JP2006508519A5 - - Google Patents
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- Publication number
- JP2006508519A5 JP2006508519A5 JP2004570766A JP2004570766A JP2006508519A5 JP 2006508519 A5 JP2006508519 A5 JP 2006508519A5 JP 2004570766 A JP2004570766 A JP 2004570766A JP 2004570766 A JP2004570766 A JP 2004570766A JP 2006508519 A5 JP2006508519 A5 JP 2006508519A5
- Authority
- JP
- Japan
- Prior art keywords
- enzyme
- electron mediator
- poly
- fuel fluid
- electron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 24
- 102000004190 Enzymes Human genes 0.000 claims 24
- 108090000790 Enzymes Proteins 0.000 claims 24
- 229940088598 enzyme Drugs 0.000 claims 24
- 239000012530 fluid Substances 0.000 claims 18
- 239000000446 fuel Substances 0.000 claims 18
- 229910002804 graphite Inorganic materials 0.000 claims 14
- 239000010439 graphite Substances 0.000 claims 14
- 239000010411 electrocatalyst Substances 0.000 claims 13
- 239000000463 material Substances 0.000 claims 12
- 239000004020 conductor Substances 0.000 claims 11
- -1 perfluorosulfonic acid-polytetrafluoroethylene Chemical class 0.000 claims 11
- 239000002551 biofuel Substances 0.000 claims 8
- 230000001590 oxidative effect Effects 0.000 claims 7
- 229910052799 carbon Inorganic materials 0.000 claims 6
- 229910052751 metal Inorganic materials 0.000 claims 6
- 239000002184 metal Substances 0.000 claims 6
- 239000011532 electronic conductor Substances 0.000 claims 5
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 claims 4
- 101710088194 Dehydrogenase Proteins 0.000 claims 4
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 claims 4
- 150000001768 cations Chemical class 0.000 claims 4
- 230000005611 electricity Effects 0.000 claims 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 4
- 239000000693 micelle Substances 0.000 claims 4
- 239000007800 oxidant agent Substances 0.000 claims 4
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 claims 4
- KCALAFIVPCAXJI-UHFFFAOYSA-N 1,10-phenanthroline-5,6-dione Chemical compound C1=CC=C2C(=O)C(=O)C3=CC=CN=C3C2=N1 KCALAFIVPCAXJI-UHFFFAOYSA-N 0.000 claims 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 3
- 230000003100 immobilizing effect Effects 0.000 claims 3
- XJCPMUIIBDVFDM-UHFFFAOYSA-M nile blue A Chemical compound [Cl-].C1=CC=C2C3=NC4=CC=C(N(CC)CC)C=C4[O+]=C3C=C(N)C2=C1 XJCPMUIIBDVFDM-UHFFFAOYSA-M 0.000 claims 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims 3
- 239000004810 polytetrafluoroethylene Substances 0.000 claims 3
- 239000000126 substance Substances 0.000 claims 3
- IBGBGRVKPALMCQ-UHFFFAOYSA-N 3,4-dihydroxybenzaldehyde Chemical compound OC1=CC=C(C=O)C=C1O IBGBGRVKPALMCQ-UHFFFAOYSA-N 0.000 claims 2
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 claims 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims 2
- 102000007698 Alcohol dehydrogenase Human genes 0.000 claims 2
- 108010021809 Alcohol dehydrogenase Proteins 0.000 claims 2
- 102100039702 Alcohol dehydrogenase class-3 Human genes 0.000 claims 2
- 108020002663 Aldehyde Dehydrogenase Proteins 0.000 claims 2
- 102000005369 Aldehyde Dehydrogenase Human genes 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 2
- LUAZZOXZPVVGSO-UHFFFAOYSA-N Benzyl viologen Chemical compound C=1C=C(C=2C=C[N+](CC=3C=CC=CC=3)=CC=2)C=C[N+]=1CC1=CC=CC=C1 LUAZZOXZPVVGSO-UHFFFAOYSA-N 0.000 claims 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims 2
