JP2003147028A - メタロセン触媒を用いて得られるアイソタクチックポリピロピレンのグラフト化物 - Google Patents
メタロセン触媒を用いて得られるアイソタクチックポリピロピレンのグラフト化物Info
- Publication number
- JP2003147028A JP2003147028A JP2002222829A JP2002222829A JP2003147028A JP 2003147028 A JP2003147028 A JP 2003147028A JP 2002222829 A JP2002222829 A JP 2002222829A JP 2002222829 A JP2002222829 A JP 2002222829A JP 2003147028 A JP2003147028 A JP 2003147028A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- polymer
- ethylene
- copolymer
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- -1 polypropylene Polymers 0.000 title claims abstract description 66
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 52
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 52
- 239000012968 metallocene catalyst Substances 0.000 title claims abstract description 20
- 239000000126 substance Substances 0.000 title description 3
- 239000000203 mixture Substances 0.000 claims abstract description 72
- 229920000642 polymer Polymers 0.000 claims abstract description 60
- 229920001577 copolymer Polymers 0.000 claims abstract description 45
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000005977 Ethylene Substances 0.000 claims abstract description 36
- 239000011230 binding agent Substances 0.000 claims abstract description 35
- 239000000178 monomer Substances 0.000 claims abstract description 30
- 229920001519 homopolymer Polymers 0.000 claims abstract description 21
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims abstract description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011954 Ziegler–Natta catalyst Substances 0.000 claims abstract description 10
- 101100233255 Mus musculus Ipp gene Proteins 0.000 claims abstract description 6
- 101100513472 Mus musculus Minpp1 gene Proteins 0.000 claims abstract description 6
- 239000004698 Polyethylene Substances 0.000 claims description 23
- 229920000573 polyethylene Polymers 0.000 claims description 22
- 150000001735 carboxylic acids Chemical class 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 229920000098 polyolefin Polymers 0.000 claims description 11
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 10
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 10
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 10
- 239000004952 Polyamide Substances 0.000 claims description 8
- 229920002647 polyamide Polymers 0.000 claims description 8
- 150000002118 epoxides Chemical class 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 229920002943 EPDM rubber Polymers 0.000 claims description 6
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 6
- 150000008064 anhydrides Chemical class 0.000 claims description 6
- 229920005606 polypropylene copolymer Polymers 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 150000001993 dienes Chemical class 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- 229920001903 high density polyethylene Polymers 0.000 claims description 4
- 239000004700 high-density polyethylene Substances 0.000 claims description 4
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 4
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 4
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 229920001567 vinyl ester resin Polymers 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 150000004679 hydroxides Chemical class 0.000 claims description 3
