JP2000072939A5 - - Google Patents
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- JP2000072939A5 JP2000072939A5 JP1998241252A JP24125298A JP2000072939A5 JP 2000072939 A5 JP2000072939 A5 JP 2000072939A5 JP 1998241252 A JP1998241252 A JP 1998241252A JP 24125298 A JP24125298 A JP 24125298A JP 2000072939 A5 JP2000072939 A5 JP 2000072939A5
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- rubber
- carbon atoms
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229920001971 elastomer Polymers 0.000 claims description 74
- 239000005060 rubber Substances 0.000 claims description 74
- 125000004432 carbon atoms Chemical group C* 0.000 claims description 53
- 239000005977 Ethylene Substances 0.000 claims description 39
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 39
- 239000000203 mixture Substances 0.000 claims description 39
- 150000001993 dienes Chemical class 0.000 claims description 18
- 239000004711 α-olefin Substances 0.000 claims description 18
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 9
- VHOQXEIFYTTXJU-UHFFFAOYSA-N 2-methylbuta-1,3-diene;2-methylprop-1-ene Chemical class CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims description 8
- 239000003431 cross linking reagent Substances 0.000 claims description 7
- 238000005227 gel permeation chromatography Methods 0.000 claims description 7
- 150000002430 hydrocarbons Chemical group 0.000 claims description 7
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052740 iodine Inorganic materials 0.000 claims description 6
- 239000011630 iodine Substances 0.000 claims description 6
- 229920005555 halobutyl Polymers 0.000 claims description 5
- 150000004291 polyenes Polymers 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- 229960003563 Calcium Carbonate Drugs 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L Magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- FKHIFSZMMVMEQY-UHFFFAOYSA-N Talc Chemical compound [Mg+2].[O-][Si]([O-])=O FKHIFSZMMVMEQY-UHFFFAOYSA-N 0.000 claims description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 229910052570 clay Inorganic materials 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- 239000011776 magnesium carbonate Substances 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 239000000391 magnesium silicate Substances 0.000 claims description 2
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 2
- 235000019792 magnesium silicate Nutrition 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910001929 titanium oxide Inorganic materials 0.000 claims description 2
- 229920001038 ethylene copolymer Polymers 0.000 claims 2
- 239000004793 Polystyrene Substances 0.000 claims 1
- 239000010419 fine particle Substances 0.000 claims 1
- 229920002223 polystyrene Polymers 0.000 claims 1
- 238000004381 surface treatment Methods 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 description 37
- 150000001875 compounds Chemical class 0.000 description 19
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 16
- -1 transition metal alkyl compound Chemical class 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 10
- 238000003786 synthesis reaction Methods 0.000 description 10
- 230000002194 synthesizing Effects 0.000 description 10
- 239000003054 catalyst Substances 0.000 description 9
