N glutaric anhydride Chemical compound O=C1CCCC(=O)O1 VANNPISTIUFMLH-UHFFFAOYSA-N 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- BEJNERDRQOWKJM-UHFFFAOYSA-N kojic acid Chemical compound OCC1=CC(=O)C(O)=CO1 BEJNERDRQOWKJM-UHFFFAOYSA-N 0.000 description 1
- 229960004705 kojic acid Drugs 0.000 description 1
- WZNJWVWKTVETCG-UHFFFAOYSA-N kojic acid Natural products OC(=O)C(N)CN1C=CC(=O)C(O)=C1 WZNJWVWKTVETCG-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229960000448 lactic acid Drugs 0.000 description 1
- 229940098895 maleic acid Drugs 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 229940044600 maleic anhydride Drugs 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 229960002510 mandelic acid Drugs 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 229940107700 pyruvic acid Drugs 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229930002330 retinoic acid Natural products 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229960001367 tartaric acid Drugs 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 229960001727 tretinoin Drugs 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 238000005550 wet granulation Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3935—Bleach activators or bleach catalysts granulated, coated or protected
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
- C11D11/0088—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads the liquefied ingredients being sprayed or adsorbed onto solid particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Catalysts (AREA)
Abstract
Description
式中、Mは、Mn(II)、Mn(III)、Mn(IV)、Mn(V)、Cu(I)、Cu(II)、Cu(III)、Fe(II)、Fe(III)、Fe(IV)、Fe(V)、Co(I)、Co(II)、Co(III)、Ti(II)、Ti(III)、Ti(IV)、V(II)、V(III)、V(IV)、V(V)、Mo(II)、Mo(III)、Mo(IV)、Mo(V)、Mo(VI)及びW(IV)、W(V)及びW(VI)、好ましくはFe(II)、Fe(III)、Fe(IV)、Fe(V)を意味し、
Lは、上記式(1)の配位子、好ましくはジメチル−2,4−ジ(2−ピリジル)−3−メチル−7−(ピリジン−2−イルメチル)−3,7−ジアザビシクロ(3.3.1)ノナン−9−オン−1,5−ジカルボキシレートまたはそれのプロトン化された形のものを意味し、
Xは、Mと配位結合を結ぶことができる、単荷電、二荷電または三荷電のアニオンあるいは中性分子を意味し、
Yは、非配位性対イオンを意味し、そして
aは、1〜10の整数を意味し、
kは、1〜10の整数を意味し、
nは、0〜10の整数を意味し、
mは、0〜20の整数を意味する。
バッチ式)、リングレイヤミキサー、またはシュージミキサーが可能である。ミキサー法ばかりではなく、流動床法においても、コーティング物質は、一成分ノズルもしくは二成分ノズル装置を介して吹き付けることができる。
実験室規模の試験において、D=150mmの流入口直径を有するGlatt社製のタイプGPCG1.1のバッチ稼働式実験室用流動床を使用した。スプレーノズルは、原料を下方から流動床中にスプレーする。
−漂白触媒 (乾質) 6.01%
−Sokalan CP 13 S (乾質)(酸性成分) 10.01%
−硫酸ナトリウム 83.48%
−残留水分 0.5%
実験室規模の試験において、D=150mmの流入口直径を有するGlatt社製のタイプGPCG1.1のバッチ稼働式実験室用流動床を使用した。スプレーノズルは、原料を下方から流動床中にスプレーする。
−漂白触媒(乾質) 5.8%
−Sokalan CP 13 S(乾質)酸性成分 12.1%
−マレイン酸(添加剤) 10.08%
−硫酸ナトリウム 71.52%
−残留水分 0.5%
Claims (10)
- 漂白触媒、酸性ポリマー、キャリア材料、場合によっては及び更に別の添加剤を含む漂白触媒顆粒物の製造方法であって、流動床装置中でキャリア材料から流動床を形成し、漂白触媒、酸性ポリマー、場合によっては及び更に別の添加剤を含む水性溶液または懸濁液を前記流動床中に計量添加し、そして造粒及び乾燥することを特徴とする、前記方法。
- 漂白触媒顆粒物を次いでコーティング層で被覆することを特徴とする、請求項1の方法。
- 次式(1)
で表される化合物が漂白触媒として使用されることを特徴とする、請求項1の方法。 - 次式(2)
[MaLkXn]Ym (2)
