JP2004531613A - 新規な高多用性の熱可塑性樹脂用核剤 - Google Patents
新規な高多用性の熱可塑性樹脂用核剤 Download PDFInfo
- Publication number
- JP2004531613A JP2004531613A JP2002591434A JP2002591434A JP2004531613A JP 2004531613 A JP2004531613 A JP 2004531613A JP 2002591434 A JP2002591434 A JP 2002591434A JP 2002591434 A JP2002591434 A JP 2002591434A JP 2004531613 A JP2004531613 A JP 2004531613A
- Authority
- JP
- Japan
- Prior art keywords
- nucleating agent
- present
- nucleating
- additive composition
- formulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002667 nucleating agent Substances 0.000 title claims abstract description 129
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 38
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 31
- 239000000203 mixture Substances 0.000 claims abstract description 122
- -1 peroxide compounds Chemical class 0.000 claims abstract description 87
- 238000002425 crystallisation Methods 0.000 claims abstract description 77
- 230000008025 crystallization Effects 0.000 claims abstract description 77
- 150000001875 compounds Chemical class 0.000 claims abstract description 69
- 229920000098 polyolefin Polymers 0.000 claims abstract description 69
- 238000009472 formulation Methods 0.000 claims abstract description 53
- 239000000654 additive Substances 0.000 claims abstract description 44
- 238000010899 nucleation Methods 0.000 claims abstract description 42
- 230000006911 nucleation Effects 0.000 claims abstract description 41
- 230000000996 additive effect Effects 0.000 claims abstract description 27
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 18
- 239000008116 calcium stearate Substances 0.000 claims abstract description 18
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 239000004743 Polypropylene Substances 0.000 claims description 61
- 229920001155 polypropylene Polymers 0.000 claims description 61
- 229920000642 polymer Polymers 0.000 claims description 51
- 238000012360 testing method Methods 0.000 claims description 42
- 229920001519 homopolymer Polymers 0.000 claims description 38
- 239000002516 radical scavenger Substances 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 17
- 238000001816 cooling Methods 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 9
- 239000000155 melt Substances 0.000 claims description 9
- 238000013329 compounding Methods 0.000 claims description 7
- 238000000605 extraction Methods 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 6
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 6
- 230000000052 comparative effect Effects 0.000 claims description 5
- 230000001747 exhibiting effect Effects 0.000 claims description 5
- 238000010998 test method Methods 0.000 claims description 5
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 239000002216 antistatic agent Substances 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 150000002892 organic cations Chemical class 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 239000004014 plasticizer Substances 0.000 claims description 4
- 239000004599 antimicrobial Substances 0.000 claims description 3
- 238000002835 absorbance Methods 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 125000005529 alkyleneoxy group Chemical group 0.000 claims 3
- 239000003063 flame retardant Substances 0.000 claims 3
- 150000002431 hydrogen Chemical class 0.000 claims 3
- 239000004611 light stabiliser Substances 0.000 claims 3
- 239000007788 liquid Substances 0.000 claims 3
- 239000008188 pellet Substances 0.000 claims 3
- 239000000049 pigment Substances 0.000 claims 3
- 239000004604 Blowing Agent Substances 0.000 claims 2
- 150000003973 alkyl amines Chemical class 0.000 claims 2
