JP2005513212A - 官能性部分を含むポリ(ビニルアルコール)−コ−ポリ(ビニルアミン)ポリマー - Google Patents
官能性部分を含むポリ(ビニルアルコール)−コ−ポリ(ビニルアミン)ポリマー Download PDFInfo
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- JP2005513212A JP2005513212A JP2003554744A JP2003554744A JP2005513212A JP 2005513212 A JP2005513212 A JP 2005513212A JP 2003554744 A JP2003554744 A JP 2003554744A JP 2003554744 A JP2003554744 A JP 2003554744A JP 2005513212 A JP2005513212 A JP 2005513212A
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- copolymer
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- 229920001577 copolymer Polymers 0.000 title claims abstract description 132
- 229920000642 polymer Polymers 0.000 title claims description 64
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical compound NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 title claims description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 73
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Substances CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 4
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 3
- -1 oxyl Chemical group 0.000 claims description 82
- 239000010410 layer Substances 0.000 claims description 62
- 150000001412 amines Chemical class 0.000 claims description 38
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 28
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 27
- 150000003839 salts Chemical class 0.000 claims description 24
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 23
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 22
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 claims description 20
- 239000000123 paper Substances 0.000 claims description 19
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- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims description 16
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 16
- 239000011253 protective coating Substances 0.000 claims description 16
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- 239000002253 acid Chemical class 0.000 claims description 14
- 229960003237 betaine Drugs 0.000 claims description 14
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- 239000004611 light stabiliser Substances 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 13
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 13
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- 239000011247 coating layer Substances 0.000 claims description 12
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 11
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 10
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- 229920002635 polyurethane Polymers 0.000 claims description 9
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- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 8
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- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 7
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims description 7
