JP2004530035A5 - - Google Patents
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- Publication number
- JP2004530035A5 JP2004530035A5 JP2003503699A JP2003503699A JP2004530035A5 JP 2004530035 A5 JP2004530035 A5 JP 2004530035A5 JP 2003503699 A JP2003503699 A JP 2003503699A JP 2003503699 A JP2003503699 A JP 2003503699A JP 2004530035 A5 JP2004530035 A5 JP 2004530035A5
- Authority
- JP
- Japan
- Prior art keywords
- nanocomposite
- rubber
- group
- clay
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000002114 nanocomposite Substances 0.000 claims description 70
- 239000003795 chemical substances by application Substances 0.000 claims description 37
- 239000004927 clay Substances 0.000 claims description 22
- -1 thiosulfate compound Chemical class 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 229920001971 elastomer Polymers 0.000 claims description 10
- 239000005060 rubber Substances 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 9
- 125000003172 aldehyde group Chemical group 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 6
- 125000002843 carboxylic acid group Chemical group 0.000 claims description 6
- 125000000524 functional group Chemical group 0.000 claims description 6
- 125000002081 peroxide group Chemical group 0.000 claims description 6
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 6
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical group [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 5
- 150000003973 alkyl amines Chemical class 0.000 claims 9
- 239000003760 tallow Substances 0.000 claims 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 6
- 150000001336 alkenes Chemical class 0.000 claims 6
- 125000000217 alkyl group Chemical group 0.000 claims 6
- 229920005557 bromobutyl Polymers 0.000 claims 6
- 229920002857 polybutadiene Polymers 0.000 claims 6
- 150000001412 amines Chemical class 0.000 claims 4
- 229910021529 ammonia Inorganic materials 0.000 claims 4
- 229920005549 butyl rubber Polymers 0.000 claims 4
- 229920001577 copolymer Polymers 0.000 claims 4
- JBAUPCNQUQGXJT-UHFFFAOYSA-N 1-ethenyl-4-methylbenzene;2-methylprop-1-ene Chemical class CC(C)=C.CC1=CC=C(C=C)C=C1 JBAUPCNQUQGXJT-UHFFFAOYSA-N 0.000 claims 3
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims 3
- 244000043261 Hevea brasiliensis Species 0.000 claims 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical class CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 3
- 229920000459 Nitrile rubber Polymers 0.000 claims 3
- 229920002367 Polyisobutene Polymers 0.000 claims 3
- 229920005683 SIBR Polymers 0.000 claims 3
- 235000021355 Stearic acid Nutrition 0.000 claims 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 3
- VLLYOYVKQDKAHN-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene Chemical compound C=CC=C.CC(=C)C=C VLLYOYVKQDKAHN-UHFFFAOYSA-N 0.000 claims 3
- 239000006229 carbon black Substances 0.000 claims 3
- 229920005556 chlorobutyl Polymers 0.000 claims 3
- NAPSCFZYZVSQHF-UHFFFAOYSA-N dimantine Chemical compound CCCCCCCCCCCCCCCCCCN(C)C NAPSCFZYZVSQHF-UHFFFAOYSA-N 0.000 claims 3
- VFLWKHBYVIUAMP-UHFFFAOYSA-N n-methyl-n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCN(C)CCCCCCCCCCCCCCCCCC VFLWKHBYVIUAMP-UHFFFAOYSA-N 0.000 claims 3
- 229920003052 natural elastomer Polymers 0.000 claims 3
- 229920001194 natural rubber Polymers 0.000 claims 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims 3
- 229920001084 poly(chloroprene) Polymers 0.000 claims 3
- 229920001195 polyisoprene Polymers 0.000 claims 3
- 229920000909 polytetrahydrofuran Polymers 0.000 claims 3
- 229920002379 silicone rubber Polymers 0.000 claims 3
- 239000008117 stearic acid Substances 0.000 claims 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims 3
- 239000011593 sulfur Substances 0.000 claims 3
- 229910052717 sulfur Inorganic materials 0.000 claims 3
- 239000011701 zinc Substances 0.000 claims 3
- 229910052725 zinc Inorganic materials 0.000 claims 3
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims 3
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 1
- 125000005210 alkyl ammonium group Chemical group 0.000 claims 1
- 125000000746 allylic group Chemical group 0.000 claims 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 claims 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 4
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 2
- 229940117916 cinnamic aldehyde Drugs 0.000 description 2
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000010954 inorganic particle Substances 0.000 description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 description 2
- WTVOIJLLMIOCPT-UHFFFAOYSA-N S1(=S)(=O)OCCCCCCO1.[Na] Chemical compound S1(=S)(=O)OCCCCCCO1.[Na] WTVOIJLLMIOCPT-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29791501P | 2001-06-13 | 2001-06-13 | |
| US60/297,915 | 2001-06-13 | ||
| PCT/US2002/016797 WO2002100936A1 (en) | 2001-06-13 | 2002-05-29 | Low permeability nanocomposites |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004530035A JP2004530035A (ja) | 2004-09-30 |
| JP2004530035A5 true JP2004530035A5 (https=) | 2006-01-05 |
| JP5002112B2 JP5002112B2 (ja) | 2012-08-15 |
Family
ID=23148255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003503699A Expired - Fee Related JP5002112B2 (ja) | 2001-06-13 | 2002-05-29 | 低透過性ナノ複合物 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7491764B2 (https=) |
| EP (1) | EP1401933B1 (https=) |
| JP (1) | JP5002112B2 (https=) |
| CN (1) | CN1268673C (https=) |
| AT (1) | ATE335784T1 (https=) |
| CA (1) | CA2449075C (https=) |
| DE (1) | DE60213812T2 (https=) |
| RU (1) | RU2309167C2 (https=) |
| WO (1) | WO2002100936A1 (https=) |
Families Citing this family (76)
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| US7714043B2 (en) | 2000-10-18 | 2010-05-11 | Exxonmobil Chemical Patents Inc. | Tire innerliners having improved cold temperature properties |
| RU2346961C1 (ru) * | 2001-06-08 | 2009-02-20 | Эксонмобил Кемикэл Пейтентс Инк. | Нанокомпозиты с низкой проницаемостью |
| US6956084B2 (en) | 2001-10-04 | 2005-10-18 | Bridgestone Corporation | Nano-particle preparation and applications |
| US7576155B2 (en) | 2002-12-18 | 2009-08-18 | Bridgestone Corporation | Method for clay exfoliation, compositions therefore, and modified rubber containing same |
| EP1581588B1 (de) | 2003-01-08 | 2007-02-28 | Süd-Chemie Ag | Zusammensetzung auf der basis präexfolierter nanoclays und ihre verwendung |
| US6875818B2 (en) | 2003-01-16 | 2005-04-05 | Bridgestone Corporation | Polymer nano-strings |
| JP2006527294A (ja) | 2003-06-12 | 2006-11-30 | ジュート−ヒェミー アクチェンゲゼルシャフト | ポリマーにおける改質された離層を有するナノコンポジット添加剤の製造方法 |
| WO2005017011A1 (en) * | 2003-08-07 | 2005-02-24 | Polyone Corporation | Catalyst systems for elastomeric compositions |
| US7205370B2 (en) | 2004-01-12 | 2007-04-17 | Bridgestone Corporation | Polymeric nano-particles of flower-like structure and applications |
| US7112369B2 (en) | 2004-03-02 | 2006-09-26 | Bridgestone Corporation | Nano-sized polymer-metal composites |
| US20050215693A1 (en) * | 2004-03-29 | 2005-09-29 | Xiaorong Wang | Clay modified rubber composition and a method for manufacturing same |
| RU2393179C2 (ru) | 2004-07-06 | 2010-06-27 | Эксонмобил Кемикэл Пейтентс Инк. | Полимерные нанокомпозиты и способы их получения |
| DE102004039451A1 (de) * | 2004-08-13 | 2006-03-02 | Süd-Chemie AG | Polymerblend aus nicht verträglichen Polymeren |
| RU2375304C2 (ru) * | 2004-12-01 | 2009-12-10 | Акцо Нобель Н.В. | Глина, содержащая заряд-компенсирующие органические ионы, и нанокомпозиционные материалы, содержащие такую глину |
| CA2588910C (en) * | 2004-12-03 | 2013-09-10 | Exxonmobil Chemical Patents Inc. | Modified layered fillers and their use to produce nanocomposite compositions |
| US7906600B2 (en) | 2004-12-29 | 2011-03-15 | Exxonmobil Chemical Patents Inc. | Processable filled, curable halogenated isoolefin elastomers |
| US7696266B2 (en) | 2004-12-29 | 2010-04-13 | Exxonmobil Chemical Patents Inc. | Select elastomeric blends and their use in articles |
| US7572855B2 (en) | 2005-01-28 | 2009-08-11 | Bridgestone Corporation | Nano-composite and compositions manufactured thereof |
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| US10414914B2 (en) | 2014-10-02 | 2019-09-17 | Exxonmobil Chemical Patents Inc. | Dynamically vulcanized alloys |
| EP3356469B1 (en) * | 2015-09-30 | 2020-04-29 | ExxonMobil Chemical Patents Inc. | Polycyclic aromatic hydrocarbon functionalized isobutylene copolymers for dispersing graphene and graphite |
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-
2002
- 2002-05-29 DE DE60213812T patent/DE60213812T2/de not_active Expired - Lifetime
- 2002-05-29 EP EP02739472A patent/EP1401933B1/en not_active Expired - Lifetime
- 2002-05-29 CN CNB028120221A patent/CN1268673C/zh not_active Expired - Lifetime
- 2002-05-29 US US10/478,606 patent/US7491764B2/en not_active Expired - Lifetime
- 2002-05-29 RU RU2003137563/04A patent/RU2309167C2/ru active IP Right Revival
- 2002-05-29 AT AT02739472T patent/ATE335784T1/de not_active IP Right Cessation
- 2002-05-29 WO PCT/US2002/016797 patent/WO2002100936A1/en not_active Ceased
- 2002-05-29 JP JP2003503699A patent/JP5002112B2/ja not_active Expired - Fee Related
- 2002-05-29 CA CA2449075A patent/CA2449075C/en not_active Expired - Fee Related
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