DE69928417D1 - Verfahren zur elektrokatalytischen entfernung von kohlenmonoxid aus einem wasserstoffreichen gas - Google Patents
Verfahren zur elektrokatalytischen entfernung von kohlenmonoxid aus einem wasserstoffreichen gasInfo
- Publication number
- DE69928417D1 DE69928417D1 DE69928417T DE69928417T DE69928417D1 DE 69928417 D1 DE69928417 D1 DE 69928417D1 DE 69928417 T DE69928417 T DE 69928417T DE 69928417 T DE69928417 T DE 69928417T DE 69928417 D1 DE69928417 D1 DE 69928417D1
- Authority
- DE
- Germany
- Prior art keywords
- carbon monoxide
- electrocatalytic
- removal
- catalytic material
- hydrogenous gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
- B01D53/326—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 in electrochemical cells
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
- C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
- C01B3/583—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction the reaction being the selective oxidation of carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/32—Purifying combustible gases containing carbon monoxide with selectively adsorptive solids, e.g. active carbon
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0435—Catalytic purification
- C01B2203/044—Selective oxidation of carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Fuel Cell (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Carbon And Carbon Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Industrial Gases (AREA)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10099098P | 1998-09-18 | 1998-09-18 | |
US100990P | 1998-09-18 | ||
US393103 | 1999-09-09 | ||
US09/393,103 US6245214B1 (en) | 1998-09-18 | 1999-09-09 | Electro-catalytic oxidation (ECO) device to remove CO from reformate for fuel cell application |
PCT/US1999/021634 WO2000016880A1 (en) | 1998-09-18 | 1999-09-17 | Electrocatalytic method and device for removing carbon monoxide from hydrogen-rich gas |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69928417D1 true DE69928417D1 (de) | 2005-12-22 |
DE69928417T2 DE69928417T2 (de) | 2006-07-27 |
Family
ID=26797784
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69928417T Expired - Fee Related DE69928417T2 (de) | 1998-09-18 | 1999-09-17 | Verfahren zur elektrokatalytischen entfernung von kohlenmonoxid aus einem wasserstoffreichen gas |
Country Status (11)
Country | Link |
---|---|
US (2) | US6245214B1 (de) |
EP (1) | EP1115470B1 (de) |
JP (1) | JP2002526355A (de) |
KR (1) | KR20010088810A (de) |
CN (1) | CN1326376A (de) |
AT (1) | ATE309853T1 (de) |
AU (1) | AU740302B2 (de) |
BR (1) | BR9916551B1 (de) |
CA (1) | CA2344698C (de) |
DE (1) | DE69928417T2 (de) |
WO (1) | WO2000016880A1 (de) |
Families Citing this family (60)
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US6429019B1 (en) * | 1999-01-19 | 2002-08-06 | Quantum Group, Inc. | Carbon monoxide detection and purification system for fuels cells |
BR0012768A (pt) * | 1999-07-27 | 2002-04-02 | Idatech Llc | Sistema de células de combustìvel |
US6979507B2 (en) | 2000-07-26 | 2005-12-27 | Idatech, Llc | Fuel cell system controller |
DE10012224A1 (de) * | 2000-03-14 | 2001-09-27 | Xcellsis Gmbh | Verfahren zur Verkürzung der Startzeit von CO-Oxidationskatalysatoren in mobilen Brennstoffzellensystemen |
