JP2006143871A - 液体漂白剤組成物 - Google Patents
液体漂白剤組成物 Download PDFInfo
- Publication number
- JP2006143871A JP2006143871A JP2004335539A JP2004335539A JP2006143871A JP 2006143871 A JP2006143871 A JP 2006143871A JP 2004335539 A JP2004335539 A JP 2004335539A JP 2004335539 A JP2004335539 A JP 2004335539A JP 2006143871 A JP2006143871 A JP 2006143871A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- group
- liquid
- bleaching
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007844 bleaching agent Substances 0.000 title claims abstract description 50
- 239000000203 mixture Substances 0.000 title claims abstract description 44
- 239000007788 liquid Substances 0.000 title claims abstract description 32
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 36
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 235000005487 catechin Nutrition 0.000 claims abstract description 14
- 150000001765 catechin Chemical class 0.000 claims abstract description 11
- 239000004094 surface-active agent Substances 0.000 claims abstract description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 31
- 239000012190 activator Substances 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 15
- 150000003839 salts Chemical class 0.000 claims description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 125000004423 acyloxy group Chemical group 0.000 claims description 6
- 239000003599 detergent Substances 0.000 claims description 6
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims description 6
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 229950001002 cianidanol Drugs 0.000 claims description 3
- 229940074391 gallic acid Drugs 0.000 claims description 3
- 235000004515 gallic acid Nutrition 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 125000006527 (C1-C5) alkyl group Chemical group 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 2
- 238000004061 bleaching Methods 0.000 abstract description 19
- 238000005406 washing Methods 0.000 abstract description 5
- 230000002378 acidificating effect Effects 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract 6
- 230000003213 activating effect Effects 0.000 abstract 4
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- -1 imide organic peroxyacid Chemical class 0.000 description 32
- 230000000694 effects Effects 0.000 description 17
- 125000000217 alkyl group Chemical group 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 150000001639 boron compounds Chemical class 0.000 description 9
- 229920005862 polyol Polymers 0.000 description 8
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 229910021538 borax Inorganic materials 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 235000010339 sodium tetraborate Nutrition 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 125000003342 alkenyl group Chemical group 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- 239000004328 sodium tetraborate Substances 0.000 description 4
- 230000006641 stabilisation Effects 0.000 description 4
- 238000011105 stabilization Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 3