[式中、Mは、Mn(II)、Mn(III)、Mn(IV)、Mn(V)、Cu(I)、Cu(II)、Cu(III)、Fe(II)、Fe(III)、Fe(IV)、Fe(V)、Co(I)、Co(II)、Co(III)、Ti(II)、Ti(III)、Ti(IV)、V(II)、V(III)、V(IV)、V(V)、Mo(II)、Mo(III)、Mo(IV)、Mo(V)、Mo(VI)及びW(IV)、W(V)及びW(VI)、好ましくはFe(II)、Fe(III)、Fe(IV)、Fe(V)を意味し、
Lは、上記式(1)に従う配位子、好ましくはジメチル−2,4−ジ−(2−ピリジル)−3−メチル−7−(ピリジン−1−イル−メチル)−3,7−ジアザビシクロ[3.3.1]ノナン−9−オン−1,5−ジカルボキシレートまたはこれのプロトン化された形のものを意味し、
Xは、Mと配位可能な、単荷電、二重荷電または三重荷電アニオンあるいは中性分子を意味し、
Yは、非配位性の対イオンを意味し、そして
aは、1〜10の整数であり、
kは、1〜10の整数であり、
nは、0〜10の整数であり、
mは、0〜20の整数である]
で表される化合物が漂白触媒として使用されることを特徴とする、請求項1の方法。 - ジメチル−2,4−ジ−(ピリジル)−3−メチル−7−(ピリジン−2−イルメチル)−3,7−ジアザビシクロ(3.3.1)ノナン−9−オン−1,5−ジカルボキシレート、またはこの化合物を配位子として含む上記式(2)の金属錯体が漂白触媒として使用されることを特徴とする、請求項1の方法。
- 硫酸ナトリウムがキャリア材料として使用されることを特徴とする、請求項1の方法。
- 20℃において5g/Lよりも多量に水中に溶解しかつ1%濃度溶液として7未満のpH値を示すポリマーが、酸性ポリマーとして使用されることを特徴とする、請求項1の方法。
- 追加的に酸性添加剤が使用されることを特徴とする、請求項1の方法。
- 流動床としてのキャリア材料の全量を仕込み、そして漂白触媒、酸性ポリマー、場合によっては及び更に別の添加剤を含む水性溶液または懸濁液でバッチ式に造粒することを特徴とする、請求項1の方法。
- キャリア材料と、漂白触媒、酸性ポリマー、場合によっては及び更に別の添加剤を含む水性溶液または懸濁液とを、流動床装置中に連続的に計量添加することを特徴とする、請求項1の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005035916A DE102005035916A1 (de) | 2005-07-28 | 2005-07-28 | Verfahren zur Herstellung von Bleichkatalysator-Granulaten |
DE102005035916.7 | 2005-07-28 | ||
PCT/EP2006/007293 WO2007012451A1 (de) | 2005-07-28 | 2006-07-25 | Verfahren zur herstellung von bleichkatalysator-granulaten |
Publications (2)
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JP2009502458A true JP2009502458A (ja) | 2009-01-29 |
JP5175726B2 JP5175726B2 (ja) | 2013-04-03 |
Family
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JP2008523211A Expired - Fee Related JP5175726B2 (ja) | 2005-07-28 | 2006-07-25 | 漂白触媒顆粒物の製造方法 |
Country Status (8)
Country | Link |
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US (1) | US20090256113A1 (ja) |
EP (1) | EP1913124B1 (ja) |
JP (1) | JP5175726B2 (ja) |
BR (1) | BRPI0613853A2 (ja) |
DE (2) | DE102005035916A1 (ja) |
ES (1) | ES2327448T3 (ja) |
MX (1) | MX2008001214A (ja) |
WO (1) | WO2007012451A1 (ja) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2010195892A (ja) * | 2009-02-24 | 2010-09-09 | Lion Corp | 洗剤添加用粒子、洗剤組成物及び洗剤添加用粒子の製造方法 |
JP2013509286A (ja) * | 2009-10-30 | 2013-03-14 | ズード−ケミー アーゲー | 複合材料の製造方法 |
JP2013515595A (ja) * | 2009-12-24 | 2013-05-09 | アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップ | グルタミン酸n,n−二酢酸キレート剤の被覆粒子 |
JP2014534323A (ja) * | 2011-11-11 | 2014-12-18 | ザ プロクター アンド ギャンブルカンパニー | シールド塩類を含有する表面処理組成物 |
JP2017520672A (ja) * | 2014-06-13 | 2017-07-27 | エコラボ ユーエスエー インコーポレイティド | 活性化過酸素及び/又はアルカリ性洗剤処方における強化された触媒安定性 |
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US11330988B2 (en) | 2007-06-12 | 2022-05-17 | Sotera Wireless, Inc. | Body-worn system for measuring continuous non-invasive blood pressure (cNIBP) |
US20110224498A1 (en) | 2010-03-10 | 2011-09-15 | Sotera Wireless, Inc. | Body-worn vital sign monitor |