- QTANTQQOYSUMLC-UHFFFAOYSA-O Ethidium cation Chemical compound C12=CC(N)=CC=C2C2=CC=C(N)C=C2[N+](CC)=C1C1=CC=CC=C1 QTANTQQOYSUMLC-UHFFFAOYSA-O 0.000 claims 2
- 108090000698 Formate Dehydrogenases Proteins 0.000 claims 2
- 108010050375 Glucose 1-Dehydrogenase Proteins 0.000 claims 2
- 108010015776 Glucose oxidase Proteins 0.000 claims 2
- 239000004366 Glucose oxidase Substances 0.000 claims 2
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 claims 2
- 102000003855 L-lactate dehydrogenase Human genes 0.000 claims 2
- 108700023483 L-lactate dehydrogenases Proteins 0.000 claims 2
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 claims 2
- LCTONWCANYUPML-UHFFFAOYSA-M Pyruvate Chemical compound CC(=O)C([O-])=O LCTONWCANYUPML-UHFFFAOYSA-M 0.000 claims 2
- 239000006229 carbon black Substances 0.000 claims 2
- 239000004917 carbon fiber Substances 0.000 claims 2
- 239000002041 carbon nanotube Substances 0.000 claims 2
- 229910021393 carbon nanotube Inorganic materials 0.000 claims 2
- NEUSVAOJNUQRTM-UHFFFAOYSA-N cetylpyridinium Chemical compound CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 NEUSVAOJNUQRTM-UHFFFAOYSA-N 0.000 claims 2
- 229960004830 cetylpyridinium Drugs 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 2
- 125000000853 cresyl group Chemical group C1(=CC=C(C=C1)C)* 0.000 claims 2
- 229910003460 diamond Inorganic materials 0.000 claims 2
- 239000010432 diamond Substances 0.000 claims 2
- 239000002079 double walled nanotube Substances 0.000 claims 2
- 239000004744 fabric Substances 0.000 claims 2
- VWWQXMAJTJZDQX-UYBVJOGSSA-N flavin adenine dinucleotide Chemical compound C1=NC2=C(N)N=CN=C2N1[C@@H]([C@H](O)[C@@H]1O)O[C@@H]1CO[P@](O)(=O)O[P@@](O)(=O)OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C2=NC(=O)NC(=O)C2=NC2=C1C=C(C)C(C)=C2 VWWQXMAJTJZDQX-UYBVJOGSSA-N 0.000 claims 2
- 235000019162 flavin adenine dinucleotide Nutrition 0.000 claims 2
- 239000011714 flavin adenine dinucleotide Substances 0.000 claims 2
- 229940093632 flavin-adenine dinucleotide Drugs 0.000 claims 2
- 229910021397 glassy carbon Inorganic materials 0.000 claims 2
- 229940116332 glucose oxidase Drugs 0.000 claims 2
- 235000019420 glucose oxidase Nutrition 0.000 claims 2
- 108010051015 glutathione-independent formaldehyde dehydrogenase Proteins 0.000 claims 2
- 230000002209 hydrophobic effect Effects 0.000 claims 2
- 239000008101 lactose Substances 0.000 claims 2
- 229920003240 metallophthalocyanine polymer Polymers 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- YYGBVRCTHASBKD-UHFFFAOYSA-M methylene green Chemical compound [Cl-].C1=CC(N(C)C)=C([N+]([O-])=O)C2=[S+]C3=CC(N(C)C)=CC=C3N=C21 YYGBVRCTHASBKD-UHFFFAOYSA-M 0.000 claims 2
- 229960000907 methylthioninium chloride Drugs 0.000 claims 2
- 239000002048 multi walled nanotube Substances 0.000 claims 2
- PGSADBUBUOPOJS-UHFFFAOYSA-N neutral red Chemical compound Cl.C1=C(C)C(N)=CC2=NC3=CC(N(C)C)=CC=C3N=C21 PGSADBUBUOPOJS-UHFFFAOYSA-N 0.000 claims 2
- 150000002892 organic cations Chemical class 0.000 claims 2
- 230000003647 oxidation Effects 0.000 claims 2
- 238000007254 oxidation reaction Methods 0.000 claims 2
- FIKAKWIAUPDISJ-UHFFFAOYSA-L paraquat dichloride Chemical compound [Cl-].[Cl-].C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 FIKAKWIAUPDISJ-UHFFFAOYSA-L 0.000 claims 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims 2
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 claims 2
- MMXZSJMASHPLLR-UHFFFAOYSA-N pyrroloquinoline quinone Chemical compound C12=C(C(O)=O)C=C(C(O)=O)N=C2C(=O)C(=O)C2=C1NC(C(=O)O)=C2 MMXZSJMASHPLLR-UHFFFAOYSA-N 0.000 claims 2
- 125000001453 quaternary ammonium group Chemical group 0.000 claims 2
- 238000007650 screen-printing Methods 0.000 claims 2
- 239000002109 single walled nanotube Substances 0.000 claims 2
- 230000000087 stabilizing effect Effects 0.000 claims 2
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 claims 2
- HNONEKILPDHFOL-UHFFFAOYSA-M tolonium chloride Chemical compound [Cl-].C1=C(C)C(N)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 HNONEKILPDHFOL-UHFFFAOYSA-M 0.000 claims 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-O triphenylphosphanium Chemical compound C1=CC=CC=C1[PH+](C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-O 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- JDVMJFIBTWIYJX-UHFFFAOYSA-N 1,10-phenanthroline-5,6-diol Chemical compound Oc1c(O)c2cccnc2c2ncccc12 JDVMJFIBTWIYJX-UHFFFAOYSA-N 0.000 claims 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical class NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 claims 1
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 claims 1
- TZMSYXZUNZXBOL-UHFFFAOYSA-N 10H-phenoxazine Chemical compound C1=CC=C2NC3=CC=CC=C3OC2=C1 TZMSYXZUNZXBOL-UHFFFAOYSA-N 0.000 claims 1
- JFJNVIPVOCESGZ-UHFFFAOYSA-N 2,3-dipyridin-2-ylpyridine Chemical compound N1=CC=CC=C1C1=CC=CN=C1C1=CC=CC=N1 JFJNVIPVOCESGZ-UHFFFAOYSA-N 0.000 claims 1
- FGFOZLCWAHRUAJ-UHFFFAOYSA-N 2-nitrofluoren-1-one Chemical class C1=CC=C2C3=CC=C([N+](=O)[O-])C(=O)C3=CC2=C1 FGFOZLCWAHRUAJ-UHFFFAOYSA-N 0.000 claims 1
- PCYGLFXKCBFGPC-UHFFFAOYSA-N 3,4-Dihydroxy hydroxymethyl benzene Natural products OCC1=CC=C(O)C(O)=C1 PCYGLFXKCBFGPC-UHFFFAOYSA-N 0.000 claims 1
- IJAMAMPVPZBIQX-UHFFFAOYSA-N 3,6-dihydro-2h-[1,4]dioxino[2,3-c]pyrrole Chemical compound O1CCOC2=CNC=C21 IJAMAMPVPZBIQX-UHFFFAOYSA-N 0.000 claims 1
- WUOUBJDINSHIPE-UHFFFAOYSA-N 3-(4-fluorophenyl)thiophene Chemical compound C1=CC(F)=CC=C1C1=CSC=C1 WUOUBJDINSHIPE-UHFFFAOYSA-N 0.000 claims 1
- RXGJTUSBYWCRBK-UHFFFAOYSA-M 5-methylphenazinium methyl sulfate Chemical compound COS([O-])(=O)=O.C1=CC=C2[N+](C)=C(C=CC=C3)C3=NC2=C1 RXGJTUSBYWCRBK-UHFFFAOYSA-M 0.000 claims 1
- ACTIUHUUMQJHFO-UHFFFAOYSA-N Coenzym Q10 Natural products COC1=C(OC)C(=O)C(CC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C)=C(C)C1=O ACTIUHUUMQJHFO-UHFFFAOYSA-N 0.000 claims 1
- FBWADIKARMIWNM-UHFFFAOYSA-N N-3,5-dichloro-4-hydroxyphenyl-1,4-benzoquinone imine Chemical compound C1=C(Cl)C(O)=C(Cl)C=C1N=C1C=CC(=O)C=C1 FBWADIKARMIWNM-UHFFFAOYSA-N 0.000 claims 1
- SKZSEQNLFOZDCK-UHFFFAOYSA-N N=1C(C(C=C2C=CC3=CC=CN=C3C12)=O)=O.[Os] Chemical compound N=1C(C(C=C2C=CC3=CC=CN=C3C12)=O)=O.[Os] SKZSEQNLFOZDCK-UHFFFAOYSA-N 0.000 claims 1
- BAWFJGJZGIEFAR-NNYOXOHSSA-N NAD zwitterion Chemical compound NC(=O)C1=CC=C[N+]([C@H]2[C@@H]([C@H](O)[C@@H](COP([O-])(=O)OP(O)(=O)OC[C@@H]3[C@H]([C@@H](O)[C@@H](O3)N3C4=NC=NC(N)=C4N=C3)O)O2)O)=C1 BAWFJGJZGIEFAR-NNYOXOHSSA-N 0.000 claims 1
- XJLXINKUBYWONI-NNYOXOHSSA-O NADP(+) Chemical compound NC(=O)C1=CC=C[N+]([C@H]2[C@@H]([C@H](O)[C@@H](COP(O)(=O)OP(O)(=O)OC[C@@H]3[C@H]([C@@H](OP(O)(O)=O)[C@@H](O3)N3C4=NC=NC(N)=C4N=C3)O)O2)O)=C1 XJLXINKUBYWONI-NNYOXOHSSA-O 0.000 claims 1
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 claims 1
- 229920000000 Poly(isothianaphthene) Polymers 0.000 claims 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 1
- 229920002125 Sokalan® Polymers 0.000 claims 1
- PGWTYMLATMNCCZ-UHFFFAOYSA-M azure A Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 PGWTYMLATMNCCZ-UHFFFAOYSA-M 0.000 claims 1
- 230000001413 cellular effect Effects 0.000 claims 1
- ACTIUHUUMQJHFO-UPTCCGCDSA-N coenzyme Q10 Chemical compound COC1=C(OC)C(=O)C(C\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CCC=C(C)C)=C(C)C1=O ACTIUHUUMQJHFO-UPTCCGCDSA-N 0.000 claims 1
- 235000017471 coenzyme Q10 Nutrition 0.000 claims 1
- 239000000084 colloidal system Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- BWTZYYGAOGUPFQ-UHFFFAOYSA-N difluoroacetylene Chemical group FC#CF BWTZYYGAOGUPFQ-UHFFFAOYSA-N 0.000 claims 1
- 239000003446 ligand Substances 0.000 claims 1
- HWYHZTIRURJOHG-UHFFFAOYSA-N luminol Chemical compound O=C1NNC(=O)C2=C1C(N)=CC=C2 HWYHZTIRURJOHG-UHFFFAOYSA-N 0.000 claims 1
- 229940101270 nicotinamide adenine dinucleotide (nad) Drugs 0.000 claims 1
- 230000035699 permeability Effects 0.000 claims 1
- 150000002988 phenazines Chemical class 0.000 claims 1
- 229950000688 phenothiazine Drugs 0.000 claims 1
- 229920000301 poly(3-hexylthiophene-2,5-diyl) polymer Polymers 0.000 claims 1
- 229920000767 polyaniline Polymers 0.000 claims 1
- 229920000128 polypyrrole Polymers 0.000 claims 1
- 229920000123 polythiophene Polymers 0.000 claims 1
- 239000011148 porous material Substances 0.000 claims 1
- ZZYXNRREDYWPLN-UHFFFAOYSA-N pyridine-2,3-diamine Chemical class NC1=CC=CN=C1N ZZYXNRREDYWPLN-UHFFFAOYSA-N 0.000 claims 1
- 150000004053 quinones Chemical class 0.000 claims 1
- NPCOQXAVBJJZBQ-UHFFFAOYSA-N reduced coenzyme Q9 Natural products COC1=C(O)C(C)=C(CC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)CCC=C(C)C)C(O)=C1OC NPCOQXAVBJJZBQ-UHFFFAOYSA-N 0.000 claims 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 claims 1
- PFZLGKHSYILJTH-UHFFFAOYSA-N thieno[2,3-c]thiophene Chemical compound S1C=C2SC=CC2=C1 PFZLGKHSYILJTH-UHFFFAOYSA-N 0.000 claims 1
- 229950003937 tolonium Drugs 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
- 229940035936 ubiquinone Drugs 0.000 claims 1
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US42982902P | 2002-11-27 | 2002-11-27 | |
| US60/429,829 | 2002-11-27 | ||
| US48607603P | 2003-07-10 | 2003-07-10 | |
| US60/486,076 | 2003-07-10 | ||
| US10/617,452 US7638228B2 (en) | 2002-11-27 | 2003-07-11 | Enzyme immobilization for use in biofuel cells and sensors |
| US10/617,452 | 2003-07-11 | ||
| PCT/US2003/037336 WO2004051774A2 (en) | 2002-11-27 | 2003-11-21 | Enzyme immobilization for use in biofuel cells and sensors |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2006508519A JP2006508519A (ja) | 2006-03-09 |
| JP2006508519A5 true JP2006508519A5 (https=) | 2007-01-18 |
| JP4878756B2 JP4878756B2 (ja) | 2012-02-15 |
Family
ID=32329874
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004570766A Expired - Fee Related JP4878756B2 (ja) | 2002-11-27 | 2003-11-21 | バイオ燃料電池およびセンサーに使用される酵素固定化 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US7638228B2 (https=) |
| EP (3) | EP2343765A1 (https=) |
| JP (1) | JP4878756B2 (https=) |
| KR (2) | KR101224672B1 (https=) |
| AU (1) | AU2003297552A1 (https=) |
| CA (1) | CA2507455A1 (https=) |
| WO (1) | WO2004051774A2 (https=) |
Families Citing this family (97)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6294281B1 (en) | 1998-06-17 | 2001-09-25 | Therasense, Inc. | Biological fuel cell and method |
| FI119267B (fi) * | 2002-06-28 | 2008-09-15 | Enfucell Oy | Biokatalyyttinen suora-alkoholipolttokenno |
| US7638228B2 (en) | 2002-11-27 | 2009-12-29 | Saint Louis University | Enzyme immobilization for use in biofuel cells and sensors |
| WO2005038968A2 (en) * | 2003-10-20 | 2005-04-28 | Catharina Philippina Janssen | Suspension for the generation of a current of electrons and the use and the preparation thereof |
| US8859151B2 (en) * | 2003-11-05 | 2014-10-14 | St. Louis University | Immobilized enzymes in biocathodes |
| EP1726059A4 (en) * | 2004-03-15 | 2008-10-22 | Univ St Louis | MICRO-FLUID biofuel cell |
| US8080206B2 (en) * | 2004-03-26 | 2011-12-20 | The University Of Iowa Research Foundation | Multicomponent analysis of volatile organic compositions in vapor samples |
| EP2532356A1 (en) | 2004-07-14 | 2012-12-12 | Glusense Ltd. | Implantable power sources and sensors |
| WO2006085993A2 (en) * | 2004-07-16 | 2006-08-17 | The Trustees Of Boston College | Device and method for achieving enhanced field emission utilizing nanostructures grown on a conductive substrate |
| US20080248354A1 (en) * | 2004-07-23 | 2008-10-09 | Canon Kabushiki Kaisha | Enzyme Electrode, and Device, Sensor, Fuel Cell and Electrochemical Reactor Employing the Enzyme Electrode |
| GB0420341D0 (en) * | 2004-09-13 | 2004-10-13 | Isis Innovation | Fuel cell |
| WO2006044954A2 (en) * | 2004-10-20 | 2006-04-27 | University Of Florida Research Foundation, Inc. | Enhanced electrical contact to microbes in microbial fuel cells |
| CN100490228C (zh) * | 2005-02-10 | 2009-05-20 | 株式会社东芝 | 燃料电池 |
| JPWO2006085619A1 (ja) * | 2005-02-10 | 2008-06-26 | 株式会社東芝 | 燃料電池 |
| WO2006099248A2 (en) * | 2005-03-12 | 2006-09-21 | Saint Louis University | Drug delivery from electroactive molecularly imprinted polymer |
| WO2006109057A1 (en) * | 2005-04-14 | 2006-10-19 | Isis Innovation Limited | Fuel cell |
| US9406959B2 (en) | 2005-05-10 | 2016-08-02 | Board Of Trustees Of Michigan State University | Electrobiocatalytic reactors having reversible bioelectronic interfaces and methods and devices related thereto |
| HUP0500701A2 (en) * | 2005-07-20 | 2007-02-28 | Univ Szegedi | Conductive-polymer electrode from multicomponent system and the use thereof |
| JP2007035437A (ja) * | 2005-07-27 | 2007-02-08 | Sony Corp | 多孔体導電材料およびその製造方法ならびに電極およびその製造方法ならびに燃料電池およびその製造方法ならびに電子機器ならびに移動体ならびに発電システムならびにコージェネレーションシステムならびに電極反応利用装置 |
| EP1946397A4 (en) * | 2005-11-02 | 2009-12-02 | Univ St Louis | HYDROPHOB-MODIFIED POLYSACCHARIDES IMMOBILIZED ENZYMES |
| KR20080080105A (ko) * | 2005-11-02 | 2008-09-02 | 세인트 루이스 유니버시티 | 바이오애노드, 바이오캐소드 및 바이오연료 전지 내의효소를 사용하는 직접 전자 전달 |
| ATE553383T1 (de) * | 2005-11-17 | 2012-04-15 | Fraunhofer Ges Forschung | Biosensor und verwendung |
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