- 239000003242 anti bacterial agent Substances 0.000 claims 2
- 125000002837 carbocyclic group Chemical group 0.000 claims 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 1
- 230000003078 antioxidant effect Effects 0.000 claims 1
- 229910000389 calcium phosphate Inorganic materials 0.000 claims 1
- 239000001506 calcium phosphate Substances 0.000 claims 1
- 235000011010 calcium phosphates Nutrition 0.000 claims 1
- 239000004088 foaming agent Substances 0.000 claims 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 13
- 229920005992 thermoplastic resin Polymers 0.000 abstract description 10
- 125000002619 bicyclic group Chemical group 0.000 abstract description 7
- 239000004343 Calcium peroxide Substances 0.000 abstract description 2
- 238000007792 addition Methods 0.000 abstract description 2
- 235000019402 calcium peroxide Nutrition 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 32
- 150000003839 salts Chemical class 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 229920003023 plastic Polymers 0.000 description 9
- 239000013078 crystal Substances 0.000 description 8
- 238000001125 extrusion Methods 0.000 description 8
- 239000004033 plastic Substances 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 7
- 229920006395 saturated elastomer Polymers 0.000 description 7
- ZURRKVIQUKNLHF-UHFFFAOYSA-N 4,7,7-trimethylbicyclo[2.2.1]heptane-3-carboxylic acid Chemical compound C1CC2(C)C(C(O)=O)CC1C2(C)C ZURRKVIQUKNLHF-UHFFFAOYSA-N 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 6
- 229910052791 calcium Inorganic materials 0.000 description 6
- 229960005069 calcium Drugs 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- ZHROMWXOTYBIMF-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C ZHROMWXOTYBIMF-UHFFFAOYSA-M 0.000 description 5
- FMZUHGYZWYNSOA-VVBFYGJXSA-N (1r)-1-[(4r,4ar,8as)-2,6-diphenyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C([C@@H]1OC(O[C@@H]([C@@H]1O1)[C@H](O)CO)C=2C=CC=CC=2)OC1C1=CC=CC=C1 FMZUHGYZWYNSOA-VVBFYGJXSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 4
- 235000010234 sodium benzoate Nutrition 0.000 description 4
- 239000004299 sodium benzoate Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 229910052712 strontium Inorganic materials 0.000 description 4
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000004580 weight loss Effects 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 229910052788 barium Inorganic materials 0.000 description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000001739 density measurement Methods 0.000 description 3
- XVIQUULQQQZUDW-UHFFFAOYSA-L disodium;bicyclo[2.2.1]hept-2-ene-3,4-dicarboxylate Chemical compound [Na+].[Na+].C1CC2(C([O-])=O)C(C(=O)[O-])=CC1C2 XVIQUULQQQZUDW-UHFFFAOYSA-L 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229920001748 polybutylene Polymers 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 238000013112 stability test Methods 0.000 description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- LSPHULWDVZXLIL-UHFFFAOYSA-N Camphoric acid Natural products CC1(C)C(C(O)=O)CCC1(C)C(O)=O LSPHULWDVZXLIL-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 2
- 150000001241 acetals Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- LSPHULWDVZXLIL-QUBYGPBYSA-N camphoric acid Chemical compound CC1(C)[C@H](C(O)=O)CC[C@]1(C)C(O)=O LSPHULWDVZXLIL-QUBYGPBYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 229940087101 dibenzylidene sorbitol Drugs 0.000 description 2
- HMGUIQPKFUZDPV-UHFFFAOYSA-L disodium;bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate Chemical compound [Na+].[Na+].C1C2C=CC1C(C(=O)[O-])C2C([O-])=O HMGUIQPKFUZDPV-UHFFFAOYSA-L 0.000 description 2