- 239000012948 isocyanate Substances 0.000 claims description 3
- 150000002513 isocyanates Chemical class 0.000 claims description 3
- 229920001684 low density polyethylene Polymers 0.000 claims description 3
- 239000004702 low-density polyethylene Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 150000002918 oxazolines Chemical class 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 239000005022 packaging material Substances 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 229920001038 ethylene copolymer Polymers 0.000 claims description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 2
- 229920001580 isotactic polymer Polymers 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 150000003841 chloride salts Chemical class 0.000 claims 1
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 claims 1
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract description 8
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract description 8
- 239000004711 α-olefin Substances 0.000 description 10
- 239000003999 initiator Substances 0.000 description 9
- 229940048053 acrylate Drugs 0.000 description 7
- 239000002904 solvent Substances 0.000 description 5
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 239000000806 elastomer Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000004708 Very-low-density polyethylene Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical group C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 3
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 229920006132 styrene block copolymer Polymers 0.000 description 3
- 229920001866 very low density polyethylene Polymers 0.000 description 3
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 2
- OMXANELYEWRDAW-UHFFFAOYSA-N 1-Hexacosene Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCC=C OMXANELYEWRDAW-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 description 2
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 2
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 150000001733 carboxylic acid esters Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- ZQMIGQNCOMNODD-UHFFFAOYSA-N diacetyl peroxide Chemical compound CC(=O)OOC(C)=O ZQMIGQNCOMNODD-UHFFFAOYSA-N 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- XLYMOEINVGRTEX-UHFFFAOYSA-N fumaric acid monoethyl ester Natural products CCOC(=O)C=CC(O)=O XLYMOEINVGRTEX-UHFFFAOYSA-N 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 150000003949 imides Chemical class 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- VAMFXQBUQXONLZ-UHFFFAOYSA-N n-alpha-eicosene Natural products CCCCCCCCCCCCCCCCCCC=C VAMFXQBUQXONLZ-UHFFFAOYSA-N 0.000 description 2
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 2
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- DNAJDTIOMGISDS-UHFFFAOYSA-N prop-2-enylsilane Chemical compound [SiH3]CC=C DNAJDTIOMGISDS-UHFFFAOYSA-N 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- BEWIWYDBTBVVIA-SNAWJCMRSA-N (e)-4-(butylamino)-4-oxobut-2-enoic acid Chemical class CCCCNC(=O)\C=C\C(O)=O BEWIWYDBTBVVIA-SNAWJCMRSA-N 0.000 description 1
- OZMRKDKXIMXNRP-BQYQJAHWSA-N (e)-4-(dibutylamino)-4-oxobut-2-enoic acid Chemical class CCCCN(CCCC)C(=O)\C=C\C(O)=O OZMRKDKXIMXNRP-BQYQJAHWSA-N 0.000 description 1