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 159000000003 magnesium salts Chemical class 0.000 description 3
- 125000006353 oxyethylene group Chemical group 0.000 description 3
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 3
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- RSYUFYQTACJFML-DZGCQCFKSA-N afzelechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C=C1 RSYUFYQTACJFML-DZGCQCFKSA-N 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 2
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 150000004967 organic peroxy acids Chemical class 0.000 description 2
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 150000003138 primary alcohols Chemical class 0.000 description 2
- 150000003333 secondary alcohols Chemical class 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 150000005846 sugar alcohols Chemical class 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- XMOCLSLCDHWDHP-SWLSCSKDSA-N (+)-Epigallocatechin Natural products C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC(O)=C(O)C(O)=C1 XMOCLSLCDHWDHP-SWLSCSKDSA-N 0.000 description 1
- SFRLSTJPMFGBDP-UHFFFAOYSA-N 1,2-diphosphonoethylphosphonic acid Chemical compound OP(O)(=O)CC(P(O)(O)=O)P(O)(O)=O SFRLSTJPMFGBDP-UHFFFAOYSA-N 0.000 description 1
- MXYOPVWZZKEAGX-UHFFFAOYSA-N 1-phosphonoethylphosphonic acid Chemical compound OP(=O)(O)C(C)P(O)(O)=O MXYOPVWZZKEAGX-UHFFFAOYSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- INJFRROOFQOUGJ-UHFFFAOYSA-N 2-[hydroxy(methoxy)phosphoryl]butanedioic acid Chemical compound COP(O)(=O)C(C(O)=O)CC(O)=O INJFRROOFQOUGJ-UHFFFAOYSA-N 0.000 description 1
- MYWGVBFSIIZBHJ-UHFFFAOYSA-N 4-phosphonobutane-1,2,3-tricarboxylic acid Chemical compound OC(=O)CC(C(O)=O)C(C(O)=O)CP(O)(O)=O MYWGVBFSIIZBHJ-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 229920000856 Amylose Polymers 0.000 description 1
- AETFVXHERMOZAM-UHFFFAOYSA-N B(O)(O)O.N.N Chemical compound B(O)(O)O.N.N AETFVXHERMOZAM-UHFFFAOYSA-N 0.000 description 1
- 229920002558 Curdlan Polymers 0.000 description 1
- 239000001879 Curdlan Substances 0.000 description 1
- AVGPOAXYRRIZMM-UHFFFAOYSA-N D-Apiose Natural products OCC(O)(CO)C(O)C=O AVGPOAXYRRIZMM-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- WQZGKKKJIJFFOK-WHZQZERISA-N D-aldose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-WHZQZERISA-N 0.000 description 1
- ASNHGEVAWNWCRQ-LJJLCWGRSA-N D-apiofuranose Chemical compound OC[C@@]1(O)COC(O)[C@@H]1O ASNHGEVAWNWCRQ-LJJLCWGRSA-N 0.000 description 1
- ASNHGEVAWNWCRQ-UHFFFAOYSA-N D-apiofuranose Natural products OCC1(O)COC(O)C1O ASNHGEVAWNWCRQ-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- RSYUFYQTACJFML-UKRRQHHQSA-N Epiafzelechin Natural products C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@H]2O)=CC=C(O)C=C1 RSYUFYQTACJFML-UKRRQHHQSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 description 1
- XMOCLSLCDHWDHP-UHFFFAOYSA-N L-Epigallocatechin Natural products OC1CC2=C(O)C=C(O)C=C2OC1C1=CC(O)=C(O)C(O)=C1 XMOCLSLCDHWDHP-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004373 Pullulan Substances 0.000 description 1
