JP2006511594A5 - - Google Patents
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- JP2006511594A5 JP2006511594A5 JP2004571969A JP2004571969A JP2006511594A5 JP 2006511594 A5 JP2006511594 A5 JP 2006511594A5 JP 2004571969 A JP2004571969 A JP 2004571969A JP 2004571969 A JP2004571969 A JP 2004571969A JP 2006511594 A5 JP2006511594 A5 JP 2006511594A5
- Authority
- JP
- Japan
- Prior art keywords
- methyl
- anhydrous basis
- free acid
- base
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 28
- 239000002253 acid Substances 0.000 claims description 20
- 230000002363 herbicidal effect Effects 0.000 claims description 20
- 229940124530 sulfonamide Drugs 0.000 claims description 20
- 150000003456 sulfonamides Chemical class 0.000 claims description 20
- 239000004009 herbicide Substances 0.000 claims description 16
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 239000008247 solid mixture Substances 0.000 claims description 8
- 150000007529 inorganic bases Chemical class 0.000 claims description 7
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- 239000001488 sodium phosphate Substances 0.000 claims description 6
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 6
- 235000011008 sodium phosphates Nutrition 0.000 claims description 6
- YMXOXAPKZDWXLY-QWRGUYRKSA-N tribenuron methyl Chemical group COC(=O)[C@H]1CCCC[C@@H]1S(=O)(=O)NC(=O)N(C)C1=NC(C)=NC(OC)=N1 YMXOXAPKZDWXLY-QWRGUYRKSA-N 0.000 claims description 6
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 6
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 239000005623 Thifensulfuron-methyl Substances 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 4
- 150000001720 carbohydrates Chemical class 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 4
- ZDXMLEQEMNLCQG-UHFFFAOYSA-N sulfometuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=CC(C)=N1 ZDXMLEQEMNLCQG-UHFFFAOYSA-N 0.000 claims description 4
- AHTPATJNIAFOLR-UHFFFAOYSA-N thifensulfuron-methyl Chemical group S1C=CC(S(=O)(=O)NC(=O)NC=2N=C(OC)N=C(C)N=2)=C1C(=O)OC AHTPATJNIAFOLR-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000005472 Bensulfuron methyl Substances 0.000 claims description 3
- 239000005496 Chlorsulfuron Substances 0.000 claims description 3
- 239000005584 Metsulfuron-methyl Substances 0.000 claims description 3
- 239000005586 Nicosulfuron Substances 0.000 claims description 3
- 239000005616 Rimsulfuron Substances 0.000 claims description 3
- XMQFTWRPUQYINF-UHFFFAOYSA-N bensulfuron-methyl Chemical group COC(=O)C1=CC=CC=C1CS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 XMQFTWRPUQYINF-UHFFFAOYSA-N 0.000 claims description 3
- NSWAMPCUPHPTTC-UHFFFAOYSA-N chlorimuron-ethyl Chemical group CCOC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(Cl)=CC(OC)=N1 NSWAMPCUPHPTTC-UHFFFAOYSA-N 0.000 claims description 3
- VJYIFXVZLXQVHO-UHFFFAOYSA-N chlorsulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)Cl)=N1 VJYIFXVZLXQVHO-UHFFFAOYSA-N 0.000 claims description 3
- RSMUVYRMZCOLBH-UHFFFAOYSA-N metsulfuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=NC(OC)=N1 RSMUVYRMZCOLBH-UHFFFAOYSA-N 0.000 claims description 3