- 125000003710 aryl alkyl group Chemical group 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 8
- 239000005062 Polybutadiene Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- UCKITPBQPGXDHV-UHFFFAOYSA-N 7-methylocta-1,6-diene Chemical compound CC(C)=CCCCC=C UCKITPBQPGXDHV-UHFFFAOYSA-N 0.000 description 6
- NLDGJRWPPOSWLC-UHFFFAOYSA-N deca-1,9-diene Chemical compound C=CCCCCCCC=C NLDGJRWPPOSWLC-UHFFFAOYSA-N 0.000 description 6
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-Octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 229910052723 transition metal Inorganic materials 0.000 description 5
- 240000008528 Hevea brasiliensis Species 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 4
- 229920005549 butyl rubber Polymers 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
- 229920001194 natural rubber Polymers 0.000 description 4
- CBENFWSGALASAD-UHFFFAOYSA-N ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 4
- 239000002685 polymerization catalyst Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-Hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 229920000459 Nitrile rubber Polymers 0.000 description 3
- SVHQOIWIRUVWII-UHFFFAOYSA-N Tetraphenylborate Chemical compound C1=CC=CC=C1[B-](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 SVHQOIWIRUVWII-UHFFFAOYSA-N 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 230000000737 periodic Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N Methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N Octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N Triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
- 125000004429 atoms Chemical group 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 230000027455 binding Effects 0.000 description 2
- BRHZQNMGSKUUMN-UHFFFAOYSA-O dimethyl(phenyl)azanium;tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide Chemical compound C[NH+](C)C1=CC=CC=C1.FC1=C(F)C(F)=C(F)C(F)=C1[B-](C=1C(=C(F)C(F)=C(F)C=1F)F)(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F BRHZQNMGSKUUMN-UHFFFAOYSA-O 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 2
- 150000008040 ionic compounds Chemical class 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N n-butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N n-heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- XWJBRBSPAODJER-UHFFFAOYSA-N octa-1,7-diene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N silicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- BIUNYMXQLNNMJR-UHFFFAOYSA-N tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1[B-](C=1C(=C(F)C(F)=C(F)C=1F)F)(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F BIUNYMXQLNNMJR-UHFFFAOYSA-N 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium(0) Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-Dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 1
- UBRWPVTUQDJKCC-UHFFFAOYSA-N 1,3-bis(2-tert-butylperoxypropan-2-yl)benzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC(C(C)(C)OOC(C)(C)C)=C1 UBRWPVTUQDJKCC-UHFFFAOYSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-Dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 1
- PAOHAQSLJSMLAT-UHFFFAOYSA-N 1-butylperoxybutane Chemical group CCCCOOCCCC PAOHAQSLJSMLAT-UHFFFAOYSA-N 0.000 description 1
