JP2003514877A - ハイドロホルミル化混合物からロジウム／フォスファイトリガンド複合体及び遊離のフォスファイトリガンド複合体を分離する方法 - Google Patents

ハイドロホルミル化混合物からロジウム／フォスファイトリガンド複合体及び遊離のフォスファイトリガンド複合体を分離する方法

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Publication number
JP2003514877A
JP2003514877A JP2001539595A JP2001539595A JP2003514877A JP 2003514877 A JP2003514877 A JP 2003514877A JP 2001539595 A JP2001539595 A JP 2001539595A JP 2001539595 A JP2001539595 A JP 2001539595A JP 2003514877 A JP2003514877 A JP 2003514877A
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JP
Japan
Prior art keywords
compound
mixture
alkyl
hydroformylation
phosphite ligand
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001539595A
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English (en)
Japanese (ja)
Other versions
JP2003514877A5 (enExample
Inventor
オンコ， ジャン ゲリング，
ピーター， コーネリス ボルマン，
フベルタス， アドリアナス スミツ，
ベール カウベンベルグ，
フランシスカス， ヘンドリク， パウル ベルゴッセン，
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DSM BV
Original Assignee
DSM NV
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8240899&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=JP2003514877(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by DSM NV filed Critical DSM NV
Publication of JP2003514877A publication Critical patent/JP2003514877A/ja
Publication of JP2003514877A5 publication Critical patent/JP2003514877A5/ja
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/027—Nanofiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/04—Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/147—Microfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/16—Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4061—Regeneration or reactivation of catalysts containing metals involving membrane separation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/786—Separation; Purification; Stabilisation; Use of additives by membrane separation process, e.g. pervaporation, perstraction, reverse osmosis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/56—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP2001539595A 1999-11-23 2000-10-27 ハイドロホルミル化混合物からロジウム／フォスファイトリガンド複合体及び遊離のフォスファイトリガンド複合体を分離する方法 Pending JP2003514877A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP99203927.1 1999-11-23
EP99203927A EP1103303A1 (en) 1999-11-23 1999-11-23 Process to separate a rhodium/phosphite ligand complex and free phosphite ligand complex from a hydroformylation mixture
PCT/EP2000/010699 WO2001037993A1 (en) 1999-11-23 2000-10-27 Process to separate a rhodium/phosphite ligand complex and free phosphite ligand complex from a hydroformylation mixture

Publications (2)

Publication Number Publication Date
JP2003514877A true JP2003514877A (ja) 2003-04-22
JP2003514877A5 JP2003514877A5 (enExample) 2007-12-20

Family

ID=8240899

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001539595A Pending JP2003514877A (ja) 1999-11-23 2000-10-27 ハイドロホルミル化混合物からロジウム／フォスファイトリガンド複合体及び遊離のフォスファイトリガンド複合体を分離する方法

Country Status (11)

Country Link
US (1) US20030018210A1 (enExample)
EP (2) EP1103303A1 (enExample)
JP (1) JP2003514877A (enExample)
KR (1) KR100697916B1 (enExample)
CN (1) CN1164365C (enExample)
AT (1) ATE245483T1 (enExample)
AU (1) AU1277601A (enExample)
CA (1) CA2392195A1 (enExample)
DE (1) DE60004088T2 (enExample)
TW (1) TW527217B (enExample)
WO (1) WO2001037993A1 (enExample)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007509029A (ja) * 2003-06-25 2007-04-12 ビーエーエスエフ　アクチェンゲゼルシャフト 少なくとも２つの官能基を有する化合物の連続的製造方法
JP2009524511A (ja) * 2006-01-26 2009-07-02 エボニック オクセノ ゲゼルシャフト ミット ベシュレンクテル ハフツング テロメリゼーション混合物からの金属−錯体触媒の分離法
JP2012522813A (ja) * 2009-04-07 2012-09-27 オクセア・ゲゼルシャフト・ミト・べシュレンクテル・ハフツング 液状ヒドロホルミル化生産物の仕上げ処理法
JP2015509491A (ja) * 2012-02-23 2015-03-30 エボニック デグサ ゲーエムベーハーＥｖｏｎｉｋ Ｄｅｇｕｓｓａ ＧｍｂＨ イソブテンのヒドロホルミル化のための、及び、生成物混合物の分離のための、方法及び装置
WO2019017490A1 (ja) * 2017-07-21 2019-01-24 宇部興産株式会社 ペンテン酸エステル誘導体の製造方法

