JP2005511869A5 - - Google Patents
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- Publication number
- JP2005511869A5 JP2005511869A5 JP2003552818A JP2003552818A JP2005511869A5 JP 2005511869 A5 JP2005511869 A5 JP 2005511869A5 JP 2003552818 A JP2003552818 A JP 2003552818A JP 2003552818 A JP2003552818 A JP 2003552818A JP 2005511869 A5 JP2005511869 A5 JP 2005511869A5
- Authority
- JP
- Japan
- Prior art keywords
- monomer
- weight water
- acrylamide
- molecular weight
- dimethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000178 monomer Substances 0.000 claims description 31
- 125000002091 cationic group Chemical group 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims 22
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 11
- 229960003237 betaine Drugs 0.000 claims 11
- 229920003169 water-soluble polymer Polymers 0.000 claims 11
- 238000000034 method Methods 0.000 claims 7
- 229920000642 polymer Polymers 0.000 claims 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 4
- 125000000129 anionic group Chemical group 0.000 claims 4
- 150000003839 salts Chemical group 0.000 claims 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 3
- 230000002776 aggregation Effects 0.000 claims 3
- -1 2-[(2-acryloylethyl) dimethylammonio] ethyl Chemical group 0.000 claims 2
- ZQRNRKASNNVFAJ-UHFFFAOYSA-N 3-[dimethyl(2-prop-2-enoyloxyethyl)azaniumyl]propane-1-sulfonate Chemical group [O-]S(=O)(=O)CCC[N+](C)(C)CCOC(=O)C=C ZQRNRKASNNVFAJ-UHFFFAOYSA-N 0.000 claims 2
- BCAIDFOKQCVACE-UHFFFAOYSA-N 3-[dimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azaniumyl]propane-1-sulfonate Chemical compound CC(=C)C(=O)OCC[N+](C)(C)CCCS([O-])(=O)=O BCAIDFOKQCVACE-UHFFFAOYSA-N 0.000 claims 2
- 238000005054 agglomeration Methods 0.000 claims 2
- WQHCGPGATAYRLN-UHFFFAOYSA-N chloromethane;2-(dimethylamino)ethyl prop-2-enoate Chemical group ClC.CN(C)CCOC(=O)C=C WQHCGPGATAYRLN-UHFFFAOYSA-N 0.000 claims 2
- 239000000945 filler Substances 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims 2
- 229920001223 polyethylene glycol Polymers 0.000 claims 2
- WUIJTQZXUURFQU-UHFFFAOYSA-N 1-methylsulfonylethene Chemical compound CS(=O)(=O)C=C WUIJTQZXUURFQU-UHFFFAOYSA-N 0.000 claims 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims 1
- UDXXYUDJOHIIDZ-UHFFFAOYSA-N 2-phosphonooxyethyl prop-2-enoate Chemical compound OP(O)(=O)OCCOC(=O)C=C UDXXYUDJOHIIDZ-UHFFFAOYSA-N 0.000 claims 1
- BLYGFIYCEOLGRR-UHFFFAOYSA-N 3-(propylamino)propane-1-sulfonic acid Chemical group CCCNCCCS(O)(=O)=O BLYGFIYCEOLGRR-UHFFFAOYSA-N 0.000 claims 1
- FYPNNJFHXFVZRS-UHFFFAOYSA-N CC(C([S+](CCCS([O-])(=O)=O)CCSC)=O)=C Chemical compound CC(C([S+](CCCS([O-])(=O)=O)CCSC)=O)=C FYPNNJFHXFVZRS-UHFFFAOYSA-N 0.000 claims 1
- APVPYUWVKOLDQF-UHFFFAOYSA-N C[N+](C)(CCC(C=C)=O)CP([O-])(O)=O Chemical group C[N+](C)(CCC(C=C)=O)CP([O-])(O)=O APVPYUWVKOLDQF-UHFFFAOYSA-N 0.000 claims 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 claims 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 1
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical group C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 claims 1
- 238000004220 aggregation Methods 0.000 claims 1
- 239000000440 bentonite Substances 0.000 claims 1
- 229910000278 bentonite Inorganic materials 0.000 claims 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims 1
- BHDFTVNXJDZMQK-UHFFFAOYSA-N chloromethane;2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound ClC.CN(C)CCOC(=O)C(C)=C BHDFTVNXJDZMQK-UHFFFAOYSA-N 0.000 claims 1
- CEJFYGPXPSZIID-UHFFFAOYSA-N chloromethylbenzene;2-(dimethylamino)ethyl prop-2-enoate Chemical compound ClCC1=CC=CC=C1.CN(C)CCOC(=O)C=C CEJFYGPXPSZIID-UHFFFAOYSA-N 0.000 claims 1
- 239000004927 clay Substances 0.000 claims 1
- 239000000701 coagulant Substances 0.000 claims 1
- 239000003623 enhancer Substances 0.000 claims 1
- 230000002708 enhancing effect Effects 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000011859 microparticle Substances 0.000 claims 1
- OKPYIWASQZGASP-UHFFFAOYSA-N n-(2-hydroxypropyl)-2-methylprop-2-enamide Chemical compound CC(O)CNC(=O)C(C)=C OKPYIWASQZGASP-UHFFFAOYSA-N 0.000 claims 1
- PNLUGRYDUHRLOF-UHFFFAOYSA-N n-ethenyl-n-methylacetamide Chemical compound C=CN(C)C(C)=O PNLUGRYDUHRLOF-UHFFFAOYSA-N 0.000 claims 1
- RQAKESSLMFZVMC-UHFFFAOYSA-N n-ethenylacetamide Chemical compound CC(=O)NC=C RQAKESSLMFZVMC-UHFFFAOYSA-N 0.000 claims 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 claims 1
- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 claims 1
- AAYRWMCIKCRHIN-UHFFFAOYSA-N propane-1-sulfonic acid;prop-2-enamide Chemical group NC(=O)C=C.CCCS(O)(=O)=O AAYRWMCIKCRHIN-UHFFFAOYSA-N 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000002002 slurry Substances 0.000 claims 1
- 159000000000 sodium salts Chemical class 0.000 claims 1
- FWFUWXVFYKCSQA-UHFFFAOYSA-M sodium;2-methyl-2-(prop-2-enoylamino)propane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(C)(C)NC(=O)C=C FWFUWXVFYKCSQA-UHFFFAOYSA-M 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- NRWCNEBHECBWRJ-UHFFFAOYSA-M trimethyl(propyl)azanium;chloride Chemical compound [Cl-].CCC[N+](C)(C)C NRWCNEBHECBWRJ-UHFFFAOYSA-M 0.000 claims 1
- OEIXGLMQZVLOQX-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical group [Cl-].C[N+](C)(C)CCCNC(=O)C=C OEIXGLMQZVLOQX-UHFFFAOYSA-N 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- NHYXMAKLBXBVEO-UHFFFAOYSA-N bromomethyl acetate Chemical compound CC(=O)OCBr NHYXMAKLBXBVEO-UHFFFAOYSA-N 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- SMJYMSAPPGLBAR-UHFFFAOYSA-N chloromethyl acetate Chemical compound CC(=O)OCCl SMJYMSAPPGLBAR-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 230000000269 nucleophilic effect Effects 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/023,370 US6709551B2 (en) | 2001-12-17 | 2001-12-17 | High molecular weight cationic and anionic polymers comprising zwitterionic monomers |
| PCT/US2002/037874 WO2003051941A1 (en) | 2001-12-17 | 2002-11-26 | High molecular weight cationic and anionic polymers comprising zwitterionic monomers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005511869A JP2005511869A (ja) | 2005-04-28 |
| JP2005511869A5 true JP2005511869A5 (https=) | 2006-02-09 |
| JP4190420B2 JP4190420B2 (ja) | 2008-12-03 |
Family
ID=21814690
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003552818A Expired - Lifetime JP4190420B2 (ja) | 2001-12-17 | 2002-11-26 | 水性懸濁液を凝集するための凝集剤、及び、製紙工程において凝集剤を用いる方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6709551B2 (https=) |
| EP (1) | EP1463767B1 (https=) |
| JP (1) | JP4190420B2 (https=) |
| KR (1) | KR20040075327A (https=) |
| CN (1) | CN1314716C (https=) |
| AU (1) | AU2002352927B2 (https=) |
| BR (1) | BR0214910B1 (https=) |
| DK (1) | DK1463767T3 (https=) |
| NO (1) | NO20043053L (https=) |
| NZ (1) | NZ532798A (https=) |
| WO (1) | WO2003051941A1 (https=) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2671973C (en) | 2002-04-09 | 2013-02-26 | Fpinnovations | Swollen starch compositions for use in papermaking |
| GB0402469D0 (en) * | 2004-02-04 | 2004-03-10 | Ciba Spec Chem Water Treat Ltd | Production of a fermentation product |
| GB0402470D0 (en) * | 2004-02-04 | 2004-03-10 | Ciba Spec Chem Water Treat Ltd | Production of a fermentation product |
| US8900641B2 (en) * | 2006-12-28 | 2014-12-02 | Nalco Company | Antimicrobial composition |
| JP4846617B2 (ja) * | 2007-02-20 | 2011-12-28 | ダイヤニトリックス株式会社 | 両性型高分子凝集剤およびこれを用いた汚泥処理方法 |
| WO2010050416A1 (ja) * | 2008-10-31 | 2010-05-06 | Mtアクアポリマー株式会社 | 水溶性高分子の溶解方法 |
| US8865632B1 (en) | 2008-11-10 | 2014-10-21 | Cesi Chemical, Inc. | Drag-reducing copolymer compositions |
| JP6080356B2 (ja) | 2009-03-30 | 2017-02-15 | テルモ株式会社 | 表面処理剤およびフィルター用濾材ならびに血液処理フィルター |
| JP5510996B2 (ja) * | 2009-11-09 | 2014-06-04 | ハイモ株式会社 | 製紙用薬剤及びそれを用いた抄紙方法 |
| KR101319930B1 (ko) * | 2011-04-20 | 2013-10-21 | 한국신발피혁연구원 | 리사이클이 가능한 가교형 탄성체 |
| CN102321213B (zh) * | 2011-06-10 | 2013-07-24 | 华南理工大学 | 一种水介质分散聚合制备含离子聚丙烯酰胺乳液的方法 |
| WO2013138156A1 (en) * | 2012-03-13 | 2013-09-19 | Isp Investments Inc. | Synthesis and application of high pressure high temperature fluid loss additive and rheology stabilizer |
| US10577531B2 (en) | 2013-03-14 | 2020-03-03 | Flotek Chemistry, Llc | Polymers and emulsions for use in oil and/or gas wells |
| JP6353057B2 (ja) * | 2013-09-17 | 2018-07-04 | ゼネラル・エレクトリック・カンパニイ | イオン交換ポリマー及びイオン交換ポリマーの製造方法 |
| US10385253B2 (en) * | 2014-07-15 | 2019-08-20 | Solvay Usa Inc. | Salt tolerant friction reducer |
| TWI666055B (zh) * | 2014-11-20 | 2019-07-21 | 美商恩特格林斯公司 | 接枝超高分子量聚乙烯微孔膜 |
| CN106632786B (zh) * | 2016-10-10 | 2019-01-08 | 长春工业大学 | 一种co2诱导原位电中和技术制备大粒径、单分散、高稳定聚合物乳液的方法 |
| CN107082844B (zh) * | 2017-06-01 | 2019-08-16 | 北京宏涛技术开发有限公司 | 用于选矿及尾矿处理的两性聚丙烯酰胺絮凝剂及制备方法 |
| CN107858860A (zh) * | 2017-10-19 | 2018-03-30 | 福建省晋江优兰发纸业有限公司 | 一种助留粘合剂在高强薄页纸中的应用方法 |
| CN115975106B (zh) * | 2022-12-26 | 2024-03-08 | 中国石油大学(华东) | 盐敏增黏聚合物驱油剂及其制备方法与应用 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL281971A (https=) | 1961-08-10 | |||
| US3269991A (en) | 1963-11-29 | 1966-08-30 | Union Carbide Corp | Ethylenically unsaturated sulfines and polymers thereof |
| US4392917A (en) | 1979-10-15 | 1983-07-12 | Diamond Shamrock Corporation | Amphoteric water-in-oil self-inverting polymer emulsion |
| US4363886A (en) | 1979-10-15 | 1982-12-14 | Diamond Shamrock Corporation | Preparation of amphoteric water-in-oil self-inverting polymer emulsion |
| US4330450A (en) | 1979-10-15 | 1982-05-18 | Diamond Shamrock Corporation | Amphoteric water-in-oil self-inverting polymer emulsion |
| US4822847A (en) | 1986-01-27 | 1989-04-18 | Exxon Research And Engineering Company | Method of increasing viscosity of an aqueous solution with a sulfo betaine polymer |
| JPH0788505B2 (ja) * | 1986-06-02 | 1995-09-27 | 三井東圧化学株式会社 | 石油三次回収薬剤 |
| JP2790497B2 (ja) * | 1989-08-03 | 1998-08-27 | 株式会社日本触媒 | 製紙用添加剤 |
| US5240982A (en) | 1990-06-13 | 1993-08-31 | National Starch And Chemical Investment Holding Corporation | Amphoteric surfactants and copolymerizable amphorteric surfactants for use in latex paint |
| JP2962816B2 (ja) * | 1990-11-27 | 1999-10-12 | 日東紡績株式会社 | 凝集剤 |
| JP2671249B2 (ja) * | 1992-11-27 | 1997-10-29 | 昭和電工株式会社 | 油中水型カチオン性エマルジョン、その製法および高分子凝集剤としての用途 |
| GB9226791D0 (en) | 1992-12-23 | 1993-02-17 | Biocompatibles Ltd | New materials |
| DE19512882A1 (de) | 1995-04-06 | 1996-10-10 | Basf Ag | Wäßrige Polymerisatdispersion |
| US5846558A (en) | 1996-03-19 | 1998-12-08 | Minnesota Mining And Manufacturing Company | Ionically conductive adhesives prepared from zwitterionic materials and medical devices using such adhesives |
| US6375932B1 (en) * | 1996-09-10 | 2002-04-23 | Mitsubishi Chemical Corporation | Hair cosmetic composition containing amine-oxide polymer |
| US5788866A (en) | 1996-09-19 | 1998-08-04 | Nalco Chemical Company | Copolymers formed from polymerization of N,N-diallyl-N-alkyl-N-(sulfoalkyl) ammonium betaine and their utility as calcium carbonate scale inhibitors |
| JP2000191733A (ja) * | 1997-12-08 | 2000-07-11 | Tosoh Corp | 共重合体、それよりなるカチオン性高分子凝集剤及びその製造方法 |
| JP4790125B2 (ja) * | 1998-11-13 | 2011-10-12 | バイオコンパテイブルズ・ユーケイ・リミテツド | 両性イオン性モノマー成分を含んでなるアニオン性−カチオン性ポリイオンコンプレックス |
| JP3977534B2 (ja) * | 1998-12-28 | 2007-09-19 | 三洋化成工業株式会社 | 高分子凝集剤 |
| US6361768B1 (en) * | 1998-12-29 | 2002-03-26 | Pmd Holdings Corp. | Hydrophilic ampholytic polymer |
| JP4221118B2 (ja) * | 1999-06-25 | 2009-02-12 | 三洋化成工業株式会社 | 高分子凝集剤 |
| US6313246B1 (en) * | 1999-07-07 | 2001-11-06 | Nalco Chemical Company | High molecular weight zwitterionic polymers |
| JP2001149703A (ja) * | 1999-09-13 | 2001-06-05 | Toagosei Co Ltd | パルプ又は製紙工業汚泥用両性高分子凝集剤、及びパルプ又は製紙工業汚泥の脱水方法 |
| JP4178687B2 (ja) * | 1999-09-21 | 2008-11-12 | 東亞合成株式会社 | 両性高分子凝集剤、及びそれを用いる汚泥の脱水方法 |
| JP2001120908A (ja) * | 1999-10-21 | 2001-05-08 | Kurita Water Ind Ltd | 高分子凝集剤及びその製造方法 |
-
2001
- 2001-12-17 US US10/023,370 patent/US6709551B2/en not_active Expired - Lifetime
-
2002
- 2002-11-26 EP EP02789887A patent/EP1463767B1/en not_active Expired - Lifetime
- 2002-11-26 NZ NZ532798A patent/NZ532798A/en unknown
- 2002-11-26 AU AU2002352927A patent/AU2002352927B2/en not_active Ceased
- 2002-11-26 JP JP2003552818A patent/JP4190420B2/ja not_active Expired - Lifetime
- 2002-11-26 DK DK02789887T patent/DK1463767T3/da active
- 2002-11-26 WO PCT/US2002/037874 patent/WO2003051941A1/en not_active Ceased
- 2002-11-26 KR KR10-2004-7009452A patent/KR20040075327A/ko not_active Abandoned
- 2002-11-26 CN CNB028252454A patent/CN1314716C/zh not_active Expired - Lifetime
- 2002-11-26 BR BRPI0214910-9A patent/BR0214910B1/pt active IP Right Grant
-
2004
- 2004-07-16 NO NO20043053A patent/NO20043053L/no not_active Application Discontinuation
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