- YZIGJVNDQRRAGR-UHFFFAOYSA-N 1-methylpyridin-1-ium;tetraphenylboranuide Chemical compound C[N+]1=CC=CC=C1.C1=CC=CC=C1[B-](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 YZIGJVNDQRRAGR-UHFFFAOYSA-N 0.000 description 1
- NOSXUFXBUISMPR-UHFFFAOYSA-N 1-tert-butylperoxyhexane Chemical compound CCCCCCOOC(C)(C)C NOSXUFXBUISMPR-UHFFFAOYSA-N 0.000 description 1
- BZUZAEPFEKIGPN-UHFFFAOYSA-N 10-methyldodeca-1,10-diene Chemical compound CC=C(C)CCCCCCCC=C BZUZAEPFEKIGPN-UHFFFAOYSA-N 0.000 description 1
- QBOYHPZSWJBLIJ-UHFFFAOYSA-N 10-methylundeca-1,9-diene Chemical compound CC(C)=CCCCCCCC=C QBOYHPZSWJBLIJ-UHFFFAOYSA-N 0.000 description 1
- KYSNRMGJOYWQQR-UHFFFAOYSA-N 11-methyldodeca-1,10-diene Chemical compound CC(C)=CCCCCCCCC=C KYSNRMGJOYWQQR-UHFFFAOYSA-N 0.000 description 1
- ITFHIGXCSJDWFO-UHFFFAOYSA-N 12-methyltetradeca-1,12-diene Chemical compound CC=C(C)CCCCCCCCCC=C ITFHIGXCSJDWFO-UHFFFAOYSA-N 0.000 description 1
- YRRXXGBEHQKNQY-UHFFFAOYSA-N 12-methyltrideca-1,11-diene Chemical compound CC(C)=CCCCCCCCCC=C YRRXXGBEHQKNQY-UHFFFAOYSA-N 0.000 description 1
- FKRGPLRPHJPHBR-UHFFFAOYSA-N 13-methylpentadeca-1,13-diene Chemical compound CC=C(C)CCCCCCCCCCC=C FKRGPLRPHJPHBR-UHFFFAOYSA-N 0.000 description 1
- BDVDLXNMLLNBHY-UHFFFAOYSA-N 13-methyltetradeca-1,12-diene Chemical compound CC(C)=CCCCCCCCCCC=C BDVDLXNMLLNBHY-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- PGYVFKIGDBMCKK-UHFFFAOYSA-N 14-methylpentadeca-1,13-diene Chemical compound CC(C)=CCCCCCCCCCCC=C PGYVFKIGDBMCKK-UHFFFAOYSA-N 0.000 description 1
- BYLSIPUARIZAHZ-UHFFFAOYSA-N 2,4,6-tris(1-phenylethyl)phenol Chemical compound C=1C(C(C)C=2C=CC=CC=2)=C(O)C(C(C)C=2C=CC=CC=2)=CC=1C(C)C1=CC=CC=C1 BYLSIPUARIZAHZ-UHFFFAOYSA-N 0.000 description 1
- CZNRFEXEPBITDS-UHFFFAOYSA-N 2,5-bis(2-methylbutan-2-yl)benzene-1,4-diol Chemical compound CCC(C)(C)C1=CC(O)=C(C(C)(C)CC)C=C1O CZNRFEXEPBITDS-UHFFFAOYSA-N 0.000 description 1
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 1
- IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 description 1
- BDCLTORUANJIBT-UHFFFAOYSA-N 3-butylperoxy-1,1,5-trimethylcyclohexane Chemical group CCCCOOC1CC(C)CC(C)(C)C1 BDCLTORUANJIBT-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-Methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- PUSWNIYIUKVCHE-UHFFFAOYSA-N 4-ethylidene-10,11-dimethyldodeca-1,10-diene Chemical compound C=CCC(=CC)CCCCCC(C)=C(C)C PUSWNIYIUKVCHE-UHFFFAOYSA-N 0.000 description 1
- MLKIBLSKMUHVGL-UHFFFAOYSA-N 4-ethylidene-10-methylundeca-1,9-diene Chemical compound C=CCC(=CC)CCCCC=C(C)C MLKIBLSKMUHVGL-UHFFFAOYSA-N 0.000 description 1
- DLMOKKCUOSQFQR-UHFFFAOYSA-N 4-ethylidene-11-methyldodeca-1,10-diene Chemical compound C=CCC(=CC)CCCCCC=C(C)C DLMOKKCUOSQFQR-UHFFFAOYSA-N 0.000 description 1
- RMTZWXLMKQEBRG-UHFFFAOYSA-N 4-ethylidene-6,7-dimethylocta-1,6-diene Chemical compound C=CCC(=CC)CC(C)=C(C)C RMTZWXLMKQEBRG-UHFFFAOYSA-N 0.000 description 1
- PKACLNMVXGSHKE-UHFFFAOYSA-N 4-ethylidene-6-propan-2-ylidenenon-1-ene Chemical compound CCCC(=C(C)C)CC(=CC)CC=C PKACLNMVXGSHKE-UHFFFAOYSA-N 0.000 description 1
- UXUVCSBXPKDUET-UHFFFAOYSA-N 4-ethylidene-7,8-dimethylundeca-1,7-diene Chemical compound CCCC(C)=C(C)CCC(=CC)CC=C UXUVCSBXPKDUET-UHFFFAOYSA-N 0.000 description 1
- NJYHDOBAWAPTCQ-UHFFFAOYSA-N 4-ethylidene-7-methyldeca-1,6-diene Chemical compound CCCC(C)=CCC(=CC)CC=C NJYHDOBAWAPTCQ-UHFFFAOYSA-N 0.000 description 1
