JP2006518012A - 織物材料の疎水化法 - Google Patents
織物材料の疎水化法 Download PDFInfo
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- JP2006518012A JP2006518012A JP2006501652A JP2006501652A JP2006518012A JP 2006518012 A JP2006518012 A JP 2006518012A JP 2006501652 A JP2006501652 A JP 2006501652A JP 2006501652 A JP2006501652 A JP 2006501652A JP 2006518012 A JP2006518012 A JP 2006518012A
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
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- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
- D06M15/233—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated aromatic, e.g. styrene
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/33—Esters containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
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- Engineering & Computer Science (AREA)
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatment Of Fiber Materials (AREA)
Abstract
Description
即ち、C2〜C24−オレフィン、特に炭素原子数2〜24個のα−オレフィン、例えばエチレン、プロピレン、1−ブテン、イソブテン、1−ヘキセン、1−オクテン、1−デセン、1−ドデセン、1−ヘキサデセン又は1−オクタデセン;
スチレン類、例えばスチレン、α−メチルスチレン、シス−スチルベン、トランス−スチルベン;
ジオレフィン、例えば1,3−ブタジエン、シクロペンタジエン、クロロプレン又はイソプレン;
C5〜C18−シクロオレフィン、例えばシクロペンテン、シクロヘキセン、ノルボルネン、2量化シクロペンタジエン;
直鎖又は分岐のC1〜C20−アルカンカルボン酸のビニルエステル、例えば酢酸ビニル、プロピオン酸ビニル、n−ブタン酸ビニル、n−ヘキサン酸ビニル、n−オクタン酸ビニル、ラウリン酸ビニル及びステアリン酸ビニル;
C1〜C20−アルコールの(メタ)アクリル酸エステル、例えばメチル(メタ)アクリレート、エチル(メタ)アクリレート、n−プロピル(メタ)アクリレート、イソプロピル(メタ)アクリレート、n−ブチル(メタ)アクリレート、イソブチル(メタ)アクリレート、tert−ブチル(メタ)アクリレート、2−エチルヘキシル(メタ)アクリレート、n−オクチル(メタ)アクリレート、n−デシル(メタ)アクリレート、n−ドデシル(メタ)アクリレート、n−エイコシル(メタ)アクリレート、
から選択され、特に好ましくはハロゲン化モノマー及びシロキサン基を有するモノマーの群から選択される。
R2がCH3又はC2H5を表し、
xが4〜12の整数、特に好ましくは6〜8の整数であり、
yが1〜11の整数、特に好ましくは1〜6の整数である。]
で表されるエステルとの共重合体、或いはグリシジル(メタ)アクリレートとフッ素化カルボン酸のビニルエステルとの共重合体。
非ハロゲン化C1〜C20−アルコールの(メタ)アクリル酸エステル{例、メチル(メタ)アクリレート、エチル(メタ)アクリレート、n−ブチル(メタ)アクリレート、n−プロピル(メタ)アクリレート、2−エチルヘキシル(メタ)アクリレート、n−オクチル(メタ)アクリレート、n−デシル(メタ)アクリレート、n−ドデシル(メタ)アクリレート、n−エイコシル(メタ)アクリレート}との共重合体も挙げることができる。
C1〜C18−アルキル、例えばメチル、エチル、n−プロピル、イソプロピル、n−ブチル、イソブチル、sec−ブチル、tert−ブチル、n−ペンチル、イソペンチル、sec−ペンチル、ネオペンチル、1,2−ジメチルプロピル、イソアミル、n−ヘキシル、イソヘキシル、sec−ヘキシル、n−へプチル、イソヘプチル、n−オクチル、n−ノニル、n−デシル、n−ドデシル、n−テトラデシル、n−ヘキサデシル、n−オクタデシル;好ましくはC1〜C6−アルキル、例えばメチル、エチル、n−プロピル、イソプロピル、n−ブチル、イソブチル、sec−ブチル、tert−ブチル、n−ペンチル、イソペンチル、sec−ペンチル、ネオペンチル、1,2−ジメチルプロピル、イソアミル、n−ヘキシル、イソヘキシル、sec−ヘキシル;さらに好ましくはC1〜C4−アルキル、例えばメチル、エチル、n−プロピル、イソプロピル、n−ブチル、イソブチル、sec−ブチル、tert−ブチル;そして中でもメチル;
C6〜C14−アリール、例えばフェニル、1−ナフチル、2−ナフチル、1−アントリル、2−アントリル、9−アントリル、1−フェナントリル、2−フェナントリル、3−フェナントリル、4−フェナントリル及び9−フェナントリル、好ましくはフェニル、1−ナフチル及び2−ナフチル、さらに好ましくはフェニル;
C3〜C12−シクロアルキル、例えばシクロプロピル、シクロブチル、シクロペンチル、シクロヘキシル、シクロへプチル、シクロオクチル、シクロノニル、シクロデシル及びシクロドデシル、好ましくはシクロペンチル、シクロヘキシル及びシクロへプチル、或いは
Si(CH3)3
から選択される。
さらに有用なポリマーとして、
ポリエーテル、例えばポリエチレングリコール、ポリプロピレングリコール、ポリブチレングリコール、ポリテトラヒドロフラン;
ポリカプロラクトン、ポリカーボネート、ポリビニルブチラール、
脂肪族又は芳香族ジカルボン酸及び/又は脂肪族又は芳香族ジアルコールから形成される部分芳香族ポリエステル、例えば、炭素原子数2〜18個の脂肪族ジアルコール(例、エチレングリコール、プロパンジオール、1,4−ブタンジオール、1,6−ヘキサンジオール、1,8−オクタンジオール又はビスフェノールA)と、炭素原子数3〜18個の脂肪族ジカルボン酸(例、コハク酸、グルタル酸、アジピン酸及びα,ω−デカンジカルボン酸)とから形成されたポリエステル;
テレフタル酸と、脂肪族ジアルコール(例、エチレングリコール、プロパンジオール、1,4−ブタンジオール、1,6−ヘキサンジオール又は1,8−オクタンジオール)とから形成されたポリエステル
を挙げることができる。
少なくとも1種の有機ポリマー、
少なくとも1種の有機又は無機の粒子状固体、
水、及び
任意に1種以上の有機溶剤、及び
任意に別の成分、例えば1種以上の乳化剤を、
有機又は無機の粒子状固体の量を、有機又は無機の固体が、少なくとも5.5g/Lの割合で上記水性液中に存在するように選択した状態で、混合することを含んでいる。
実施例1.1(液1.1の製造)
下記の配合を機械的撹拌によりフラスコ内で混合した:
883.5mlの脱塩水、
62.4gのランダム共重合体の水性分散液(固形分20質量%){この共重合体は10質量%のメタクリル酸及び90質量%の下記の化合物:
15.6gのランダム共重合体の水性分散液(固形分20質量%){この共重合体は20質量%のアクリル酸及び80質量%のエチレンから形成され、Mw20000g/モルを有し、N,N−ジメチルエタノールアミンでpH8.5と9.5の間に中和されている}、及び
25.2gのイソプロパノール。
下記の配合を機械的撹拌によりフラスコ内で混合した:
899.5mlの脱塩水、
52.4gのランダム共重合体の水性分散液(固形分20質量%){この共重合体は10質量%のメタクリル酸及び90質量%の下記の化合物:
14.6gのランダム共重合体の水性分散液(固形分20質量%){この共重合体は20質量%のアクリル酸及び80質量%のエチレンから形成され、Mw20000g/モルを有し、N,N−ジメチルエタノールアミンでpH8.5と9.5の間に中和されている}、及び
25.2gのイソプロパノール。
下記の配合を機械的撹拌によりフラスコ内で撹拌した:
884.5mlの脱塩水、
66.3gのランダム共重合体の水性分散液(固形分20質量%){この共重合体は10質量%のメタクリル酸及び90質量%の下記の化合物:
13.8gのランダム共重合体の水性分散液(固形分20質量%){この共重合体は20質量%のアクリル酸及び80質量%のエチレンから形成され、Mw20000g/モルを有し、N,N−ジメチルエタノールアミンでpH8.5と9.5の間に中和されている}、及び
30.2gのイソプロパノール。
下記の配合を機械的撹拌によりフラスコ内で撹拌した:
886.3mlの脱塩水、
20.8gのランダム共重合体の水性分散液(固形分20質量%){この共重合体は10質量%のメタクリル酸及び90質量%の下記の化合物:
57gのランダム共重合体の水性分散液(固形分20質量%){この共重合体は20質量%のアクリル酸及び80質量%のエチレンから形成され、Mw25000g/モルを有し、N,N−ジメチルエタノールアミンでpH8.5と9.5の間に中和されている}、及び
28.4gのイソプロパノール。
実施例2.1
220g/m2の基本重量(坪量)のポリエステル織布を、パッダ(Mathis社製、モデルHVF12085)上において液1.1で処理した。ロールの絞り圧力は2.6バールであった。これにより60%のウエットピックアップを製造した。塗布速度は2m/分であった。次いで、処理されたポリエステル織布を、120℃のテンターで乾燥した。最終加熱処理を、循環空気を用いて150℃で3分間行った。処理されたポリエステル織布2.1を得た。
160g/m2の基本重量(坪量)のポリアミド織布を、パッダ(Mathis社製、モデルHVF12085)上において液1.1で処理した。ロールの絞り圧力は2.6バールであった。これにより65%のウエットピックアップを製造した。塗布速度は2m/分であった。次いで、処理されたポリアミド織布を、120℃のテンターで乾燥した。最終加熱処理を、循環空気を用いて150℃で3分間行った。処理されたポリアミド織布2.2を得た。
295g/m2の基本重量(坪量)のポリアクリル織布を、パッダ(Mathis社製、モデルHVF12085)上において液1.1で処理した。ロールの絞り圧力は2.6バールであった。これにより50%のウエットピックアップを製造した。塗布速度は2m/分であった。次いで、処理されたポリアクリル織布を、120℃のテンターで乾燥した。最終加熱処理を、循環空気を用いて150℃で3分間行った。処理されたポリアクリル織布2.3を得た。
220g/m2の基本重量(坪量)のポリエステル織布を、パッダ(Mathis社製、モデルHVF12085)上において液1.2で処理した。ロールの絞り圧力は2.6バールであった。これにより60%のウエットピックアップを製造した。塗布速度は2m/分であった。次いで、処理されたポリアミド織布を、120℃のテンターで乾燥した。最終加熱処理を、循環空気を用いて150℃で3分間行った。処理されたポリエステル織布2.4を得た。
160g/m2の基本重量(坪量)のポリアミド織布を、パッダ(Mathis社製、モデルHVF12085)上において液1.2で処理した。ロールの絞り圧力は2.6バールであった。これにより65%のウエットピックアップを製造した。塗布速度は2m/分であった。次いで、処理されたポリアミド織布を、120℃のテンターで乾燥した。最終加熱処理を、循環空気を用いて150℃で3分間行った。処理されたポリアミド織布2.5を得た。
295g/m2の基本重量(坪量)のポリアクリル織布を、パッダ(Mathis社製、モデルHVF12085)上において液1.2で処理した。ロールの絞り圧力は2.6バールであった。これにより50%のウエットピックアップを製造した。塗布速度は2m/分であった。次いで、処理されたポリアミド織布を、120℃のテンターで乾燥した。最終加熱処理を、循環空気を用いて150℃で3分間行った。処理されたポリアクリル織布2.6を得た。
本発明に従い処理された試験されるべき織物サンプルを、手で引張り、傾斜が1°〜90°の範囲で連続的に調整可能である平坦な木製ボードに釘で固定した。その後、カニューレ(cannula)を用いて、10mmの高さから、単一の水滴を織物サンプルに滴下した。水滴は4.7mgの質量であった。傾斜角度を徐々に増加させ、玉になって動き出し、付着の痕跡がなくなる傾斜角度まで、徐々に増加させた。その結果を表1に示す。
Claims (12)
- 少なくとも1種の有機ポリマー及び少なくとも1種の有機又は無機の粒子状固体を含む少なくとの1種の水性液を用いて織物材料を処理することにより、織物材料を仕上げる方法であって、該有機又は無機の固体が、少なくとも5.5g/Lの割合で上記水性液中に存在していることを特徴とする方法。
- 少なくとも1種の有機又は無機の固体が疎水性である請求項1に記載の方法。
- 処理前に、織物の表面に結合層を設ける請求項1又は2に記載の方法。
- 固体が、少なくとも1種の無機の固体である請求項1〜3のいずれか1項に記載の方法。
- 有機又は無機の固体が、少なくとも7g/Lの割合で上記水性液中に存在している請求項1〜4のいずれか1項に記載の方法。
- 有機又は無機の固体が、1〜350nmの範囲の粒径(メジアン値、数平均)を有する請求項1〜5のいずれか1項に記載の方法。
- 請求項1〜6のいずれか1項に記載の方法により仕上げられた織物材料。
- 少なくとも1種の有機ポリマー及び少なくとも1種の有機又は無機の粒子状固体を含む水性液であって、有機又は無機の固体が、少なくとも5.5g/Lの割合で上記水性液中に存在していることを特徴とする水性液。
- 織物材料を仕上げるために、請求項8に記載の水性液を使用する方法。
- 下記の成分:
少なくとも1種の有機ポリマー、
少なくとも1種の有機又は無機の粒子状固体、
水、及び
任意に1種以上の有機溶剤、及び
任意に別の成分
を混合することにより請求項8に記載の水性液を製造する方法であって、
有機又は無機の粒子状固体の量を、該有機又は無機の粒子状固体が、少なくとも5.5g/Lの割合で上記水性液中に存在するように選択することを特徴とする方法。 - 請求項8に記載の水性液を製造するために配合物を使用する方法であって、
上記配合物が、有機ポリマー、有機又は無機の粒子状固体、任意に1種以上の有機溶剤、及び任意に1種以上の乳化剤、及びさらに任意に水を含み、そして水の割合が15質量%以下であることを特徴とする使用方法。 - 有機ポリマー、有機又は無機の粒子状固体、任意に1種以上の有機溶剤、及び任意に1種以上の乳化剤、及びさらに任意に水を含み、且つ水の割合が15質量%以下であることを特徴とする配合物。
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JP2007538165A (ja) * | 2004-05-19 | 2007-12-27 | ビーエーエスエフ アクチェンゲゼルシャフト | 吸収材料を仕上げ処理する方法 |
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Also Published As
Publication number | Publication date |
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DE502004011953D1 (de) | 2011-01-13 |
US20060174418A1 (en) | 2006-08-10 |
US7790238B2 (en) | 2010-09-07 |
JP4531039B2 (ja) | 2010-08-25 |
US7955518B2 (en) | 2011-06-07 |
WO2004074568A1 (de) | 2004-09-02 |
DE10306893A1 (de) | 2004-08-26 |
ES2356143T3 (es) | 2011-04-05 |
ATE490369T1 (de) | 2010-12-15 |
US20100305256A1 (en) | 2010-12-02 |
EP1597425A1 (de) | 2005-11-23 |
EP1597425B1 (de) | 2010-12-01 |
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