JP2003234486A - 光電変換素子 - Google Patents
光電変換素子Info
- Publication number
- JP2003234486A JP2003234486A JP2002031458A JP2002031458A JP2003234486A JP 2003234486 A JP2003234486 A JP 2003234486A JP 2002031458 A JP2002031458 A JP 2002031458A JP 2002031458 A JP2002031458 A JP 2002031458A JP 2003234486 A JP2003234486 A JP 2003234486A
- Authority
- JP
- Japan
- Prior art keywords
- transport layer
- photoelectric conversion
- layer
- conversion element
- hole transport
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 77
- 230000005525 hole transport Effects 0.000 claims abstract description 105
- 239000011230 binding agent Substances 0.000 claims abstract description 21
- 239000000463 material Substances 0.000 claims description 102
- 239000000126 substance Substances 0.000 claims description 74
- 239000013078 crystal Substances 0.000 claims description 50
- -1 metal halide compound Chemical class 0.000 claims description 48
- 238000000576 coating method Methods 0.000 claims description 47
- 239000011248 coating agent Substances 0.000 claims description 30
- 150000001875 compounds Chemical class 0.000 claims description 26
- 229910052751 metal Inorganic materials 0.000 claims description 22
- 239000002184 metal Substances 0.000 claims description 22
- 238000010438 heat treatment Methods 0.000 claims description 21
- 239000010949 copper Substances 0.000 claims description 16
- 229910001511 metal iodide Inorganic materials 0.000 claims description 15
- 150000002500 ions Chemical class 0.000 claims description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- 239000011593 sulfur Substances 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 229910001507 metal halide Inorganic materials 0.000 claims description 7
- 150000004820 halides Chemical class 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 4
- 230000002401 inhibitory effect Effects 0.000 claims description 3
- 230000004888 barrier function Effects 0.000 abstract description 86
- 239000000758 substrate Substances 0.000 abstract description 26
- 239000008151 electrolyte solution Substances 0.000 abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 117
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- 239000000843 powder Substances 0.000 description 31
- 239000004408 titanium dioxide Substances 0.000 description 31
- 238000000034 method Methods 0.000 description 29
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- 239000000049 pigment Substances 0.000 description 27
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 18
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 18
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- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 12
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- ZMZDMBWJUHKJPS-UHFFFAOYSA-N thiocyanic acid Chemical compound SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 8
- 230000000996 additive effect Effects 0.000 description 7
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- 150000004703 alkoxides Chemical class 0.000 description 6
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 6
- 229910017052 cobalt Inorganic materials 0.000 description 6
- 239000010941 cobalt Substances 0.000 description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
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- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 5
- 239000012046 mixed solvent Substances 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- MYONAGGJKCJOBT-UHFFFAOYSA-N benzimidazol-2-one Chemical compound C1=CC=CC2=NC(=O)N=C21 MYONAGGJKCJOBT-UHFFFAOYSA-N 0.000 description 4
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 4
- 229910052793 cadmium Inorganic materials 0.000 description 4
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- 238000004140 cleaning Methods 0.000 description 4
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- 238000007598 dipping method Methods 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000007062 hydrolysis Effects 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- ITNVWQNWHXEMNS-UHFFFAOYSA-N methanolate;titanium(4+) Chemical compound [Ti+4].[O-]C.[O-]C.[O-]C.[O-]C ITNVWQNWHXEMNS-UHFFFAOYSA-N 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 239000004332 silver Substances 0.000 description 4
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 4
- GKXDJYKZFZVASJ-UHFFFAOYSA-M tetrapropylazanium;iodide Chemical compound [I-].CCC[N+](CCC)(CCC)CCC GKXDJYKZFZVASJ-UHFFFAOYSA-M 0.000 description 4
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 description 4
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