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 7
- 150000002734 metacrylic acid derivatives Chemical class 0.000 claims description 7
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 7
- 229920000573 polyethylene Polymers 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- 239000004952 Polyamide Substances 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 6
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 229920000126 latex Polymers 0.000 claims description 6
- 239000004816 latex Substances 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 229920000570 polyether Polymers 0.000 claims description 6
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 5
- 239000006096 absorbing agent Substances 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 5
- 230000004888 barrier function Effects 0.000 claims description 5
- 239000000945 filler Substances 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 229920001519 homopolymer Polymers 0.000 claims description 5
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 239000008107 starch Substances 0.000 claims description 5
- 235000019698 starch Nutrition 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 5
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 claims description 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- ZSZRUEAFVQITHH-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 2-(trimethylazaniumyl)ethyl phosphate Chemical compound CC(=C)C(=O)OCCOP([O-])(=O)OCC[N+](C)(C)C ZSZRUEAFVQITHH-UHFFFAOYSA-N 0.000 claims description 4
- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 claims description 4
- ZCILGMFPJBRCNO-UHFFFAOYSA-N 4-phenyl-2H-benzotriazol-5-ol Chemical group OC1=CC=C2NN=NC2=C1C1=CC=CC=C1 ZCILGMFPJBRCNO-UHFFFAOYSA-N 0.000 claims description 4
- VMRIVYANZGSGRV-UHFFFAOYSA-N 4-phenyl-2h-triazin-5-one Chemical group OC1=CN=NN=C1C1=CC=CC=C1 VMRIVYANZGSGRV-UHFFFAOYSA-N 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- 108010010803 Gelatin Proteins 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 239000004642 Polyimide Substances 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 239000008273 gelatin Substances 0.000 claims description 4
- 229920000159 gelatin Polymers 0.000 claims description 4
- 235000019322 gelatine Nutrition 0.000 claims description 4
- 235000011852 gelatine desserts Nutrition 0.000 claims description 4
- 125000005647 linker group Chemical group 0.000 claims description 4
- 229920001721 polyimide Polymers 0.000 claims description 4
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 4
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 claims description 3
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000005062 Polybutadiene Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 239000007983 Tris buffer Substances 0.000 claims description 3
