JP2002526355A - 電気触媒法及び水素に富むガスから一酸化炭素を除去する方法及び装置 - Google Patents
電気触媒法及び水素に富むガスから一酸化炭素を除去する方法及び装置Info
- Publication number
- JP2002526355A JP2002526355A JP2000573836A JP2000573836A JP2002526355A JP 2002526355 A JP2002526355 A JP 2002526355A JP 2000573836 A JP2000573836 A JP 2000573836A JP 2000573836 A JP2000573836 A JP 2000573836A JP 2002526355 A JP2002526355 A JP 2002526355A
- Authority
- JP
- Japan
- Prior art keywords
- carbon monoxide
- eco
- reformate
- hydrogen
- anode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 152
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims abstract description 152
- 238000000034 method Methods 0.000 title claims abstract description 79
- 229910052739 hydrogen Inorganic materials 0.000 title abstract description 44
- 239000001257 hydrogen Substances 0.000 title abstract description 43
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract description 38
- 239000007789 gas Substances 0.000 title abstract description 34
- 239000003054 catalyst Substances 0.000 claims abstract description 58
- 239000000463 material Substances 0.000 claims abstract description 51
- 238000006243 chemical reaction Methods 0.000 claims abstract description 28
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 76
- 238000001179 sorption measurement Methods 0.000 claims description 45
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 38
- 239000001569 carbon dioxide Substances 0.000 claims description 38
- 238000012545 processing Methods 0.000 claims description 21
- 230000008569 process Effects 0.000 claims description 18
- 229930195733 hydrocarbon Natural products 0.000 claims description 17
- 150000002430 hydrocarbons Chemical class 0.000 claims description 17
- 239000004215 Carbon black (E152) Substances 0.000 claims description 15
- 239000010411 electrocatalyst Substances 0.000 claims description 13
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 239000000446 fuel Substances 0.000 abstract description 89
- 239000007800 oxidant agent Substances 0.000 abstract description 10
- 229910052751 metal Inorganic materials 0.000 description 72
- 239000002184 metal Substances 0.000 description 72
- 230000003197 catalytic effect Effects 0.000 description 53
- 230000008929 regeneration Effects 0.000 description 30
- 238000011069 regeneration method Methods 0.000 description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 28
- 239000012528 membrane Substances 0.000 description 23
- 229910001868 water Inorganic materials 0.000 description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 21
- 238000007254 oxidation reaction Methods 0.000 description 21
- 239000001301 oxygen Substances 0.000 description 21
- 229910052760 oxygen Inorganic materials 0.000 description 21
- 239000000203 mixture Substances 0.000 description 16
- 230000003647 oxidation Effects 0.000 description 16
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 16
- 230000001590 oxidative effect Effects 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 238000002407 reforming Methods 0.000 description 8
- 230000007423 decrease Effects 0.000 description 7
- 238000006056 electrooxidation reaction Methods 0.000 description 7
- 229910000510 noble metal Inorganic materials 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 230000002441 reversible effect Effects 0.000 description 7
- 229910052723 transition metal Inorganic materials 0.000 description 7
- 150000003624 transition metals Chemical class 0.000 description 7
