JP2004018857A - ホスホニットと他の成分との混合物 - Google Patents
ホスホニットと他の成分との混合物 Download PDFInfo
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- JP2004018857A JP2004018857A JP2003169378A JP2003169378A JP2004018857A JP 2004018857 A JP2004018857 A JP 2004018857A JP 2003169378 A JP2003169378 A JP 2003169378A JP 2003169378 A JP2003169378 A JP 2003169378A JP 2004018857 A JP2004018857 A JP 2004018857A
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- 239000000203 mixture Substances 0.000 title claims abstract description 63
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 239000004615 ingredient Substances 0.000 title description 2
- 239000004952 Polyamide Substances 0.000 claims abstract description 24
- 229920002647 polyamide Polymers 0.000 claims abstract description 24
- 229920000728 polyester Polymers 0.000 claims abstract description 21
- 150000002148 esters Chemical class 0.000 claims abstract description 19
- 150000003839 salts Chemical class 0.000 claims abstract description 9
- 150000001408 amides Chemical class 0.000 claims abstract description 8
- 150000004668 long chain fatty acids Chemical class 0.000 claims abstract description 8
- 150000001733 carboxylic acid esters Chemical class 0.000 claims abstract description 5
- 239000003063 flame retardant Substances 0.000 claims description 43
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 35
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 32
- 229920000642 polymer Polymers 0.000 claims description 32
- -1 alkali metal salt Chemical group 0.000 claims description 23
- 239000002253 acid Substances 0.000 claims description 21
- 239000012170 montan wax Substances 0.000 claims description 20
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 18
- 238000012545 processing Methods 0.000 claims description 17
- 229910052698 phosphorus Inorganic materials 0.000 claims description 14
- 239000011574 phosphorus Substances 0.000 claims description 14
- 239000012778 molding material Substances 0.000 claims description 13
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 10
- 239000007795 chemical reaction product Substances 0.000 claims description 10
- 238000000465 moulding Methods 0.000 claims description 10
- 235000021317 phosphate Nutrition 0.000 claims description 10
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 8
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 7
- 239000008188 pellet Substances 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 159000000007 calcium salts Chemical class 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 5
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical group CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 4
- 229920000877 Melamine resin Polymers 0.000 claims description 4
- 229920000388 Polyphosphate Polymers 0.000 claims description 4
- 229910001382 calcium hypophosphite Inorganic materials 0.000 claims description 4
- FIASKJZPIYCESA-UHFFFAOYSA-L calcium;octacosanoate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCCCCCCCCCC([O-])=O FIASKJZPIYCESA-UHFFFAOYSA-L 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 4
- 239000001205 polyphosphate Substances 0.000 claims description 4
- 235000011176 polyphosphates Nutrition 0.000 claims description 4
- 229920002292 Nylon 6 Polymers 0.000 claims description 3
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 239000004305 biphenyl Chemical group 0.000 claims description 3
- 235000010290 biphenyl Nutrition 0.000 claims description 3
- 238000013329 compounding Methods 0.000 claims description 3
- 239000010419 fine particle Substances 0.000 claims description 3
- 238000006068 polycondensation reaction Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000001993 wax Substances 0.000 claims description 3
- HQURVGSRQBOZEX-UHFFFAOYSA-N 3,5-diamino-2-hydroxybenzoic acid Chemical compound NC1=CC(N)=C(O)C(C(O)=O)=C1 HQURVGSRQBOZEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 2
