KR100697916B1 - 히드로포르밀화 혼합물로부터 로듐/포스파이트 리간드 착화합물 및 유리 포스파이트 리간드 착화합물의 분리방법 - Google Patents

히드로포르밀화 혼합물로부터 로듐/포스파이트 리간드 착화합물 및 유리 포스파이트 리간드 착화합물의 분리방법 Download PDF

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KR100697916B1
KR100697916B1 KR1020027006531A KR20027006531A KR100697916B1 KR 100697916 B1 KR100697916 B1 KR 100697916B1 KR 1020027006531 A KR1020027006531 A KR 1020027006531A KR 20027006531 A KR20027006531 A KR 20027006531A KR 100697916 B1 KR100697916 B1 KR 100697916B1
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South Korea
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compound
mixture
alkyl
hydroformylation
pentenoate
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Korean (ko)
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KR20020052214A (ko
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겔링온코잔
보르만페터코르넬리스
스미츠후베르투스아드리아누스
카우벤베르그비르레
베르고센프란시스쿠스헨드릭파울
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디에스엠 아이피 어셋츠 비.브이.
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/027—Nanofiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/04—Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/147—Microfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14—Ultrafiltration; Microfiltration
    • B01D61/16—Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4061—Regeneration or reactivation of catalysts containing metals involving membrane separation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/786—Separation; Purification; Stabilisation; Use of additives by membrane separation process, e.g. pervaporation, perstraction, reverse osmosis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/56—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020027006531A 1999-11-23 2000-10-27 히드로포르밀화 혼합물로부터 로듐/포스파이트 리간드 착화합물 및 유리 포스파이트 리간드 착화합물의 분리방법 Expired - Fee Related KR100697916B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP99203927A EP1103303A1 (en) 1999-11-23 1999-11-23 Process to separate a rhodium/phosphite ligand complex and free phosphite ligand complex from a hydroformylation mixture
EP99203927.1 1999-11-23

Publications (2)

Publication Number Publication Date
KR20020052214A KR20020052214A (ko) 2002-07-02
KR100697916B1 true KR100697916B1 (ko) 2007-03-20

Family

ID=8240899

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020027006531A Expired - Fee Related KR100697916B1 (ko) 1999-11-23 2000-10-27 히드로포르밀화 혼합물로부터 로듐/포스파이트 리간드 착화합물 및 유리 포스파이트 리간드 착화합물의 분리방법

Country Status (11)

Country Link
US (1) US20030018210A1 (enExample)
EP (2) EP1103303A1 (enExample)
JP (1) JP2003514877A (enExample)
KR (1) KR100697916B1 (enExample)
CN (1) CN1164365C (enExample)
AT (1) ATE245483T1 (enExample)
AU (1) AU1277601A (enExample)
CA (1) CA2392195A1 (enExample)
DE (1) DE60004088T2 (enExample)
TW (1) TW527217B (enExample)
WO (1) WO2001037993A1 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2337090C2 (ru) 2002-08-31 2008-10-27 Оксено Олефинхеми Гмбх Способ гидроформилирования олефиновых соединений в присутствии циклических эфиров угольной кислоты
DE10328715A1 (de) * 2003-06-25 2005-01-13 Basf Ag Verfahren zur kontinuierlichen Herstellung einer Verbindung, die mindestens zwei funktionelle Gruppen trägt
DE102005046250B4 (de) * 2005-09-27 2020-10-08 Evonik Operations Gmbh Anlage zur Abtrennung von organischen Übergangsmetallkomplexkatalysatoren
DE102006003618A1 (de) * 2006-01-26 2007-08-02 Oxeno Olefinchemie Gmbh Verfahren zur Abtrennung von Metall-Komplexkatalysatoren aus Telomerisationsgemischen
DE102009001225A1 (de) 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom
DE102009001230A1 (de) * 2009-02-27 2010-09-02 Evonik Oxeno Gmbh Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen
DE102009016652A1 (de) * 2009-04-07 2010-10-14 Oxea Gmbh Verfahren zur Aufarbeitung eines flüssigen Hydroformylierungsaustrags
JP2012525245A (ja) 2009-04-29 2012-10-22 ビーエーエスエフ ソシエタス・ヨーロピア 膜濾過による触媒の調整方法
DE102012202779A1 (de) * 2012-02-23 2013-08-29 Evonik Oxeno Gmbh Verfahren und Vorrichtung zur technischen Hydroformylierung von Isobuten und zum Auftrennen des Produktgemisches
DE102012223572A1 (de) 2012-12-18 2014-06-18 Evonik Industries Ag Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren
RU2585285C1 (ru) * 2015-04-20 2016-05-27 Открытое акционерное общество "Нефтяная компания "Роснефть" Способ непрерывного гидроформилирования олефинов c2-c8
JP7215421B2 (ja) * 2017-07-21 2023-01-31 Ｕｂｅ株式会社 ペンテン酸エステル誘導体の製造方法
WO2019094290A1 (en) 2017-11-13 2019-05-16 Dow Technology Investments Llc Processes for recovery of rhodium from a hydroformylation process
CN112479841B (zh) * 2020-11-26 2022-09-20 万华化学集团股份有限公司 一种丙烯氢甲酰化合成丁醛的工艺
WO2024123510A1 (en) 2022-12-06 2024-06-13 Dow Technology Investments Llc Process of controlling heavies in a recycle catalyst stream

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1312076A (en) 1970-05-15 1973-04-04 Bp Chem Int Ltd Hydroformylation process
WO1996034687A1 (en) * 1995-05-01 1996-11-07 Union Carbide Chemicals & Plastics Technology Corporation Membrane separation process
EP0810029B1 (de) * 1996-05-15 2001-11-14 Celanese Chemicals Europe GmbH Verfahren zur Herstellung von Aldehyden

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0839794A1 (en) * 1996-11-04 1998-05-06 Dsm N.V. Process for the continuous preparation of an alkyl 5-formylvalerate compound

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1312076A (en) 1970-05-15 1973-04-04 Bp Chem Int Ltd Hydroformylation process
WO1996034687A1 (en) * 1995-05-01 1996-11-07 Union Carbide Chemicals & Plastics Technology Corporation Membrane separation process
EP0810029B1 (de) * 1996-05-15 2001-11-14 Celanese Chemicals Europe GmbH Verfahren zur Herstellung von Aldehyden

Also Published As

Publication number Publication date
AU1277601A (en) 2001-06-04
JP2003514877A (ja) 2003-04-22
DE60004088D1 (de) 2003-08-28
DE60004088T2 (de) 2004-04-22
US20030018210A1 (en) 2003-01-23
KR20020052214A (ko) 2002-07-02
EP1232008B1 (en) 2003-07-23
WO2001037993A1 (en) 2001-05-31
CN1424939A (zh) 2003-06-18
ATE245483T1 (de) 2003-08-15
EP1103303A1 (en) 2001-05-30
EP1232008A1 (en) 2002-08-21
CA2392195A1 (en) 2001-05-31
CN1164365C (zh) 2004-09-01
TW527217B (en) 2003-04-11

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