JP2005518928A5 - - Google Patents
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- Publication number
- JP2005518928A5 JP2005518928A5 JP2003572679A JP2003572679A JP2005518928A5 JP 2005518928 A5 JP2005518928 A5 JP 2005518928A5 JP 2003572679 A JP2003572679 A JP 2003572679A JP 2003572679 A JP2003572679 A JP 2003572679A JP 2005518928 A5 JP2005518928 A5 JP 2005518928A5
- Authority
- JP
- Japan
- Prior art keywords
- catalyst composition
- metal oxide
- molecular sieve
- acetone
- binder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 12
- 229910044991 metal oxide Inorganic materials 0.000 claims 11
- 150000004706 metal oxides Chemical class 0.000 claims 11
- 239000003054 catalyst Substances 0.000 claims 9
- 239000002808 molecular sieve Substances 0.000 claims 8
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 8
- 239000011230 binding agent Substances 0.000 claims 4
- 239000011159 matrix material Substances 0.000 claims 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 2
- 239000012018 catalyst precursor Substances 0.000 claims 2
- 230000000737 periodic effect Effects 0.000 claims 2
- 239000011148 porous material Substances 0.000 claims 2
- 229920006395 saturated elastomer Polymers 0.000 claims 2
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 1
- 239000000395 magnesium oxide Substances 0.000 claims 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
Claims (8)
- (ａ)２０ｍ２／ｇよりも大きい表面積を有し、２００℃より高い温度でか焼されている金属酸化物であり、アセトンで飽和され、前記アセトンで２５℃において１時間接触させたときに、アセトンの８０％より多くを変換させる金属酸化物、
(ｂ)バインダー、
(ｃ)マトリックス物質及び
(ｄ)５オングストローム未満の平均細孔サイズを有する分子篩
を含有する触媒組成物。 - 金属酸化物の表面積が７０ｍ２／ｇよりも大きい、請求項１に記載の触媒組成物。
- 金属酸化物が、元素の周期表の２族から選ばれる、請求項１又は請求項２に記載の触媒組成物。
- ３族の金属酸化物をさらに含有する、請求項３に記載の触媒組成物。
- 分子篩、及び少なくとも一つの、元素周期表の２族から選ばれる金属の酸化物を含有し、金属酸化物が、１００℃において、少なくとも０.０３ｍｇ／金属酸化物ｍ２の、二酸化炭素の取り込みを有する、触媒組成物。
- (ａ)シリコアルミノ燐酸塩分子篩及び／又はアルミノ燐酸塩分子篩、バインダー及びマトリックス物質を配合させ、触媒前駆体を生成し、(ｂ)前記触媒前駆体に、２００℃乃至７００℃の範囲の温度にか焼された少なくとも一つの金属酸化物を添加することを含む、触媒組成物を製造する方法。
- 分子篩、バインダー、マトリックス物質及び金属酸化物を含有する分子篩触媒組成物であり、金属酸化物は、アセトンで飽和され、前記アセトンで２５℃において１時間接触させたときに、アセトンの８０％より多くを変換させる、分子篩触媒組成物の存在下で、供給原料を一つ以上のオレフィンに変換する方法。
- 少なくとも一つのオキシジェネートを含有する供給原料を、小細孔分子篩、バインダー、マトリックス物質、２００℃乃至７００℃の範囲の温度にか焼されている酸化マグネシウム、及び３族金属酸化物を含有する触媒組成物と接触させることを含む、一つ以上のオレフィンを生成する方法。
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36096302P | 2002-02-28 | 2002-02-28 | |
| US36601202P | 2002-03-20 | 2002-03-20 | |
| US37469702P | 2002-04-22 | 2002-04-22 | |
| US10/215,511 US6906232B2 (en) | 2002-08-09 | 2002-08-09 | Molecular sieve compositions, catalysts thereof, their making and use in conversion processes |
| PCT/US2003/003951 WO2003074175A2 (en) | 2002-02-28 | 2003-02-10 | Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005518928A JP2005518928A (ja) | 2005-06-30 |
| JP2005518928A5 true JP2005518928A5 (ja) | 2006-03-30 |
Family
ID=27792286
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003572679A Withdrawn JP2005518928A (ja) | 2002-02-28 | 2003-02-10 | 分子篩組成物、それらの触媒、それらの製造、及び変換法における使用 |
