JP2008095151A - 水素貯蔵材料の製造方法およびハイブリッド粉末 - Google Patents
水素貯蔵材料の製造方法およびハイブリッド粉末 Download PDFInfo
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- JP2008095151A JP2008095151A JP2006278709A JP2006278709A JP2008095151A JP 2008095151 A JP2008095151 A JP 2008095151A JP 2006278709 A JP2006278709 A JP 2006278709A JP 2006278709 A JP2006278709 A JP 2006278709A JP 2008095151 A JP2008095151 A JP 2008095151A
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 170
- 239000001257 hydrogen Substances 0.000 title claims abstract description 155
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 155
- 239000000843 powder Substances 0.000 title claims abstract description 42
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 26
- 239000011232 storage material Substances 0.000 title claims abstract description 20
- 238000003860 storage Methods 0.000 claims abstract description 112
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 58
- 239000000956 alloy Substances 0.000 claims abstract description 58
- 239000000463 material Substances 0.000 claims abstract description 58
- 229910021392 nanocarbon Inorganic materials 0.000 claims abstract description 54
- 239000007790 solid phase Substances 0.000 claims abstract description 8
- 239000007791 liquid phase Substances 0.000 claims abstract description 6
- 239000007789 gas Substances 0.000 claims description 24
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 229910000765 intermetallic Inorganic materials 0.000 claims description 8
- 150000004678 hydrides Chemical class 0.000 claims description 4
- 239000012071 phase Substances 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 abstract description 16
- 238000000034 method Methods 0.000 abstract description 13
- 238000002156 mixing Methods 0.000 abstract description 5
- 238000007711 solidification Methods 0.000 abstract 1
- 230000008023 solidification Effects 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- 230000007423 decrease Effects 0.000 description 9
- 238000005259 measurement Methods 0.000 description 9
- 238000010298 pulverizing process Methods 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 6
- 230000006866 deterioration Effects 0.000 description 6
- 229910002335 LaNi5 Inorganic materials 0.000 description 5
- 229910019758 Mg2Ni Inorganic materials 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000003575 carbonaceous material Substances 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 230000001629 suppression Effects 0.000 description 4
- 230000002950 deficient Effects 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000002134 carbon nanofiber Substances 0.000 description 2
- 238000004033 diameter control Methods 0.000 description 2
- 239000002079 double walled nanotube Substances 0.000 description 2
- 230000005489 elastic deformation Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000002048 multi walled nanotube Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 239000002109 single walled nanotube Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000001308 synthesis method Methods 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000001241 arc-discharge method Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009689 gas atomisation Methods 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000000608 laser ablation Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000011301 petroleum pitch Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- -1 that is Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
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- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Powder Metallurgy (AREA)
Abstract
【解決手段】水素吸蔵合金を、気相状態または液相状態から固相状態に相変態させるときに、ナノカーボン材を噴射して、ナノカーボン材を凝固核として成長させた水素吸蔵合金は、水素反応速度及び水素吸蔵量を向上させ、更に微粉末化を抑制することが判明した。
【選択図】図1
Description
2 ナノカーボン材
3 加熱用ヒータ
4 ノズル径制御弁
5 溶湯ノズル
6 ガスノズル
7 ハイブリッド粉末
8 ガス
10 ガスアトマイザ装置
Claims (5)
- 水素ガスを貯蔵する水素貯蔵材料の製造方法であって、
水素と反応して水素化物をつくる、金属、合金及び金属間化合物の中のいずれか1つを、液相状態から固相状態に相変態させるときに、ナノメートルサイズの微細構造を有するナノカーボン材を核にすることを特徴とする水素貯蔵材料の製造方法。 - 前記金属、前記合金及び前記金属間化合物の中のいずれか1つを、ガスアトマイズ装置を使用して、液相状態から固相状態に相変態させることを特徴とする請求項1に記載の水素貯蔵材料の製造方法。
- 水素ガスを貯蔵する水素貯蔵材料の製造方法であって、
水素と反応して水素化物をつくる、金属、合金及び金属間化合物の中のいずれか1つを、気相状態から固相状態に相変態させるときに、ナノメートルサイズの微細構造を有するナノカーボン材を核にすることを特徴とする水素貯蔵材料の製造方法。 - 前記金属、前記合金及び前記金属間化合物の中のいずれか1つに対する、前記ナノカーボン材の重量比が0.1%以上でかつ10%以下であることを特徴とする請求項1から3のいずれか1項に記載の水素貯蔵材料の製造方法。
- 請求項1から4のいずれか1項に記載の水素貯蔵材料の製造方法によって製造されることを特徴とするハイブリッド粉末。
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105950915A (zh) * | 2016-05-16 | 2016-09-21 | 扬州大学 | 一种纳米级粉体Mg2Ni化合物的制备方法 |
WO2020171165A1 (ja) * | 2019-02-22 | 2020-08-27 | 東ソー株式会社 | コアシェル複合体及びその製造方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103769588A (zh) * | 2014-01-24 | 2014-05-07 | 江苏理工学院 | 3d打印金属熔体输送装置 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61177303A (ja) * | 1985-02-01 | 1986-08-09 | Kawasaki Steel Corp | 複合粉末の製造方法および装置 |
JPS6350403A (ja) * | 1986-08-18 | 1988-03-03 | Daido Steel Co Ltd | 金属−セラミクス複合粉末の製造方法 |
JPH02188403A (ja) * | 1989-01-13 | 1990-07-24 | Mitsubishi Petrochem Co Ltd | 水素吸蔵化合物 |
JP2005336562A (ja) * | 2004-05-27 | 2005-12-08 | Shinshu Univ | 金属・カーボンナノファイバー複合体およびその製造方法 |
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- 2006-10-12 JP JP2006278709A patent/JP4851294B2/ja not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61177303A (ja) * | 1985-02-01 | 1986-08-09 | Kawasaki Steel Corp | 複合粉末の製造方法および装置 |
JPS6350403A (ja) * | 1986-08-18 | 1988-03-03 | Daido Steel Co Ltd | 金属−セラミクス複合粉末の製造方法 |
JPH02188403A (ja) * | 1989-01-13 | 1990-07-24 | Mitsubishi Petrochem Co Ltd | 水素吸蔵化合物 |
JP2005336562A (ja) * | 2004-05-27 | 2005-12-08 | Shinshu Univ | 金属・カーボンナノファイバー複合体およびその製造方法 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105950915A (zh) * | 2016-05-16 | 2016-09-21 | 扬州大学 | 一种纳米级粉体Mg2Ni化合物的制备方法 |
WO2020171165A1 (ja) * | 2019-02-22 | 2020-08-27 | 東ソー株式会社 | コアシェル複合体及びその製造方法 |
JP2020132969A (ja) * | 2019-02-22 | 2020-08-31 | 東ソー株式会社 | コアシェル複合体及びその製造方法 |
CN113454250A (zh) * | 2019-02-22 | 2021-09-28 | 东曹株式会社 | 核壳复合体和其制造方法 |
JP7342374B2 (ja) | 2019-02-22 | 2023-09-12 | 東ソー株式会社 | コアシェル複合体及びその製造方法 |
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