- OLBNUAAKBZOEAZ-UHFFFAOYSA-N 4-ethylidene-7-methylnona-1,6-diene Chemical compound CCC(C)=CCC(=CC)CC=C OLBNUAAKBZOEAZ-UHFFFAOYSA-N 0.000 description 1
- FCRAPARCDIBORN-UHFFFAOYSA-N 4-ethylidene-7-methylocta-1,6-diene Chemical compound C=CCC(=CC)CC=C(C)C FCRAPARCDIBORN-UHFFFAOYSA-N 0.000 description 1
- QDJZWIQLQXYELD-UHFFFAOYSA-N 4-ethylidene-8,9-dimethyldeca-1,8-diene Chemical compound C=CCC(=CC)CCCC(C)=C(C)C QDJZWIQLQXYELD-UHFFFAOYSA-N 0.000 description 1
- HBPSHRBTXIZBDI-UHFFFAOYSA-N 4-ethylidene-8-methylnona-1,7-diene Chemical compound C=CCC(=CC)CCC=C(C)C HBPSHRBTXIZBDI-UHFFFAOYSA-N 0.000 description 1
- YXBYLWBGURJODE-UHFFFAOYSA-N 4-ethylidene-9,10-dimethylundeca-1,9-diene Chemical compound C=CCC(=CC)CCCCC(C)=C(C)C YXBYLWBGURJODE-UHFFFAOYSA-N 0.000 description 1
- NNTQDUWXJJRSJL-UHFFFAOYSA-N 4-ethylidene-9-methyldeca-1,8-diene Chemical compound C=CCC(=CC)CCCC=C(C)C NNTQDUWXJJRSJL-UHFFFAOYSA-N 0.000 description 1
- KQLYKUOOOHJKCH-UHFFFAOYSA-N 4-ethylidenedeca-1,6-diene Chemical compound CCCC=CCC(=CC)CC=C KQLYKUOOOHJKCH-UHFFFAOYSA-N 0.000 description 1
- IUHXXTKUQIFRLV-UHFFFAOYSA-N 4-ethylidenenona-1,7-diene Chemical compound CC=CCCC(=CC)CC=C IUHXXTKUQIFRLV-UHFFFAOYSA-N 0.000 description 1
- JBVMSEMQJGGOFR-UHFFFAOYSA-N 4-methylhexa-1,4-diene Chemical compound CC=C(C)CC=C JBVMSEMQJGGOFR-UHFFFAOYSA-N 0.000 description 1
- FYZHLRMYDRUDES-UHFFFAOYSA-N 5,7-dimethylocta-1,6-diene Chemical compound CC(C)=CC(C)CCC=C FYZHLRMYDRUDES-UHFFFAOYSA-N 0.000 description 1
- HFVZWWUGHWNHFL-UHFFFAOYSA-N 5,9-dimethyldeca-1,4,8-triene Chemical compound CC(C)=CCCC(C)=CCC=C HFVZWWUGHWNHFL-UHFFFAOYSA-N 0.000 description 1
- WNEYWVBECXCQRT-UHFFFAOYSA-N 5-methylhept-1-ene Chemical compound CCC(C)CCC=C WNEYWVBECXCQRT-UHFFFAOYSA-N 0.000 description 1
- OJVSJOBJBMTKIW-UHFFFAOYSA-N 5-methylhepta-1,5-diene Chemical compound CC=C(C)CCC=C OJVSJOBJBMTKIW-UHFFFAOYSA-N 0.000 description 1
- JIUFYGIESXPUPL-UHFFFAOYSA-N 5-methylhex-1-ene Chemical compound CC(C)CCC=C JIUFYGIESXPUPL-UHFFFAOYSA-N 0.000 description 1
- VSQLAQKFRFTMNS-UHFFFAOYSA-N 5-methylhexa-1,4-diene Chemical compound CC(C)=CCC=C VSQLAQKFRFTMNS-UHFFFAOYSA-N 0.000 description 1
- VHIVJUNIYOCPSI-UHFFFAOYSA-N 6,10-dimethylundeca-1,5,9-triene Chemical compound CC(C)=CCCC(C)=CCCC=C VHIVJUNIYOCPSI-UHFFFAOYSA-N 0.000 description 1
- DHBQJICESILRNK-UHFFFAOYSA-N 6-methylocta-1,6-diene Chemical compound CC=C(C)CCCC=C DHBQJICESILRNK-UHFFFAOYSA-N 0.000 description 1
- UQEJJSKNCOAIIZ-UHFFFAOYSA-N 7,8-diethyl-4-ethylidenedeca-1,7-diene Chemical compound CCC(CC)=C(CC)CCC(=CC)CC=C UQEJJSKNCOAIIZ-UHFFFAOYSA-N 0.000 description 1
- GQWSXMDIUMCXKX-UHFFFAOYSA-N 7-ethyl-4-ethylidene-8-methylundeca-1,7-diene Chemical compound CCCC(C)=C(CC)CCC(=CC)CC=C GQWSXMDIUMCXKX-UHFFFAOYSA-N 0.000 description 1
- IFKFMPUNGADJML-UHFFFAOYSA-N 7-ethyl-4-ethylidenenona-1,6-diene Chemical compound CCC(CC)=CCC(=CC)CC=C IFKFMPUNGADJML-UHFFFAOYSA-N 0.000 description 1
- XGJONQYTWPCPRL-UHFFFAOYSA-N 7-methylnona-1,7-diene Chemical compound CC=C(C)CCCCC=C XGJONQYTWPCPRL-UHFFFAOYSA-N 0.000 description 1
- ORSOHOYCAKNPQE-UHFFFAOYSA-N 8-methyldeca-1,8-diene Chemical compound CC=C(C)CCCCCC=C ORSOHOYCAKNPQE-UHFFFAOYSA-N 0.000 description 1
- VMEDJHVTTJXKCN-UHFFFAOYSA-N 8-methylnona-1,7-diene Chemical compound CC(C)=CCCCCC=C VMEDJHVTTJXKCN-UHFFFAOYSA-N 0.000 description 1
