JP2004315825A5 - - Google Patents
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- Publication number
- JP2004315825A5 JP2004315825A5 JP2004123567A JP2004123567A JP2004315825A5 JP 2004315825 A5 JP2004315825 A5 JP 2004315825A5 JP 2004123567 A JP2004123567 A JP 2004123567A JP 2004123567 A JP2004123567 A JP 2004123567A JP 2004315825 A5 JP2004315825 A5 JP 2004315825A5
- Authority
- JP
- Japan
- Prior art keywords
- aliphatic
- metal
- catalyst
- ratio
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 239000003054 catalyst Substances 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- -1 aliphatic dicarboxylic acid compound Chemical class 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- 238000005809 transesterification reaction Methods 0.000 claims description 7
- 239000003426 co-catalyst Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- 125000004429 atom Chemical group 0.000 claims description 3
- 125000004437 phosphorous atom Chemical group 0.000 claims description 3
- 238000000034 method Methods 0.000 claims 9
- 150000001875 compounds Chemical class 0.000 claims 8
- 239000002253 acid Substances 0.000 claims 6
- 239000000203 mixture Substances 0.000 claims 6
- 239000002994 raw material Substances 0.000 claims 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 4
- 229920003232 aliphatic polyester Polymers 0.000 claims 4
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 claims 4
- 229960002261 magnesium phosphate Drugs 0.000 claims 4
- 229910000157 magnesium phosphate Inorganic materials 0.000 claims 4
- 239000004137 magnesium phosphate Substances 0.000 claims 4
- 235000010994 magnesium phosphates Nutrition 0.000 claims 4
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims 3
- 125000001931 aliphatic group Chemical group 0.000 claims 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 2
- 229910019142 PO4 Inorganic materials 0.000 claims 2
- 150000001491 aromatic compounds Chemical class 0.000 claims 2
- 239000007809 chemical reaction catalyst Substances 0.000 claims 2
- 125000000524 functional group Chemical group 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 2
- 239000010452 phosphate Substances 0.000 claims 2
- 238000006068 polycondensation reaction Methods 0.000 claims 2
- 150000008065 acid anhydrides Chemical class 0.000 claims 1
- 150000007824 aliphatic compounds Chemical class 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- 150000005690 diesters Chemical class 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 230000009257 reactivity Effects 0.000 claims 1
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 10
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 8
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 7
- 238000003756 stirring Methods 0.000 description 6
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 229920002961 polybutylene succinate Polymers 0.000 description 5
- 239000004631 polybutylene succinate Substances 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 4
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 4
- MSVHHPWGDJNREX-UHFFFAOYSA-L magnesium;dihydrogen phosphate;hydroxide Chemical compound O.[Mg+2].OP([O-])([O-])=O MSVHHPWGDJNREX-UHFFFAOYSA-L 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N terephthalic acid group Chemical group C(C1=CC=C(C(=O)O)C=C1)(=O)O KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- RYSXWUYLAWPLES-MTOQALJVSA-N (Z)-4-hydroxypent-3-en-2-one titanium Chemical compound [Ti].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O RYSXWUYLAWPLES-MTOQALJVSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 description 1
- 229940062672 calcium dihydrogen phosphate Drugs 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- MHJAJDCZWVHCPF-UHFFFAOYSA-L dimagnesium phosphate Chemical compound [Mg+2].OP([O-])([O-])=O MHJAJDCZWVHCPF-UHFFFAOYSA-L 0.000 description 1
- 229910000395 dimagnesium phosphate Inorganic materials 0.000 description 1
- BEQVQKJCLJBTKZ-UHFFFAOYSA-N diphenylphosphinic acid Chemical compound C=1C=CC=CC=1P(=O)(O)C1=CC=CC=C1 BEQVQKJCLJBTKZ-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000019691 monocalcium phosphate Nutrition 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004123567A JP4266359B2 (ja) | 2000-09-11 | 2004-04-19 | 脂肪族ポリエステル系重合体の製造方法及び脂肪族ポリエステル系重合体 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000275723 | 2000-09-11 | ||
| JP2001101886 | 2001-03-30 | ||
| JP2004123567A JP4266359B2 (ja) | 2000-09-11 | 2004-04-19 | 脂肪族ポリエステル系重合体の製造方法及び脂肪族ポリエステル系重合体 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001275688A Division JP3865120B2 (ja) | 2000-09-11 | 2001-09-11 | 脂肪族ポリエステル系重合体の製造方法及び脂肪族ポリエステル系重合体 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004315825A JP2004315825A (ja) | 2004-11-11 |
| JP2004315825A5 true JP2004315825A5 (enExample) | 2006-05-11 |
| JP4266359B2 JP4266359B2 (ja) | 2009-05-20 |
Family
ID=33479472
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004123567A Expired - Fee Related JP4266359B2 (ja) | 2000-09-11 | 2004-04-19 | 脂肪族ポリエステル系重合体の製造方法及び脂肪族ポリエステル系重合体 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4266359B2 (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006274253A (ja) * | 2005-03-02 | 2006-10-12 | Daicel Chem Ind Ltd | 低分岐度高分子量脂肪族ポリエステル、その製造方法、成形品及びフィルム |
| JP2006274254A (ja) * | 2005-03-02 | 2006-10-12 | Daicel Chem Ind Ltd | 低分岐度高分子量脂肪族ポリエステル、その製造方法、成形品及びフィルム |
| JP2006274252A (ja) * | 2005-03-02 | 2006-10-12 | Daicel Chem Ind Ltd | 低分岐度高分子量脂肪族ポリエステル、成形品及びフィルム |
| CN116554452B (zh) * | 2022-01-27 | 2025-10-31 | 中国科学院宁波材料技术与工程研究所 | 基于二甘醇酸或其酯化物的聚酯及其制备方法和制品 |
-
2004
- 2004-04-19 JP JP2004123567A patent/JP4266359B2/ja not_active Expired - Fee Related
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