- BZVFXWPGZHIDSJ-AATRIKPKSA-N (e)-4-(diethylamino)-4-oxobut-2-enoic acid Chemical class CCN(CC)C(=O)\C=C\C(O)=O BZVFXWPGZHIDSJ-AATRIKPKSA-N 0.000 description 1
- HBQGCOWNLUOCBU-ONEGZZNKSA-N (e)-4-(ethylamino)-4-oxobut-2-enoic acid Chemical class CCNC(=O)\C=C\C(O)=O HBQGCOWNLUOCBU-ONEGZZNKSA-N 0.000 description 1
- FSQQTNAZHBEJLS-OWOJBTEDSA-N (e)-4-amino-4-oxobut-2-enoic acid Chemical class NC(=O)\C=C\C(O)=O FSQQTNAZHBEJLS-OWOJBTEDSA-N 0.000 description 1
- XLYMOEINVGRTEX-ONEGZZNKSA-N (e)-4-ethoxy-4-oxobut-2-enoic acid Chemical compound CCOC(=O)\C=C\C(O)=O XLYMOEINVGRTEX-ONEGZZNKSA-N 0.000 description 1
- BSSNZUFKXJJCBG-OWOJBTEDSA-N (e)-but-2-enediamide Chemical class NC(=O)\C=C\C(N)=O BSSNZUFKXJJCBG-OWOJBTEDSA-N 0.000 description 1
- BEWIWYDBTBVVIA-PLNGDYQASA-N (z)-4-(butylamino)-4-oxobut-2-enoic acid Chemical class CCCCNC(=O)\C=C/C(O)=O BEWIWYDBTBVVIA-PLNGDYQASA-N 0.000 description 1
- OZMRKDKXIMXNRP-FPLPWBNLSA-N (z)-4-(dibutylamino)-4-oxobut-2-enoic acid Chemical class CCCCN(CCCC)C(=O)\C=C/C(O)=O OZMRKDKXIMXNRP-FPLPWBNLSA-N 0.000 description 1
- BZVFXWPGZHIDSJ-WAYWQWQTSA-N (z)-4-(diethylamino)-4-oxobut-2-enoic acid Chemical class CCN(CC)C(=O)\C=C/C(O)=O BZVFXWPGZHIDSJ-WAYWQWQTSA-N 0.000 description 1
- HBQGCOWNLUOCBU-ARJAWSKDSA-N (z)-4-(ethylamino)-4-oxobut-2-enoic acid Chemical class CCNC(=O)\C=C/C(O)=O HBQGCOWNLUOCBU-ARJAWSKDSA-N 0.000 description 1
- WLQXEFXDBYHMRG-UPHRSURJSA-N (z)-4-(oxiran-2-ylmethoxy)-4-oxobut-2-enoic acid Chemical compound OC(=O)\C=C/C(=O)OCC1CO1 WLQXEFXDBYHMRG-UPHRSURJSA-N 0.000 description 1
- BSSNZUFKXJJCBG-UPHRSURJSA-N (z)-but-2-enediamide Chemical class NC(=O)\C=C/C(N)=O BSSNZUFKXJJCBG-UPHRSURJSA-N 0.000 description 1
- CHHWNYBAWJMTRY-UHFFFAOYSA-N 1,2,2-tributoxyethenylsilane Chemical compound CCCCOC([SiH3])=C(OCCCC)OCCCC CHHWNYBAWJMTRY-UHFFFAOYSA-N 0.000 description 1
- UBRWPVTUQDJKCC-UHFFFAOYSA-N 1,3-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC(C(C)(C)OOC(C)(C)C)=C1 UBRWPVTUQDJKCC-UHFFFAOYSA-N 0.000 description 1
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- JNPCNDJVEUEFBO-UHFFFAOYSA-N 1-butylpyrrole-2,5-dione Chemical compound CCCCN1C(=O)C=CC1=O JNPCNDJVEUEFBO-UHFFFAOYSA-N 0.000 description 1
- 229940106006 1-eicosene Drugs 0.000 description 1
- FIKTURVKRGQNQD-UHFFFAOYSA-N 1-eicosene Natural products CCCCCCCCCCCCCCCCCC=CC(O)=O FIKTURVKRGQNQD-UHFFFAOYSA-N 0.000 description 1
- YKMMLFOYDTYAGR-UHFFFAOYSA-N 1-phenyl-2-(propan-2-ylamino)pentan-1-one Chemical compound CCCC(NC(C)C)C(=O)C1=CC=CC=C1 YKMMLFOYDTYAGR-UHFFFAOYSA-N 0.000 description 1
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 1
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- JJRUAPNVLBABCN-UHFFFAOYSA-N 2-(ethenoxymethyl)oxirane Chemical compound C=COCC1CO1 JJRUAPNVLBABCN-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- ZYIPKNMNGBFPRA-UHFFFAOYSA-N 2-[2-(oxiran-2-yl)ethylidene]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)=CCC1CO1 ZYIPKNMNGBFPRA-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- OETYJMFIQOKCMB-UHFFFAOYSA-N 2-methyl-2-pent-3-enylpropanedioic acid Chemical compound CC(CCC=CC)(C(=O)O)C(=O)O OETYJMFIQOKCMB-UHFFFAOYSA-N 0.000 description 1
- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 1
- RPBWMJBZQXCSFW-UHFFFAOYSA-N 2-methylpropanoyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(=O)C(C)C RPBWMJBZQXCSFW-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Wrappers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0110252A FR2828198B1 (fr) | 2001-07-31 | 2001-07-31 | Polypropylene isotactique obtenu par catalyse metallocene greffe |
| FR0110252 | 2001-07-31 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2005025041A Division JP2005213509A (ja) | 2001-07-31 | 2005-02-01 | メタロセン触媒を用いて得られるアイソタクチックポリピロピレンのグラフト化物 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2003147028A true JP2003147028A (ja) | 2003-05-21 |
Family
ID=8866127
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002222829A Pending JP2003147028A (ja) | 2001-07-31 | 2002-07-31 | メタロセン触媒を用いて得られるアイソタクチックポリピロピレンのグラフト化物 |
| JP2005025041A Pending JP2005213509A (ja) | 2001-07-31 | 2005-02-01 | メタロセン触媒を用いて得られるアイソタクチックポリピロピレンのグラフト化物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2005025041A Pending JP2005213509A (ja) | 2001-07-31 | 2005-02-01 | メタロセン触媒を用いて得られるアイソタクチックポリピロピレンのグラフト化物 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US6750288B2 (enExample) |
| EP (1) | EP1283227B1 (enExample) |
| JP (2) | JP2003147028A (enExample) |
| CN (1) | CN1203123C (enExample) |
| AT (1) | ATE353084T1 (enExample) |
| CA (1) | CA2396203C (enExample) |
| DE (1) | DE60217947T2 (enExample) |
| DK (1) | DK1283227T3 (enExample) |
| ES (1) | ES2281497T3 (enExample) |
| FR (1) | FR2828198B1 (enExample) |
| PT (1) | PT1283227E (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2317391A1 (en) | 2009-11-02 | 2011-05-04 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| EP2317393A1 (en) | 2009-11-02 | 2011-05-04 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| EP2317392A1 (en) | 2009-11-02 | 2011-05-04 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge and electrophotographic apparatus |
| EP2317390A1 (en) | 2009-11-02 | 2011-05-04 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| EP2317389A1 (en) | 2009-11-02 | 2011-05-04 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| EP2423752A1 (en) | 2010-08-27 | 2012-02-29 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| EP2447781A1 (en) | 2010-10-28 | 2012-05-02 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| US8927184B2 (en) | 2010-11-26 | 2015-01-06 | Canon Kabushiki Kaisha | Method of producing electrophotographic photosensitive member |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2830868B1 (fr) * | 2001-10-11 | 2004-12-03 | Atofina | Composition a base de polypropylene isotactique obtenu par catalyse metallocene et de polypropylene isotactique obtenu par catalyse ziegler natta, greffe |
| WO2004046214A2 (en) | 2002-10-15 | 2004-06-03 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7247675B2 (en) * | 2003-12-30 | 2007-07-24 | Kimberly-Clark Worldwide, Inc. | Elastomer compositions and method of making them |
| EP1557256A1 (en) * | 2004-01-26 | 2005-07-27 | Arkema | Copolyester-based structure for manufacturing transparent hollow bodies by coextrusion blow-molding |
| KR100601401B1 (ko) | 2004-11-02 | 2006-07-13 | 주식회사 익성 | 차음 조성물 및 그 차음재 |
| EP1876191B1 (en) * | 2005-04-28 | 2011-12-28 | Mitsubishi Chemical Corporation | Acid-modified polypropylene resin, method for producing same, and resin composition using same |
| EP1721739A1 (en) | 2005-05-09 | 2006-11-15 | Total Petrochemicals Research Feluy | Bi-layer rotomoulding applications |
| GR1005582B (el) * | 2005-08-11 | 2007-07-16 | ΣΥΝΘΕΤΟΣ ΚΥΚΛΙΚΟΣ ΣΩΛΗΝ ΑΠΟ ΧΑΛΚΟ ΜΕ ΜΕΙΓΜΑ ΠΛΑΣΤΙΚΟΥ ΠΕΡΙΒΛΗΜΑΤΟΣ (PE-HD-MD-LD-LLD,PE-Xa-b,c,PE-RT,PP-RC,LSF ΠΟΛΥΟΛΕΦΙΝΙΚΗΣ ΒΑΣΕΩΣ, PET,EVA,PVC H ΡΕ) ΑΝΕΥ ΡΑΦΗΣ, ΜΕ ΙΣΧΥΡΑ ΣΥΝΔΕΔΕΜΕΝΑ ΤΑ ΣΥΣΤΑΤΙΚΑ ΤΟΥ ΜΕΡΗ ΜΕΣΩ ΜΕΙΓΜΑΤΟΣ ΣΥΓΚΟΛΛΗΤΙΚΗΣ ΟΥΣΙΑΣ, ΚΑΤΑΛΛΗΛΟΣ ΓΙΑ ΕΓΚΑΤΑΣΤΑΣΕΙΣ ΥΓΙΕΙΝΗΣ, ΘΕΡΜΑΝΣΗΣ-ΚΛΙΜΑΤΙΣΜΟΥ ΚΑΙ ΑΕΡΙΩΝ (ΨΥΚΤΙΚΩΝ, ΚΑΥΣΙΜΩΝ ΚΑΙ ΦΥΣΙΚΟΥ ΑΕΡΙΟΥ) ΚΑΙ ΜΕΘΟΔΟΣ ΚΑΤΑΣΚΕΥΗΣ | |
| US7416766B2 (en) * | 2005-08-16 | 2008-08-26 | S.C. Johnson & Son, Inc. | Bottles made from metallocene polypropylene for delivery of fragrances |
| US20070270551A1 (en) * | 2006-05-19 | 2007-11-22 | Huntsman Polymers Corporation | Olefin based polymer blend composition |
| CN109320664A (zh) * | 2006-06-15 | 2019-02-12 | 陶氏环球技术有限责任公司 | 官能化烯烃共聚体、组合物和由其制成的制品及其制法 |
| JP5578854B2 (ja) * | 2008-01-11 | 2014-08-27 | 三井化学株式会社 | 変性プロピレン樹脂 |
| US8106134B2 (en) * | 2008-08-28 | 2012-01-31 | Bridgestone Sports Co., Ltd. | Golf ball and method of improving golf ball performance |
| EP2230273A1 (en) * | 2009-03-09 | 2010-09-22 | Total Petrochemicals Research Feluy | Polypropylene composition in blown film |
| EP3233487B1 (en) * | 2014-12-16 | 2021-03-10 | Dow Global Technologies LLC | A multilayer structure and a packaging comprising the same |
| CN109135168A (zh) * | 2018-06-21 | 2019-01-04 | 济南大学 | 一种高寒带耐低温受电弓导流罩 |
| AU2020344705A1 (en) * | 2019-09-13 | 2022-03-24 | Cornell University | Graft copolymers for compatibilization of polyethylene and polypropylene |
| BR112023002671A2 (pt) | 2020-08-14 | 2023-05-02 | Superior Plastics Extrusion Co Inc Dba Impact Plastics | Estruturas de películas poliméricas aumentadas por barreiras, métodos de preparação e artigos das mesmas |
| CN113415056B (zh) * | 2021-06-30 | 2023-03-17 | 福建技术师范学院 | 一种柔性光泽型环保热熔直覆膜及其制备方法 |
| CN116218208B (zh) * | 2023-04-24 | 2024-03-19 | 上海金发科技发展有限公司 | 一种pa/pp合金材料及其制备方法和应用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5326824A (en) * | 1990-05-18 | 1994-07-05 | Mitsui Toatsu Chemicals, Incorporated | Syndiotactic propylene copolymer, method for preparing same, and its use |
| IT1245846B (it) * | 1990-11-13 | 1994-10-25 | Himont Inc | Polipropilene sindiotattico aggraffato. |
| US6150462A (en) * | 1995-01-24 | 2000-11-21 | Acushnet Company | Golf ball compositions formed from single site catalyzed polymers |
| US5981658A (en) * | 1995-01-24 | 1999-11-09 | Acushnet Company | Golf ball incorporating grafted metallocene catalyzed polymer blends |
| JP3506537B2 (ja) | 1995-06-19 | 2004-03-15 | 三井化学株式会社 | グラフト変性プロピレン系重合体 |
| KR100580409B1 (ko) * | 1996-12-13 | 2006-05-16 | 다우 글로벌 테크놀로지스 인크. | 내마모성, 실란-가교결합성 중합체 및 중합체 블렌드 조성물 |
| US6268062B1 (en) * | 1998-04-06 | 2001-07-31 | Applied Extrusion Technologies, Inc. | Polypropylene blends and films prepared therewith |
| EP1065245A4 (en) * | 1999-01-18 | 2002-10-02 | Jujo Paper Co Ltd | BINDING RESIN COMPOSITION AND METHOD FOR THE PRODUCTION THEREOF |
| ITSA990005A1 (it) * | 1999-02-11 | 2000-08-11 | Univ Degli Studi Salerno | Copolimeri a base di propilene contenenti unita' stireniche |
| JP2000234004A (ja) | 1999-02-16 | 2000-08-29 | Nof Corp | 熱可塑性樹脂及びその成形体 |
| US6503635B1 (en) * | 1999-11-08 | 2003-01-07 | Exxon Mobil Oil Corporation | Metallized multi-layer film |
| FR2806734A1 (fr) * | 2000-03-24 | 2001-09-28 | Atofina | Liant de coextrusion a base de polyethylene metallocene cogreffe |
-
2001
- 2001-07-31 FR FR0110252A patent/FR2828198B1/fr not_active Expired - Fee Related
-
2002
- 2002-06-25 DE DE60217947T patent/DE60217947T2/de not_active Expired - Lifetime
- 2002-06-25 EP EP02291576A patent/EP1283227B1/fr not_active Expired - Lifetime
- 2002-06-25 DK DK02291576T patent/DK1283227T3/da active
- 2002-06-25 PT PT02291576T patent/PT1283227E/pt unknown
- 2002-06-25 AT AT02291576T patent/ATE353084T1/de not_active IP Right Cessation
- 2002-06-25 ES ES02291576T patent/ES2281497T3/es not_active Expired - Lifetime
- 2002-07-30 CA CA002396203A patent/CA2396203C/fr not_active Expired - Fee Related
- 2002-07-31 JP JP2002222829A patent/JP2003147028A/ja active Pending
- 2002-07-31 US US10/208,192 patent/US6750288B2/en not_active Expired - Lifetime
- 2002-07-31 CN CNB021272727A patent/CN1203123C/zh not_active Expired - Fee Related
-
2004
- 2004-05-03 US US10/836,332 patent/US6890661B2/en not_active Expired - Fee Related
-
2005
- 2005-02-01 JP JP2005025041A patent/JP2005213509A/ja active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8524430B2 (en) | 2009-11-02 | 2013-09-03 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| US8632931B2 (en) | 2009-11-02 | 2014-01-21 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| EP2317392A1 (en) | 2009-11-02 | 2011-05-04 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge and electrophotographic apparatus |
| EP2317390A1 (en) | 2009-11-02 | 2011-05-04 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| EP2317389A1 (en) | 2009-11-02 | 2011-05-04 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| US8343699B2 (en) | 2009-11-02 | 2013-01-01 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| US8470504B2 (en) | 2009-11-02 | 2013-06-25 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| US8524431B2 (en) | 2009-11-02 | 2013-09-03 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge and electrophotographic apparatus |
| EP2317393A1 (en) | 2009-11-02 | 2011-05-04 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| EP2317391A1 (en) | 2009-11-02 | 2011-05-04 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| US8546050B2 (en) | 2010-08-27 | 2013-10-01 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| EP2423752A1 (en) | 2010-08-27 | 2012-02-29 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| EP2447781A1 (en) | 2010-10-28 | 2012-05-02 | Canon Kabushiki Kaisha | Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus |
| US8927184B2 (en) | 2010-11-26 | 2015-01-06 | Canon Kabushiki Kaisha | Method of producing electrophotographic photosensitive member |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1203123C (zh) | 2005-05-25 |
| EP1283227B1 (fr) | 2007-01-31 |
| CA2396203A1 (fr) | 2003-01-31 |
| CN1403498A (zh) | 2003-03-19 |
| JP2005213509A (ja) | 2005-08-11 |
| DE60217947D1 (de) | 2007-03-22 |
| PT1283227E (pt) | 2007-04-30 |
| DK1283227T3 (da) | 2007-05-21 |
| US20030040579A1 (en) | 2003-02-27 |
| CA2396203C (fr) | 2007-09-04 |
| ATE353084T1 (de) | 2007-02-15 |
| US6750288B2 (en) | 2004-06-15 |
| ES2281497T3 (es) | 2007-10-01 |
| FR2828198B1 (fr) | 2007-02-23 |
| US20040202806A1 (en) | 2004-10-14 |
| DE60217947T2 (de) | 2007-10-31 |
| FR2828198A1 (fr) | 2003-02-07 |
| EP1283227A1 (fr) | 2003-02-12 |
| US6890661B2 (en) | 2005-05-10 |
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