- CQHKDHVZYZUZMJ-UHFFFAOYSA-N [2,2-bis(hydroxymethyl)-3-prop-2-enoyloxypropyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(CO)COC(=O)C=C CQHKDHVZYZUZMJ-UHFFFAOYSA-N 0.000 claims description 3
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- 239000003822 epoxy resin Substances 0.000 claims description 3
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 3
- 125000003827 glycol group Chemical group 0.000 claims description 3
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
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- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
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- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 claims description 2
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- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 claims description 2
- WUIJTQZXUURFQU-UHFFFAOYSA-N 1-methylsulfonylethene Chemical compound CS(=O)(=O)C=C WUIJTQZXUURFQU-UHFFFAOYSA-N 0.000 claims description 2
- SUFSXWBMZQUYOC-UHFFFAOYSA-N 2,2-bis(ethenoxymethyl)propane-1,3-diol Chemical compound C=COCC(CO)(CO)COC=C SUFSXWBMZQUYOC-UHFFFAOYSA-N 0.000 claims description 2
- OXEMYLNXNAJPGY-UHFFFAOYSA-N 2-(2,2-diphenylpropoxy)ethyl prop-2-enoate Chemical compound C(C=C)(=O)OCCOCC(C)(C1=CC=CC=C1)C1=CC=CC=C1 OXEMYLNXNAJPGY-UHFFFAOYSA-N 0.000 claims description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 2
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims description 2
- BEWCNXNIQCLWHP-UHFFFAOYSA-N 2-(tert-butylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCNC(C)(C)C BEWCNXNIQCLWHP-UHFFFAOYSA-N 0.000 claims description 2
- FDSUVTROAWLVJA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)COCC(CO)(CO)CO FDSUVTROAWLVJA-UHFFFAOYSA-N 0.000 claims description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 2
- VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 claims description 2
- DNHDSWZXBHTLDP-UHFFFAOYSA-N 3-(2-ethenylpyridin-1-ium-1-yl)propane-1-sulfonate Chemical compound [O-]S(=O)(=O)CCC[N+]1=CC=CC=C1C=C DNHDSWZXBHTLDP-UHFFFAOYSA-N 0.000 claims description 2
- PDZZTATWZUUWFF-UHFFFAOYSA-N 3-(3-ethenylimidazol-1-ium-1-yl)propane-1-sulfonic acid;hydroxide Chemical compound [OH-].OS(=O)(=O)CCCN1C=C[N+](C=C)=C1 PDZZTATWZUUWFF-UHFFFAOYSA-N 0.000 claims description 2
- ZQRNRKASNNVFAJ-UHFFFAOYSA-N 3-[dimethyl(2-prop-2-enoyloxyethyl)azaniumyl]propane-1-sulfonate Chemical compound [O-]S(=O)(=O)CCC[N+](C)(C)CCOC(=O)C=C ZQRNRKASNNVFAJ-UHFFFAOYSA-N 0.000 claims description 2
- KVKJQOXYGGPBIW-UHFFFAOYSA-N 3-[dimethyl-[3-(prop-2-enoylamino)propyl]azaniumyl]propane-1-sulfonate Chemical compound [O-]S(=O)(=O)CCC[N+](C)(C)CCCNC(=O)C=C KVKJQOXYGGPBIW-UHFFFAOYSA-N 0.000 claims description 2
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- 239000004641 Diallyl-phthalate Substances 0.000 claims description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 2
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- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 2
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 claims description 2
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- 239000002033 PVDF binder Substances 0.000 claims description 2
- 229920002845 Poly(methacrylic acid) Polymers 0.000 claims description 2
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- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 2
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- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 235000012243 magnesium silicates Nutrition 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 229940050176 methyl chloride Drugs 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- VSEAAEQOQBMPQF-UHFFFAOYSA-N morpholin-3-one Chemical compound O=C1COCCN1 VSEAAEQOQBMPQF-UHFFFAOYSA-N 0.000 description 1
- IZRZMBCKGLWYSC-UHFFFAOYSA-N n'-(2-aminoethyl)ethane-1,2-diamine;2-methylprop-2-enamide Chemical compound CC(=C)C(N)=O.CC(=C)C(N)=O.CC(=C)C(N)=O.NCCNCCN IZRZMBCKGLWYSC-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
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- 239000004745 nonwoven fabric Substances 0.000 description 1
- 238000010534 nucleophilic substitution reaction Methods 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000001741 organic sulfur group Chemical group 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 150000002917 oxazolidines Chemical class 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
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- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 230000019612 pigmentation Effects 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- IWELDVXSEVIIGI-UHFFFAOYSA-N piperazin-2-one Chemical compound O=C1CNCCN1 IWELDVXSEVIIGI-UHFFFAOYSA-N 0.000 description 1
- JTHRRMFZHSDGNJ-UHFFFAOYSA-N piperazine-2,3-dione Chemical compound O=C1NCCNC1=O JTHRRMFZHSDGNJ-UHFFFAOYSA-N 0.000 description 1
- XUWHAWMETYGRKB-UHFFFAOYSA-N piperidin-2-one Chemical compound O=C1CCCCN1 XUWHAWMETYGRKB-UHFFFAOYSA-N 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000007342 radical addition reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000007763 reverse roll coating Methods 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 150000003902 salicylic acid esters Chemical class 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000007767 slide coating Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- SJDWKAHMQWSMPV-UHFFFAOYSA-N tert-butyl n-ethenylcarbamate Chemical compound CC(C)(C)OC(=O)NC=C SJDWKAHMQWSMPV-UHFFFAOYSA-N 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- 125000002813 thiocarbonyl group Chemical group *C(*)=S 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
Lは、互いに独立に、−NH−、−N=、>N−、>N+<、−O−または−CO−である化学連結基であり、
COPOLYMERは、式:
であり、
R2およびR4は、独立にHまたはC1〜C6アルキルであり、
x+y+zは、約3〜約50モル%であり、かつ
q、nおよびmは、残りのモル%を一緒に構成し、
添字x、y、z、n、mおよびqは、独立に、0であってもよく、
qが0でなければ、bは0であってもよい)
のプレポリマーから誘導され、
式中、
FUNCTIONAL MOIETY(A)は、少なくとも1個の官能性部分含有化合物から誘導され、該化合物は、光安定剤、架橋剤、ポリマー改質剤、ガス退色防止剤、媒染剤、相溶化剤、緩衝剤およびグリコール可溶化剤部分からなる群より選択される少なくとも1個の官能性部分を含有し、また、
式中、
N,N−ジメチル−N−アクリロイルオキシエチル−N−(3−スルホプロピル)アンモニウムベタイン、
N,N−ジメチル−N−アクリロイルオキシエチル−N−(2−カルボキシメチル)アンモニウムベタイン、
N,N−ジメチル−N−アクリルアミドプロピル−N−(3−スルホプロピル)アンモニウムベタイン、
N,N−ジメチル−N−アクリルアミドプロピル−N−(2−カルボキシメチル)アンモニウムベタイン、
2−(メチルチオ)エチル メタクリロイル−S−(スルホプロピル)スルホニウムベタイン、
2−〔(2−アクリロイルエチル)ジメチルアンモニオ〕エチル2−メチルホスフェート、
2−(アクリロイルオキシエチル)2′−(トリメチルアンモニウム)エチルホスフェート、
〔(2−アクリルオキシエチル)ジメチルアンモニオ〕メチルホスホン酸、
2−メタクリロイルオキシエチルホスホリルコリン(MPC)、
2−〔(3−アクリルアミノプロピル)ジメチルアンモニオ〕エチル2′−イソプロピルホスフェート(AAPI)、
1−ビニル−3−(3−スルホプロピル)イミダゾリウムヒドロキシド、
(2−アクリルオキシエチル)カルボキシメチル(メチル)スルホニウムクロリド、
1−(3−スルホプロピル)−2−ビニルピリジニウムベタイン、
N−(4−スルホブチル)−N−メチル−N,N−ジアリルアミンアンモニウムベタイン(MDABS)および
N,N−ジアリル−N−メチル−N−(2−スルホエチル)アンモニウムベタイン
からなる群より選択される両イオン性モノマーである。
本発明のコポリマーは、オリゴマーアミン塩およびポリマーアミン塩等のカチオン種、たとえば、米国特許第5,474,843号明細書および他の文献に開示されているものと共に、有利に使用される。代表的なカチオン性ポリマーとしては、ジアルキルアミノアルキルアクリレート類およびメタクリレート類の第四級塩類もしくは酸塩類、ジアルキルアミノアルキルアクリルアミド類およびメタクリルアミド類の第四級塩類もしくは酸塩類、N,N−ジアリルジアルキルアンモニウムハライド、マンニッヒ反応生成物等々から選択される1種以上のモノマーを含有するものなどがある。代表例は、N,N−ジメチルアミノエチルアクリレートメチルクロリド第四級塩(DMAEA−MeCl−q)、ジアリルジメチルアンモニウムクロリド(DADMAC)等々である。
2−(2−ヒドロキシフェニル)−2H−ベンゾトリアゾール類、たとえば既知の市販されているヒドロキシフェニル−2H−ベンゾトリアゾール類、2−ヒドロキシベンゾフェノン類、置換された安息香酸および非置換の安息香酸のエステル類、たとえば4−tert−ブチルフェニルサリチレート、アクリレート類およびマロネート類、オキサミド類、トリスアリール−o−ヒドロキシフェニル−s−トリアジン類および立体的ヒンダードアミン安定剤、たとえばN−H、N−アシル、N−オキシル、N−ヒドロキシル、N−アルキル、N−アルコキシおよびN−ヒドロキシアルコキシヒンダードアミン類からなる群より選択されるUV吸収剤および光安定剤から選択される。
インクジェット印刷用インクは周知である。こうしたインクは、液体ビヒクルおよびその中に溶解または懸濁された染料または顔料を含む。使用される液体ビヒクルは、水または水と水混和性有機溶媒との混合物を含む。該インクはまた、記録媒体システムに組み入れられる添加剤または他の成分のためのビヒクルであってもよい。
実施例1
水(3415g)を、必要な補助装置を備えた5L実験用反応フラスコに仕込んだ。このフラスコを窒素で置換し、80℃に加熱した。2,2′−アゾビス(アミジノプロパン)二塩酸塩(5g、水20gに溶解)ならびにアクリルアミド(150g)、メトキシポリエチレングリコールメタクリレート(62.5g、分子量約350)、N−(3−スルホプロピル)−N−メタクリルオキシエチル−N,N−ジメチルアンモニウムベタイン(37.5g)および水(140.1g)の溶液を、反応フラスコに加えた。発熱が検出されるとただちに、アクリルアミド(450g)、メトキシポリエチレングリコールメタクリレート(187.5g、分子量約350)、N−(3−スルホプロピル)−N−メタクリルオキシエチル−N,N−ジメチルアンモニウムベタイン(112.5g)および水(420.4g)の溶液を、30分間にわたって反応フラスコに加えた。添加が完了するとただちに、反応器内容物をさらに1時間、80℃に維持した後、冷却して濾過した。GPCによる測定で250,000の分子量を有し、450cP(Brookfield RVT、20rpm、スピンドル3)の粘度を有する20%水溶液として、標題のコポリマーを得た。
異なる比率の10%ポリマー水溶液を混合し、続いてポリエチレン被覆紙に流延した。代表的な手順を以下に示す。10%水溶液としての実施例16の生成物100部、および溶液としてのポリビニルアルコール100部を、一緒に25分間混合した。撹拌を止め、20分間、溶液を脱気させておいた。次いで、オーブン乾燥後に20μmの皮膜厚さが得られるように、マイヤー・バーを使用して、水性ポリマー溶液を、ポリエチレン被覆紙シートに塗布した。
コポリマー配合物(50/50) 20°光沢示度
実施例16/実施例2 14.8
実施例16/PVOH 29.4
実施例16/実施例11 31.1
実施例16/実施例17 47.2
実施例16/実施例10 59.6
実施例16/実施例2 20.1
実施例16/PVOH 33.9
実施例16/実施例11 36.8
実施例16/実施例10 37.1
実施例16/実施例17 57.6
実施例16/実施例2 56.3
実施例16/PVOH 69.4
実施例16/実施例11 72.0
実施例16/実施例17 83.3
実施例16/実施例10 88.5
PVOHは、Celaneseから入手したCelvol325である。
実施例16/実施例2 63.0
実施例16/PVOH 78.1
実施例16/実施例10 80.5
実施例16/実施例17 86.8
PVOHは、Celaneseから入手したCelvol325である。
Claims (33)
- 式:
〔式中、
bは、1以上であり、
Lは、互いに独立に、−NH−、−N=、>N−、>N+<、−O−または−CO−である化学連結基であり、
COPOLYMERは、式:
(式中、R1およびR3は、独立に、H;3−プロピオン酸もしくはそのC1〜C6アルキルエステル;または2−メチル−3−プロピオン酸もしくはそのC1〜C6アルキルエステルであり、
R2およびR4は、独立に、HまたはC1〜C6アルキルであり、