DE10013659A1 (de) * | 2000-03-20 | 2001-12-20 | Volkswagen Ag | Verfahren zum Behandeln von einer Brennstoffzelle, insbesondere eines Fahrzeugs, zuzuführenden Betriebsstoffen und entsprechende Brennstoffzellenvorrichtung |
DE10019772B4 (de) * | 2000-04-20 | 2007-06-21 | Nucellsys Gmbh | Vorrichtung zum Ausgleichen von Konzentrationsschwankungen in Brennstoffzellensystemen |
JP3871501B2 (ja) * | 2000-08-07 | 2007-01-24 | 株式会社ノリタケカンパニーリミテド | ゼオライト膜とその製造方法と膜リアクター |
ES2640910T3 (es) * | 2000-10-27 | 2017-11-07 | Air Products And Chemicals, Inc. | Sistemas y procesos para proporcionar hidrógeno a células de combustible |
DE10111560C1 (de) * | 2001-03-10 | 2002-06-06 | Xcellsis Gmbh | Verfahren und Vorrichtung zur Entfernung von Kohlenmonoxid aus einem Gasstrom |
US6689194B2 (en) * | 2001-03-12 | 2004-02-10 | Motorola, Inc | Fuel cell system having a replaceable getter element for purifying the fuel supply |
US6733909B2 (en) * | 2001-05-03 | 2004-05-11 | Ford Motor Company | Fuel cell power plant with electrochemical enhanced carbon monoxide removal |
US6896792B2 (en) * | 2001-06-13 | 2005-05-24 | Ballard Power Systems Inc. | Method and device for improved catalytic activity in the purification of fluids |
FR2829296B1 (fr) | 2001-09-05 | 2005-05-27 | Renault | Dispositif et procede d'alimentation en hydrogene d'une pile a combustible et utilisation pour la traction electrique d'un vehicule |
US6939640B2 (en) * | 2001-09-21 | 2005-09-06 | E. I. Dupont De Nemours And Company | Anode electrocatalysts for coated substrates used in fuel cells |
US6998991B1 (en) * | 2001-10-01 | 2006-02-14 | Quantum Group Inc. | Dual carbon monoxide sensor system with control catalyst: new CO and humidity method and apparatus |
WO2003067695A2 (en) * | 2002-02-06 | 2003-08-14 | Battelle Memorial Institute | Polymer electrolyte membrane fuel cell system |
AU2003219726A1 (en) | 2002-02-06 | 2003-09-02 | Battelle Memorial Institute | Methods of removing contaminants from a fuel cell electrode |
US7147947B2 (en) * | 2002-02-25 | 2006-12-12 | Delphi Technologies, Inc. | Selective carbon monoxide oxidation catalyst, method of making the same and systems using the same |
JP3722079B2 (ja) * | 2002-03-27 | 2005-11-30 | 日産自動車株式会社 | 一酸化炭素除去装置 |
US20030188475A1 (en) * | 2002-03-29 | 2003-10-09 | Shabbir Ahmed | Dynamic fuel processor with controlled declining temperatures |
US8790114B2 (en) * | 2002-09-27 | 2014-07-29 | GM Global Technology Operations LLC | Byproduct compound retention device for fuel rich start-up combustor |
EP1579522A2 (de) * | 2002-12-05 | 2005-09-28 | Battelle Memorial Institute | Verfahren zum entfernen von schmutz von brennstoffzellenelektrode |
US7678346B2 (en) * | 2003-01-30 | 2010-03-16 | Gm Global Technology Operations, Inc. | Dual function CO clean-up/sorber unit |
US7192460B2 (en) * | 2003-02-28 | 2007-03-20 | Modine Manufacturing Company | Reformate cooling system and method for use in a fuel processing subsystem |
US7763368B2 (en) * | 2003-06-27 | 2010-07-27 | Ultracell Corporation | Efficient micro fuel cell systems and methods |
US8318368B2 (en) * | 2003-06-27 | 2012-11-27 | UltraCell, L.L.C. | Portable systems for engine block |
US8821832B2 (en) | 2003-06-27 | 2014-09-02 | UltraCell, L.L.C. | Fuel processor for use with portable fuel cells |
US20060127711A1 (en) * | 2004-06-25 | 2006-06-15 | Ultracell Corporation, A California Corporation | Systems and methods for fuel cartridge distribution |