- 241000219112 Cucumis Species 0.000 claims description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- ZJKCITHLCNCAHA-UHFFFAOYSA-K aluminum dioxidophosphanium Chemical group [Al+3].[O-][PH2]=O.[O-][PH2]=O.[O-][PH2]=O ZJKCITHLCNCAHA-UHFFFAOYSA-K 0.000 claims description 2
- 229910001377 aluminum hypophosphite Inorganic materials 0.000 claims description 2
- 150000001413 amino acids Chemical class 0.000 claims description 2
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 2
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 2
- 125000002529 biphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C12)* 0.000 claims description 2
- 229940064002 calcium hypophosphite Drugs 0.000 claims description 2
- 229910001424 calcium ion Inorganic materials 0.000 claims description 2
- LITFOGPYONJRNO-UHFFFAOYSA-L calcium phosphinate Chemical compound [Ca+2].[O-]P=O.[O-]P=O LITFOGPYONJRNO-UHFFFAOYSA-L 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 150000003857 carboxamides Chemical class 0.000 claims description 2
- 150000004985 diamines Chemical class 0.000 claims description 2
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 claims description 2
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 claims description 2
- 239000012803 melt mixture Substances 0.000 claims description 2
- 125000000962 organic group Chemical group 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 2
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims description 2
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 2
- 239000006069 physical mixture Substances 0.000 claims description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 2
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 125000001424 substituent group Chemical group 0.000 claims description 2
- 150000005846 sugar alcohols Polymers 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- CNALVHVMBXLLIY-IUCAKERBSA-N tert-butyl n-[(3s,5s)-5-methylpiperidin-3-yl]carbamate Chemical compound C[C@@H]1CNC[C@@H](NC(=O)OC(C)(C)C)C1 CNALVHVMBXLLIY-IUCAKERBSA-N 0.000 claims description 2
- 150000003751 zinc Chemical class 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 4
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 125000001118 alkylidene group Chemical group 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 2
- 239000010452 phosphate Substances 0.000 claims 2
- 239000004594 Masterbatch (MB) Substances 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 claims 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims 1
- 150000003627 tricarboxylic acid derivatives Chemical class 0.000 claims 1
- 239000000654 additive Substances 0.000 abstract description 15
- 239000004033 plastic Substances 0.000 abstract description 14
- 229920003023 plastic Polymers 0.000 abstract description 14
- 230000000996 additive effect Effects 0.000 abstract description 6
- 230000009471 action Effects 0.000 abstract description 3
- 238000010586 diagram Methods 0.000 abstract 1
- 239000003365 glass fiber Substances 0.000 description 9
- 238000002845 discoloration Methods 0.000 description 6
- 239000000155 melt Substances 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 4
- OYNOCRWQLLIRON-UHFFFAOYSA-N 1-n,3-n-bis(2,2,6,6-tetramethylpiperidin-4-yl)benzene-1,3-dicarboxamide Chemical group C1C(C)(C)NC(C)(C)CC1NC(=O)C1=CC=CC(C(=O)NC2CC(C)(C)NC(C)(C)C2)=C1 OYNOCRWQLLIRON-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 3
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical class O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 3
- 238000012667 polymer degradation Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 150000003628 tricarboxylic acids Chemical class 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 238000005727 Friedel-Crafts reaction Methods 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- NXHKQBCTZHECQF-UHFFFAOYSA-N ethyl(methyl)phosphinic acid Chemical compound CCP(C)(O)=O NXHKQBCTZHECQF-UHFFFAOYSA-N 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 2
