JP2006070247A - 鋳型製造用フラン樹脂組成物 - Google Patents
鋳型製造用フラン樹脂組成物 Download PDFInfo
- Publication number
- JP2006070247A JP2006070247A JP2005208586A JP2005208586A JP2006070247A JP 2006070247 A JP2006070247 A JP 2006070247A JP 2005208586 A JP2005208586 A JP 2005208586A JP 2005208586 A JP2005208586 A JP 2005208586A JP 2006070247 A JP2006070247 A JP 2006070247A
- Authority
- JP
- Japan
- Prior art keywords
- resin composition
- furan resin
- mold
- urea
- binder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 239000007849 furan resin Substances 0.000 title claims abstract description 51
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 238000005266 casting Methods 0.000 title abstract description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000004202 carbamide Substances 0.000 claims abstract description 29
- 239000011230 binding agent Substances 0.000 claims abstract description 27
- 125000001424 substituent group Chemical group 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 150000002989 phenols Chemical class 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 33
- 239000011342 resin composition Substances 0.000 abstract description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 2
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 125000005745 ethoxymethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])* 0.000 abstract 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 abstract 1
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 abstract 1
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 description 45
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 26
- 239000004576 sand Substances 0.000 description 19
- 239000003795 chemical substances by application Substances 0.000 description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- -1 aldehyde compounds Chemical class 0.000 description 6
- 238000006068 polycondensation reaction Methods 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 5
- DSLRVRBSNLHVBH-UHFFFAOYSA-N 2,5-furandimethanol Chemical compound OCC1=CC=C(CO)O1 DSLRVRBSNLHVBH-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 150000001299 aldehydes Chemical class 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 239000006087 Silane Coupling Agent Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229960001755 resorcinol Drugs 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- NKRNKUWYXIABEN-UHFFFAOYSA-N 2,5-bis(ethoxymethyl)furan Chemical compound CCOCC1=CC=C(COCC)O1 NKRNKUWYXIABEN-UHFFFAOYSA-N 0.000 description 2
- DZEPFNDOOWFEKN-UHFFFAOYSA-N 2,5-bis(methoxymethyl)furan Chemical compound COCC1=CC=C(COC)O1 DZEPFNDOOWFEKN-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- JPYHHZQJCSQRJY-UHFFFAOYSA-N Phloroglucinol Natural products CCC=CCC=CCC=CCC=CCCCCC(=O)C1=C(O)C=C(O)C=C1O JPYHHZQJCSQRJY-UHFFFAOYSA-N 0.000 description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 2
- 229940092714 benzenesulfonic acid Drugs 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 description 2
- 229940015043 glyoxal Drugs 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052863 mullite Inorganic materials 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 2
- 229960001553 phloroglucinol Drugs 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- WHOZNOZYMBRCBL-OUKQBFOZSA-N (2E)-2-Tetradecenal Chemical compound CCCCCCCCCCC\C=C\C=O WHOZNOZYMBRCBL-OUKQBFOZSA-N 0.000 description 1
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- JIRHAGAOHOYLNO-UHFFFAOYSA-N (3-cyclopentyloxy-4-methoxyphenyl)methanol Chemical compound COC1=CC=C(CO)C=C1OC1CCCC1 JIRHAGAOHOYLNO-UHFFFAOYSA-N 0.000 description 1
- MQCPOLNSJCWPGT-UHFFFAOYSA-N 2,2'-Bisphenol F Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1O MQCPOLNSJCWPGT-UHFFFAOYSA-N 0.000 description 1
- PSZORLXATPJPGW-UHFFFAOYSA-N 2-(ethoxymethyl)-5-(methoxymethyl)furan Chemical compound CCOCC1=CC=C(COC)O1 PSZORLXATPJPGW-UHFFFAOYSA-N 0.000 description 1
- GXICAIPZEZBXCA-UHFFFAOYSA-N 2-(ethoxymethyl)-5-methylfuran Chemical compound CCOCC1=CC=C(C)O1 GXICAIPZEZBXCA-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- JOFDQONITRMYMX-UHFFFAOYSA-N [5-(methoxymethyl)furan-2-yl]methanol Chemical compound COCC1=CC=C(CO)O1 JOFDQONITRMYMX-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 229940013361 cresol Drugs 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- 229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
- 235000019797 dipotassium phosphate Nutrition 0.000 description 1
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 description 1
- ZJXZSIYSNXKHEA-UHFFFAOYSA-N ethyl dihydrogen phosphate Chemical compound CCOP(O)(O)=O ZJXZSIYSNXKHEA-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 229960004337 hydroquinone Drugs 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- CAAULPUQFIIOTL-UHFFFAOYSA-L methyl phosphate(2-) Chemical compound COP([O-])([O-])=O CAAULPUQFIIOTL-UHFFFAOYSA-L 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- WRDZMZGYHVUYRU-UHFFFAOYSA-N n-[(4-methoxyphenyl)methyl]aniline Chemical compound C1=CC(OC)=CC=C1CNC1=CC=CC=C1 WRDZMZGYHVUYRU-UHFFFAOYSA-N 0.000 description 1
- 229910052609 olivine Inorganic materials 0.000 description 1
- 239000010450 olivine Substances 0.000 description 1
- 229940044654 phenolsulfonic acid Drugs 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
- B22C1/20—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents
- B22C1/22—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents of resins or rosins
- B22C1/2233—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents of resins or rosins obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- B22C1/224—Furan polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
- B22C1/20—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents
- B22C1/22—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents of resins or rosins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Mold Materials And Core Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
【解決手段】フラン樹脂の縮合に関与していない尿素の含有量が1〜10重量%であり、且つpH(25℃)が7〜10である鋳型製造用フラン樹脂組成物、更に2,5位がヒドロキシメチル基、メトキシメチル基、又はエトキシメチル基で置換されたフランもしくは、オルト位又はパラ位の電荷密度を高める置換基を有するフェノールの何れかを硬化促進剤として用いた該樹脂組成物、及びこれらを鋳型製造用粘結剤として用いた鋳型の製造方法を提供する。
【選択図】なし
Description
カラム:TSK−gelAmido80(4.6mmφ×250mm)
移動相:アセトニトリル/水=95/5(アイソクラティック)
カラムオーブン:40℃
流速:1.0mL/min(MS導入スプリット:1/4)
検出:MSD(SIM):POSI検出 m/z:60.1±10
分解能0.5amu、DWELLTIME:250msec、イオン源ヒータ:300℃
分析時間:15分
サンプル調製:アセトン/水=95/5で希釈
*フラン樹脂:フルフリルアルコール70.5重量%、フルフリルアルコール/尿素/ホルムアルデヒド重縮合物24.5重量%、水4.0質量%、尿素以外のその他の成分1.0重量%
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005208586A JP5014601B2 (ja) | 2004-08-06 | 2005-07-19 | 鋳型製造用フラン樹脂組成物 |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004230310 | 2004-08-06 | ||
JP2004230310 | 2004-08-06 | ||
JP2005208586A JP5014601B2 (ja) | 2004-08-06 | 2005-07-19 | 鋳型製造用フラン樹脂組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006070247A true JP2006070247A (ja) | 2006-03-16 |
JP5014601B2 JP5014601B2 (ja) | 2012-08-29 |
Family
ID=35787289
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2005208586A Active JP5014601B2 (ja) | 2004-08-06 | 2005-07-19 | 鋳型製造用フラン樹脂組成物 |
Country Status (6)
Country | Link |
---|---|
US (1) | US8124719B2 (ja) |
EP (1) | EP1839774B1 (ja) |
JP (1) | JP5014601B2 (ja) |
KR (1) | KR101183806B1 (ja) |
CN (1) | CN100473476C (ja) |
WO (1) | WO2006014017A1 (ja) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008023529A (ja) * | 2006-07-18 | 2008-02-07 | Kao Corp | 鋳型製造用フラン樹脂組成物 |
KR101175837B1 (ko) | 2009-11-05 | 2012-08-24 | 코오롱인더스트리 주식회사 | 푸란수지 조성물,푸란수지?경화제 조성물,및 이의 주물용사 조성물 |
WO2013141186A1 (en) | 2012-03-23 | 2013-09-26 | Kao Corporation | Binder composition for making foundry molds |
JP2014024103A (ja) * | 2012-07-27 | 2014-02-06 | Kao Corp | 鋳型造型用粘結剤組成物 |
JP2014100726A (ja) * | 2012-11-20 | 2014-06-05 | Kao Corp | 鋳型造型用粘結剤組成物 |
JP2014213368A (ja) * | 2013-04-26 | 2014-11-17 | 花王株式会社 | 鋳型造型用粘結剤組成物 |
JP2015089553A (ja) * | 2013-11-05 | 2015-05-11 | 花王株式会社 | 自硬性鋳型造型用粘結剤組成物 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102012201971A1 (de) | 2012-02-09 | 2013-08-14 | Hüttenes-Albertus Chemische Werke GmbH | Cold-Box-Bindemittelsysteme und Mischungen zur Verwendung als Additive für solche Bindemittelsysteme |
US10199613B2 (en) * | 2014-03-31 | 2019-02-05 | Dai Nippon Printing Co., Ltd. | Packaging material for batteries |
KR101893686B1 (ko) * | 2017-03-21 | 2018-09-04 | 주식회사 케이씨씨 | 푸란수지 조성물 |
KR102118148B1 (ko) * | 2018-11-26 | 2020-06-02 | 주식회사 케이씨씨 | 푸란수지 조성물 |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS5446126A (en) * | 1977-09-21 | 1979-04-11 | Kao Corp | Binder composition for cast sand |
JPS5518408A (en) * | 1978-07-25 | 1980-02-08 | Anatori Aburamobuichi Kuruguri | Manufacture of carbamideefuran resin |
JPS5788943A (en) * | 1980-11-20 | 1982-06-03 | Ube Ind Ltd | Production of binder for self-curing mold |
JPH0394952A (ja) * | 1989-09-07 | 1991-04-19 | Aisin Chem Co Ltd | ホットボックス用樹脂被覆砂粒 |
JPH04371343A (ja) * | 1991-06-20 | 1992-12-24 | Kaou Quaker Kk | 高圧鋳造砂中子用粘結剤組成物 |
JPH05192737A (ja) * | 1991-09-10 | 1993-08-03 | Kao Corp | 鋳物砂用粘結剤組成物及び鋳型組成物 |
JPH0623475A (ja) * | 1991-03-11 | 1994-02-01 | Kaou Quaker Kk | 加熱硬化鋳型用硬化剤組成物 |
JPH0899149A (ja) * | 1994-09-30 | 1996-04-16 | Kao Corp | 鋳型用粘結剤組成物、鋳型組成物および鋳型の製造方法 |
JP2000225437A (ja) * | 1999-02-04 | 2000-08-15 | Kao Corp | 鋳型製造法 |
Family Cites Families (6)
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---|---|---|---|---|
JPS5126122A (ja) | 1974-08-27 | 1976-03-03 | Takeo Shinohara | Yusoyomoshikomifukushadenpyo |
US4271054A (en) * | 1980-03-19 | 1981-06-02 | Ashland Oil, Inc. | Preparation of furan polymers |
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JP2784715B2 (ja) | 1993-02-22 | 1998-08-06 | 花王株式会社 | 鋳型製造用粘結剤組成物、鋳型製造用砂組成物及び鋳型の製造方法 |
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- 2005-07-19 JP JP2005208586A patent/JP5014601B2/ja active Active
- 2005-08-04 US US11/631,938 patent/US8124719B2/en not_active Expired - Fee Related
- 2005-08-04 KR KR1020077002828A patent/KR101183806B1/ko active IP Right Grant
- 2005-08-04 EP EP05780249A patent/EP1839774B1/en not_active Expired - Fee Related
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- 2005-08-04 CN CNB2005800261049A patent/CN100473476C/zh active Active
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Cited By (11)
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JP2008023529A (ja) * | 2006-07-18 | 2008-02-07 | Kao Corp | 鋳型製造用フラン樹脂組成物 |
KR101175837B1 (ko) | 2009-11-05 | 2012-08-24 | 코오롱인더스트리 주식회사 | 푸란수지 조성물,푸란수지?경화제 조성물,및 이의 주물용사 조성물 |
WO2013141186A1 (en) | 2012-03-23 | 2013-09-26 | Kao Corporation | Binder composition for making foundry molds |
JP2013223881A (ja) * | 2012-03-23 | 2013-10-31 | Kao Corp | 鋳型造型用粘結剤組成物 |
KR20140138983A (ko) | 2012-03-23 | 2014-12-04 | 카오카부시키가이샤 | 주형 조형용 점결제 조성물 |
US9636742B2 (en) | 2012-03-23 | 2017-05-02 | Kao Corporation | Binder composition for making foundry molds |
KR101991543B1 (ko) * | 2012-03-23 | 2019-06-20 | 카오카부시키가이샤 | 주형 조형용 점결제 조성물 |
JP2014024103A (ja) * | 2012-07-27 | 2014-02-06 | Kao Corp | 鋳型造型用粘結剤組成物 |
JP2014100726A (ja) * | 2012-11-20 | 2014-06-05 | Kao Corp | 鋳型造型用粘結剤組成物 |
JP2014213368A (ja) * | 2013-04-26 | 2014-11-17 | 花王株式会社 | 鋳型造型用粘結剤組成物 |
JP2015089553A (ja) * | 2013-11-05 | 2015-05-11 | 花王株式会社 | 自硬性鋳型造型用粘結剤組成物 |
Also Published As
Publication number | Publication date |
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CN1993194A (zh) | 2007-07-04 |
EP1839774A1 (en) | 2007-10-03 |
JP5014601B2 (ja) | 2012-08-29 |
WO2006014017A1 (ja) | 2006-02-09 |
EP1839774B1 (en) | 2012-02-29 |
KR101183806B1 (ko) | 2012-09-21 |
KR20070046841A (ko) | 2007-05-03 |
EP1839774A4 (en) | 2009-04-15 |
US8124719B2 (en) | 2012-02-28 |
US20080045692A1 (en) | 2008-02-21 |
CN100473476C (zh) | 2009-04-01 |
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