WO2005004256A2 (en) * | 2003-06-27 | 2005-01-13 | Ultracell Corporation | Annular fuel processor and methods |
US20050014059A1 (en) | 2003-06-27 | 2005-01-20 | Ultracell Corporation | Micro fuel cell architecture |
WO2005004258A2 (en) * | 2003-06-27 | 2005-01-13 | Ultracell Corporation | Portable fuel cartridge for fuel cells |
US20060156627A1 (en) * | 2003-06-27 | 2006-07-20 | Ultracell Corporation | Fuel processor for use with portable fuel cells |
US7666539B2 (en) * | 2003-06-27 | 2010-02-23 | Ultracell Corporation | Heat efficient portable fuel cell systems |
US7241521B2 (en) | 2003-11-18 | 2007-07-10 | Npl Associates, Inc. | Hydrogen/hydrogen peroxide fuel cell |
US20050255368A1 (en) * | 2004-05-12 | 2005-11-17 | Ultracell Corporation, A California Corporation | High surface area micro fuel cell architecture |
US7842428B2 (en) * | 2004-05-28 | 2010-11-30 | Idatech, Llc | Consumption-based fuel cell monitoring and control |
US8277997B2 (en) * | 2004-07-29 | 2012-10-02 | Idatech, Llc | Shared variable-based fuel cell system control |
US7648792B2 (en) * | 2004-06-25 | 2010-01-19 | Ultracell Corporation | Disposable component on a fuel cartridge and for use with a portable fuel cell system |
US7968250B2 (en) * | 2004-06-25 | 2011-06-28 | Ultracell Corporation | Fuel cartridge connectivity |
US7205060B2 (en) * | 2004-08-06 | 2007-04-17 | Ultracell Corporation | Method and system for controlling fluid delivery in a fuel cell |
US20060029841A1 (en) * | 2004-08-09 | 2006-02-09 | Engelhard Corporation | High surface area, electronically conductive supports for selective CO oxidation catalysts |
CN1317180C (zh) * | 2004-10-28 | 2007-05-23 | 中国石油化工股份有限公司 | 一种去除富氢气体中一氧化碳的方法 |
US7807313B2 (en) * | 2004-12-21 | 2010-10-05 | Ultracell Corporation | Compact fuel cell package |
US7422994B2 (en) * | 2005-01-05 | 2008-09-09 | Symyx Technologies, Inc. | Platinum-copper-tungsten fuel cell catalyst |
US20060194082A1 (en) * | 2005-02-02 | 2006-08-31 | Ultracell Corporation | Systems and methods for protecting a fuel cell |
US9263756B1 (en) * | 2006-04-05 | 2016-02-16 | University Of Central Florida Research Foundation, Inc. | Electrochemical method for the removal of PPM levels of carbon monoxide from hydrogen for a fuel cell |
US7887958B2 (en) * | 2006-05-15 | 2011-02-15 | Idatech, Llc | Hydrogen-producing fuel cell systems with load-responsive feedstock delivery systems |
US7666534B1 (en) * | 2006-09-19 | 2010-02-23 | The United States Of America As Represented By The Untied States Department Of Energy | Electro-catalytic oxidation device for removing carbon from a fuel reformate |
WO2008092024A1 (en) * | 2007-01-24 | 2008-07-31 | Treadstone Technologies, Inc. | Electrochemical processor for hydrogen processing and power generation |
TW200840120A (en) * | 2007-03-20 | 2008-10-01 | Industrie De Nora Spa | Electrochemical cell and method for operating the same |
US20090092879A1 (en) * | 2007-10-05 | 2009-04-09 | Eric Rolland Kreidler | Fuel Cells with Sputter Deposited Pt and Pt Alloy Electrodes |
US20090139207A1 (en) * | 2007-11-30 | 2009-06-04 | Caterpillar Inc. | Thermo-electric auxiliary power unit |
EP2607490A1 (de) | 2011-12-22 | 2013-06-26 | Evonik Industries AG | Verfahren zur verbesserten Abtrennung einer hydrophoben organischen Lösung von einem wässrigen Kulturmedium |
US9463415B2 (en) * | 2013-05-31 | 2016-10-11 | Sustainable Innovations, LLC | Hydrogen recycling apparatus and method of operation |
CN104258723B (zh) * | 2014-10-09 | 2016-07-20 | 安徽蓝盾光电子股份有限公司 | 高效co涤除器 |
DE102017218334A1 (de) | 2017-10-13 | 2019-04-18 | Thyssenkrupp Ag | Reformerbrennstoffzelle |
JP7099331B2 (ja) * | 2019-01-08 | 2022-07-12 | トヨタ自動車株式会社 | 内燃機関の排気浄化装置 |
JP7183796B2 (ja) | 2019-01-08 | 2022-12-06 | トヨタ自動車株式会社 | 電気化学リアクタ |
JP7222023B2 (ja) * | 2020-05-26 | 2023-02-14 | インディアン オイル コーポレイション リミテッド | Co汚染された水素ガスでpem燃料電池を動作させるための方法及び装置 |
JP2024007764A (ja) * | 2022-07-06 | 2024-01-19 | 株式会社デンソー | 電気化学セル |
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US3884838A (en) | 1970-09-01 | 1975-05-20 | Inst Gas Technology | Ruthenium-reduced amorphous tungsten oxide catalyst |
CA1252451A (en) | 1984-07-04 | 1989-04-11 | Taisuke Nishida | Method of separating carbon monoxide and carbon monoxide adsorbent used in this method |
US4711828A (en) | 1985-05-27 | 1987-12-08 | Babcock-Hitachi Kabushiki Kaisha | Carbon monoxide-oxygen fuel cell |
US4910099A (en) | 1988-12-05 | 1990-03-20 | The United States Of America As Represented By The United States Department Of Energy | Preventing CO poisoning in fuel cells |
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US5531809A (en) | 1994-09-14 | 1996-07-02 | Air Products And Chemicals, Inc. | Pretreatment layer for CO-VSA |
US5804325A (en) | 1995-01-13 | 1998-09-08 | Westfield Trading Corporation | Non poisoning fuel cell and method |
DE19615562C1 (de) * | 1996-04-19 | 1997-10-09 | Zsw | Vorrichtung und Verfahren zur kombinierten Reinigung und Kompression von CO-haltigem Wasserstoff sowie Verwendung des mit dem Verfahren erhaltenen Wasserstoffs als Brenngas in Brennstoffzellen |
-
1999
- 1999-09-09 US US09/393,103 patent/US6245214B1/en not_active Expired - Lifetime
- 1999-09-17 AT AT99946992T patent/ATE309853T1/de not_active IP Right Cessation
- 1999-09-17 JP JP2000573836A patent/JP2002526355A/ja active Pending
- 1999-09-17 DE DE69928417T patent/DE69928417T2/de not_active Expired - Fee Related
- 1999-09-17 EP EP99946992A patent/EP1115470B1/de not_active Expired - Lifetime
- 1999-09-17 AU AU59284/99A patent/AU740302B2/en not_active Ceased
- 1999-09-17 CA CA002344698A patent/CA2344698C/en not_active Expired - Fee Related
- 1999-09-17 KR KR1020017003536A patent/KR20010088810A/ko not_active Application Discontinuation
- 1999-09-17 BR BRPI9916551-1A patent/BR9916551B1/pt not_active IP Right Cessation
- 1999-09-17 WO PCT/US1999/021634 patent/WO2000016880A1/en active IP Right Grant
- 1999-09-17 CN CN99813379A patent/CN1326376A/zh active Pending
-
2001
- 2001-05-03 US US09/849,473 patent/US20010037948A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
EP1115470A1 (de) | 2001-07-18 |
ATE309853T1 (de) | 2005-12-15 |
BR9916551B1 (pt) | 2009-05-05 |
BR9916551A (pt) | 2004-08-03 |
AU740302B2 (en) | 2001-11-01 |
DE69928417T2 (de) | 2006-07-27 |
AU5928499A (en) | 2000-04-10 |
US20010037948A1 (en) | 2001-11-08 |
US6245214B1 (en) | 2001-06-12 |
WO2000016880A1 (en) | 2000-03-30 |
CN1326376A (zh) | 2001-12-12 |
CA2344698C (en) | 2008-11-18 |
KR20010088810A (ko) | 2001-09-28 |
JP2002526355A (ja) | 2002-08-20 |
EP1115470B1 (de) | 2005-11-16 |
CA2344698A1 (en) | 2000-03-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |