JP2004534032A5 - - Google Patents
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- Publication number
- JP2004534032A5 JP2004534032A5 JP2002589437A JP2002589437A JP2004534032A5 JP 2004534032 A5 JP2004534032 A5 JP 2004534032A5 JP 2002589437 A JP2002589437 A JP 2002589437A JP 2002589437 A JP2002589437 A JP 2002589437A JP 2004534032 A5 JP2004534032 A5 JP 2004534032A5
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- copper
- butadiene
- catalyst composition
- complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 15
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 11
- -1 diolefin compound Chemical class 0.000 claims description 11
- 239000003054 catalyst Substances 0.000 claims description 10
- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 claims description 8
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 2
- 239000003085 diluting agent Substances 0.000 claims description 2
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000005669 hydrocyanation reaction Methods 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims description 2
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical group OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 claims description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 claims 1
- 239000012442 inert solvent Substances 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29029401P | 2001-05-11 | 2001-05-11 | |
| PCT/US2002/014607 WO2002092551A2 (en) | 2001-05-11 | 2002-05-10 | Copper-catalyzed vapor phase hydrocyanation of diolefinic compounds |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004534032A JP2004534032A (ja) | 2004-11-11 |
| JP2004534032A5 true JP2004534032A5 (enExample) | 2006-01-05 |
| JP4187534B2 JP4187534B2 (ja) | 2008-11-26 |
Family
ID=23115347
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002589437A Expired - Fee Related JP4187534B2 (ja) | 2001-05-11 | 2002-05-10 | 銅触媒を用いたジオレフィン化合物の気相接触ヒドロシアン化法 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6753440B2 (enExample) |
| EP (1) | EP1395547B1 (enExample) |
| JP (1) | JP4187534B2 (enExample) |
| BR (1) | BRPI0209588A2 (enExample) |
| CA (1) | CA2447051A1 (enExample) |
| CZ (1) | CZ20033001A3 (enExample) |
| DE (1) | DE60203286T2 (enExample) |
| MX (1) | MXPA03010214A (enExample) |
| MY (1) | MY124852A (enExample) |
| PL (1) | PL374445A1 (enExample) |
| RU (1) | RU2003135852A (enExample) |
| SG (1) | SG160228A1 (enExample) |
| SK (1) | SK13662003A3 (enExample) |
| TW (1) | TW580489B (enExample) |
| UA (1) | UA75918C2 (enExample) |
| WO (1) | WO2002092551A2 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6888032B2 (en) | 2002-08-02 | 2005-05-03 | Massachusetts Institute Of Technology | Copper-catalyzed formation of carbon-heteroatom and carbon-carbon bonds |
| FR2849027B1 (fr) * | 2002-12-23 | 2005-01-21 | Rhodia Polyamide Intermediates | Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques |
| FR2850966B1 (fr) * | 2003-02-10 | 2005-03-18 | Rhodia Polyamide Intermediates | Procede de fabrication de composes dinitriles |
| FR2854892B1 (fr) * | 2003-05-12 | 2005-06-24 | Rhodia Polyamide Intermediates | Procede de fabrication de dinitriles |
| FR2854891B1 (fr) | 2003-05-12 | 2006-07-07 | Rhodia Polyamide Intermediates | Procede de preparation de dinitriles |
| EP1948591A1 (en) * | 2005-10-18 | 2008-07-30 | INVISTA Technologies S.à.r.l. | Process of making 3-aminopentanenitrile |
| JP2009530278A (ja) * | 2006-03-17 | 2009-08-27 | インビスタ テクノロジーズ エス エイ アール エル | 塩基性添加剤による処理でトリ有機ホスファイトを精製する方法 |
| US7709674B2 (en) * | 2006-07-14 | 2010-05-04 | Invista North America S.A R.L | Hydrocyanation process with reduced yield losses |
| US7919646B2 (en) * | 2006-07-14 | 2011-04-05 | Invista North America S.A R.L. | Hydrocyanation of 2-pentenenitrile |
| US7880028B2 (en) * | 2006-07-14 | 2011-02-01 | Invista North America S.A R.L. | Process for making 3-pentenenitrile by hydrocyanation of butadiene |
| CN101687658B (zh) | 2007-05-14 | 2013-07-24 | 因温斯特技术公司 | 高效反应器和方法 |
| CN101952004B (zh) * | 2007-06-13 | 2015-08-12 | 因温斯特技术公司 | 改善己二腈质量的方法 |
| EP2229354B1 (en) * | 2008-01-15 | 2013-03-20 | Invista Technologies S.à.r.l. | Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile |
| WO2009091790A1 (en) * | 2008-01-15 | 2009-07-23 | Invista Technologies S.A.R.L. | Hydrocyanation of pentenenitriles |
| US20090240068A1 (en) * | 2008-03-19 | 2009-09-24 | Invista North America S.A.R.L. | Methods of making cyclododecatriene and methods of making laurolactone |
| US8247621B2 (en) * | 2008-10-14 | 2012-08-21 | Invista North America S.A.R.L. | Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols |
| CN102471218B (zh) * | 2009-08-07 | 2014-11-05 | 因温斯特技术公司 | 用于形成二酯的氢化并酯化 |
| EP2425915B1 (en) * | 2010-09-01 | 2015-12-02 | Directa Plus S.p.A. | Multi mode production complex for nano-particles of metal |
| EP2425916B1 (en) | 2010-09-01 | 2014-11-12 | Directa Plus S.p.A. | Multiple feeder reactor for the production of nanoparticles of metal |
| CN112892560B (zh) * | 2021-01-27 | 2022-10-25 | 南开大学 | 用于乙炔氢氯化反应的含氟弱配位阴离子改性铜基催化剂及其制备方法与应用 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2077260A (en) | 1935-05-22 | 1937-04-13 | Thomas D Stablow | Jar sealer |
| GB1084599A (en) | 1964-10-15 | 1967-09-27 | Asahi Chemical Ind | Process for the preparation of unsaturated aliphatic nitriles |
| US3578695A (en) | 1967-07-26 | 1971-05-11 | Standard Oil Co Ohio | Olefinic nitriles by the catalytic oxidation of olefins using hydrogen cyanide |
| US3869500A (en) | 1968-03-23 | 1975-03-04 | Asahi Chemical Ind | Process for the production of unsaturated aliphatic nitriles |
| US3547972A (en) | 1968-04-01 | 1970-12-15 | Du Pont | Addition of hydrogen cyanide to butadiene |
| US3584029A (en) | 1968-04-09 | 1971-06-08 | Asahi Chemical Ind | Process for the production of lower saturated aliphatic nitriles |
| US3766237A (en) | 1972-01-25 | 1973-10-16 | Du Pont | Hydrocyanation of olefins |
| US3865863A (en) | 1972-06-22 | 1975-02-11 | Hoffmann La Roche | 2-(Benzoyl)-3-dimethylaminoacrylonitriles |
| GB1565443A (en) | 1977-03-28 | 1980-04-23 | Ici Ltd | Manufacture of organic nitriles |
| GB1594694A (en) | 1977-04-04 | 1981-08-05 | Ici Ltd | Manufacture of organic nitriles by hydrocyanation of olefins |
| US5916837A (en) | 1994-01-12 | 1999-06-29 | E.I. Du Pont De Nemours And Company | Porous microcomposite of metal cation exchanged perfluorinated ion-exchanged polymer and network of metal oxide, silica or metal oxide and silica |
| US5449807A (en) | 1994-11-18 | 1995-09-12 | E. I. Du Pont De Nemours And Company | Catalyzed vapor phase hydrocyanation of diolefinic compounds |
-
2002
- 2002-05-08 US US10/140,736 patent/US6753440B2/en not_active Expired - Fee Related
- 2002-05-10 RU RU2003135852/04A patent/RU2003135852A/ru not_active Application Discontinuation
- 2002-05-10 EP EP02769693A patent/EP1395547B1/en not_active Expired - Lifetime
- 2002-05-10 PL PL02374445A patent/PL374445A1/xx unknown
- 2002-05-10 TW TW091109774A patent/TW580489B/zh not_active IP Right Cessation
- 2002-05-10 BR BRPI0209588A patent/BRPI0209588A2/pt not_active IP Right Cessation
- 2002-05-10 DE DE60203286T patent/DE60203286T2/de not_active Expired - Lifetime
- 2002-05-10 CA CA002447051A patent/CA2447051A1/en not_active Abandoned
- 2002-05-10 JP JP2002589437A patent/JP4187534B2/ja not_active Expired - Fee Related
- 2002-05-10 SK SK1366-2003A patent/SK13662003A3/sk unknown
- 2002-05-10 MX MXPA03010214A patent/MXPA03010214A/es active IP Right Grant
- 2002-05-10 WO PCT/US2002/014607 patent/WO2002092551A2/en not_active Ceased
- 2002-05-10 MY MYPI20021701A patent/MY124852A/en unknown
- 2002-05-10 CZ CZ20033001A patent/CZ20033001A3/cs unknown
- 2002-05-10 SG SG200800339-4A patent/SG160228A1/en unknown
- 2002-10-05 UA UA20031110119A patent/UA75918C2/uk unknown
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