BR112016003054B1 (pt) | 2013-08-16 | 2022-02-15 | Chemsenti Limited | Formulação de branqueamento, partícula, método e uso de uma partícula |
DK3190168T3 (da) * | 2016-01-06 | 2019-07-15 | Dalli Werke Gmbh & Co Kg | Belagt blegemiddelkatalysator |
PT3426756T (pt) * | 2016-03-11 | 2019-10-18 | Unilever Nv | Suspensão detergente derramável compreendendo grânulos catalisadores de branqueamento |
DE102017004742A1 (de) | 2017-05-17 | 2018-11-22 | Weylchem Wiesbaden Gmbh | Beschichtete Granulate, deren Verwendung und Wasch- und Reinigungsmittel enthaltend diese |
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-
2005
- 2005-07-28 DE DE102005035916A patent/DE102005035916A1/de not_active Withdrawn
-
2006
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- 2006-07-25 BR BRPI0613853-5A patent/BRPI0613853A2/pt not_active Application Discontinuation
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- 2006-07-25 US US11/989,444 patent/US20090256113A1/en not_active Abandoned
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JPH0214300A (ja) * | 1988-04-28 | 1990-01-18 | Colgate Palmolive Co | 粒状洗剤組成物 |
JPH03168300A (ja) * | 1989-11-13 | 1991-07-22 | Unilever Nv | 粒状洗剤添加剤集合体の製造方法及び洗剤組成物におけるその使用 |
JP2000087088A (ja) * | 1998-09-09 | 2000-03-28 | Clariant Gmbh | 漂白活性化剤顆粒物 |
JP2003193093A (ja) * | 2001-12-15 | 2003-07-09 | Clariant Gmbh | 漂白活性化剤共顆粒物 |
WO2004104155A1 (en) * | 2003-05-21 | 2004-12-02 | Ciba Specialty Chemicals Holding Inc. | Stable particulate composition comprising bleach catalysts |
JP2007533788A (ja) * | 2003-10-31 | 2007-11-22 | ユニリーバー・ナームローゼ・ベンノートシヤープ | 基質の触媒的漂白のためのビスピドン−誘導(bispidon−derivated)配位子およびこれらの錯体 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010195892A (ja) * | 2009-02-24 | 2010-09-09 | Lion Corp | 洗剤添加用粒子、洗剤組成物及び洗剤添加用粒子の製造方法 |
JP2013509286A (ja) * | 2009-10-30 | 2013-03-14 | ズード−ケミー アーゲー | 複合材料の製造方法 |
US9327272B2 (en) | 2009-10-30 | 2016-05-03 | Clariant International Ltd. | Method for producing a composite material |
JP2013515595A (ja) * | 2009-12-24 | 2013-05-09 | アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップ | グルタミン酸n,n−二酢酸キレート剤の被覆粒子 |
JP2014534323A (ja) * | 2011-11-11 | 2014-12-18 | ザ プロクター アンド ギャンブルカンパニー | シールド塩類を含有する表面処理組成物 |
JP2017520672A (ja) * | 2014-06-13 | 2017-07-27 | エコラボ ユーエスエー インコーポレイティド | 活性化過酸素及び/又はアルカリ性洗剤処方における強化された触媒安定性 |
Also Published As
Publication number | Publication date |
---|---|
DE502006004011D1 (de) | 2009-07-30 |
US20090256113A1 (en) | 2009-10-15 |
WO2007012451A1 (de) | 2007-02-01 |
EP1913124A1 (de) | 2008-04-23 |
MX2008001214A (es) | 2008-03-24 |
BRPI0613853A2 (pt) | 2011-02-15 |
DE102005035916A1 (de) | 2007-02-01 |
ES2327448T3 (es) | 2009-10-29 |
JP5175726B2 (ja) | 2013-04-03 |
EP1913124B1 (de) | 2009-06-17 |
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