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 6
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- 229910052697 platinum Inorganic materials 0.000 description 6
- 239000010948 rhodium Substances 0.000 description 6
- 229910052707 ruthenium Inorganic materials 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 5
- 239000000376 reactant Substances 0.000 description 5
- 238000000629 steam reforming Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 230000003993 interaction Effects 0.000 description 4
- 229910052703 rhodium Inorganic materials 0.000 description 4
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- 239000002803 fossil fuel Substances 0.000 description 3
- 239000003502 gasoline Substances 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 229920000554 ionomer Polymers 0.000 description 3
- 229910052741 iridium Inorganic materials 0.000 description 3
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 3
- 229910052763 palladium Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000001172 regenerating effect Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920000557 Nafion® Polymers 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000011278 co-treatment Methods 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000003487 electrochemical reaction Methods 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
- 239000013081 microcrystal Substances 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000005518 polymer electrolyte Substances 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 230000003252 repetitive effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- -1 Pt-Co Chemical class 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000007172 homogeneous catalysis Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-M hydroperoxide group Chemical group [O-]O MHAJPDPJQMAIIY-UHFFFAOYSA-M 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
- B01D53/326—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 in electrochemical cells
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
- C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
- C01B3/583—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction the reaction being the selective oxidation of carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/32—Purifying combustible gases containing carbon monoxide with selectively adsorptive solids, e.g. active carbon
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0435—Catalytic purification
- C01B2203/044—Selective oxidation of carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Fuel Cell (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Carbon And Carbon Compounds (AREA)
- Industrial Gases (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10099098P | 1998-09-18 | 1998-09-18 | |
| US60/100,990 | 1998-09-18 | ||
| US09/393,103 US6245214B1 (en) | 1998-09-18 | 1999-09-09 | Electro-catalytic oxidation (ECO) device to remove CO from reformate for fuel cell application |
| US09/393,103 | 1999-09-09 | ||
| PCT/US1999/021634 WO2000016880A1 (en) | 1998-09-18 | 1999-09-17 | Electrocatalytic method and device for removing carbon monoxide from hydrogen-rich gas |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002526355A true JP2002526355A (ja) | 2002-08-20 |
| JP2002526355A5 JP2002526355A5 (enExample) | 2006-11-16 |
Family
ID=26797784
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000573836A Pending JP2002526355A (ja) | 1998-09-18 | 1999-09-17 | 電気触媒法及び水素に富むガスから一酸化炭素を除去する方法及び装置 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US6245214B1 (enExample) |
| EP (1) | EP1115470B1 (enExample) |
| JP (1) | JP2002526355A (enExample) |
| KR (1) | KR20010088810A (enExample) |
| CN (1) | CN1326376A (enExample) |
| AT (1) | ATE309853T1 (enExample) |
| AU (1) | AU740302B2 (enExample) |
| BR (1) | BR9916551B1 (enExample) |
| CA (1) | CA2344698C (enExample) |
| DE (1) | DE69928417T2 (enExample) |
| WO (1) | WO2000016880A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024009858A1 (ja) * | 2022-07-06 | 2024-01-11 | 株式会社デンソー | 電気化学セル |
Families Citing this family (70)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE38493E1 (en) * | 1996-04-24 | 2004-04-13 | Questair Technologies Inc. | Flow regulated pressure swing adsorption system |
| US6921597B2 (en) | 1998-09-14 | 2005-07-26 | Questair Technologies Inc. | Electrical current generation system |
| US6429019B1 (en) * | 1999-01-19 | 2002-08-06 | Quantum Group, Inc. | Carbon monoxide detection and purification system for fuels cells |
| CA2377412C (en) * | 1999-07-27 | 2003-08-05 | Idatech, Llc | Fuel cell system controller |
| US6979507B2 (en) * | 2000-07-26 | 2005-12-27 | Idatech, Llc | Fuel cell system controller |
| DE10012224A1 (de) * | 2000-03-14 | 2001-09-27 | Xcellsis Gmbh | Verfahren zur Verkürzung der Startzeit von CO-Oxidationskatalysatoren in mobilen Brennstoffzellensystemen |
| DE10013659A1 (de) * | 2000-03-20 | 2001-12-20 | Volkswagen Ag | Verfahren zum Behandeln von einer Brennstoffzelle, insbesondere eines Fahrzeugs, zuzuführenden Betriebsstoffen und entsprechende Brennstoffzellenvorrichtung |
| DE10019772B4 (de) * | 2000-04-20 | 2007-06-21 | Nucellsys Gmbh | Vorrichtung zum Ausgleichen von Konzentrationsschwankungen in Brennstoffzellensystemen |
| JP3871501B2 (ja) * | 2000-08-07 | 2007-01-24 | 株式会社ノリタケカンパニーリミテド | ゼオライト膜とその製造方法と膜リアクター |
| JP2004512650A (ja) | 2000-10-27 | 2004-04-22 | クエストエアー テクノロジーズ インコーポレイテッド | 燃料電池に水素を供給するシステムおよび方法 |
| US7097925B2 (en) | 2000-10-30 | 2006-08-29 | Questair Technologies Inc. | High temperature fuel cell power plant |
| CA2325072A1 (en) | 2000-10-30 | 2002-04-30 | Questair Technologies Inc. | Gas separation for molten carbonate fuel cell |
| US6866950B2 (en) | 2000-12-08 | 2005-03-15 | Questair Technologies Inc. | Methods and apparatuses for gas separation by pressure swing adsorption with partial gas product feed to fuel cell power source |
| CA2329475A1 (en) | 2000-12-11 | 2002-06-11 | Andrea Gibbs | Fast cycle psa with adsorbents sensitive to atmospheric humidity |
| DE10111560C1 (de) * | 2001-03-10 | 2002-06-06 | Xcellsis Gmbh | Verfahren und Vorrichtung zur Entfernung von Kohlenmonoxid aus einem Gasstrom |
| US6689194B2 (en) * | 2001-03-12 | 2004-02-10 | Motorola, Inc | Fuel cell system having a replaceable getter element for purifying the fuel supply |
| US6733909B2 (en) * | 2001-05-03 | 2004-05-11 | Ford Motor Company | Fuel cell power plant with electrochemical enhanced carbon monoxide removal |
| CA2390293A1 (en) * | 2001-06-13 | 2002-12-13 | Ballard Power Systems Inc. | Method and device for improved catalytic activity in the purification of fluids |
| FR2829296B1 (fr) | 2001-09-05 | 2005-05-27 | Renault | Dispositif et procede d'alimentation en hydrogene d'une pile a combustible et utilisation pour la traction electrique d'un vehicule |
| US6939640B2 (en) * | 2001-09-21 | 2005-09-06 | E. I. Dupont De Nemours And Company | Anode electrocatalysts for coated substrates used in fuel cells |
| US6998991B1 (en) * | 2001-10-01 | 2006-02-14 | Quantum Group Inc. | Dual carbon monoxide sensor system with control catalyst: new CO and humidity method and apparatus |
| CA2475504C (en) | 2002-02-06 | 2013-07-09 | Battelle Memorial Institute | Methods of removing contaminants from a fuel cell electrode |
| AU2003210939A1 (en) * | 2002-02-06 | 2003-09-02 | Battelle Memorial Institute | Polymer electrolyte membrane fuel cell system |
| US7147947B2 (en) * | 2002-02-25 | 2006-12-12 | Delphi Technologies, Inc. | Selective carbon monoxide oxidation catalyst, method of making the same and systems using the same |
| CA2476409A1 (en) | 2002-03-14 | 2003-09-18 | Questair Technologies Inc. | Hydrogen recycle for solid oxide fuel cell |
| WO2003076048A1 (en) | 2002-03-14 | 2003-09-18 | Questair Technologies Inc. | Gas separation by combined pressure swing and displacement purge |
| JP3722079B2 (ja) * | 2002-03-27 | 2005-11-30 | 日産自動車株式会社 | 一酸化炭素除去装置 |
| US20030188475A1 (en) * | 2002-03-29 | 2003-10-09 | Shabbir Ahmed | Dynamic fuel processor with controlled declining temperatures |
| US8790114B2 (en) * | 2002-09-27 | 2014-07-29 | GM Global Technology Operations LLC | Byproduct compound retention device for fuel rich start-up combustor |
| US7285350B2 (en) | 2002-09-27 | 2007-10-23 | Questair Technologies Inc. | Enhanced solid oxide fuel cell systems |
| EP1579522A2 (en) * | 2002-12-05 | 2005-09-28 | Battelle Memorial Institute | Methods of removing sulfur from a fuel cell electrode |
| US7678346B2 (en) * | 2003-01-30 | 2010-03-16 | Gm Global Technology Operations, Inc. | Dual function CO clean-up/sorber unit |
| US7192460B2 (en) * | 2003-02-28 | 2007-03-20 | Modine Manufacturing Company | Reformate cooling system and method for use in a fuel processing subsystem |
| US7276096B2 (en) * | 2003-06-27 | 2007-10-02 | Ultracell Corporation | Fuel processor dewar and methods |
| US20060156627A1 (en) * | 2003-06-27 | 2006-07-20 | Ultracell Corporation | Fuel processor for use with portable fuel cells |
| WO2005004258A2 (en) * | 2003-06-27 | 2005-01-13 | Ultracell Corporation | Portable fuel cartridge for fuel cells |
| US20050014059A1 (en) * | 2003-06-27 | 2005-01-20 | Ultracell Corporation | Micro fuel cell architecture |
| US8318368B2 (en) * | 2003-06-27 | 2012-11-27 | UltraCell, L.L.C. | Portable systems for engine block |
| US20050186455A1 (en) * | 2003-06-27 | 2005-08-25 | Ultracell Corporation, A California Corporation | Micro fuel cell system start up and shut down systems and methods |
| US20060127711A1 (en) * | 2004-06-25 | 2006-06-15 | Ultracell Corporation, A California Corporation | Systems and methods for fuel cartridge distribution |
| US7666539B2 (en) * | 2003-06-27 | 2010-02-23 | Ultracell Corporation | Heat efficient portable fuel cell systems |
| US8821832B2 (en) | 2003-06-27 | 2014-09-02 | UltraCell, L.L.C. | Fuel processor for use with portable fuel cells |
| US7241521B2 (en) | 2003-11-18 | 2007-07-10 | Npl Associates, Inc. | Hydrogen/hydrogen peroxide fuel cell |
| US20050255368A1 (en) * | 2004-05-12 | 2005-11-17 | Ultracell Corporation, A California Corporation | High surface area micro fuel cell architecture |
| US7842428B2 (en) * | 2004-05-28 | 2010-11-30 | Idatech, Llc | Consumption-based fuel cell monitoring and control |
| US8277997B2 (en) * | 2004-07-29 | 2012-10-02 | Idatech, Llc | Shared variable-based fuel cell system control |
| US7648792B2 (en) * | 2004-06-25 | 2010-01-19 | Ultracell Corporation | Disposable component on a fuel cartridge and for use with a portable fuel cell system |
| US7968250B2 (en) * | 2004-06-25 | 2011-06-28 | Ultracell Corporation | Fuel cartridge connectivity |
| US7189280B2 (en) | 2004-06-29 | 2007-03-13 | Questair Technologies Inc. | Adsorptive separation of gas streams |
| US7205060B2 (en) * | 2004-08-06 | 2007-04-17 | Ultracell Corporation | Method and system for controlling fluid delivery in a fuel cell |
| US20060029841A1 (en) * | 2004-08-09 | 2006-02-09 | Engelhard Corporation | High surface area, electronically conductive supports for selective CO oxidation catalysts |
| CN1317180C (zh) * | 2004-10-28 | 2007-05-23 | 中国石油化工股份有限公司 | 一种去除富氢气体中一氧化碳的方法 |
| US7807313B2 (en) * | 2004-12-21 | 2010-10-05 | Ultracell Corporation | Compact fuel cell package |
| US7422994B2 (en) * | 2005-01-05 | 2008-09-09 | Symyx Technologies, Inc. | Platinum-copper-tungsten fuel cell catalyst |
| US20060194082A1 (en) * | 2005-02-02 | 2006-08-31 | Ultracell Corporation | Systems and methods for protecting a fuel cell |
| US9263756B1 (en) * | 2006-04-05 | 2016-02-16 | University Of Central Florida Research Foundation, Inc. | Electrochemical method for the removal of PPM levels of carbon monoxide from hydrogen for a fuel cell |
| US7887958B2 (en) * | 2006-05-15 | 2011-02-15 | Idatech, Llc | Hydrogen-producing fuel cell systems with load-responsive feedstock delivery systems |
| US7666534B1 (en) * | 2006-09-19 | 2010-02-23 | The United States Of America As Represented By The Untied States Department Of Energy | Electro-catalytic oxidation device for removing carbon from a fuel reformate |
| US20080190780A1 (en) * | 2007-01-24 | 2008-08-14 | Treadstone Technologies, Inc. | Electrochemical processor for hydrogen processing and electrical power generation |
| TW200840120A (en) * | 2007-03-20 | 2008-10-01 | Industrie De Nora Spa | Electrochemical cell and method for operating the same |
| WO2009085358A2 (en) * | 2007-10-05 | 2009-07-09 | Honda Motor Co., Ltd. | Fuel cells with sputter deposited pt and pt alloy electrodes |
| US20090139207A1 (en) * | 2007-11-30 | 2009-06-04 | Caterpillar Inc. | Thermo-electric auxiliary power unit |
| EP2607490A1 (de) | 2011-12-22 | 2013-06-26 | Evonik Industries AG | Verfahren zur verbesserten Abtrennung einer hydrophoben organischen Lösung von einem wässrigen Kulturmedium |
| US9463415B2 (en) * | 2013-05-31 | 2016-10-11 | Sustainable Innovations, LLC | Hydrogen recycling apparatus and method of operation |
| CN104258723B (zh) * | 2014-10-09 | 2016-07-20 | 安徽蓝盾光电子股份有限公司 | 高效co涤除器 |
| DE102017218334A1 (de) | 2017-10-13 | 2019-04-18 | Thyssenkrupp Ag | Reformerbrennstoffzelle |
| JP7183796B2 (ja) | 2019-01-08 | 2022-12-06 | トヨタ自動車株式会社 | 電気化学リアクタ |
| JP7099331B2 (ja) * | 2019-01-08 | 2022-07-12 | トヨタ自動車株式会社 | 内燃機関の排気浄化装置 |
| JP7222023B2 (ja) * | 2020-05-26 | 2023-02-14 | インディアン オイル コーポレイション リミテッド | Ｃｏ汚染された水素ガスでｐｅｍ燃料電池を動作させるための方法及び装置 |
| EP4218989A1 (en) * | 2022-01-26 | 2023-08-02 | Siemens Energy Global GmbH & Co. KG | Unit for direct capture of carbon dioxide |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3884838A (en) | 1970-09-01 | 1975-05-20 | Inst Gas Technology | Ruthenium-reduced amorphous tungsten oxide catalyst |
| EP0170884B1 (en) | 1984-07-04 | 1989-01-18 | Nippon Kokan Kabushiki Kaisha | Method of separating carbon monoxide |
| US4711828A (en) | 1985-05-27 | 1987-12-08 | Babcock-Hitachi Kabushiki Kaisha | Carbon monoxide-oxygen fuel cell |
| US4910099A (en) | 1988-12-05 | 1990-03-20 | The United States Of America As Represented By The United States Department Of Energy | Preventing CO poisoning in fuel cells |
| JP2607682B2 (ja) * | 1989-05-25 | 1997-05-07 | 三菱重工業株式会社 | 燃料電池に供給する水素ガスの精製装置 |
| US5215729A (en) | 1990-06-22 | 1993-06-01 | Buxbaum Robert E | Composite metal membrane for hydrogen extraction |
| US5211984A (en) | 1991-02-19 | 1993-05-18 | The Regents Of The University Of California | Membrane catalyst layer for fuel cells |
| US5271916A (en) | 1991-07-08 | 1993-12-21 | General Motors Corporation | Device for staged carbon monoxide oxidation |
| US5482680A (en) * | 1992-10-09 | 1996-01-09 | Ballard Power Systems, Inc. | Electrochemical fuel cell assembly with integral selective oxidizer |
| US5432021A (en) | 1992-10-09 | 1995-07-11 | Ballard Power Systems Inc. | Method and apparatus for oxidizing carbon monoxide in the reactant stream of an electrochemical fuel cell |
| US5316747A (en) | 1992-10-09 | 1994-05-31 | Ballard Power Systems Inc. | Method and apparatus for the selective oxidation of carbon monoxide in a hydrogen-containing gas mixture |
| GB9324101D0 (en) | 1993-11-23 | 1994-01-12 | Johnson Matthey Plc | Improved manufacture of electrodes |
| US5531809A (en) | 1994-09-14 | 1996-07-02 | Air Products And Chemicals, Inc. | Pretreatment layer for CO-VSA |
| US5804325A (en) | 1995-01-13 | 1998-09-08 | Westfield Trading Corporation | Non poisoning fuel cell and method |
| DE19615562C1 (de) * | 1996-04-19 | 1997-10-09 | Zsw | Vorrichtung und Verfahren zur kombinierten Reinigung und Kompression von CO-haltigem Wasserstoff sowie Verwendung des mit dem Verfahren erhaltenen Wasserstoffs als Brenngas in Brennstoffzellen |
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1999
- 1999-09-09 US US09/393,103 patent/US6245214B1/en not_active Expired - Lifetime
- 1999-09-17 JP JP2000573836A patent/JP2002526355A/ja active Pending
- 1999-09-17 DE DE69928417T patent/DE69928417T2/de not_active Expired - Fee Related
- 1999-09-17 AT AT99946992T patent/ATE309853T1/de not_active IP Right Cessation
- 1999-09-17 BR BRPI9916551-1A patent/BR9916551B1/pt not_active IP Right Cessation
- 1999-09-17 CN CN99813379A patent/CN1326376A/zh active Pending
- 1999-09-17 EP EP99946992A patent/EP1115470B1/en not_active Expired - Lifetime
- 1999-09-17 KR KR1020017003536A patent/KR20010088810A/ko not_active Withdrawn
- 1999-09-17 WO PCT/US1999/021634 patent/WO2000016880A1/en not_active Ceased
- 1999-09-17 CA CA002344698A patent/CA2344698C/en not_active Expired - Fee Related
- 1999-09-17 AU AU59284/99A patent/AU740302B2/en not_active Ceased
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2001
- 2001-05-03 US US09/849,473 patent/US20010037948A1/en not_active Abandoned
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2024009858A1 (ja) * | 2022-07-06 | 2024-01-11 | 株式会社デンソー | 電気化学セル |
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|---|---|
| BR9916551A (pt) | 2004-08-03 |
| US6245214B1 (en) | 2001-06-12 |
| BR9916551B1 (pt) | 2009-05-05 |
| EP1115470A1 (en) | 2001-07-18 |
| DE69928417D1 (de) | 2005-12-22 |
| DE69928417T2 (de) | 2006-07-27 |
| AU740302B2 (en) | 2001-11-01 |
| CA2344698C (en) | 2008-11-18 |
| CN1326376A (zh) | 2001-12-12 |
| AU5928499A (en) | 2000-04-10 |
| ATE309853T1 (de) | 2005-12-15 |
| US20010037948A1 (en) | 2001-11-08 |
| CA2344698A1 (en) | 2000-03-30 |
| WO2000016880A1 (en) | 2000-03-30 |
| KR20010088810A (ko) | 2001-09-28 |
| EP1115470B1 (en) | 2005-11-16 |
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