- 229920001218 Pullulan Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 150000001323 aldoses Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- SRBFZHDQGSBBOR-STGXQOJASA-N alpha-D-lyxopyranose Chemical compound O[C@@H]1CO[C@H](O)[C@@H](O)[C@H]1O SRBFZHDQGSBBOR-STGXQOJASA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- DLEPCXYNAPUMDZ-UHFFFAOYSA-N butan-2-ylphosphonic acid Chemical compound CCC(C)P(O)(O)=O DLEPCXYNAPUMDZ-UHFFFAOYSA-N 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 235000019316 curdlan Nutrition 0.000 description 1
- 229940078035 curdlan Drugs 0.000 description 1
- 229960002086 dextran Drugs 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- DXMRKRXRMGYFDG-UHFFFAOYSA-N dipotassium;hydrogen borate Chemical compound [K+].[K+].OB([O-])[O-] DXMRKRXRMGYFDG-UHFFFAOYSA-N 0.000 description 1
- XMOCLSLCDHWDHP-IUODEOHRSA-N epi-Gallocatechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@H]2O)=CC(O)=C(O)C(O)=C1 XMOCLSLCDHWDHP-IUODEOHRSA-N 0.000 description 1
- DZYNKLUGCOSVKS-UHFFFAOYSA-N epigallocatechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3cc(O)c(O)c(O)c3 DZYNKLUGCOSVKS-UHFFFAOYSA-N 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 150000004665 fatty acids Chemical group 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- GTTBQSNGUYHPNK-UHFFFAOYSA-N hydroxymethylphosphonic acid Chemical compound OCP(O)(O)=O GTTBQSNGUYHPNK-UHFFFAOYSA-N 0.000 description 1
- 150000002454 idoses Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- 229960002160 maltose Drugs 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 229960001855 mannitol Drugs 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- ZJAOAACCNHFJAH-UHFFFAOYSA-N phosphonoformic acid Chemical class OC(=O)P(O)(O)=O ZJAOAACCNHFJAH-UHFFFAOYSA-N 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007962 solid dispersion Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229940032147 starch Drugs 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- WYXIGTJNYDDFFH-UHFFFAOYSA-Q triazanium;borate Chemical compound [NH4+].[NH4+].[NH4+].[O-]B([O-])[O-] WYXIGTJNYDDFFH-UHFFFAOYSA-Q 0.000 description 1
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
【解決手段】 (a)過酸化水素、(b)漂白活性化剤、及び(c)カテキン類を含有する液体漂白剤組成物、(a)過酸化水素、(b)漂白活性化剤、及び(c)カテキン類を含有する組成物からなる液体漂白剤、並びに(a)過酸化水素、(b)漂白活性化剤、(c)カテキン類、及び(d)界面活性剤を含有する組成物からなる液体漂白洗浄剤。
【選択図】 なし
Description
本発明の(b)成分の漂白活性化剤としては、アルカノイル基の炭素数が8〜14のアルカノイルオキシベンゼンスルホン酸又はカルボン酸あるいはそれらの塩から選ばれる少なくとも1種が挙げられ、良好な貯蔵安定性を得る観点から、炭素数8〜14の分岐アルカノイルオキシ基を有するアルカノイルオキシベンゼンスルホン酸又はカルボン酸あるいはそれらの塩が好ましく、アルカノイルオキシ基のエステル結合を形成する炭素原子のα位又はβ位に側鎖を有するアルカノイルオキシベンゼンスルホン酸又はカルボン酸あるいはそれらの塩が更に好ましい。
本発明の(c)成分のカテキン類とは、3−オキシフラバンのポリオキシ誘導体の総称であって、不整炭素原子が2位と3位にあるので、4種の異性体d−,l−,d−エピ−,l−エピ−とそれらのラセミ体がある。天然から分離されたカテキン類には、狭義のカテキン(3,5,7,3’,4’−ペンタオキシフラバン)、ガロカテキン及びそれらの3−ガロイル誘導体とアフゼレキンがある。
一般式(1)で表される化合物の中では、R1〜R6の全てが水素原子である式(1−1)で表される化合物、R1〜R4が水素原子、R5が没食子酸のカルボキシル基からOHを除いた残基、R6が水酸基である式(1−2)で表される化合物が好ましい。
本発明の組成物中の(a)成分の含有量は、漂白効果を得る観点から、0.1〜30質量%が好ましく、0.5〜10質量%がより好ましく、1〜6質量%が更に好ましい。(b)成分の含有量は、優れた漂白効果を発現させる観点から、0.1〜10質量%が好ましく、0.1〜6質量%がより好ましく、0.1〜3質量%が更に好ましい。(c)成分の含有量は、(b)成分の安定性を改善する観点から、0.01〜5質量%が好ましく、0.05〜3質量%がより好ましく、0.1〜1.5質量%が更に好ましい。
[式中、R3aは炭素数10〜18、好ましくは12〜14のアルキル基又はアルケニル基を示す。EOはオキシエチレン基、POはオキシプロピレン基、pはEOの平均付加モル数を示す0〜20の数、qはPOの平均付加モル数を示す0〜20の数であり、p及びqの両者が0の場合を除く。好ましくはpは6〜15、より好ましくは7〜12の数であり、qは0〜10、より好ましくは1〜5、特に好ましくは1〜3の数である。]
なお、一般式(3)においては、EOとPOとはランダム付加形態またはブロック付加形態のいずれの形態で配列されていてもよい。
本発明において、(d)成分としては、(d1)及び(d2)から選ばれる界面活性剤が好適であり、特に(d2)成分を含有することが洗浄効果の点から最も好ましく、特にオキシエチレン基及びオキシプロピレン基を有するポリオキシアルキレンアルキルエーテル型非イオン界面活性剤が好適であり、一般式(3)において、pが8〜12、qが0〜3のポリオキシアルキレンアルキルエーテル型非イオン界面活性剤が最も好ましい。
(2)ソルビット、マンニット、マルチトース、イノシトール、フィチン酸から選ばれる糖アルコール類
(3)グルコース、アピオース、アラビノース、ガラクトース、リキソース、マンノース、ガロース、アルドース、イドース、タロース、キシロース、フルクトースから選ばれる還元糖類
(4)デンプン、デキストラン、キサンタンガム、グアガム、カードラン、プルラン、アミロース、セルロースから選ばれる多糖類
本発明では、特に上記(2)の糖アルコール類が好適であり、特にソルビットが安定性及び漂白/洗浄効果の点から好適である。
下記成分を用い、表1に示す組成の液体漂白剤組成物を調製した。この液体漂白剤組成物について、下記方法で漂白活性化剤の貯蔵安定性を評価した。結果を表1に示す。
a−1;過酸化水素
b−1;上記式(2−1)で表される漂白活性化剤
b−2;上記式(2−3)で表される漂白活性化剤
c−1;上記式(1−1)で表される化合物
c−2;上記式(1−2)で表される化合物
c’−1;4−メトキシフェノール
d−1;ラウリルベンゼンスルホン酸ナトリウム
d−2;ポリオキシエチレンラウリルエーテル(オキシエチレン平均付加モル数8、HLB13.1)
d−3;C12H25O−(C2H4O)7―(C3H6O)2−(C2H4O)4−H
e−1;1−ヒドロキシエチリデン−1,1−ジホスホン酸
<漂白活性化剤の貯蔵安定性評価法>
液体漂白剤組成物を100mLガラス製サンプルビンに80g入れ、20℃で1ヶ月間貯蔵した。貯蔵前後の液体漂白剤組成物中の漂白活性化剤の含有量を高速液体クロマトグラフィーで測定し、下式により漂白活性化剤残存率を求めた。
Claims (8)
- (a)過酸化水素、(b)漂白活性化剤、及び(c)カテキン類を含有する液体漂白剤組成物。
- (b)成分の漂白活性化剤が、炭素数8〜14の分岐アルカノイルオキシ基を有するアルカノイルオキシベンゼンスルホン酸又はカルボン酸あるいはそれらの塩から選ばれる少なくとも1種である請求項1又は2記載の液体漂白剤組成物。
- (b)成分の漂白活性化剤が、アルカノイルオキシ基のエステル結合を形成する炭素原子のα位又はβ位に側鎖を有するアルカノイルオキシベンゼンスルホン酸又はカルボン酸あるいはそれらの塩である請求項1〜3いずれかに記載の液体漂白剤組成物。
- 20℃におけるpHが4〜7である請求項1〜4いずれかに記載の液体漂白剤組成物。
- 更に、(d)界面活性剤を含有する請求項1〜5いずれかに記載の液体漂白剤組成物。
- (a)過酸化水素、(b)漂白活性化剤、及び(c)カテキン類を含有する組成物からなる液体漂白剤。
- (a)過酸化水素、(b)漂白活性化剤、(c)カテキン類、及び(d)界面活性剤を含有する組成物からなる液体漂白洗浄剤。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004335539A JP4509746B2 (ja) | 2004-11-19 | 2004-11-19 | 液体漂白剤組成物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004335539A JP4509746B2 (ja) | 2004-11-19 | 2004-11-19 | 液体漂白剤組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006143871A true JP2006143871A (ja) | 2006-06-08 |
JP4509746B2 JP4509746B2 (ja) | 2010-07-21 |
Family
ID=36623938
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2004335539A Expired - Fee Related JP4509746B2 (ja) | 2004-11-19 | 2004-11-19 | 液体漂白剤組成物 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP4509746B2 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008195917A (ja) * | 2007-01-18 | 2008-08-28 | Kao Corp | 抗菌性洗浄剤組成物 |
JP2009073952A (ja) * | 2007-09-21 | 2009-04-09 | Kao Corp | 抗菌性洗浄剤組成物 |
JP2019131935A (ja) * | 2018-02-02 | 2019-08-08 | 株式会社 伊藤園 | 茶ポリフェノールを有効成分とする吸収性向上剤 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5945385A (ja) * | 1982-09-09 | 1984-03-14 | Kiyouiku Bunka Kenkyusho | 抗酸化剤 |
JPS59166585A (ja) * | 1983-03-10 | 1984-09-19 | Osaka Chem Lab | 抗酸化剤 |
JPS64199A (en) * | 1987-03-17 | 1989-01-05 | Procter & Gamble Co:The | Bleaching agent composition |
JPH047399A (ja) * | 1990-04-24 | 1992-01-10 | Kao Corp | 漂白剤用組成物 |