x+y+zは、約3〜約50モル%であり、かつ
q、nおよびmは、残りのモル%を一緒に構成し、
添字x、y、z、n、mおよびqは、独立に、0であってもよく、
qが0でなければ、bは0であってもよい)
のプレポリマーから誘導され、
式中、
FUNCTIONAL MOIETY(A)は、少なくとも1個の官能性部分含有化合物から誘導され、前記化合物は、光安定剤、架橋剤、ポリマー改質剤、ガス退色防止剤、媒染剤、相溶化剤、緩衝剤およびグリコール可溶化剤部分からなる群より選択される少なくとも1個の官能性部分を含有し、また、
式中、
は、少なくとも1個のエチレン性不飽和官能性部分含有化合物から誘導され、前記化合物は、光安定剤、架橋剤、ポリマー改質剤、ガス退色防止剤、媒染剤、相溶化剤、緩衝剤およびグリコール可溶化剤部分からなる群より選択される少なくとも1個の官能性部分を含有する〕
として表される、官能性部分含有PVOH/PVAmコポリマー。 - 前記官能性部分が、ヒドロキシフェニルベンゾトリアゾール、ヒドロキシフェニルトリアジンおよびヒンダードアミン光安定剤部分からなる群より選択される光安定剤部分である、請求項1に記載のコポリマー。
- 前記ヒンダードアミン部分が、オキシルヒンダードアミン部分、ヒドロキシルヒンダードアミン部分、アルコキシヒンダードアミン部分またはヒドロキシアルコキシヒンダードアミン部分である、請求項2に記載のコポリマー。
- 前記官能性部分含有化合物または前記エチレン性不飽和官能性部分含有化合物が、アクリルアミド、メタクリルアミド、N−メチルアクリルアミド、N,N−ジメチル(メタ)アクリルアミド、N−イソプロピル(メタ)アクリルアミド、N−(2−ヒドロキシプロピル)メタクリルアミド、N−メチロールアクリルアミド、N−ビニルホルムアミド、N−ビニルアセトアミド、N−ビニル−N−メチルアセトアミド、ポリ(エチレングリコール)(メタ)アクリレート、ポリ(エチレングリコール)モノメチルエーテルモノ(メタ)アクリレート、N−ビニル−2−ピロリドン、グリセリンモノ((メタ)アクリレート)、2−ヒドロキシエチル(メタ)アクリレート、ビニルメチルスルホン、酢酸ビニル、ジアセトンアクリルアミド、メチルメタクリレート、アクリル酸、ヒドロキシエチルメタクリレート(HEMA)、ジメチルアミノエチルメタクリレート、tert−ブチルアミノエチルメタクリレート、ステアリルポリオキシエチレン(20)メタクリレートおよびステアリルポリオキシエチレン(10)アリルエーテルからなる群より選択される、請求項1に記載のコポリマー。
- 前記官能性部分含有化合物または前記エチレン性不飽和官能性部分含有化合物が、
N,N−ジメチル−N−アクリロイルオキシエチル−N−(3−スルホプロピル)アンモニウムベタイン、
N,N−ジメチル−N−アクリロイルオキシエチル−N−(2−カルボキシメチル)アンモニウムベタイン、
N,N−ジメチル−N−アクリルアミドプロピル−N−(3−スルホプロピル)アンモニウムベタイン、
N,N−ジメチル−N−アクリルアミドプロピル−N−(2−カルボキシメチル)アンモニウムベタイン、
2−(メチルチオ)エチルメタクリロイル−S−(スルホプロピル)スルホニウムベタイン、
2−〔(2−アクリロイルエチル)ジメチルアンモニオ〕エチル2−メチルホスフェート、
2−(アクリロイルエチル)2′−(トリメチルアンモニウム)エチルホスフェート、
〔(2−アクリルオキシエチル)ジメチルアンモニオ〕メチルホスホン酸、
2−メタクリロイルオキシエチルホスホリルコリン(MPC)、
2−〔(3−アクリルアミドプロピル)ジメチルアンモニオ〕エチル2′−イソプロピルホスフェート(AAPI)、
1−ビニル−3−(3−スルホプロピル)イミダゾリウムヒドロキシド、
(2−アクリルオキシエチル)カルボキシメチル(メチル)スルホニウムクロリド、
1−(3−スルホプロピル)−2−ビニルピリジニウムベタイン、
N−(4−スルホブチル)−N−メチル−N,N−ジアリルアミンアンモニウムベタイン(MDABS)および
N,N−ジアリル−N−メチル−N−(2−スルホエチル)アンモニウムベタイン
からなる群より選択される、請求項1に記載のコポリマー。 - 前記官能性部分含有化合物または前記エチレン性不飽和官能性部分含有化合物が、ジアルキルアミノアルキルアクリレート類およびメタクリレート類の第四級塩類もしくは酸塩類、ジアルキルアミノアルキルアクリルアミド類およびメタクリルアミド類の第四級塩類もしくは酸塩類、N,N−ジアリルジアルキルアンモニウムハライド、N,N−ジメチルアミノエチルアクリレートメチルクロリド第四級塩(DMAEA.MCQ)およびジアリルジメチルアンモニウムクロリド(DADMAC)からなる群より選択される、請求項1に記載のコポリマー。
- 前記官能性部分含有化合物または前記エチレン性不飽和官能性部分含有化合物が、メチルアクリレート、エチルアクリレート、ブチルアクリレート、2−エチルヘキシルアクリレート、2−ヒドロキシエチルアクリレート、イソボルニルアクリレート、メチルメタクリレート、エチルメタクリレート、アクリロニトリル、アクリルアミド、メタクリルアミド、N−置換(メタ)アクリルアミド、酢酸ビニル、イソブチルビニルエーテル、スチレン、アルキルスチレン、ハロスチレン、N−ビニルピロリドン、塩化ビニルおよび塩化ビニリデンからなる群より選択される、請求項1に記載のコポリマー。
- 前記官能性部分含有化合物または前記エチレン性不飽和官能性部分含有化合物が、エチレングリコールジアクリレート、プロピレングリコールジアクリレート、ネオペンチルグリコールジアクリレート、ヘキサメチレングリコールジアクリレート、ビスフェノールAジアクリレート、4,4′−ビス(2−アクリロイルオキシエトキシ)ジフェニルプロパン、トリメチロールプロパントリアクリレート、ポリオキシエチレントリメチロールプロパントリアクリレート、ポリオキシプロピレントリメチロールプロパントリアクリレート、ペンタエリトリトールトリアクリレートまたはテトラアクリレート、ペンタエリトリトールジビニルエーテル、ビニルアクリレート、ジビニルベンゼン、コハク酸ジビニル、ジアリルフタレート、トリアリルホスフェート、トリアリルイソシアヌレートおよびトリス(2−アクリロイルエチル)イソシアヌレートからなる群より選択される、請求項1に記載のコポリマー。
- 前記官能性部分含有化合物または前記エチレン性不飽和官能性部分含有化合物が、アクリル化エポキシ樹脂、アクリル化ポリエーテル類、アクリル化ポリウレタン類、アクリル化ポリエステル類および不飽和ポリエステル樹脂からなる群より選択される、請求項1に記載のコポリマー。
- 前記官能性部分含有化合物または前記エチレン性不飽和官能性部分含有化合物が、エチレン性不飽和基を鎖中または側鎖中に含有するポリマーであって、前記ポリマーが、不飽和ポリエステル類、アクリル化ポリエステル類、ポリアミド類またはポリウレタン類およびそれらのコポリマー、ポリブタジエンまたはブタジエンコポリマー、ポリイソプレンまたはイソプレンコポリマーおよび(メタ)アクリル基を側鎖に含有するポリマーまたはコポリマーからなる群より選択される、請求項1に記載のコポリマー。
- 前記官能性部分含有化合物または前記エチレン性不飽和官能性部分含有化合物が、トリメチロールプロパントリアクリレート、トリメチロールエタントリアクリレート、トリメチロールプロパントリメタクリレート、トリメチロールエタントリメタクリレート、テトラメチレングリコールジメタクリレート、トリエチレングリコールジメタクリレート、テトラエチレングリコールジアクリレート、ペンタエリトリトールジアクリレート、ペンタエリトリトールトリアクリレート、ペンタエリトリトールテトラアクリレート、ジペンタエリトリトールジアクリレート、ジペンタエリトリトールトリアクリレート、ジペンタエリトリトールテトラアクリレート、ジペンタエリトリトールペンタアクリレート、ジペンタエリトリトールヘキサアクリレート、トリペンタエリトリトールオクタアクリレート、ペンタエリトリトールジメタクリレート、ペンタエリトリトールトリメタクリレート、ジペンタエリトリトールジメタクリレート、ジペンタエリトリトールテトラメタクリレート、トリペンタエリトリトールオクタメタクリレート、ペンタエリトリトールジイタコネート、ジペンタエリトリトールトリスイタコネート、ジペンタエリトリトールペンタイタコネート、ジペンタエリトリトールヘキサイタコネート、エチレングリコールジアクリレート、1,3−ブタンジオールジアクリレート、1,3−ブタンジオールジメタクリレート、1,4−ブタンジオールジイタコネート、ソルビトールトリアクリレート、ソルビトールテトラアクリレート、ペンタエリトリトール修飾トリアクリレート、ソルビトールテトラメタクリレート、ソルビトールペンタアクリレート、ソルビトールヘキサアクリレート、オリゴエステルアクリレート類およびメタクリレート類、グリセリンジ−およびトリアクリレート、1,4−シクロヘキサンジアクリレート、200〜1500の分子量を有するポリエチレングリコールのビスアクリレート類およびビスメタクリレート類、メチレンビスアクリルアミド、1,6−ヘキサメチレンビスアクリルアミド、ジエチレントリアミントリスメタクリルアミド、ビス(メタクリルアミドプロポキシ)エタン、β−メタクリルアミドエチルメタクリレートおよびN−〔(β−ヒドロキシエトキシ)エチル〕アクリルアミドからなる群より選択される、請求項1に記載のコポリマー。
- 化学線、熱および酸素の悪影響を受ける有機物質、ならびに有効な安定化量の、請求項1に記載のコポリマーを含む組成物。
- 支持材および1個以上のコーティング層をその上に含むインクジェット記録媒体システムであって、コーティング層の少なくとも1個が前記コポリマーを含む、請求項14に記載の組成物。
- 支持材のすぐ上にコーティングを含み、前記コーティングが前記コポリマーを含む、請求項15に記載の記録媒体システム。
- 支持材および少なくとも1個のインクジェットインク受容層を含み、前記受容層の1個以上が、前記コポリマーを含む、請求項15に記載の記録媒体システム。
- 前記受容層の1個以上が、ゼラチン、デンプン、スチレンブタジエンゴムラテックス、(メタ)アクリル酸エステル類のホモポリマーおよびコポリマー、ポリアクリル酸、ニトリルブタジエンゴムラテックス、ポリエチレングリコール、ポリアクリルアミド、ポリビニルアルコール、ポリウレタンラテックスおよび懸濁液、ビニルアルコール/酢酸ビニルコポリマー、ポリアルキルオキサゾリン、ポリフェニルオキサゾリン、ポリエチレンイミン類、メチルセルロース、ヒドロキシメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルメチルセルロース、ヒドロキシプロピルエチルセルロース、ヒドロキシエチルメチルセルロース、カルボキシメチルセルロース、ポリ(N−ビニルピロリドン)等のポリ(N−ビニル複素環)、直鎖状ポリ(N−ビニルアミド類)の(コ)ポリマー、ポリビニルアミンの(コ)ポリマーおよびカチオン性ポリマーからなる群より選択される少なくとも1種のポリマーをさらに含む、請求項17に記載の記録媒体システム。
- 前記支持材と前記インク受容層(単数又は複数)との間にバリヤー層をさらに含む、請求項17に記載の記録媒体システム。
- 支持材、少なくとも1個のインクジェットインク受容層、および保護コーティング層を含み、前記保護コーティング層が前記コポリマーを含む、請求項15に記載の記録媒体システム。
- 保護コーティング層を含む、請求項17に記載の記録媒体システム。
- 保護コーティング層を含み、前記保護コーティング層が前記コポリマーを含む、請求項17に記載の記録媒体システム。
- 保護コーティング層を含む、請求項19に記載の記録媒体システム。
- 保護コーティング層を含み、前記保護コーティング層が前記コポリマーを含む、請求項19に記載の記録媒体システム。
- インクジェットインクをさらに含む、請求項15に記載の記録媒体システム。
- 非晶質シリカ、結晶質シリカ、アルミニウム三水和物、カオリン、タルク、チョーク、ベントナイト、ゼオライト、ガラスビーズ、炭酸カルシウム、カリウムナトリウムアルミニウムケイ酸塩、けいそう土、アルミニウムのケイ酸塩、マグネシウムのケイ酸塩、二酸化チタン、ポリオレフィン類、ポリスチレン、ポリウレタン、デンプン、ポリ(メチルメタクリレート)およびポリテトラフルオロエチレンからなる群より選択される1種以上の顔料、充填剤または有機粒状物質をさらに含む、請求項15に記載の記録媒体システム。
- 界面活性剤、帯電防止剤、増粘剤、懸濁化剤、pH調節化合物、光安定剤、酸化防止剤、湿潤剤、静菌剤、架橋剤および蛍光増白剤からなる群より選択される1種以上の添加剤をさらに含む、請求項15に記載の記録媒体システム。
- 前記添加剤が、フェノール系酸化防止剤、ヒドロキシベンゾトリアゾール紫外線吸収剤、ベンゾフェノン紫外線吸収剤、ヒドロキシフェニルトリアジン紫外線吸収剤およびヒンダードアミン光安定剤からなる群より選択される、請求項27に記載の記録媒体システム。
- 前記支持材が、セルロースエステル類、酢酸セルロース、ポリエステル類、ポリスチレン、ポリエチレン、ポリ(酢酸ビニル)、ポリプロピレン、ポリカーボネート、ポリメタクリル酸ならびにメチルおよびエチルエステル類、ナイロン類等のポリアミド類、ポリ(エチレンテレフタレート)(PET)等のポリエステル類、ポリイミド類、ポリエーテル類、ポリ塩化ビニル、ポリテトラフルオロエチレン、ポリフッ化ビニリデンまたはポリスルホンアミド類を含む、請求項15に記載の記録媒体システム。
- 前記支持材が紙または透明なポリ(エチレンテレフタレート)である、請求項15に記載の記録媒体システム。
- 請求項15に記載のコポリマーを含む、インクジェットインク。
- インクジェット記録媒体システムを作製する方法であって、1個以上のコーティング層を支持材上に塗布することを含み、コーティング層の少なくとも1個が請求項15に記載のコポリマーを含む方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US34232401P | 2001-12-21 | 2001-12-21 | |
US42043902P | 2002-10-22 | 2002-10-22 | |
PCT/EP2002/014321 WO2003054030A2 (en) | 2001-12-21 | 2002-12-16 | Poly(vinylalcohol)-co-poly(vinylamine) polymers comprising functioal moieties |
Publications (2)
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JP2005513212A true JP2005513212A (ja) | 2005-05-12 |
JP4326957B2 JP4326957B2 (ja) | 2009-09-09 |
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Family Applications (1)
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JP2003554744A Expired - Fee Related JP4326957B2 (ja) | 2001-12-21 | 2002-12-16 | 官能性部分を含むポリ(ビニルアルコール)−コ−ポリ(ビニルアミン)ポリマー |
Country Status (13)
Country | Link |
---|---|
US (1) | US7572843B2 (ja) |
EP (1) | EP1456250B1 (ja) |
JP (1) | JP4326957B2 (ja) |
KR (1) | KR20040068328A (ja) |
CN (1) | CN1307209C (ja) |
AT (1) | ATE420900T1 (ja) |
AU (1) | AU2002366738A1 (ja) |
BR (1) | BR0215221A (ja) |
CA (1) | CA2467678A1 (ja) |
DE (1) | DE60230917D1 (ja) |
MX (1) | MXPA04006095A (ja) |
TW (1) | TW200301265A (ja) |
WO (1) | WO2003054030A2 (ja) |
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JP2012502164A (ja) * | 2008-09-12 | 2012-01-26 | セキスイ・スペシャルティ・ケミカルズ・アメリカ・エルエルシー | 向上したnvfコポリマープロセス |
JP2012524177A (ja) * | 2009-04-16 | 2012-10-11 | セラニーズ・インターナショナル・コーポレイション | 色堅牢度および仕上げ化合物 |
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- 2002-12-16 EP EP02805325A patent/EP1456250B1/en not_active Expired - Lifetime
- 2002-12-16 DE DE60230917T patent/DE60230917D1/de not_active Expired - Lifetime
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- 2002-12-16 BR BR0215221-5A patent/BR0215221A/pt not_active IP Right Cessation
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---|---|---|---|---|
JP2012502163A (ja) * | 2008-09-12 | 2012-01-26 | セキスイ・スペシャルティ・ケミカルズ・アメリカ・エルエルシー | 向上したバリア層 |
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JP2012251139A (ja) * | 2011-05-09 | 2012-12-20 | Mitsubishi Rayon Co Ltd | (メタ)アクリル酸エステルおよびその重合体 |
Also Published As
Publication number | Publication date |
---|---|
CN1606574A (zh) | 2005-04-13 |
DE60230917D1 (de) | 2009-03-05 |
AU2002366738A1 (en) | 2003-07-09 |
JP4326957B2 (ja) | 2009-09-09 |
US7572843B2 (en) | 2009-08-11 |
MXPA04006095A (es) | 2004-11-01 |
BR0215221A (pt) | 2004-12-14 |
KR20040068328A (ko) | 2004-07-30 |
TW200301265A (en) | 2003-07-01 |
CN1307209C (zh) | 2007-03-28 |
EP1456250A2 (en) | 2004-09-15 |
US20050020729A1 (en) | 2005-01-27 |
CA2467678A1 (en) | 2003-07-03 |
ATE420900T1 (de) | 2009-01-15 |
WO2003054030A2 (en) | 2003-07-03 |
WO2003054030A3 (en) | 2003-10-23 |
EP1456250B1 (en) | 2009-01-14 |
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