- PWENCKJTWWADRJ-UHFFFAOYSA-N 9-methyldeca-1,8-diene Chemical compound CC(C)=CCCCCCC=C PWENCKJTWWADRJ-UHFFFAOYSA-N 0.000 description 1
- AJEIWMUSRKQKPH-UHFFFAOYSA-N 9-methylundeca-1,9-diene Chemical compound CC=C(C)CCCCCCC=C AJEIWMUSRKQKPH-UHFFFAOYSA-N 0.000 description 1
- 241000180579 Arca Species 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 239000007848 Bronsted acid Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- OSLRVXQZMQEGRT-UHFFFAOYSA-N C[SiH](C)[N-]C(C)(C)C Chemical compound C[SiH](C)[N-]C(C)(C)C OSLRVXQZMQEGRT-UHFFFAOYSA-N 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N Decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N Decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N Di-tert-butyl peroxide Chemical group CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Dilauryl thiodipropionate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- DVSDBMFJEQPWNO-UHFFFAOYSA-N Methyllithium Chemical compound C[Li] DVSDBMFJEQPWNO-UHFFFAOYSA-N 0.000 description 1
- 241000357292 Monodactylus Species 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N Nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- JFNLZVQOOSMTJK-UHFFFAOYSA-N Norbornene Chemical compound C1C2CCC1C=C2 JFNLZVQOOSMTJK-UHFFFAOYSA-N 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N Pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N Triethylaluminium Chemical group CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N Trimethylaluminium Chemical group C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- RBQGALRSGWYFMO-UHFFFAOYSA-L [Cl-].[Cl-].C1(C=CC=C1)[Zr+2]C1=CC=CC=2C3=CC=CC=C3CC1=2 Chemical compound [Cl-].[Cl-].C1(C=CC=C1)[Zr+2]C1=CC=CC=2C3=CC=CC=C3CC1=2 RBQGALRSGWYFMO-UHFFFAOYSA-L 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000004416 alkarylalkyl group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002837 carbocyclic group Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920005556 chlorobutyl Polymers 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- HASGOCLZFTZSTN-UHFFFAOYSA-N cyclohexane;hexane Chemical compound CCCCCC.C1CCCCC1 HASGOCLZFTZSTN-UHFFFAOYSA-N 0.000 description 1
- 125000004663 dialkyl amino group Chemical group 0.000 description 1
- OAMUREIFBAAWJX-UHFFFAOYSA-O dibutyl(methyl)azanium;tetraphenylboranuide Chemical compound CCCC[NH+](C)CCCC.C1=CC=CC=C1[B-](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 OAMUREIFBAAWJX-UHFFFAOYSA-O 0.000 description 1
- CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical group CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- IYPLTVKTLDQUGG-UHFFFAOYSA-N dodeca-1,11-diene Chemical compound C=CCCCCCCCCC=C IYPLTVKTLDQUGG-UHFFFAOYSA-N 0.000 description 1
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- GEAWFZNTIFJMHR-UHFFFAOYSA-N hepta-1,6-diene Chemical compound C=CCCCC=C GEAWFZNTIFJMHR-UHFFFAOYSA-N 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- KLGZELKXQMTEMM-UHFFFAOYSA-N hydride Chemical compound [H-] KLGZELKXQMTEMM-UHFFFAOYSA-N 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000001771 impaired Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002738 metalloids Chemical group 0.000 description 1
- 229940094933 n-dodecane Drugs 0.000 description 1
- VJHGSLHHMIELQD-UHFFFAOYSA-N nona-1,8-diene Chemical compound C=CCCCCCC=C VJHGSLHHMIELQD-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N o-xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- LAGGTOBQMQHXON-UHFFFAOYSA-N octa-2,6-diene Chemical compound CC=CCCC=CC LAGGTOBQMQHXON-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000012169 petroleum derived wax Substances 0.000 description 1
- 235000019381 petroleum wax Nutrition 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000004083 survival Effects 0.000 description 1
- QQIMUPFCBBIKKN-UHFFFAOYSA-N tetradeca-1,11-diene Chemical compound CCC=CCCCCCCCCC=C QQIMUPFCBBIKKN-UHFFFAOYSA-N 0.000 description 1
- XMRSTLBCBDIKFI-UHFFFAOYSA-N tetradeca-1,13-diene Chemical compound C=CCCCCCCCCCCC=C XMRSTLBCBDIKFI-UHFFFAOYSA-N 0.000 description 1
- PKOLCPGOUTYGFF-UHFFFAOYSA-O tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide;tributylazanium Chemical compound CCCC[NH+](CCCC)CCCC.FC1=C(F)C(F)=C(F)C(F)=C1[B-](C=1C(=C(F)C(F)=C(F)C=1F)F)(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F PKOLCPGOUTYGFF-UHFFFAOYSA-O 0.000 description 1
- BOJSJKYSHLVBEK-UHFFFAOYSA-O tetrakis(2,3,4,5,6-pentafluorophenyl)boranuide;triethylazanium Chemical compound CC[NH+](CC)CC.FC1=C(F)C(F)=C(F)C(F)=C1[B-](C=1C(=C(F)C(F)=C(F)C=1F)F)(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F BOJSJKYSHLVBEK-UHFFFAOYSA-O 0.000 description 1
- SHTJDQBVDZPFSI-UHFFFAOYSA-O tetraphenylboranuide;tributylazanium Chemical compound CCCC[NH+](CCCC)CCCC.C1=CC=CC=C1[B-](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 SHTJDQBVDZPFSI-UHFFFAOYSA-O 0.000 description 1
- XQSMJIJEESBUTH-UHFFFAOYSA-O tetraphenylboranuide;triethylazanium Chemical compound CC[NH+](CC)CC.C1=CC=CC=C1[B-](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 XQSMJIJEESBUTH-UHFFFAOYSA-O 0.000 description 1
- HHBWPCWFGJXCHW-UHFFFAOYSA-O tetraphenylboranuide;trimethylazanium Chemical compound C[NH+](C)C.C1=CC=CC=C1[B-](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 HHBWPCWFGJXCHW-UHFFFAOYSA-O 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- BPHFKBMQSYYNGQ-UHFFFAOYSA-N trideca-1,12-diene Chemical compound C=CCCCCCCCCCC=C BPHFKBMQSYYNGQ-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-O trimethylammonium Chemical compound C[NH+](C)C GETQZCLCWQTVFV-UHFFFAOYSA-O 0.000 description 1
- VOSLXTGMYNYCPW-UHFFFAOYSA-N undeca-1,10-diene Chemical compound C=CCCCCCCCC=C VOSLXTGMYNYCPW-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 1
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10241252A JP2000072939A (ja) | 1998-08-27 | 1998-08-27 | ゴム組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10241252A JP2000072939A (ja) | 1998-08-27 | 1998-08-27 | ゴム組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000072939A JP2000072939A (ja) | 2000-03-07 |
| JP2000072939A5 true JP2000072939A5 (fr) | 2005-10-20 |
Family
ID=17071483
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10241252A Pending JP2000072939A (ja) | 1998-08-27 | 1998-08-27 | ゴム組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000072939A (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114369297B (zh) * | 2020-10-16 | 2023-12-08 | 旭化成株式会社 | 交联用橡胶组合物、交联橡胶的制造方法、以及轮胎用胎面 |
-
1998
- 1998-08-27 JP JP10241252A patent/JP2000072939A/ja active Pending
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