- FXDGCBFGSXNGQD-UHFFFAOYSA-L disodium;bicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound [Na+].[Na+].C1CC2C(C([O-])=O)C(C(=O)[O-])C1C2 FXDGCBFGSXNGQD-UHFFFAOYSA-L 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 229920005672 polyolefin resin Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229910052701 rubidium Inorganic materials 0.000 description 2
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 238000007655 standard test method Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000003856 thermoforming Methods 0.000 description 2
- 239000000811 xylitol Substances 0.000 description 2
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 2
- 235000010447 xylitol Nutrition 0.000 description 2
- 229960002675 xylitol Drugs 0.000 description 2
- HDUNAIVOFOKALD-RLCYQCIGSA-N (1s,2s)-1-[(4r)-2-(4-methylphenyl)-1,3-dioxolan-4-yl]-2-[(4s)-2-(4-methylphenyl)-1,3-dioxolan-4-yl]ethane-1,2-diol Chemical compound C1=CC(C)=CC=C1C1O[C@@H]([C@@H](O)[C@H](O)[C@H]2OC(OC2)C=2C=CC(C)=CC=2)CO1 HDUNAIVOFOKALD-RLCYQCIGSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- 0 C[C@](*(C(*)(C1(C2(*)P)P)C(O)=O)C(O)=O)(C1(*)P)C2(P)P Chemical compound C[C@](*(C(*)(C1(C2(*)P)P)C(O)=O)C(O)=O)(C1(*)P)C2(P)P 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 238000005698 Diels-Alder reaction Methods 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 206010039897 Sedation Diseases 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000159 acid neutralizing agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Chemical group 0.000 description 1
- LLSDKQJKOVVTOJ-UHFFFAOYSA-L calcium chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Ca+2] LLSDKQJKOVVTOJ-UHFFFAOYSA-L 0.000 description 1
- 229940052299 calcium chloride dihydrate Drugs 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- MIHDGSOYBPAAHC-UHFFFAOYSA-L calcium;bicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound [Ca+2].C1CC2C(C([O-])=O)C(C(=O)[O-])C1C2 MIHDGSOYBPAAHC-UHFFFAOYSA-L 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000008395 clarifying agent Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- WRJINBFZTQADKT-UHFFFAOYSA-N cycloheptane-1,1-dicarboxylic acid Chemical compound OC(=O)C1(C(O)=O)CCCCCC1 WRJINBFZTQADKT-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000010102 injection blow moulding Methods 0.000 description 1
- 238000010103 injection stretch blow moulding Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 238000012417 linear regression Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 230000036280 sedation Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000012430 stability testing Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C61/00—Compounds having carboxyl groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C61/12—Saturated polycyclic compounds
- C07C61/125—Saturated polycyclic compounds having a carboxyl group bound to a condensed ring system
- C07C61/13—Saturated polycyclic compounds having a carboxyl group bound to a condensed ring system having two rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0083—Nucleating agents promoting the crystallisation of the polymer matrix
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
- C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/864,460 US6559211B2 (en) | 2001-05-23 | 2001-05-23 | Highly versatile thermoplastic nucleators |
| PCT/US2002/006418 WO2002094759A1 (en) | 2001-05-23 | 2002-03-04 | Novel highly versatile thermoplastic nucleators |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004531613A true JP2004531613A (ja) | 2004-10-14 |
| JP2004531613A5 JP2004531613A5 (enExample) | 2005-12-22 |
Family
ID=25343322
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002591434A Pending JP2004531613A (ja) | 2001-05-23 | 2002-03-04 | 新規な高多用性の熱可塑性樹脂用核剤 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US6559211B2 (enExample) |
| EP (1) | EP1389178A4 (enExample) |
| JP (1) | JP2004531613A (enExample) |
| CN (1) | CN1511134A (enExample) |
| WO (1) | WO2002094759A1 (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006117776A (ja) * | 2004-10-21 | 2006-05-11 | Sumitomo Chemical Co Ltd | ポリプロピレン系樹脂組成物 |
| JP2007509196A (ja) * | 2003-10-03 | 2007-04-12 | ミリケン・アンド・カンパニー | ビシクロ［２．２．１］ヘプタンジカルボン酸塩の改善型造核添加剤調製物 |
| JP2008516069A (ja) * | 2004-10-13 | 2008-05-15 | ミリケン・アンド・カンパニー | ２つの核剤を含む熱可塑性ポリマー組成物 |
| JP2012057113A (ja) * | 2010-09-13 | 2012-03-22 | Adeka Corp | 帯電防止性ポリオレフィン系樹脂組成物及びそれを用いた成形品 |
| WO2020054492A1 (ja) | 2018-09-11 | 2020-03-19 | 新日本理化株式会社 | ポリオレフィン系樹脂中での分散性に優れた脂環式ジカルボン酸の金属塩、該脂環式ジカルボン酸の金属塩の製造方法、該脂環式ジカルボン酸の金属塩を含むポリオレフィン系樹脂用の結晶核剤、該結晶核剤を含んでなる結晶核剤組成物、ポリオレフィン系樹脂組成物、並びに、ポリオレフィン系樹脂成形体 |
Families Citing this family (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6541554B2 (en) * | 2001-05-17 | 2003-04-01 | Milliken & Company | Low-shrink polypropylene fibers |
| US6656404B2 (en) * | 2001-05-17 | 2003-12-02 | Milliken & Company | Methods of making low-shrink polypropylene fibers |
| US6559211B2 (en) * | 2001-05-23 | 2003-05-06 | Milliken & Company | Highly versatile thermoplastic nucleators |
| US6998081B2 (en) * | 2001-12-21 | 2006-02-14 | Milliken & Company | Method of producing low-shrink polypropylene tape fibers |
| US20030134082A1 (en) * | 2001-12-21 | 2003-07-17 | Morin Brian G. | Carpet comprising a low-shrink backing of polypropylene tape fibers |
| US20030134118A1 (en) * | 2001-12-21 | 2003-07-17 | Morin Brian G. | Low-shrink polypropylene tape fibers |
| US20050197435A1 (en) * | 2002-06-14 | 2005-09-08 | Dotson Darin L. | Polymer additive compositions for bimolecular nucleation in thermoplastics |
| EP2261292B1 (en) | 2002-10-15 | 2014-07-23 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| US7550528B2 (en) * | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7700707B2 (en) * | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US20040084802A1 (en) * | 2002-11-02 | 2004-05-06 | Morin Brian G. | Method of producing low-shrink polypropylene tape fibers comprising high amounts of nucleating agents |
| US6887567B2 (en) * | 2002-11-02 | 2005-05-03 | Milliken & Company | Low-shrink polypropylene tape fibers comprising high amounts of nucleating agents |
| US6759124B2 (en) | 2002-11-16 | 2004-07-06 | Milliken & Company | Thermoplastic monofilament fibers exhibiting low-shrink, high tenacity, and extremely high modulus levels |
| US20040096639A1 (en) * | 2002-11-16 | 2004-05-20 | Morin Brian G. | Uniform production methods for colored and non-colored polypropylene fibers |
| US6863976B2 (en) | 2002-11-16 | 2005-03-08 | Milliken & Company | Polypropylene monofilament and tape fibers exhibiting certain creep-strain characteristics and corresponding crystalline configurations |
| US7041368B2 (en) * | 2002-11-17 | 2006-05-09 | Milliken & Company | High speed spinning procedures for the manufacture of high denier polypropylene fibers and yarns |
| US20040152815A1 (en) * | 2002-11-17 | 2004-08-05 | Morin Brian G. | High speed spinning procedures for the manufacture of low denier polypropylene fibers and yarns |
| US20040096621A1 (en) * | 2002-11-17 | 2004-05-20 | Dai Weihua Sonya | High denier textured polypropylene fibers and yarns |
| US20050048281A1 (en) * | 2003-08-30 | 2005-03-03 | Royer Joseph R. | Thermoplastic fibers exhibiting durable high color strength characteristics |
| US20050046065A1 (en) * | 2003-08-30 | 2005-03-03 | Cowan Martin E. | Thermoplastic fibers exhibiting durable high color strength characteristics |
| US6849330B1 (en) | 2003-08-30 | 2005-02-01 | Milliken & Company | Thermoplastic fibers exhibiting durable high color strength characteristics |
| US6946507B2 (en) * | 2003-10-03 | 2005-09-20 | Milliken & Company | Nucleating additive formulations of bicyclo[2.2.1]heptane dicarboxylate salts |
| US6936650B2 (en) * | 2003-10-03 | 2005-08-30 | Milliken & Company | Nucleating additive formulations of bicyclo[2.2.1]heptane dicarboxylate salts |
| US20070123620A1 (en) * | 2003-12-08 | 2007-05-31 | Huntsman Polymers Corporation | Radiation resistant polypropylene useful in medical applications |
| CA2550009C (en) * | 2003-12-30 | 2013-05-14 | Metabolix, Inc. | Nucleating agents |
| US20060069209A1 (en) * | 2004-09-29 | 2006-03-30 | Klosiewicz Daniel W | Heat stable functionalized polyolefin emulsions |
| CA2592026C (en) * | 2004-12-22 | 2010-11-30 | Advantage Polymers, Llc | Thermoplastic compositions and method of use thereof for molded articles |
| US20060142452A1 (en) * | 2004-12-23 | 2006-06-29 | Sonya Wolters | Polyolfins, methods of making polyolefins and related plastic additive compositions |
| US7871709B2 (en) | 2005-09-07 | 2011-01-18 | Equistar Chemicals, Lp | Modified tie-layer compositions and improved clarity multi-layer barrier films produced therewith |
| US7786203B2 (en) * | 2005-09-16 | 2010-08-31 | Milliken & Company | Polymer compositions comprising nucleating or clarifying agents and articles made using such compositions |
| US20080171834A1 (en) * | 2006-12-19 | 2008-07-17 | Kien-Mun Tang | Thermoplastic and nucleating agent compositions and methods |
| US8436085B2 (en) * | 2007-03-14 | 2013-05-07 | Equistar Chemicals, Lp | Barrier properties of substantially linear HDPE film with nucleating agents |
| RU2485146C2 (ru) * | 2007-12-31 | 2013-06-20 | Бриджстоун Корпорейшн | Способ получения полимерной композиции и полимерная композиция |
| ATE510880T1 (de) * | 2008-08-05 | 2011-06-15 | Bridgestone Corp | Verfahren zur verbesserung der kaltflussbeständigkeit von polymeren |
| US9187627B2 (en) * | 2008-10-23 | 2015-11-17 | Equistar Chemicals, Lp | Polyethylene having faster crystallization rate and improved environmental stress cracking resistance |
| US9475930B2 (en) | 2012-08-17 | 2016-10-25 | Metabolix, Inc. | Biobased rubber modifiers for polymer blends |
| CN110105623B (zh) | 2012-12-21 | 2021-05-25 | 美利肯公司 | 添加剂组合物和其使用方法 |
| WO2014194220A1 (en) | 2013-05-30 | 2014-12-04 | Metabolix, Inc. | Recyclate blends |
| US9580575B2 (en) | 2013-09-23 | 2017-02-28 | Milliken & Company | Polyethylene articles |
| EP3122817B1 (en) | 2014-03-27 | 2020-07-29 | CJ CheilJedang Corporation | Highly filled polymer systems |
| US9994692B2 (en) | 2014-11-25 | 2018-06-12 | Milliken & Company | Process for extruding polypropylene |
| US9994695B2 (en) | 2014-11-25 | 2018-06-12 | Milliken & Company | Process for extruding polypropylene |
| ES2680625T3 (es) | 2015-06-23 | 2018-09-10 | Omya International Ag | Producto material de carga tratado superficialmente para alfa-nucleación de poliolefinas |
| WO2017039953A1 (en) | 2015-08-31 | 2017-03-09 | Dow Global Technologies Llc | Resins for use as tie layer in multilayer structure and multilayer structures comprising the same |
| EP3293212B1 (en) * | 2016-09-12 | 2023-02-22 | Thai Polyethylene Co., Ltd. | Polymer composition for container closures |
| US11091619B2 (en) | 2017-12-15 | 2021-08-17 | Braskem America, Inc. | High molecular weight polymers having improved crystallization |
| DE102018001471B3 (de) | 2018-02-23 | 2019-03-28 | Daimler Ag | Elektrischer Antrieb für ein Kraftfahrzeug, insbesondere für einen Kraftwagen |
| TWI798764B (zh) | 2020-08-03 | 2023-04-11 | 美商美力肯及公司 | 熱塑性聚合物組成物及其成型方法 |
| TWI790693B (zh) | 2020-08-03 | 2023-01-21 | 美商美力肯及公司 | 熱塑性聚合物組成物及由其製造薄膜之方法 |
| TW202229448A (zh) | 2021-01-26 | 2022-08-01 | 美商美力肯及公司 | 熱塑性聚合物組成物以及由其製造物件及薄膜之方法 |
Family Cites Families (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL269334A (enExample) * | 1960-12-21 | |||
| US3234233A (en) * | 1962-07-27 | 1966-02-08 | Rexall Drug Chemical | Substituted bicycloheptane-2, 3-dicarboximides |
| US3201363A (en) * | 1962-09-20 | 1965-08-17 | Hercules Powder Co Ltd | Extrusion aids for polyethylene |
| US3367926A (en) * | 1964-03-25 | 1968-02-06 | Dow Chemical Co | Modification of crystalline structure of crystallizable high polymers |
| US3408341A (en) | 1964-10-21 | 1968-10-29 | Eastman Kodak Co | Crystallinity promoters |
| US3320267A (en) * | 1964-10-21 | 1967-05-16 | Mcneilab Inc | 2, 3-dicarboxylic acid and derivatives of norbornanes and the corresponding norbornenes |
| US3517086A (en) | 1966-01-31 | 1970-06-23 | Sumitomo Chemical Co | Nucleated blend of polypropylene,polyethylene,and ethylene propylene copolymer |
| GB1204729A (en) * | 1967-12-28 | 1970-09-09 | Shell Int Research | Process for the improvement of synthetic diene polymers |
| GB1318520A (en) * | 1969-11-27 | 1973-05-31 | Ici Ltd | Chemical compositions |
| DE2002489A1 (de) | 1970-01-21 | 1971-07-29 | Huels Chemische Werke Ag | Kristallisationsfaehige thermoplastische Massen |
| JPS531319B1 (enExample) * | 1971-03-16 | 1978-01-18 | ||
| US3829450A (en) * | 1972-11-01 | 1974-08-13 | Universal Oil Prod Co | Polyhalosubstituted polyhydropolycyclicdicarboxylic acid and anhydride |
| US3873643A (en) * | 1972-12-18 | 1975-03-25 | Chemplex Co | Graft copolymers of polyolefins and cyclic acid and acid anhydride monomers |
| US3882194A (en) * | 1973-01-26 | 1975-05-06 | Chemplex Co | Cografted copolymers of a polyolefin, an acid or acid anhydride and an ester monomer |
| US3941746A (en) * | 1973-12-28 | 1976-03-02 | Ciba-Geigy Corporation | Containing hindered phenolic norbornane-2,3-dicarboximides stabilized compositions |
| US3933779A (en) * | 1974-02-21 | 1976-01-20 | Fine Organics Inc. | Antistatic polymer blend |
| US3954913A (en) * | 1975-01-06 | 1976-05-04 | The Standard Oil Company | Stabilized nitrile polymers |
| JPS51133400A (en) * | 1975-05-15 | 1976-11-19 | Japan Synthetic Rubber Co Ltd | A process for manufacturing animpact resistant thermoplastic resin |
| CH615911A5 (enExample) * | 1975-06-18 | 1980-02-29 | Ciba Geigy Ag | |
| JPS58445B2 (ja) * | 1975-10-17 | 1983-01-06 | 三井化学株式会社 | 熱可塑性エラストマ−の製造方法 |
| JPS5340760A (en) | 1976-09-28 | 1978-04-13 | Teijin Ltd | Preparation of unsaturated imide esters |
| US4200279A (en) * | 1978-04-05 | 1980-04-29 | Lambert Lloyd J Jr | Leg extension, leg curl, hip, thigh, back and buttocks machine |
| US4240626A (en) * | 1978-11-08 | 1980-12-23 | Lambert Lloyd J Jr | Abdominal waist machine |
| JPS5718682A (en) | 1980-07-08 | 1982-01-30 | Mitsui Toatsu Chem Inc | Preparation of bis p-ethylbenzylidene sorbitol |
| JPS581736A (ja) | 1981-06-25 | 1983-01-07 | Adeka Argus Chem Co Ltd | ポリオレフイン系樹脂組成物 |
| US4452942A (en) * | 1982-02-19 | 1984-06-05 | Chemplex Company | Adhesive blends containing anacid or anhydride grafted LLDPE |
| JPS58160343A (ja) | 1982-03-17 | 1983-09-22 | Nippon Ester Co Ltd | ポリエステル組成物 |
| DE3215911A1 (de) * | 1982-04-29 | 1983-11-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur behandlung von (co)polymerisaten zur entfernung von restmonomeren |
| US4500089A (en) * | 1983-01-20 | 1985-02-19 | Nautilus Sports/Medical Industries, Inc. | Weight lifting lower back exercising machine |
| US4590129A (en) * | 1983-06-13 | 1986-05-20 | Ciba-Geigy Corporation | Fluoroaliphatic-thio,-sulfinyl, or sulfonyl substituted bicycloaliphatic amic acid amine salts, and compositions and use thereof |
| US4476184A (en) * | 1983-08-09 | 1984-10-09 | The Boeing Company | Thermally stable polysulfone compositions for composite structures |
| JPS6117834A (ja) | 1984-07-04 | 1986-01-25 | Matsushita Electric Ind Co Ltd | ガステ−ブル |
| US4778837A (en) * | 1985-05-03 | 1988-10-18 | American Cyanamid Company | Low basicity hindered amine light stabilizers |
| US4704421A (en) * | 1985-08-06 | 1987-11-03 | El Paso Products Company | Nucleation of propylene polymers |
| US4739017A (en) * | 1986-06-06 | 1988-04-19 | The Dow Chemical Company | Retro Diels Alder assisted polymer grafting process |
| US4801637A (en) * | 1986-06-18 | 1989-01-31 | Shell Oil Company | Nucleation process for inducing crystallization in poly(alpha olefins) |
| EP0267695B1 (en) | 1986-11-11 | 1992-01-08 | Imperial Chemical Industries Plc | Composition comprising a carboxylic acid and an amine |
| JPH01180514A (ja) | 1988-01-13 | 1989-07-18 | Hitachi Chem Co Ltd | 眼鏡レンズ用樹脂組成物及び眼鏡レンズ |
| EP0336573B1 (en) * | 1988-03-29 | 1995-07-05 | Cytec Technology Corp. | Composition and use |
| US5549534A (en) * | 1989-02-07 | 1996-08-27 | Parviainen; Arno | Spine rehabilitation apparatus |
| JPH0826485B2 (ja) | 1989-08-11 | 1996-03-13 | 帝人株式会社 | 香りを有する芯鞘型中実複合短繊維 |
| US5135975A (en) * | 1989-09-20 | 1992-08-04 | Milliken Research Corporation | Bis(3,4-dialkylbenzylidene) sorbitol acetals and compositions containing same |
| US5049605A (en) | 1989-09-20 | 1991-09-17 | Milliken Research Corporation | Bis(3,4-dialkylbenzylidene) sorbitol acetals and compositions containing same |
| FR2656620B1 (fr) | 1990-01-04 | 1992-04-24 | M & T Chemicals Inc | Composition de resine synthetique polyolefinique contenant un agent nucleant. |
| US5015372A (en) * | 1990-02-07 | 1991-05-14 | The United States Of America As Represented By The Secretary Of The Navy | Toxin containing perforated antifouling polymer nozzle grommet |
| JPH05139460A (ja) | 1991-11-15 | 1993-06-08 | Daito Nitto Kk | 徐放性薬剤封入袋 |
| JP3046428B2 (ja) | 1991-12-05 | 2000-05-29 | 旭電化工業株式会社 | 結晶性合成樹脂組成物 |
| JP3226333B2 (ja) | 1992-06-29 | 2001-11-05 | 富士通株式会社 | 弾性表面波素子 |
| JP3401888B2 (ja) | 1993-12-20 | 2003-04-28 | 新日本理化株式会社 | ポリオレフィン系樹脂組成物 |
| GB9411800D0 (en) | 1994-06-13 | 1994-08-03 | Sandoz Ltd | Organic compounds |
| US5468793A (en) * | 1994-07-25 | 1995-11-21 | Wico Corporation | Plastic compositions with antistatic properties |
| US5922793A (en) | 1996-12-27 | 1999-07-13 | Minnesota Mining And Manufacturing Company | Modifying agents for polyolefins |
| US5929146A (en) | 1996-12-27 | 1999-07-27 | Minnesota Mining And Manufacturing Company | Modifying agents for polyolefins |
| US5981636A (en) | 1996-12-27 | 1999-11-09 | 3M Innovative Properties Company | Modifying agents for polyolefins |
| US6465551B1 (en) * | 2001-03-24 | 2002-10-15 | Milliken & Company | Bicyclo[2.2.1]heptane dicarboxylate salts as polyolefin nucleators |
| US6534574B1 (en) * | 2001-03-24 | 2003-03-18 | Milliken & Company | Highly nucleated thermoplastic articles |
| US6559211B2 (en) * | 2001-05-23 | 2003-05-06 | Milliken & Company | Highly versatile thermoplastic nucleators |
| US6583206B2 (en) * | 2001-06-05 | 2003-06-24 | Milliken & Company | Saturated [2.2.2] dicarboxylate salt thermoplastic nucleators and thermoplastic compositions thereof |
| US6521685B1 (en) * | 2001-07-03 | 2003-02-18 | Milliken & Company | Clarifying agent formulations for thermoplastics exhibiting very high nucleation efficacy |
| US6585819B2 (en) * | 2001-08-11 | 2003-07-01 | Milliken & Company | Clarified thermoplastics exhibiting very high nucleation efficacy |
-
2001
- 2001-05-23 US US09/864,460 patent/US6559211B2/en not_active Expired - Lifetime
-
2002
- 2002-03-04 CN CNA028103300A patent/CN1511134A/zh active Pending
- 2002-03-04 WO PCT/US2002/006418 patent/WO2002094759A1/en not_active Ceased
- 2002-03-04 JP JP2002591434A patent/JP2004531613A/ja active Pending
- 2002-03-04 EP EP02725063A patent/EP1389178A4/en not_active Withdrawn
- 2002-11-05 US US10/288,040 patent/US7094820B2/en not_active Expired - Lifetime
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007509196A (ja) * | 2003-10-03 | 2007-04-12 | ミリケン・アンド・カンパニー | ビシクロ［２．２．１］ヘプタンジカルボン酸塩の改善型造核添加剤調製物 |
| JP2008516069A (ja) * | 2004-10-13 | 2008-05-15 | ミリケン・アンド・カンパニー | ２つの核剤を含む熱可塑性ポリマー組成物 |
| JP2006117776A (ja) * | 2004-10-21 | 2006-05-11 | Sumitomo Chemical Co Ltd | ポリプロピレン系樹脂組成物 |
| JP2012057113A (ja) * | 2010-09-13 | 2012-03-22 | Adeka Corp | 帯電防止性ポリオレフィン系樹脂組成物及びそれを用いた成形品 |
| WO2020054492A1 (ja) | 2018-09-11 | 2020-03-19 | 新日本理化株式会社 | ポリオレフィン系樹脂中での分散性に優れた脂環式ジカルボン酸の金属塩、該脂環式ジカルボン酸の金属塩の製造方法、該脂環式ジカルボン酸の金属塩を含むポリオレフィン系樹脂用の結晶核剤、該結晶核剤を含んでなる結晶核剤組成物、ポリオレフィン系樹脂組成物、並びに、ポリオレフィン系樹脂成形体 |
| KR20210057119A (ko) | 2018-09-11 | 2021-05-20 | 신닛폰 리카 가부시키가이샤 | 폴리올레핀계 수지 중에서의 분산성이 우수한 지환식 디카복실산의 금속염, 당해 지환식 디카복실산의 금속염의 제조 방법, 당해 지환식 디카복실산의 금속염을 포함하는 폴리올레핀계 수지용 결정핵제, 당해 결정핵제를 포함하여 이루어지는 결정핵제 조성물, 폴리올레핀계 수지 조성물, 그리고, 폴리올레핀계 수지 성형체 |
| US11667599B2 (en) | 2018-09-11 | 2023-06-06 | New Japan Chemical Co., Ltd. | Metal salt of an alicyclic dicarboxylic acid having excellent dispersibility in polyolefin resin, production method for said metal salt of an alicyclic dicarboxylic acid, crystal nucleating agent for polyolefin resin containing said metal salt of an alicyclic dicarboxylic acid, crystal nucleating agent composition containing said crystal nucleating agent, polyolefin resin composition, and polyolefin resin molded article |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1389178A1 (en) | 2004-02-18 |
| US20030096895A1 (en) | 2003-05-22 |
| US6559211B2 (en) | 2003-05-06 |
| CN1511134A (zh) | 2004-07-07 |
| EP1389178A4 (en) | 2006-03-01 |
| US20030008956A1 (en) | 2003-01-09 |
| WO2002094759A1 (en) | 2002-11-28 |
| US7094820B2 (en) | 2006-08-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US7094820B2 (en) | Polymer additive compositions comprising highly versatile thermoplastic nucleators | |
| US6465551B1 (en) | Bicyclo[2.2.1]heptane dicarboxylate salts as polyolefin nucleators | |
| EP1379368B1 (en) | Metal salts of hexahydrophthalic acid as nucleating additives for crystalline thermoplastics | |
| JP3958215B2 (ja) | ヘキサヒドロフタル酸シス−２ナトリウム塩組成物およびその組成物を含んでなる有核ポリマー | |
| US6585819B2 (en) | Clarified thermoplastics exhibiting very high nucleation efficacy | |
| EP1409579B1 (en) | Clarifying agent formulations for thermoplastics exhibiting very high nucleation efficacy | |
| US7129323B2 (en) | Bimolecular nucleation methods for thermoplastics | |
| US6583206B2 (en) | Saturated [2.2.2] dicarboxylate salt thermoplastic nucleators and thermoplastic compositions thereof | |
| US6599968B2 (en) | Thermoplastic nucleating compounds | |
| US20050197435A1 (en) | Polymer additive compositions for bimolecular nucleation in thermoplastics |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20040830 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20040830 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20060828 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20061031 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20070130 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20070206 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20071002 |