- RARSHUDCJQSEFJ-UHFFFAOYSA-N p-Hydroxypropiophenone Chemical compound CCC(=O)C1=CC=C(O)C=C1 RARSHUDCJQSEFJ-UHFFFAOYSA-N 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- KHDIHBBQVBFTPO-UHFFFAOYSA-N 1-n,3-n-di(piperidin-1-yl)benzene-1,3-dicarboxamide Chemical compound C=1C=CC(C(=O)NN2CCCCC2)=CC=1C(=O)NN1CCCCC1 KHDIHBBQVBFTPO-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000004596 additive masterbatch Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- ZCILODAAHLISPY-UHFFFAOYSA-N biphenyl ether Natural products C1=C(CC=C)C(O)=CC(OC=2C(=CC(CC=C)=CC=2)O)=C1 ZCILODAAHLISPY-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 150000001718 carbodiimides Chemical class 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 229960005215 dichloroacetic acid Drugs 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 238000010943 off-gassing Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- CPJSUEIXXCENMM-UHFFFAOYSA-N phenacetin Chemical compound CCOC1=CC=C(NC(C)=O)C=C1 CPJSUEIXXCENMM-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 238000009757 thermoplastic moulding Methods 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 235000019386 wax ester Nutrition 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- JLYXXMFPNIAWKQ-UHFFFAOYSA-N γ Benzene hexachloride Chemical compound ClC1C(Cl)C(Cl)C(Cl)C(Cl)C1Cl JLYXXMFPNIAWKQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/48—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof
- C07F9/4808—Phosphonous acids [RP(OH)2] including [RHP(=O)(OH)]; Thiophosphonous acids including [RP(SH)2], [RHP(=S)(SH)]; Derivatives thereof the acid moiety containing a substituent or structure which is considered as characteristic
- C07F9/485—Polyphosphonous acids or derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5393—Phosphonous compounds, e.g. R—P(OR')2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10226732A DE10226732A1 (de) | 2002-06-14 | 2002-06-14 | Mischungen aus einem Phosphonit und anderen Komponenten |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004018857A true JP2004018857A (ja) | 2004-01-22 |
| JP2004018857A5 JP2004018857A5 (enExample) | 2006-06-15 |
Family
ID=29557841
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003169378A Pending JP2004018857A (ja) | 2002-06-14 | 2003-06-13 | ホスホニットと他の成分との混合物 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US6964746B2 (enExample) |
| EP (1) | EP1371656A1 (enExample) |
| JP (1) | JP2004018857A (enExample) |
| DE (1) | DE10226732A1 (enExample) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006126528A1 (ja) * | 2005-05-24 | 2006-11-30 | Fuji Electric Holdings Co., Ltd. | 難燃性樹脂加工品 |
| JP2013528676A (ja) * | 2010-04-29 | 2013-07-11 | クラリアント・ファイナンス・（ビーブイアイ）・リミテッド | 熱可塑性及び熱硬化性ポリマー用の難燃剤−安定化剤の組み合わせ |
| JP2013529230A (ja) * | 2010-04-29 | 2013-07-18 | クラリアント・ファイナンス・（ビーブイアイ）・リミテッド | 熱可塑性及び熱硬化性ポリマー用の難燃剤−安定化剤の組み合わせ |
| WO2014200082A1 (ja) * | 2013-06-13 | 2014-12-18 | 株式会社クラレ | ポリアミド樹脂組成物およびそれからなる成形品 |
| CN105237968A (zh) * | 2015-11-10 | 2016-01-13 | 安徽工业大学 | 一种阻燃聚丁二酸丁二醇酯复合材料及其制备方法 |
| JP2016509114A (ja) * | 2013-03-08 | 2016-03-24 | クラリアント・インターナシヨナル・リミテツド | 難燃性ポリアミド組成物 |
| JP2018501381A (ja) * | 2015-01-07 | 2018-01-18 | クラリアント・プラスティクス・アンド・コーティングス・リミテッド | ポリアミド類の安定化 |
| JP2019518856A (ja) * | 2016-06-27 | 2019-07-04 | クラリアント・プラスティクス・アンド・コーティングス・リミテッド | 重縮合ポリマーの調製のための添加剤組成物の使用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10152229A1 (de) * | 2001-10-20 | 2003-04-30 | Clariant Gmbh | Verfahren zur Herstellung von Polykondensaten |
| DE10309385B4 (de) * | 2003-03-03 | 2007-01-18 | Clariant Produkte (Deutschland) Gmbh | Flammschutzmittel-Stabilisator-Kombination für thermoplastische Polymere und ihre Verwendung sowie flammfest ausgerüstete Kunststoff-Formmassen |