JPH0770593A (ja) * | 1993-06-30 | 1995-03-14 | Procter & Gamble Co:The | ペルオキシ酸漂白剤を有する安定な流動性水性液体洗剤組成物 |
JPH0948998A (ja) * | 1995-08-03 | 1997-02-18 | Kao Corp | 液体漂白剤組成物の製造方法 |
JPH11181492A (ja) * | 1997-12-24 | 1999-07-06 | Lion Corp | 液体漂白剤組成物 |
-
2004
- 2004-11-19 JP JP2004335539A patent/JP4509746B2/ja not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5945385A (ja) * | 1982-09-09 | 1984-03-14 | Kiyouiku Bunka Kenkyusho | 抗酸化剤 |
JPS59166585A (ja) * | 1983-03-10 | 1984-09-19 | Osaka Chem Lab | 抗酸化剤 |
JPS64199A (en) * | 1987-03-17 | 1989-01-05 | Procter & Gamble Co:The | Bleaching agent composition |
JPH047399A (ja) * | 1990-04-24 | 1992-01-10 | Kao Corp | 漂白剤用組成物 |
JPH0770593A (ja) * | 1993-06-30 | 1995-03-14 | Procter & Gamble Co:The | ペルオキシ酸漂白剤を有する安定な流動性水性液体洗剤組成物 |
JPH0948998A (ja) * | 1995-08-03 | 1997-02-18 | Kao Corp | 液体漂白剤組成物の製造方法 |
JPH11181492A (ja) * | 1997-12-24 | 1999-07-06 | Lion Corp | 液体漂白剤組成物 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008195917A (ja) * | 2007-01-18 | 2008-08-28 | Kao Corp | 抗菌性洗浄剤組成物 |
JP2009073952A (ja) * | 2007-09-21 | 2009-04-09 | Kao Corp | 抗菌性洗浄剤組成物 |
JP2019131935A (ja) * | 2018-02-02 | 2019-08-08 | 株式会社 伊藤園 | 茶ポリフェノールを有効成分とする吸収性向上剤 |
Also Published As
Publication number | Publication date |
---|---|
JP4509746B2 (ja) | 2010-07-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4785123B2 (ja) | 液体洗浄剤組成物 | |
JP4785124B2 (ja) | 液体洗浄剤組成物 | |
JP4732144B2 (ja) | 液体洗浄剤組成物の製造方法 | |
ES2271419T3 (es) | Composicion detergente liquida. | |
AU2005307532B2 (en) | Liquid detergent composition | |
JP5234557B2 (ja) | 液体漂白剤組成物 | |
JP4509746B2 (ja) | 液体漂白剤組成物 | |
JP4663301B2 (ja) | 液体漂白剤組成物 | |
JP2004043795A (ja) | 液体洗浄剤組成物 | |
JP4166639B2 (ja) | 液体洗浄剤組成物 | |
JP4994632B2 (ja) | 液体漂白洗浄剤組成物 | |
JP2008133477A (ja) | 液体洗浄剤組成物 | |
JP5058619B2 (ja) | 液体漂白剤組成物 | |
JP4577884B2 (ja) | 液体洗浄剤組成物 | |
JP4979923B2 (ja) | 液体漂白剤組成物 | |
JP5844223B2 (ja) | 界面活性剤混合物 | |
JP4818657B2 (ja) | 液体漂白剤組成物 | |
JP4818658B2 (ja) | 液体漂白剤組成物 | |
JP2011037945A (ja) | 液体洗浄剤組成物 | |
JP4920304B2 (ja) | 液体漂白剤組成物、及びその製造方法 | |
JP5132930B2 (ja) | 液体洗浄剤組成物 | |
JP2016132688A (ja) | 手洗い用食器洗浄剤組成物 | |
JP6472984B2 (ja) | 手洗い用食器洗浄剤組成物 | |
JP2010095602A (ja) | 液体漂白洗浄剤組成物の製造方法 | |
JP2007016130A (ja) | 無機質汚れの除去性向上剤 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070123 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20091218 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100105 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100225 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20100427 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20100428 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130514 Year of fee payment: 3 |
|
R151 | Written notification of patent or utility model registration |
Ref document number: 4509746 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R151 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130514 Year of fee payment: 3 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140514 Year of fee payment: 4 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |