JP2006187951A - インモールド転写用フィルム - Google Patents
インモールド転写用フィルム Download PDFInfo
- Publication number
- JP2006187951A JP2006187951A JP2005001558A JP2005001558A JP2006187951A JP 2006187951 A JP2006187951 A JP 2006187951A JP 2005001558 A JP2005001558 A JP 2005001558A JP 2005001558 A JP2005001558 A JP 2005001558A JP 2006187951 A JP2006187951 A JP 2006187951A
- Authority
- JP
- Japan
- Prior art keywords
- film
- layer
- group
- antistatic
- mold transfer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229920006317 cationic polymer Polymers 0.000 claims description 10
- 239000003431 cross linking reagent Substances 0.000 claims description 6
- 239000011888 foil Substances 0.000 abstract description 22
- 238000000465 moulding Methods 0.000 abstract description 13
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- 239000012790 adhesive layer Substances 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 3
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- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- HDPLHDGYGLENEI-UHFFFAOYSA-N 2-[1-(oxiran-2-ylmethoxy)propan-2-yloxymethyl]oxirane Chemical compound C1OC1COC(C)COCC1CO1 HDPLHDGYGLENEI-UHFFFAOYSA-N 0.000 description 1
- WTYYGFLRBWMFRY-UHFFFAOYSA-N 2-[6-(oxiran-2-ylmethoxy)hexoxymethyl]oxirane Chemical compound C1OC1COCCCCCCOCC1CO1 WTYYGFLRBWMFRY-UHFFFAOYSA-N 0.000 description 1
- KUAUJXBLDYVELT-UHFFFAOYSA-N 2-[[2,2-dimethyl-3-(oxiran-2-ylmethoxy)propoxy]methyl]oxirane Chemical compound C1OC1COCC(C)(C)COCC1CO1 KUAUJXBLDYVELT-UHFFFAOYSA-N 0.000 description 1
- AGXAFZNONAXBOS-UHFFFAOYSA-N 2-[[3-(oxiran-2-ylmethyl)phenyl]methyl]oxirane Chemical compound C=1C=CC(CC2OC2)=CC=1CC1CO1 AGXAFZNONAXBOS-UHFFFAOYSA-N 0.000 description 1
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- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
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Landscapes
- Laminated Bodies (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Abstract
【解決手段】 ポリエステルフィルム、そのうえ一方の面に設けられた易接着層、および他方の面に設けられた帯電防止層からなり、帯電防止層が離型成分を含む帯電防止性塗布層であることを特徴とする、インモールド転写用フィルム。
【選択図】 なし
Description
[ポリエステルフィルム]
本発明においてポリエステルフィルムを構成するポリエステルは、芳香族二塩基酸またはそのエステル形成性誘導体とジオールまたはそのエステル形成性誘導体とから合成される線状飽和ポリエステルである。かかるポリエステルの具体例として、ポリエチレンテレフタレート、ポリエチレンイソフタレート、ポリブチレンテレフタレート、ポリ(1,4−シクロヘキシレンジメチレンテレフタレート)、ポリエチレン−2,6−ナフタレートを例示することができる。
本発明においては、ポリエステルフィルムの一方の面に易接着層が設けられる。易接着層は塗布により設けられた易接着性の塗布層であることが好ましい。
本発明において、帯電防止層は離型成分を含む帯電防止性塗布層である。そして、離型成分は、好ましくは反応基を有するシリコーンである。離型成分が反応基を含有しないシリコーンはフィルム背面への転写が発生し、印刷層の成型物への転写不具合が発生する可能性があり、好ましくない。
30モル%≦a<79モル%
20モル%≦b<100−(a+c)モル%
1モル%≦c≦40モル%
これらの条件を満たす成分から構成されると、塗膜の造膜性、凝集力や塗膜の耐水性、耐薬品に優れる塗膜を得ることができる。
無機微粒子としては、例えば酸化ケイ素、酸化アルミニウム、酸化マグネシウム、炭酸カルシウム、カオリン、タルク、酸化チタン、酸化亜鉛、硫酸バリウム、酸化ジルコニウム、酸化チタン、酸化錫、三酸化アンチモン、カーボンブラック、二硫化モリブデンからなる粒子を例示することができる。有機微粒子としては、例えばアクリル系架橋重合体、スチレン系架橋重合体、シリコーン樹脂、フッ素樹脂、ベンゾグアナミン樹脂、フェノール樹脂、ナイロン樹脂のような耐熱性樹脂からなる有機微粒子を例示することができる。
エポキシ化合物は、ポリエポキシ化合物、ジエポキシ化合物、モノエポキシ化合物、グリシジルアミン化合物等が挙げられ、ポリエポキシ化合物としては、例えば、ソルビトール、ポリグリシジルエーテル、ポリグリセロールポリグリシジルエーテル、ペンタエリスリトールポリグリシジルエーテル、ジグリセロールポリグリシジルエーテル、トリグリシジルトリス(2−ヒドロキシエチル)イソシアネート、グリセロールポリグリシジルエーテル、トリメチロールプロパンポリグリシジルエーテル、ジエポキシ化合物としては、例えば、ネオペンチルグリコールジグリシジルエーテル、1,6−ヘキサンジオールジグリシジルエーテル、レゾルシンジグリシジルエーテル、エチレングリコールジグリシジルエーテル、ポリエチレングリコールジグリシジルエーテル、プロピレングリコールジグリシジルエーテル、ポリプロピレングリコールジグリシジルエーテル、ポリテトラメチレングリコールジグリシジルエーテル、モノエポキシ化合物としては、例えば、アリルグリシジルエーテル、2−エチルヘキシルグリシジルエーテル、フェニルグリシジルエーテル、グリシジルアミン化合物としてはN,N,N’,N’,−テトラグリシジル−m−キシリレンジアミン、1,3−ビス(N,N−ジグリシジルアミノ)シクロヘキサン等が挙げられる。
本発明において帯電防止層および易接着層の塗設に用いられる上記組成物は、塗布層を形成させるために、水溶液、水分散液或いは乳化液等の水性塗液の形態で使用されることが好ましい。塗膜を形成するために、必要に応じて、前記組成物以外の他の樹脂、例えば着色剤、界面活性剤、紫外線吸収剤等を添加することができる。
(1)離型層接着性
フィルムの塗布面の上にメラミン樹脂のメチルエチルケトン/トルエン溶液を塗布し1μm厚さの離型層(メジューム層)の膜を形成させ、ホットプレス法により積層体として空型に乗せて成形したときの離型層の状況を観察し、下記の基準で評価した。
A:変化無し
B:一部分が剥離
C:全体的に剥離
この評価で、Aまでが実用性能を満足する。
フィルムの帯電防止層の表面を指で10cm長を10往復擦りつけ、塗膜の欠落状態を観察し、帯電防止層密着性を下記の基準で評価した。
A+:変化無し
A:若干表面に変化有り
B:擦過面積の半分までが欠落
C:擦過面積の大部分が欠落
この評価で、Aまでが実用性能を満足する。
サンプルフィルムの帯電防止層表面の表面固有抵抗を、タケダ理研社製・固有抵抗測定器を使用し、測定温度23℃、測定湿度60%の条件で、印加電圧100Vで1分後の表面固有抵抗値(Ω/□)を測定した。
サンプルフィルムの帯電防止層面とインモールド用転写箔の印刷面との耐ブロッキング性を評価するため、スタンピングホイルの顔料箔(COLORIT)Pタイプ(クルツ社製)を使用して、帯電防止面と印刷面を合わせ、
[条件1] 温度60℃、圧力1kg/cm2 および
[条件2] 温度80℃、圧力1kg/cm2
を加えて、24時間その環境に保持した後、帯電防止層面とラベルのシール面のブロッキング状態を観察し、下記の基準で評価した。
A+:印刷層の剥離面積0%、印刷層表面に変化無し
A:印刷層の剥離面積0%、印刷層表面が白化
B:印刷層の剥離面積1〜30%
C:全体的に剥離面積31〜100%
この評価で、Aまでが実用性能を満足する。
包埋樹脂でフィルムを固定し断面をミクロトームで切断し、2%オスミウム酸で60℃、2時間染色して、透過型電子顕微鏡(日本電子製JEM2010)を用いて、塗布層の厚みを測定した。
サンプルフィルムを易接着面と帯電防止層面を重ね合わせ、温度50℃、圧力50kg/cm2、時間24時間の処理を実施した後、易接着層表面を38から40mN/mの濡れ張力マジックの濡れ状態を観察し、下記の基準で評価した。
A+:均一に塗れる
A:1〜10%はじく
B:11〜50%はじく
C:51〜100%はじく
この評価で、Bまでが実用性能を満足する。
平均粒子径が2μmの酸化ケイ素の微粒子を0.01wt%を含む溶融ポリエチレンテレフタレート([η]=0.64dl/g、Tg=78℃)をダイより押出し、常法により冷却ドラムで冷却して未延伸フィルムとし、次いで縦方向に3.4倍に延伸した後、表に示す塗布層構成成分からなる塗布液、すなわち易接着層(8wt%塗布液)をフィルムの表面に、帯電防止層(4wt%塗布液)をフィルムの裏面にそれぞれロールコーターで均一に塗布した。
易接着層と帯電防止層を設けていない以外は実施例1と同様にしてポリエステルフィルムを製造した。次いで、この塗布フィルムを引き続いて105℃で乾燥し、140℃で3.5倍に延伸し、更に220℃で熱固定して表に示す塗膜を有する二軸延伸ポリエステルフィルム(厚さ50μm)を得た。
カチオンポリマー:下記式に示す構造が80モル%/メチルアクリレート15モル%/N−メチロールアクリルアミド5モル%からなる共重合体である。
微粒子2:シリカ微粒子(平均粒子径:40nm)(日産化学株式会社製 商品名スノーテックスOL)
離型剤1:エポキシ基含有シリコーン(GE東芝シリコーン株式会社製 商品名TSF4730)
離型剤2:アミノ基含有シリコーン(GE東芝シリコーン株式会社製 商品名TSF4700)
離型剤3:反応基を含まないシリコーン(信越化学工業株式会社製 商品名KF−140)
架橋剤:オキサゾリン(株式会社日本触媒製 商品名エポクロスWS−700)
添加剤:ポリエチレンワックス(中京油脂株式会社製 商品名ポロリンL−618)
界面活性剤:ポリオキシエチレン(n=7)ラウリルエーテル(三洋化成株式会社製 商品名ナロアクティーN−70)
Claims (4)
- ポリエステルフィルム、そのうえ一方の面に設けられた易接着層、および他方の面に設けられた帯電防止層からなり、帯電防止層が離型成分を含む帯電防止性塗布層であることを特徴とする、インモールド転写用フィルム。
- 離型成分が反応基を有するシリコーンである、請求項1記載のインモールド転写用フィルム。
- 帯電防止性塗布層がさらにカチオンポリマーおよび架橋剤成分を含有する、請求項1記載のインモールド転写用フィルム。
- 帯電防止性塗布層の表面固有抵抗値が1×1013Ω/□以下である、請求項1記載のインモールド転写用フィルム。
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Cited By (7)
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JP2008246753A (ja) * | 2007-03-29 | 2008-10-16 | Mitsubishi Plastics Ind Ltd | 成形同時転写用二軸延伸ポリエステルフィルム |
JP2009262443A (ja) * | 2008-04-25 | 2009-11-12 | Teijin Dupont Films Japan Ltd | インモールド転写箔用フィルム |
JP2010247423A (ja) * | 2009-04-15 | 2010-11-04 | Teijin Dupont Films Japan Ltd | 離型フィルム |
JP2011201254A (ja) * | 2010-03-26 | 2011-10-13 | Teijin Dupont Films Japan Ltd | 帯電防止離型性ポリエステルフィルム |
JP2012006166A (ja) * | 2010-06-22 | 2012-01-12 | Teijin Dupont Films Japan Ltd | インモールド転写用フィルム |
JP2012011582A (ja) * | 2010-06-29 | 2012-01-19 | Teijin Dupont Films Japan Ltd | 帯電防止離型性ポリエステルフィルム |
JP2012011656A (ja) * | 2010-06-30 | 2012-01-19 | Teijin Dupont Films Japan Ltd | インモールド転写材用粘着離型ポリエステルフィルム |
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2005
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Cited By (7)
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JP2008246753A (ja) * | 2007-03-29 | 2008-10-16 | Mitsubishi Plastics Ind Ltd | 成形同時転写用二軸延伸ポリエステルフィルム |
JP2009262443A (ja) * | 2008-04-25 | 2009-11-12 | Teijin Dupont Films Japan Ltd | インモールド転写箔用フィルム |
JP2010247423A (ja) * | 2009-04-15 | 2010-11-04 | Teijin Dupont Films Japan Ltd | 離型フィルム |
JP2011201254A (ja) * | 2010-03-26 | 2011-10-13 | Teijin Dupont Films Japan Ltd | 帯電防止離型性ポリエステルフィルム |
JP2012006166A (ja) * | 2010-06-22 | 2012-01-12 | Teijin Dupont Films Japan Ltd | インモールド転写用フィルム |
JP2012011582A (ja) * | 2010-06-29 | 2012-01-19 | Teijin Dupont Films Japan Ltd | 帯電防止離型性ポリエステルフィルム |
JP2012011656A (ja) * | 2010-06-30 | 2012-01-19 | Teijin Dupont Films Japan Ltd | インモールド転写材用粘着離型ポリエステルフィルム |
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