JP2008201050A - レーザー光線発色シート - Google Patents
レーザー光線発色シート Download PDFInfo
- Publication number
- JP2008201050A JP2008201050A JP2007041282A JP2007041282A JP2008201050A JP 2008201050 A JP2008201050 A JP 2008201050A JP 2007041282 A JP2007041282 A JP 2007041282A JP 2007041282 A JP2007041282 A JP 2007041282A JP 2008201050 A JP2008201050 A JP 2008201050A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- laser beam
- resin
- coloring
- coloring sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- 229910000152 cobalt phosphate Inorganic materials 0.000 description 1
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- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 1
- GAYAMOAYBXKUII-UHFFFAOYSA-L cobalt(2+);dibenzoate Chemical compound [Co+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 GAYAMOAYBXKUII-UHFFFAOYSA-L 0.000 description 1
- ZBDSFTZNNQNSQM-UHFFFAOYSA-H cobalt(2+);diphosphate Chemical compound [Co+2].[Co+2].[Co+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O ZBDSFTZNNQNSQM-UHFFFAOYSA-H 0.000 description 1
- MULYSYXKGICWJF-UHFFFAOYSA-L cobalt(2+);oxalate Chemical compound [Co+2].[O-]C(=O)C([O-])=O MULYSYXKGICWJF-UHFFFAOYSA-L 0.000 description 1
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- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
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- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
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- BUJJNPWRTNNUCG-UHFFFAOYSA-L iron(2+);dibenzoate Chemical compound [Fe+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 BUJJNPWRTNNUCG-UHFFFAOYSA-L 0.000 description 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- NZPIUJUFIFZSPW-UHFFFAOYSA-H lanthanum carbonate Chemical compound [La+3].[La+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O NZPIUJUFIFZSPW-UHFFFAOYSA-H 0.000 description 1
- 229960001633 lanthanum carbonate Drugs 0.000 description 1
- YXEUGTSPQFTXTR-UHFFFAOYSA-K lanthanum(3+);trihydroxide Chemical compound [OH-].[OH-].[OH-].[La+3] YXEUGTSPQFTXTR-UHFFFAOYSA-K 0.000 description 1
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 description 1
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- 239000007788 liquid Substances 0.000 description 1
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
- 239000011654 magnesium acetate Substances 0.000 description 1
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- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
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- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 1
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 1
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- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 1
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- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
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- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 1
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- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
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- NMHMNPHRMNGLLB-UHFFFAOYSA-N phloretic acid Chemical compound OC(=O)CCC1=CC=C(O)C=C1 NMHMNPHRMNGLLB-UHFFFAOYSA-N 0.000 description 1
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Images
Landscapes
- Heat Sensitive Colour Forming Recording (AREA)
- Laminated Bodies (AREA)
Abstract
【解決手段】主に耐久性を有する構造物およびその部品、具体的には住宅、店舗、公共建物およびそれを構成する移動機器およびその部品、弱電機器、公共建築物およびその部品、ガス、水道、電気のメーター類および配線、配管、貯蔵施設などに使われる型番、製造番号、注意書き、マーク類などに表記に使われるシートのうち、レーザー光線による発色により、文字、図形、絵柄をシートの層間等に設けた、耐久性が高くかつ工程が少なく簡便に貼れるシート、特に屋外用レーザー光線発色シートを提供することにある。
【選択図】図1
Description
1)金属の単体としては、鉄、亜鉛、スズ、ニッケル、銅、銀、金等が挙げられる。
ヘキサメチレンジイソシアネート系が使用される。
レーザー光線(キーエンス(株)製:「YVO4 レーザーマーカー MD−V9600」出力6W、波長1064nm、捜査スピード500mm/sec、レーザー出力20%、Q−SW周波数10kHz)を前記透明熱可塑性樹脂層より照射して、文字と写真データを描画した。結果、線の太さ4μm〜50μmのカタカナ文字と連続調の写真が発色した。
実施例1と同様にレーザーマーカーMD−V9600を用いて描画した結果、線の太さ40μm〜200μmのカタカナ文字と連続調の写真が発色した。
実施例1と同様にレーザーマーカーMD−V9600を用いて描画した結果、線の太さ40μm〜200μmのカタカナ文字と連続調の写真が発色した。
実施例1と同様にレーザーマーカーMD−V9600を用いて描画した結果、線の太さ40μm〜200μmのカタカナ文字と連続調の写真が発色した。
2…粘着剤層
3…熱可塑性樹脂基材層
4…着色インキ層
5…レーザー光線発色層
6…透明熱可塑性樹脂層
7…表面保護層
10、11、12…レーザー光線発色シート
Claims (11)
- レーザー光線により発色する発色層上にレーザー光線を透過する透明熱可塑性樹脂層を設けてなるレーザー光線発色シートにおいて、前記透明熱可塑性樹脂層上にさらにレーザー光線を透過する透明表面保護層を設けてなることを特徴とするレーザー光線発色シート。
- 前記レーザー光線発色シートの裏面側に粘着剤層を設けてなることを特徴とする、請求項1記載のレーザー光線発色シート。
- 前記発色層の前記透明熱可塑性樹脂層を設けた側とは反対側に熱可塑性樹脂からなる基材層を設けてなることを特徴とする、請求項1、2のいずれか記載のレーザー光線発色シート。
- 前記透明熱可塑性樹脂層と発色層の間にレーザー光線を透過する接着剤層を設けてなることを特徴とする請求項1〜3のいずれか記載のレーザー光線発色シート。
- 前記発色層と基材層との間に着色インキ層を設けてなることを特徴とする請求項3、4のいずれか記載のレーザー光線発色シート。
- 前記透明表面保護層、透明熱可塑性樹脂層、接着剤層の少なくとも1層に最大吸収波長が400nm以下の紫外線吸収剤及びヒンダードアミン系光安定剤を添加してなることを特徴とする請求項1〜5のいずれか記載のレーザー光線発色シート。
- 前記粘着剤層あるいは基材層のいずれかまたは両方にも、最大吸収波長が400nm以下の紫外線吸収剤及びヒンダードアミン系光安定剤を添加してなることを特徴とする請求項6記載のレーザー光線発色シート。
- 前記透明熱可塑性樹脂層および基材層は、結晶性延伸ポリエステル樹脂、非晶状態の結晶性ポリエステル樹脂、非結晶性ポリエステル樹脂、アクリル樹脂、ポリオレフィン系樹脂、ポリカーボネート樹脂、ポリエチレンナフタレート樹脂いずれか1種以上からなる樹脂の単層又は複合層からなることを特徴とする、請求項1〜7のいずれか記載のレーザー光線発色シート。
- 前記発色層は、銅・モリブデン複合酸化物、アンチモンドープ酸化錫被覆マイカ、アンチモンドープ酸化錫/酸化チタン/二酸化珪素被覆マイカ、のいずれか1種以上から選ばれる金属化合物を含むことを特徴とする請求項1〜8のいずれか記載のレーザー光線発色シート。
- 前記発色層のバインダーおよび/または着色インキ層のバインダーが、ウレタン系樹脂および/またはその混合物からなることを特徴とする請求項1〜9のいずれか記載のレーザー光線発色シート。
- 前記透明表面保護層が2液硬化型アクリルウレタン系樹脂で、硬化剤がイソシアネート系で、かつヘキサメチレンジイソシアネート系であることを特徴とする請求項1〜10のいずれか記載のレーザー光線発色シート。
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