- RTCOGUMHFFWOJV-UHFFFAOYSA-N nicosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(=O)N(C)C)=N1 RTCOGUMHFFWOJV-UHFFFAOYSA-N 0.000 claims description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 3
- 235000011181 potassium carbonates Nutrition 0.000 claims description 3
- 229910000160 potassium phosphate Inorganic materials 0.000 claims description 3
- 235000011009 potassium phosphates Nutrition 0.000 claims description 3
- MEFOUWRMVYJCQC-UHFFFAOYSA-N rimsulfuron Chemical compound CCS(=O)(=O)C1=CC=CN=C1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 MEFOUWRMVYJCQC-UHFFFAOYSA-N 0.000 claims description 3
- 235000017550 sodium carbonate Nutrition 0.000 claims description 3
- RBSXHDIPCIWOMG-UHFFFAOYSA-N 1-(4,6-dimethoxypyrimidin-2-yl)-3-(2-ethylsulfonylimidazo[1,2-a]pyridin-3-yl)sulfonylurea Chemical compound CCS(=O)(=O)C=1N=C2C=CC=CN2C=1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 RBSXHDIPCIWOMG-UHFFFAOYSA-N 0.000 claims description 2
- OFSLKOLYLQSJPB-UHFFFAOYSA-N Cyclosulfamuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)NC=2C(=CC=CC=2)C(=O)C2CC2)=N1 OFSLKOLYLQSJPB-UHFFFAOYSA-N 0.000 claims description 2
- QNXAVFXEJCPCJO-UHFFFAOYSA-N Diclosulam Chemical compound N=1N2C(OCC)=NC(F)=CC2=NC=1S(=O)(=O)NC1=C(Cl)C=CC=C1Cl QNXAVFXEJCPCJO-UHFFFAOYSA-N 0.000 claims description 2
- 239000001692 EU approved anti-caking agent Substances 0.000 claims description 2
- UWVKRNOCDUPIDM-UHFFFAOYSA-N Ethoxysulfuron Chemical compound CCOC1=CC=CC=C1OS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 UWVKRNOCDUPIDM-UHFFFAOYSA-N 0.000 claims description 2
- 239000005529 Florasulam Substances 0.000 claims description 2
- QZXATCCPQKOEIH-UHFFFAOYSA-N Florasulam Chemical compound N=1N2C(OC)=NC=C(F)C2=NC=1S(=O)(=O)NC1=C(F)C=CC=C1F QZXATCCPQKOEIH-UHFFFAOYSA-N 0.000 claims description 2
- RXCPQSJAVKGONC-UHFFFAOYSA-N Flumetsulam Chemical compound N1=C2N=C(C)C=CN2N=C1S(=O)(=O)NC1=C(F)C=CC=C1F RXCPQSJAVKGONC-UHFFFAOYSA-N 0.000 claims description 2
- 239000005560 Foramsulfuron Substances 0.000 claims description 2
- 239000005564 Halosulfuron methyl Substances 0.000 claims description 2
- FMGZEUWROYGLAY-UHFFFAOYSA-N Halosulfuron-methyl Chemical group ClC1=NN(C)C(S(=O)(=O)NC(=O)NC=2N=C(OC)C=C(OC)N=2)=C1C(=O)OC FMGZEUWROYGLAY-UHFFFAOYSA-N 0.000 claims description 2
- 239000005567 Imazosulfuron Substances 0.000 claims description 2
- NAGRVUXEKKZNHT-UHFFFAOYSA-N Imazosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N3C=CC=CC3=NC=2Cl)=N1 NAGRVUXEKKZNHT-UHFFFAOYSA-N 0.000 claims description 2
- 239000005582 Metosulam Substances 0.000 claims description 2
- VGHPMIFEKOFHHQ-UHFFFAOYSA-N Metosulam Chemical compound N1=C2N=C(OC)C=C(OC)N2N=C1S(=O)(=O)NC1=C(Cl)C=CC(C)=C1Cl VGHPMIFEKOFHHQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005589 Oxasulfuron Substances 0.000 claims description 2
- 239000005604 Prosulfuron Substances 0.000 claims description 2
- LTUNNEGNEKBSEH-UHFFFAOYSA-N Prosulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)CCC(F)(F)F)=N1 LTUNNEGNEKBSEH-UHFFFAOYSA-N 0.000 claims description 2
- BGNQYGRXEXDAIQ-UHFFFAOYSA-N Pyrazosulfuron-ethyl Chemical group C1=NN(C)C(S(=O)(=O)NC(=O)NC=2N=C(OC)C=C(OC)N=2)=C1C(=O)OCC BGNQYGRXEXDAIQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005619 Sulfosulfuron Substances 0.000 claims description 2
- 239000005629 Tritosulfuron Substances 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- BIKACRYIQSLICJ-UHFFFAOYSA-N cloransulam-methyl Chemical group N=1N2C(OCC)=NC(F)=CC2=NC=1S(=O)(=O)NC1=C(Cl)C=CC=C1C(=O)OC BIKACRYIQSLICJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims description 2
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 2
- 235000019797 dipotassium phosphate Nutrition 0.000 claims description 2
- 229910000396 dipotassium phosphate Inorganic materials 0.000 claims description 2
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 2
- 229910000397 disodium phosphate Inorganic materials 0.000 claims description 2
- 235000019800 disodium phosphate Nutrition 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- PXDNXJSDGQBLKS-UHFFFAOYSA-N foramsulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=C(NC=O)C=2)C(=O)N(C)C)=N1 PXDNXJSDGQBLKS-UHFFFAOYSA-N 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- NIFKBBMCXCMCAO-UHFFFAOYSA-N methyl 2-[(4,6-dimethoxypyrimidin-2-yl)carbamoylsulfamoyl]-4-(methanesulfonamidomethyl)benzoate Chemical group COC(=O)C1=CC=C(CNS(C)(=O)=O)C=C1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 NIFKBBMCXCMCAO-UHFFFAOYSA-N 0.000 claims description 2
- ZTYVMAQSHCZXLF-UHFFFAOYSA-N methyl 2-[[4,6-bis(difluoromethoxy)pyrimidin-2-yl]carbamoylsulfamoyl]benzoate Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(OC(F)F)=CC(OC(F)F)=N1 ZTYVMAQSHCZXLF-UHFFFAOYSA-N 0.000 claims description 2
- VWGAYSCWLXQJBQ-UHFFFAOYSA-N methyl 4-iodo-2-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]benzoate Chemical group COC(=O)C1=CC=C(I)C=C1S(=O)(=O)NC(=O)NC1=NC(C)=NC(OC)=N1 VWGAYSCWLXQJBQ-UHFFFAOYSA-N 0.000 claims description 2
- AIMMSOZBPYFASU-UHFFFAOYSA-N n-(4,6-dimethoxypyrimidin-2-yl)-n'-[3-(2,2,2-trifluoroethoxy)pyridin-1-ium-2-yl]sulfonylcarbamimidate Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)OCC(F)(F)F)=N1 AIMMSOZBPYFASU-UHFFFAOYSA-N 0.000 claims description 2
- IOXAXYHXMLCCJJ-UHFFFAOYSA-N oxetan-3-yl 2-[(4,6-dimethylpyrimidin-2-yl)carbamoylsulfamoyl]benzoate Chemical compound CC1=CC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(=O)OC2COC2)=N1 IOXAXYHXMLCCJJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 2
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 2
- 239000011736 potassium bicarbonate Substances 0.000 claims description 2
- 229940093956 potassium carbonate Drugs 0.000 claims description 2
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 2
- 229940086066 potassium hydrogencarbonate Drugs 0.000 claims description 2
- 229960003339 sodium phosphate Drugs 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- KVEQCVKVIFQSGC-UHFFFAOYSA-N tritosulfuron Chemical compound FC(F)(F)C1=NC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(F)(F)F)=N1 KVEQCVKVIFQSGC-UHFFFAOYSA-N 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims 1
- 238000009472 formulation Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 4
- 241000207892 Convolvulus Species 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- IMEVJVISCHQJRM-UHFFFAOYSA-N triflusulfuron-methyl Chemical group COC(=O)C1=CC=CC(C)=C1S(=O)(=O)NC(=O)NC1=NC(OCC(F)(F)F)=NC(N(C)C)=N1 IMEVJVISCHQJRM-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41019702P | 2002-09-12 | 2002-09-12 | |
| US60/410,197 | 2002-09-12 | ||
| US46870603P | 2003-05-07 | 2003-05-07 | |
| US60/468,706 | 2003-05-07 | ||
| PCT/US2003/028256 WO2004023876A1 (en) | 2002-09-12 | 2003-09-09 | Process for preparing paste-extruded sulfonamide compositions |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2006511594A JP2006511594A (ja) | 2006-04-06 |
| JP2006511594A5 true JP2006511594A5 (cg-RX-API-DMAC7.html) | 2006-10-26 |
| JP4884672B2 JP4884672B2 (ja) | 2012-02-29 |
Family
ID=31997917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004571969A Expired - Fee Related JP4884672B2 (ja) | 2002-09-12 | 2003-09-09 | ペースト押出スルホンアミド組成物の調製方法 |
Country Status (25)
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR0110399A (pt) * | 2000-04-26 | 2003-04-08 | Ishihara Sangyo Kaisha | Composição herbicida sólida |
| AR041211A1 (es) * | 2002-09-12 | 2005-05-11 | Du Pont | Procedimiento para preparar composiciones de sulfonamida extruidas en pasta |
| GB0413209D0 (en) * | 2004-06-14 | 2004-07-14 | Agform Ltd | Chemical composition |
| US7799343B2 (en) | 2005-02-11 | 2010-09-21 | Dow Agrosciences Llc | Safer control of broadleaf weeds in turf with granular formulations of ALS inhibiting herbicides |
| IN2014DN02255A (cg-RX-API-DMAC7.html) | 2005-02-11 | 2015-07-10 | Dow Agrosciences Llc | |
| JP5122841B2 (ja) * | 2006-03-24 | 2013-01-16 | 石原産業株式会社 | 除草組成物 |
| WO2008008180A2 (en) * | 2006-07-07 | 2008-01-17 | E. I. Du Pont De Nemours And Company | Paste-extruded sulfonamide compositions containing polyols |
| CN102573467B (zh) * | 2009-10-13 | 2015-04-08 | Fmc有限公司 | 颗粒形式的除草剂组合物 |
| AR081621A1 (es) * | 2010-02-04 | 2012-10-10 | Bayer Cropscience Ag | Procedimiento para la produccion de formulaciones estables de materiales solidos de sulfonamidas |
| US20140080706A1 (en) * | 2011-06-01 | 2014-03-20 | Basf Se | Method of preparing an aqueous tank mix comprising a base |
| TWI613967B (zh) * | 2012-04-27 | 2018-02-11 | Rotam Agrochem Int Co Ltd | 含磺醯胺游離酸活性成分的可溶性顆粒劑 |
| CN103371160A (zh) | 2012-04-27 | 2013-10-30 | 龙灯农业化工国际有限公司 | 一种降低药物残留的农药组合物 |
| CN102823608B (zh) * | 2012-09-28 | 2014-10-22 | 江苏省农用激素工程技术研究中心有限公司 | 含磺酰磺隆和双氟磺草胺的除草组合物 |
| RU2641009C2 (ru) | 2012-12-12 | 2018-01-15 | ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи | Синергический способ борьбы с сорняками с применением пеноксулама и мефенацета |
| CN102972418B (zh) * | 2012-12-25 | 2014-10-15 | 联保作物科技有限公司 | 一种双氟磺草胺水分散粒剂及其制备方法 |
| MX2015011043A (es) | 2013-02-25 | 2015-10-22 | Dow Agrosciences Llc | Métodos para el control de malezas en plantíos de piña. |
| US9288989B2 (en) | 2013-02-25 | 2016-03-22 | Dow Agrosciences Llc | Synergistic weed control from applications of penoxsulam and acetochlor |
| CA2863477A1 (fr) | 2014-09-16 | 2016-03-16 | Premier Tech Technologies Ltee | Un herbicide selectif |
| PL3387904T3 (pl) | 2014-12-22 | 2020-08-10 | Mitsui Agriscience International S.A./N.V. | Ciekłe kompozycje chwastobójcze zawierające sulfonylomocznik |
| MX372576B (es) | 2016-06-21 | 2020-04-03 | Battelle Uk Ltd | Composiciones herbicidas liquidas que contienen sal de li y sulfonilurea |
| CN116686838B (zh) * | 2019-08-14 | 2025-07-08 | 青岛奥迪斯生物科技有限公司 | 一种含三嗪氟草胺的除草组合物 |
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| JP5000810B2 (ja) * | 2000-04-26 | 2012-08-15 | 石原産業株式会社 | 固形除草組成物 |
| TWI243019B (en) | 2000-08-31 | 2005-11-11 | Basf Ag | Process for the preparation of a solid herbicidal formulation |
| ZA200206143B (en) | 2001-05-02 | 2003-04-02 | Christoffel Johannes Kok | Dry herbicidal composition. |
| AR041211A1 (es) * | 2002-09-12 | 2005-05-11 | Du Pont | Procedimiento para preparar composiciones de sulfonamida extruidas en pasta |
| GB0413209D0 (en) | 2004-06-14 | 2004-07-14 | Agform Ltd | Chemical composition |
-
2003
- 2003-09-08 AR ARP030103258A patent/AR041211A1/es active IP Right Grant
- 2003-09-09 ES ES03795675.2T patent/ES2262018T7/es active Active
- 2003-09-09 CA CA2498006A patent/CA2498006C/en not_active Expired - Lifetime
- 2003-09-09 KR KR1020057004005A patent/KR20050050100A/ko not_active Abandoned
- 2003-09-09 DK DK03795675.2T patent/DK1536685T4/da active
- 2003-09-09 IL IL166698A patent/IL166698A/en active IP Right Grant
- 2003-09-09 US US10/524,807 patent/US8071508B2/en not_active Expired - Lifetime
- 2003-09-09 BR BR0314466-6A patent/BR0314466A/pt not_active Application Discontinuation
- 2003-09-09 JP JP2004571969A patent/JP4884672B2/ja not_active Expired - Fee Related
- 2003-09-09 EA EA200500483A patent/EA007733B1/ru unknown
- 2003-09-09 DE DE60304583T patent/DE60304583T3/de not_active Expired - Lifetime
- 2003-09-09 PT PT03795675T patent/PT1536685E/pt unknown
- 2003-09-09 MX MXPA05002643A patent/MXPA05002643A/es active IP Right Grant
- 2003-09-09 CN CN038217589A patent/CN1681391B/zh not_active Expired - Lifetime
- 2003-09-09 NZ NZ538351A patent/NZ538351A/en not_active IP Right Cessation
- 2003-09-09 PL PL375879A patent/PL212095B1/pl unknown
- 2003-09-09 UA UAA200502653A patent/UA83196C2/ru unknown
- 2003-09-09 CN CN2010102309736A patent/CN101904337B/zh not_active Expired - Lifetime
- 2003-09-09 AU AU2003266010A patent/AU2003266010B2/en not_active Ceased
- 2003-09-09 EP EP03795675.2A patent/EP1536685B3/en not_active Expired - Lifetime
- 2003-09-09 AT AT03795675T patent/ATE322826T1/de active
- 2003-09-09 WO PCT/US2003/028256 patent/WO2004023876A1/en not_active Ceased
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2005
- 2005-02-24 CO CO05017692A patent/CO5700678A2/es not_active Application Discontinuation
- 2005-03-10 MA MA28140A patent/MA27432A1/fr unknown
- 2005-04-08 NO NO20051749A patent/NO333361B1/no not_active IP Right Cessation
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2006
- 2006-05-08 CY CY20061100595T patent/CY1106081T1/el unknown
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2011
- 2011-10-31 US US13/285,422 patent/US20120046173A1/en not_active Abandoned
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