| JP2003572681A Pending JP2005518930A (ja) | 2002-02-28 | 2003-02-10 | 分子篩組成物、それらの触媒、それらの製造、及び変換法における使用 |
| JP2003572680A Withdrawn JP2005518929A (ja) | 2002-02-28 | 2003-02-10 | 分子篩組成物、それらの触媒、それらの製造、及び変換法における使用 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003572681A Pending JP2005518930A (ja) | 2002-02-28 | 2003-02-10 | 分子篩組成物、それらの触媒、それらの製造、及び変換法における使用 |
| JP2003572680A Withdrawn JP2005518929A (ja) | 2002-02-28 | 2003-02-10 | 分子篩組成物、それらの触媒、それらの製造、及び変換法における使用 |
Country Status (11)
| Country | Link |
|---|---|
| EP (3) | EP1478462A2 (ja) |
| JP (3) | JP2005518928A (ja) |
| KR (3) | KR20040091080A (ja) |
| CN (3) | CN1298427C (ja) |
| AU (3) | AU2003225560B2 (ja) |
| BR (1) | BR0308011A (ja) |
| CA (2) | CA2477428C (ja) |
| EA (3) | EA007873B1 (ja) |
| MY (2) | MY140018A (ja) |
| TW (3) | TWI306780B (ja) |
| WO (3) | WO2003074177A2 (ja) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1298427C (zh) * | 2002-02-28 | 2007-02-07 | 埃克森美孚化学专利公司 | 分子筛组合物,含有该组合物的催化剂以及它们的制备方法和在转化方法中的应用 |
| US7074739B2 (en) * | 2002-11-19 | 2006-07-11 | Exxonmobil Chemical Patents Inc. | Multi-component molecular sieve catalyst compositions and their use in aromatics reactions |
| US6951830B2 (en) | 2003-08-05 | 2005-10-04 | Exxonmobil Chemical Patents Inc. | Molecular sieve catalyst compositions, their production and use in conversion processes |
| US7404891B2 (en) * | 2004-03-29 | 2008-07-29 | Exxonmobil Chemical Patents Inc. | Heat recovery technique for catalyst regenerator flue gas |
| US7166757B2 (en) | 2004-07-30 | 2007-01-23 | Exxonmobil Chemical Patents Inc. | Conversion of oxygenates to olefins |
| WO2007021394A2 (en) * | 2005-08-18 | 2007-02-22 | Exxonmobil Chemical Patents Inc. | Catalytic conversion of oxygenates to olefins |
| CN101003018A (zh) * | 2006-01-20 | 2007-07-25 | 中国石油天然气股份有限公司 | 一种多相催化固体碱催化剂及其制备方法和应用 |
| US7335621B2 (en) | 2006-04-19 | 2008-02-26 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and preparation thereof |
| JP4710744B2 (ja) | 2006-07-18 | 2011-06-29 | トヨタ自動車株式会社 | 複合金属酸化物の製造方法 |
| US7595275B2 (en) | 2006-08-15 | 2009-09-29 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and their synthesis |
| CN101239866B (zh) * | 2007-02-07 | 2010-12-01 | 中国石油化工股份有限公司 | 含氧化合物生产乙烯、丙烯的方法 |
| CN101239878B (zh) * | 2007-02-07 | 2010-05-19 | 中国石油化工股份有限公司 | 碳四及其以上烯烃增产乙烯、丙烯的方法 |
| CA2578494A1 (en) * | 2007-02-14 | 2008-08-14 | Nova Chemicals Corporation | Catalytic cracking of ethers to 1-olefins |
| EP2022565A1 (en) * | 2007-07-06 | 2009-02-11 | Casale Chemicals S.A. | Process for preparing silicoaluminoposphate (SAPO) molecular sieves, catalysts containing said sieves and catalytic dehydration processes using said catalysts |
| EP2183203A1 (en) * | 2007-08-13 | 2010-05-12 | Saudi Basic Industries Corporation | Process for converting aliphatic oxygenates to aromatics |
| DE102007059129A1 (de) * | 2007-12-07 | 2009-06-10 | Süd-Chemie AG | Katalysator mit erhöhter Olefinselektivität zur Umsetzung von Oxygenaten zu Olefinen |
| US20110105819A1 (en) * | 2008-04-04 | 2011-05-05 | Petr Vasiliev | Zeolite catalyst zeolite secondary structure |
| JP5818133B2 (ja) * | 2011-05-20 | 2015-11-18 | 国立大学法人東京工業大学 | オレフィン製造用触媒及びオレフィンの製造方法 |
| CN102344328B (zh) * | 2011-07-25 | 2014-03-12 | 浙江大学 | 一种使用移动床技术将甲醇转化为丙烯的半连续方法 |
| EP2907571B1 (en) | 2012-10-15 | 2017-12-13 | Mitsubishi Gas Chemical Company, Inc. | Method for producing catalyst for use in production of methylamine compound, and method for producing methylamine compound |
| US9656244B2 (en) | 2013-05-07 | 2017-05-23 | Synthos S.A. | Process for the production of 1,3-butadiene |
| CN107661774B (zh) * | 2016-07-27 | 2020-11-03 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制低碳烯烃的方法 |
| CN107661773B (zh) * | 2016-07-29 | 2020-08-04 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制液体燃料联产低碳烯烃的方法 |
| CN108568311B (zh) * | 2017-03-07 | 2021-03-23 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制乙烯的方法 |
| RU2747308C1 (ru) * | 2017-04-27 | 2021-05-04 | Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайенсиз | Способ in-situ получения катализатора для получения по меньшей мере одного из толуола, пара-ксилола и низших олефинов, а также процесс реакции |
| CN109939667B (zh) * | 2018-01-26 | 2021-01-05 | 中国科学院大连化学物理研究所 | 一种催化剂及合成气直接转化制低碳烯烃的方法 |
| CN109939722B (zh) * | 2018-01-26 | 2021-05-25 | 中国科学院大连化学物理研究所 | 一种有机碱修饰的复合催化剂及一氧化碳加氢制乙烯的方法 |
| US20210370276A1 (en) * | 2018-10-30 | 2021-12-02 | Exxonmobil Chemical Patents Inc. | Group 1 Metal Ion Content of Microporous Molecular Sieve Catalysts |
| CN111346664B (zh) * | 2018-12-24 | 2022-11-15 | 中国石油化工股份有限公司 | 改性钒硅分子筛及其制备方法以及硫醚氧化方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4465889A (en) * | 1982-07-02 | 1984-08-14 | Summit Gas Systems Pte. Ltd. | Catalytic conversion of methanol, dimethyl ether and mixtures thereof to a hydrocarbon product rich in iso-C4 compounds and new catalysts therefor |
| US4781816A (en) | 1987-10-19 | 1988-11-01 | Phillips Petroleum Company | Cracking process |
| US6040264A (en) * | 1996-04-04 | 2000-03-21 | Exxon Chemical Patents Inc. | Use of alkaline earth metal containing small pore non-zeolitic molecular sieve catalysts in oxygenate conversion |
| TW412510B (en) * | 1996-12-31 | 2000-11-21 | Exxon Chemical Patents Inc | Oxygenate conversions using small pore non-zeolitic molecular sieve catalysts |
| US6423879B1 (en) * | 1997-10-02 | 2002-07-23 | Exxonmobil Oil Corporation | Selective para-xylene production by toluene methylation |
| JP4221532B2 (ja) * | 1998-06-26 | 2009-02-12 | 三菱瓦斯化学株式会社 | メチルアミン製造用触媒及び該触媒を用いたメチルアミン類の製造方法 |
| US6388156B1 (en) * | 1999-05-14 | 2002-05-14 | Exxonmobil Chemical Patents Inc. | Direct selective synthesis of para-xylene by reacting an aromatic compound with a methylating agent formed from CO, Co2 and H2 |
| AU2001236984A1 (en) * | 2000-03-01 | 2001-09-12 | Exxonmobil Chemical Patents Inc | Thorium-containing sapo molecular sieve for producing olefins |
| US6448197B1 (en) * | 2000-07-13 | 2002-09-10 | Exxonmobil Chemical Patents Inc. | Method for making a metal containing small pore molecular sieve catalyst |
| AU2001275901A1 (en) * | 2000-07-13 | 2002-01-30 | Uop Llc | Attrition resistant catalyst for light olefin production |
| CA2369318A1 (en) * | 2002-01-28 | 2003-07-28 | Universite Concordia | Hybrid catalysts for the deep catalytic cracking of petroleum naphthas and other hydrocarbon feedstocks for the selective production of light olefins |
| CN1298427C (zh) * | 2002-02-28 | 2007-02-07 | 埃克森美孚化学专利公司 | 分子筛组合物,含有该组合物的催化剂以及它们的制备方法和在转化方法中的应用 |
-
2003
- 2003-02-10 CN CNB038047616A patent/CN1298427C/zh not_active Expired - Fee Related
- 2003-02-10 AU AU2003225560A patent/AU2003225560B2/en not_active Ceased
- 2003-02-10 KR KR10-2004-7013377A patent/KR20040091080A/ko active IP Right Grant
- 2003-02-10 WO PCT/US2003/004169 patent/WO2003074177A2/en active Application Filing
- 2003-02-10 CN CNB038068079A patent/CN1327964C/zh not_active Expired - Fee Related
- 2003-02-10 CA CA2477428A patent/CA2477428C/en not_active Expired - Fee Related
- 2003-02-10 CA CA002477432A patent/CA2477432A1/en not_active Abandoned
- 2003-02-10 EP EP03743671A patent/EP1478462A2/en not_active Withdrawn
- 2003-02-10 AU AU2003216248A patent/AU2003216248B2/en not_active Ceased
- 2003-02-10 EA EA200401102A patent/EA007873B1/ru not_active IP Right Cessation
- 2003-02-10 WO PCT/US2003/003951 patent/WO2003074175A2/en active Application Filing
- 2003-02-10 BR BR0308011-0A patent/BR0308011A/pt not_active IP Right Cessation
- 2003-02-10 CN CNB038082659A patent/CN100335172C/zh not_active Expired - Fee Related
- 2003-02-10 KR KR10-2004-7013384A patent/KR20040089680A/ko not_active Application Discontinuation
- 2003-02-10 EA EA200401101A patent/EA007872B1/ru not_active IP Right Cessation
- 2003-02-10 EP EP03709038A patent/EP1478461A2/en not_active Withdrawn
- 2003-02-10 JP JP2003572679A patent/JP2005518928A/ja not_active Withdrawn
- 2003-02-10 WO PCT/US2003/004153 patent/WO2003074176A2/en active Application Filing
- 2003-02-10 JP JP2003572681A patent/JP2005518930A/ja active Pending
- 2003-02-10 KR KR10-2004-7013378A patent/KR20040089679A/ko not_active Application Discontinuation
- 2003-02-10 AU AU2003212993A patent/AU2003212993A1/en not_active Abandoned
- 2003-02-10 EA EA200401061A patent/EA007871B1/ru not_active IP Right Cessation
- 2003-02-10 JP JP2003572680A patent/JP2005518929A/ja not_active Withdrawn
- 2003-02-10 EP EP03743673A patent/EP1478464A2/en not_active Withdrawn
- 2003-02-14 TW TW092103144A patent/TWI306780B/zh not_active IP Right Cessation
- 2003-02-14 TW TW092103154A patent/TWI265825B/zh not_active IP Right Cessation
- 2003-02-14 TW TW092103148A patent/TWI265824B/zh not_active IP Right Cessation
- 2003-02-21 MY MYPI20030609A patent/MY140018A/en unknown
- 2003-02-21 MY MYPI20030610A patent/MY139847A/en unknown
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