| EP1680466B1 (en) * | 2003-11-07 | 2008-06-18 | Italmatch Chemicals S.P.A. | Halogen-free flame retardant polycarbonate compositions |
| ES2305710T3 (es) * | 2004-01-07 | 2008-11-01 | Italmatch Chemicals S.P.A. | Composiciones de poliamida con retardo de llama por hipofosfito de aluminio. |
| DE102004016790A1 (de) * | 2004-04-06 | 2005-11-17 | Clariant Gmbh | Verwendung von Wachsen als Modifizierungsmittel für gefüllte Kunststoffe |
| DE102004019716A1 (de) * | 2004-04-20 | 2005-08-04 | Ticona Gmbh | Flammenschutzmittelzusammensetzung, flammgeschützte Formmasse, Verfahren zu deren Herstellung und deren Verwendung |
| US7700680B2 (en) * | 2004-06-10 | 2010-04-20 | Italmatch Chemicals S.P.A. | Polyester compositions flame retarded with halogen-free additives |
| FR2873380B1 (fr) * | 2004-07-20 | 2006-11-03 | Arkema Sa | Poudres de polyamides ignifuges et leur utilisation dans un procede d'agglomeration par fusion |
| DE102004035508A1 (de) * | 2004-07-22 | 2006-02-16 | Clariant Gmbh | Flammgeschützte Polymerformmassen |
| US7495047B2 (en) * | 2005-10-06 | 2009-02-24 | At&T Intellectual Property, I, L.P. | Poly(arylene ether) composition, method, and article |
| US20070080330A1 (en) * | 2005-10-06 | 2007-04-12 | Peters Edward N | Flame retardant composition and method |
| US7488766B2 (en) * | 2005-10-06 | 2009-02-10 | Sabic Innovative Plastics Ip B.V. | Polymer composition, method, and article |
| KR101116480B1 (ko) * | 2007-03-30 | 2012-03-07 | 미쓰이 가가쿠 가부시키가이샤 | 난연성 폴리아마이드 조성물 |
| US20100025643A1 (en) * | 2008-07-31 | 2010-02-04 | Clariant International Ltd. | Flame-retardant mixture for thermoplastic polymers, and flame-retardant polymers |
| US20110180300A1 (en) * | 2008-09-30 | 2011-07-28 | Polyone Corporation | Flame retardant thermoplastic elastomers |
| US8604105B2 (en) | 2010-09-03 | 2013-12-10 | Eastman Chemical Company | Flame retardant copolyester compositions |
| US9312047B2 (en) | 2012-06-22 | 2016-04-12 | Honeywell International Inc. | Method and compositions for producing polymer blends |
| US20140206800A1 (en) * | 2013-01-22 | 2014-07-24 | Sabic Innovative Plastics Ip B.V. | Thermoplastic Compositions Containing Nanoscale-Sized Particle Additives For Laser Direct Structuring And Methods For The Manufacture And Use Thereof |
| CN103788638A (zh) * | 2014-03-07 | 2014-05-14 | 天津长芦海晶集团有限公司 | 一种以聚酰胺6为基体的阻燃复合材料及其制备方法 |
| WO2016188890A1 (en) * | 2015-05-26 | 2016-12-01 | Sabic Global Technologies B.V. | Poly(butylene terephthalate) composition and associated article |
| US11401416B2 (en) | 2017-10-17 | 2022-08-02 | Celanese Sales Germany Gmbh | Flame retardant polyamide composition |
| CN109735065B (zh) * | 2018-12-28 | 2021-11-12 | 武汉融科包装材料有限公司 | 钢卷包装用无卤阻燃再生pet片材专用料及其制备方法 |
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| EP0000354A1 (de) * | 1977-07-07 | 1979-01-24 | Ciba-Geigy Ag | Phosphonite enthaltende Gemische und damit stabilisierte Polymeren |
| FR2557882B1 (fr) * | 1984-01-06 | 1986-05-02 | Solvay | Compositions stabilisees a base de polymeres d'alpha-olefines |
| DE3716723A1 (de) * | 1987-05-19 | 1988-12-01 | Hoechst Ag | Wachsartige verbindungen aromatischer alkohole, ihre herstellung und verwendung |
| CA2013049A1 (en) * | 1989-03-28 | 1990-09-28 | Pieter Gijsman | Polyamide 4.6 composition |
| US5256718A (en) | 1990-02-14 | 1993-10-26 | Mitsui Petrochemical Industries, Ltd. | Flame retardant polyamide thermoplastic resin composition |
| CA2037025C (en) * | 1990-02-27 | 1996-12-03 | Mitsui Chemicals, Incorporated | Ethylene/pentene-1 copolymer, process for the preparation of the same, and ethylene/pentene-1 copolymer composition |
| GB9025727D0 (en) * | 1990-11-27 | 1991-01-09 | Bip Chemicals Ltd | Improvements in or relating to polyester compositions |
| US5616636A (en) * | 1992-03-11 | 1997-04-01 | Sandoz Ltd. | Phosphonite-hals and phosphite-hals compounds as stabilizers |