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- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 229910006404 SnO 2 Inorganic materials 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 3
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 3
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- 150000004694 iodide salts Chemical class 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 3
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- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 3
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- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- 229910001887 tin oxide Inorganic materials 0.000 description 3
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 description 2
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 2
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- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
Landscapes
- Hybrid Cells (AREA)
- Photovoltaic Devices (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002031458A JP2003234486A (ja) | 2002-02-07 | 2002-02-07 | 光電変換素子 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002031458A JP2003234486A (ja) | 2002-02-07 | 2002-02-07 | 光電変換素子 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2003234486A true JP2003234486A (ja) | 2003-08-22 |
| JP2003234486A5 JP2003234486A5 (enrdf_load_stackoverflow) | 2005-08-18 |
Family
ID=27774861
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002031458A Withdrawn JP2003234486A (ja) | 2002-02-07 | 2002-02-07 | 光電変換素子 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2003234486A (enrdf_load_stackoverflow) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007311243A (ja) * | 2006-05-19 | 2007-11-29 | Fujikura Ltd | 作用極および光電変換素子 |
| JP2008010189A (ja) * | 2006-06-27 | 2008-01-17 | Matsushita Electric Works Ltd | 光電変換素子 |
| WO2009089472A3 (en) * | 2008-01-10 | 2009-10-08 | Massachusetts Institute Of Technology | Photovoltaic devices |
| WO2010050575A1 (ja) | 2008-10-29 | 2010-05-06 | 富士フイルム株式会社 | 色素、これを用いた光電変換素子、光電気化学電池、および色素の製造方法 |
| EP2302650A2 (en) | 2009-09-28 | 2011-03-30 | Fujifilm Corporation | Method of producing photoelectric conversion element, photoelectric conversion element, and photoelectrochemical cell |
| EP2306479A2 (en) | 2009-09-28 | 2011-04-06 | Fujifilm Corporation | Method of producing photoelectric conversion element, photoelectric conversion element, and photoelectrochemical cell |
| WO2014084296A1 (ja) * | 2012-11-30 | 2014-06-05 | 日本化薬株式会社 | 色素増感太陽電池 |
| WO2014129575A1 (ja) | 2013-02-22 | 2014-08-28 | 富士フイルム株式会社 | 光電変換素子、光電変換素子の製造方法および色素増感太陽電池 |
| WO2015137324A1 (ja) * | 2014-03-14 | 2015-09-17 | 東京応化工業株式会社 | 結晶成長制御剤、ｐ型半導体微粒子又はｐ型半導体微粒子膜の形成方法、正孔輸送層形成用組成物、及び太陽電池 |
| JP2015177036A (ja) * | 2014-03-14 | 2015-10-05 | 東京応化工業株式会社 | 結晶成長制御剤、ｐ型半導体微粒子又はｐ型半導体微粒子膜の形成方法、正孔輸送層形成用組成物、及び太陽電池 |
| JP2015177037A (ja) * | 2014-03-14 | 2015-10-05 | 東京応化工業株式会社 | 正孔輸送層形成用組成物及び太陽電池 |
-
2002
- 2002-02-07 JP JP2002031458A patent/JP2003234486A/ja not_active Withdrawn
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007311243A (ja) * | 2006-05-19 | 2007-11-29 | Fujikura Ltd | 作用極および光電変換素子 |
| JP2008010189A (ja) * | 2006-06-27 | 2008-01-17 | Matsushita Electric Works Ltd | 光電変換素子 |
| WO2009089472A3 (en) * | 2008-01-10 | 2009-10-08 | Massachusetts Institute Of Technology | Photovoltaic devices |
| EP2845882A2 (en) | 2008-10-29 | 2015-03-11 | Fujifilm Corporation | Dye, Photoelectric Conversion Element and Photoelectrochemical Cell |
| WO2010050575A1 (ja) | 2008-10-29 | 2010-05-06 | 富士フイルム株式会社 | 色素、これを用いた光電変換素子、光電気化学電池、および色素の製造方法 |
| EP2302650A2 (en) | 2009-09-28 | 2011-03-30 | Fujifilm Corporation | Method of producing photoelectric conversion element, photoelectric conversion element, and photoelectrochemical cell |
| EP2306479A2 (en) | 2009-09-28 | 2011-04-06 | Fujifilm Corporation | Method of producing photoelectric conversion element, photoelectric conversion element, and photoelectrochemical cell |
| WO2014084296A1 (ja) * | 2012-11-30 | 2014-06-05 | 日本化薬株式会社 | 色素増感太陽電池 |
| CN104823254A (zh) * | 2012-11-30 | 2015-08-05 | 日本化药株式会社 | 染料敏化太阳能电池 |
| WO2014129575A1 (ja) | 2013-02-22 | 2014-08-28 | 富士フイルム株式会社 | 光電変換素子、光電変換素子の製造方法および色素増感太陽電池 |
| WO2015137324A1 (ja) * | 2014-03-14 | 2015-09-17 | 東京応化工業株式会社 | 結晶成長制御剤、ｐ型半導体微粒子又はｐ型半導体微粒子膜の形成方法、正孔輸送層形成用組成物、及び太陽電池 |
| JP2015177036A (ja) * | 2014-03-14 | 2015-10-05 | 東京応化工業株式会社 | 結晶成長制御剤、ｐ型半導体微粒子又はｐ型半導体微粒子膜の形成方法、正孔輸送層形成用組成物、及び太陽電池 |
| JP2015177037A (ja) * | 2014-03-14 | 2015-10-05 | 東京応化工業株式会社 | 正孔輸送層形成用組成物及び太陽電池 |
| KR101760633B1 (ko) | 2014-03-14 | 2017-07-21 | 도오꾜오까고오교 가부시끼가이샤 | 결정 성장 제어제, p 형 반도체 미립자 또는 p 형 반도체 미립자막의 형성 방법, 정공 수송층 형성용 조성물, 및 태양 전지 |
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