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2003253389A1 (en) 2002-08-31 2004-03-19 Oxeno Olefinchemie Gmbh Method for the hydroformylation of olefinically unsaturated compounds, especially olefins, in the presence of cyclic carbonic acid esters
DE102005046250B4 (de) * 2005-09-27 2020-10-08 Evonik Operations Gmbh Anlage zur Abtrennung von organischen Übergangsmetallkomplexkatalysatoren
DE102009001230A1 (de) * 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen
DE102009001225A1 (de) 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom
JP2012525245A (ja) * 2009-04-29 2012-10-22 ビーエーエスエフ ソシエタス・ヨーロピア 膜濾過による触媒の調整方法
DE102012223572A1 (de) 2012-12-18 2014-06-18 Evonik Industries Ag Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren
RU2585285C1 (ru) * 2015-04-20 2016-05-27 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ непрерывного гидроформилирования олефинов c2-c8
WO2019094290A1 (en) 2017-11-13 2019-05-16 Dow Technology Investments Llc Processes for recovery of rhodium from a hydroformylation process
CN112479841B (zh) * 2020-11-26 2022-09-20 万华化学集团股份有限公司 一种丙烯氢甲酰化合成丁醛的工艺
CN120225491A (zh) 2022-12-06 2025-06-27 陶氏技术投资有限责任公司 控制再循环催化剂料流中的重质物的方法

Citations (2)

* Cited by examiner, † Cited by third party
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JPH1059890A (ja) * 1996-05-15 1998-03-03 Hoechst Ag アルデヒドの製造方法
JPH10503425A (ja) * 1995-05-01 1998-03-31 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー コーポレイション 膜分離方法

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GB1312076A (en) * 1970-05-15 1973-04-04 Bp Chem Int Ltd Hydroformylation process
EP0839794A1 (en) * 1996-11-04 1998-05-06 Dsm N.V. Process for the continuous preparation of an alkyl 5-formylvalerate compound

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10503425A (ja) * 1995-05-01 1998-03-31 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー コーポレイション 膜分離方法
JPH1059890A (ja) * 1996-05-15 1998-03-03 Hoechst Ag アルデヒドの製造方法

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007509029A (ja) * 2003-06-25 2007-04-12 ビーエーエスエフ　アクチェンゲゼルシャフト 少なくとも２つの官能基を有する化合物の連続的製造方法
JP2009524511A (ja) * 2006-01-26 2009-07-02 エボニック オクセノ ゲゼルシャフト ミット ベシュレンクテル ハフツング テロメリゼーション混合物からの金属−錯体触媒の分離法
JP2012522813A (ja) * 2009-04-07 2012-09-27 オクセア・ゲゼルシャフト・ミト・べシュレンクテル・ハフツング 液状ヒドロホルミル化生産物の仕上げ処理法
KR101740296B1 (ko) * 2009-04-07 2017-05-26 옥세아 게엠베하 액체 하이드로포밀화 생산물의 후처리 방법
JP2015509491A (ja) * 2012-02-23 2015-03-30 エボニック デグサ ゲーエムベーハーＥｖｏｎｉｋ Ｄｅｇｕｓｓａ ＧｍｂＨ イソブテンのヒドロホルミル化のための、及び、生成物混合物の分離のための、方法及び装置
WO2019017490A1 (ja) * 2017-07-21 2019-01-24 宇部興産株式会社 ペンテン酸エステル誘導体の製造方法
JPWO2019017490A1 (ja) * 2017-07-21 2020-05-28 宇部興産株式会社 ペンテン酸エステル誘導体の製造方法
JP7215421B2 (ja) 2017-07-21 2023-01-31 Ｕｂｅ株式会社 ペンテン酸エステル誘導体の製造方法

Also Published As

Publication number Publication date
WO2001037993A1 (en) 2001-05-31
ATE245483T1 (de) 2003-08-15
CN1424939A (zh) 2003-06-18
KR20020052214A (ko) 2002-07-02
CN1164365C (zh) 2004-09-01
EP1103303A1 (en) 2001-05-30
US20030018210A1 (en) 2003-01-23
DE60004088D1 (de) 2003-08-28
TW527217B (en) 2003-04-11
EP1232008A1 (en) 2002-08-21
EP1232008B1 (en) 2003-07-23
AU1277601A (en) 2001-06-04
CA2392195A1 (en) 2001-05-31
DE60004088T2 (de) 2004-04-22
KR100697916B1 (ko) 2007-03-20

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