| DE59305110D1 (de) * | 1992-06-04 | 1997-02-27 | Ciba Geigy Ag | Stabilisierte chlorhaltige Polymerzusammensetzungen |
| US6284857B1 (en) * | 1993-07-22 | 2001-09-04 | Mitsui Chemical, Inc. | Propylene polymer, propylene block copolymer, process for preparing said polymer and said block copolymer, and propylene polymer composition |
| TW339343B (en) * | 1994-08-17 | 1998-09-01 | Toray Industries | Copolymerized polyamide and a production process/thereof |
| US6002004A (en) * | 1995-03-28 | 1999-12-14 | Witco Vinyl Additives Gmbh | Pyrrolodiazine derivatives as stabilizers for chilorine-containing polymers |
| EP1327658A1 (de) * | 1995-10-13 | 2003-07-16 | Crompton Vinyl Additives GmbH | Stabilisatorkombinationen für chlorhaltige Polymere |
| BR9906616B1 (pt) * | 1998-09-01 | 2011-06-28 | fosfonitos, processo para sua preparação e uso dos mesmos. | |
| ES2254053T3 (es) * | 1999-01-30 | 2006-06-16 | Clariant Produkte (Deutschland) Gmbh | Combinacion de agentes ignifugantes para polimeros termoplasticos. |
| DE19903709A1 (de) * | 1999-01-30 | 2000-08-10 | Clariant Gmbh | Flammschutzmittel-Kombination für thermoplastische Polymere II |
| DE19920276A1 (de) | 1999-05-04 | 2000-11-09 | Basf Ag | Thermoplastische Formmassen |
| DE19933901A1 (de) * | 1999-07-22 | 2001-02-01 | Clariant Gmbh | Flammschutzmittel-Kombination |
| US20010034420A1 (en) * | 2000-01-26 | 2001-10-25 | Ken Honma | Thermoplastic resin composition, process for producing the same and molded product using the same |
| ES2269383T3 (es) * | 2000-04-28 | 2007-04-01 | Teijin Chemicals, Ltd. | Granulos coloreantes patron para moldes opticos y substrato de disco optico coloreado. |
| US6537670B1 (en) * | 2000-11-03 | 2003-03-25 | Cytec Technology Corp. | Bis(alkyleneoxybenzophenone) ultraviolet light absorbers |
-
2002
- 2002-06-14 DE DE10226732A patent/DE10226732A1/de not_active Withdrawn
-
2003
- 2003-06-06 EP EP03012866A patent/EP1371656A1/de not_active Ceased
- 2003-06-12 US US10/459,976 patent/US6964746B2/en not_active Expired - Fee Related
- 2003-06-13 JP JP2003169378A patent/JP2004018857A/ja active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2006328124A (ja) * | 2005-05-24 | 2006-12-07 | Fuji Electric Holdings Co Ltd | 難燃性樹脂加工品 |
| US7851528B2 (en) | 2005-05-24 | 2010-12-14 | Fuji Electric Holdings Co., Ltd. | Flame-retardant resin processed article |
| WO2006126528A1 (ja) * | 2005-05-24 | 2006-11-30 | Fuji Electric Holdings Co., Ltd. | 難燃性樹脂加工品 |
| JP2013528676A (ja) * | 2010-04-29 | 2013-07-11 | クラリアント・ファイナンス・（ビーブイアイ）・リミテッド | 熱可塑性及び熱硬化性ポリマー用の難燃剤−安定化剤の組み合わせ |
| JP2013529230A (ja) * | 2010-04-29 | 2013-07-18 | クラリアント・ファイナンス・（ビーブイアイ）・リミテッド | 熱可塑性及び熱硬化性ポリマー用の難燃剤−安定化剤の組み合わせ |
| JP2016509114A (ja) * | 2013-03-08 | 2016-03-24 | クラリアント・インターナシヨナル・リミテツド | 難燃性ポリアミド組成物 |
| JPWO2014200082A1 (ja) * | 2013-06-13 | 2017-02-23 | 株式会社クラレ | ポリアミド樹脂組成物およびそれからなる成形品 |
| KR20160018529A (ko) * | 2013-06-13 | 2016-02-17 | 가부시키가이샤 구라레 | 폴리아미드 수지 조성물 및 그것으로 이루어지는 성형품 |
| WO2014200082A1 (ja) * | 2013-06-13 | 2014-12-18 | 株式会社クラレ | ポリアミド樹脂組成物およびそれからなる成形品 |
| US10364339B2 (en) | 2013-06-13 | 2019-07-30 | Kuraray Co., Ltd. | Polyamide resin composition and molded article produced therefrom |
| KR102189978B1 (ko) * | 2013-06-13 | 2020-12-11 | 주식회사 쿠라레 | 폴리아미드 수지 조성물 및 그것으로 이루어지는 성형품 |
| JP2018501381A (ja) * | 2015-01-07 | 2018-01-18 | クラリアント・プラスティクス・アンド・コーティングス・リミテッド | ポリアミド類の安定化 |
| CN105237968A (zh) * | 2015-11-10 | 2016-01-13 | 安徽工业大学 | 一种阻燃聚丁二酸丁二醇酯复合材料及其制备方法 |
| JP2019518856A (ja) * | 2016-06-27 | 2019-07-04 | クラリアント・プラスティクス・アンド・コーティングス・リミテッド | 重縮合ポリマーの調製のための添加剤組成物の使用 |
Also Published As
| Publication number | Publication date |
|---|---|
| US6964746B2 (en) | 2005-11-15 |
| EP1371656A1 (de) | 2003-12-17 |
| DE10226732A1 (de) | 2004-01-08 |
| US20040051088A1 (en) | 2004-03-18 |
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