ITFI20060030A1 - Processo per la preparazione di dispersioni acquose di ti02 in forma nanoparticelle e dispersioni ottenibili con questo processo - Google Patents
Processo per la preparazione di dispersioni acquose di ti02 in forma nanoparticelle e dispersioni ottenibili con questo processo Download PDFInfo
- Publication number
- ITFI20060030A1 ITFI20060030A1 IT000030A ITFI20060030A ITFI20060030A1 IT FI20060030 A1 ITFI20060030 A1 IT FI20060030A1 IT 000030 A IT000030 A IT 000030A IT FI20060030 A ITFI20060030 A IT FI20060030A IT FI20060030 A1 ITFI20060030 A1 IT FI20060030A1
- Authority
- IT
- Italy
- Prior art keywords
- process according
- dispersions
- preparation
- tio2
- titanium alkoxide
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 43
- 239000006185 dispersion Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 230000008569 process Effects 0.000 title claims description 33
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 58
- 230000001699 photocatalysis Effects 0.000 claims abstract description 18
- 238000000576 coating method Methods 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 5
- 238000005202 decontamination Methods 0.000 claims abstract description 4
- 230000003588 decontaminative effect Effects 0.000 claims abstract description 4
- 239000007789 gas Substances 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000010936 titanium Substances 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 11
- -1 titanium alkoxide Chemical class 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 10
- 239000013504 Triton X-100 Substances 0.000 claims description 7
- 229920004890 Triton X-100 Polymers 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- 239000000919 ceramic Substances 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- 229910052684 Cerium Inorganic materials 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical group CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000002537 cosmetic Substances 0.000 claims description 3
- 238000009472 formulation Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 229910052723 transition metal Inorganic materials 0.000 claims description 3
- 150000003624 transition metals Chemical class 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 210000002615 epidermis Anatomy 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 claims description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 2
- NBTOZLQBSIZIKS-UHFFFAOYSA-N methoxide Chemical compound [O-]C NBTOZLQBSIZIKS-UHFFFAOYSA-N 0.000 claims description 2
- OGHBATFHNDZKSO-UHFFFAOYSA-N propan-2-olate Chemical compound CC(C)[O-] OGHBATFHNDZKSO-UHFFFAOYSA-N 0.000 claims description 2
- 230000001681 protective effect Effects 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- 210000003298 dental enamel Anatomy 0.000 claims 1
- 239000012433 hydrogen halide Substances 0.000 claims 1
- 229910000039 hydrogen halide Inorganic materials 0.000 claims 1
- 229960005235 piperonyl butoxide Drugs 0.000 claims 1
- IKNCGYCHMGNBCP-UHFFFAOYSA-N propan-1-olate Chemical compound CCC[O-] IKNCGYCHMGNBCP-UHFFFAOYSA-N 0.000 claims 1
- 239000004753 textile Substances 0.000 claims 1
- 239000004408 titanium dioxide Substances 0.000 description 10
- 239000002245 particle Substances 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000012512 characterization method Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000002296 dynamic light scattering Methods 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000002105 nanoparticle Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000005345 coagulation Methods 0.000 description 3
- 230000015271 coagulation Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000000445 field-emission scanning electron microscopy Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 239000002957 persistent organic pollutant Substances 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000004627 transmission electron microscopy Methods 0.000 description 2
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 206010029098 Neoplasm skin Diseases 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 208000000453 Skin Neoplasms Diseases 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 229910001773 titanium mineral Inorganic materials 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
-
- B01J35/39—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
- C01G23/053—Producing by wet processes, e.g. hydrolysing titanium salts
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/245—Oxides by deposition from the vapour phase
- C03C17/2456—Coating containing TiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/25—Oxides by deposition from the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3669—Treatment with low-molecular organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
- C01P2002/54—Solid solutions containing elements as dopants one element only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/90—Other properties not specified above
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/212—TiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/71—Photocatalytic coatings
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Manufacturing & Machinery (AREA)
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Colloid Chemistry (AREA)
- Cosmetics (AREA)
Priority Applications (19)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT000030A ITFI20060030A1 (it) | 2006-02-01 | 2006-02-01 | Processo per la preparazione di dispersioni acquose di ti02 in forma nanoparticelle e dispersioni ottenibili con questo processo |
| PL07726249T PL1996515T3 (pl) | 2006-02-01 | 2007-01-29 | Sposób wytwarzania wodnych dyspersji TiO₂ w postaci nanocząstek i dyspersje wytwarzane tym sposobem |
| US12/162,539 US8431621B2 (en) | 2006-02-01 | 2007-01-29 | Method for the preparation of aqueous dispersions of TiO2 in the form of nanoparticles, and dispersions obtainable with this method |
| ES07726249T ES2357369T3 (es) | 2006-02-01 | 2007-01-29 | MÉTODO PARA LA PREPARACIÓN DE DISPERSIONES ACUOSAS DE TiO2 EN FORMA DE NANOPARTÍCULAS, Y DISPERSIONES OBTENIBLES CON ESTE MÉTODO. |
| DE602007010908T DE602007010908D1 (de) | 2006-02-01 | 2007-01-29 | Verfahren zur herstellung von wässrigen dispersionen von tio2 in form von nanopartikeln und danach erhältliche dispersionen |
| PCT/EP2007/050826 WO2007088151A1 (en) | 2006-02-01 | 2007-01-29 | Method for the preparation of aqueous dispersions of tio2 in the form of nanoparticles, and dispersions obtainable with this method |
| RU2008135345/05A RU2431604C2 (ru) | 2006-02-01 | 2007-01-29 | СПОСОБ ПРИГОТОВЛЕНИЯ ВОДНЫХ ДИСПЕРСИЙ TiO2 В ФОРМЕ НАНОЧАСТИЦ И ДИСПЕРСИИ, КОТОРЫЕ МОГУТ БЫТЬ ПОЛУЧЕНЫ ЭТИМ СПОСОБОМ |
| KR1020087019004A KR101353850B1 (ko) | 2006-02-01 | 2007-01-29 | 이산화티타늄 나노입자상 수분산액 제조 방법 및 그방법으로 수득할 수 있는 분산액 |
| JP2008552790A JP5281415B2 (ja) | 2006-02-01 | 2007-01-29 | ナノ粒子の形態のＴｉＯ２の水性分散液の製造方法、及びこの方法で得られる分散体 |
| AU2007211536A AU2007211536B2 (en) | 2006-02-01 | 2007-01-29 | Method for the preparation of aqueous dispersions of TiO2 in the form of nanoparticles, and dispersions obtainable with this method |
| CN2007800041476A CN101378993B (zh) | 2006-02-01 | 2007-01-29 | 制备TiO2纳米颗粒水性分散液的方法以及由此所得分散液 |
| CA2640938A CA2640938C (en) | 2006-02-01 | 2007-01-29 | Method for the preparation of aqueous dispersions of tio2 in the form of nanoparticles, and dispersions obtainable with this method |
| EP07726249A EP1996515B1 (en) | 2006-02-01 | 2007-01-29 | Method for the preparation of aqueous dispersions of tio2 in the form of nanoparticles, and dispersions obtainable with this method |
| DK07726249.1T DK1996515T3 (da) | 2006-02-01 | 2007-01-29 | Fremgangsmåde til frembringelsen af vandige dispergeringer af TIO2 i form af nanopartikler, samt dispergeringer, der kan frembringes ved denne fremgangsmåde |
| BRPI0707256-2A BRPI0707256B1 (pt) | 2006-02-01 | 2007-01-29 | Método para a preparação de dispersões de nanopartículas de tio2 na forma de anatase, dispersões de nanopartículas de tio2 na forma de anatase, dispersões de nanopartículas de tio2 em água e seus usos |
| PT07726249T PT1996515E (pt) | 2006-02-01 | 2007-01-29 | Método para a preparação de dispersões aquosas de tio2 na forma de nanopartículas, e dispersões obteníveis com este método |
| AT07726249T ATE490220T1 (de) | 2006-02-01 | 2007-01-29 | Verfahren zur herstellung von wässrigen dispersionen von tio2 in form von nanopartikeln und danach erhältliche dispersionen |
| NZ570356A NZ570356A (en) | 2006-02-01 | 2007-01-29 | Method for the preparation of aqueous dispersions of TiO2 in the form of nanoparticles, and dispersions obtainable with this method |
| ZA200806991A ZA200806991B (en) | 2006-02-01 | 2008-08-13 | Method for the preparation of aqueous dispersions of TiO2 in the form of nanoparticles, and dispersions obtainable with this method |
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| EP (1) | EP1996515B1 (ru) |
| JP (1) | JP5281415B2 (ru) |
| KR (1) | KR101353850B1 (ru) |
| CN (1) | CN101378993B (ru) |
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| BR (1) | BRPI0707256B1 (ru) |
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| ITFI20060034A1 (it) | 2006-02-03 | 2007-08-04 | Colorobbia Italiana Spa | Processo per la funzionalizzazione di superfici metalliche in titanio con particelle di titanio nanometriche e prodotti cosi' funzionalizzati |
| KR100921381B1 (ko) | 2008-02-19 | 2009-10-14 | 성균관대학교산학협력단 | 비표면적이 증가된 신규한 이산화티탄 촉매 및 이의제조방법 |
| US20110220855A1 (en) * | 2010-03-12 | 2011-09-15 | Weir John D | Self-Cleaning Coating for Protection Against Hazardous Biopathogens and Toxic Chemical Agents Utilizing Both Super Hydrophobic Effects and Suitable Oxide Interfaces |
| CN101844805A (zh) * | 2010-06-08 | 2010-09-29 | 上海工程技术大学 | 一种制备水性高分散纳米二氧化钛的方法 |
| SI23501A (sl) | 2010-10-25 | 2012-04-30 | CINKARNA Metalurško kemiÄŤna industrija Celje, d.d. | Postopek za pridobivanje nanodelcev anatasa visoke specifične površine in sferične morfologije |
| ITFI20110038A1 (it) | 2011-03-03 | 2012-09-04 | Colorobbia Italiana Spa | Cerameri, loro applicazione ed uso. |
| KR101341250B1 (ko) * | 2011-11-28 | 2013-12-12 | 박홍욱 | 연소 및 광촉매성 세라믹 코팅제 조성물 및 이를 이용한 유해가스 저감 코팅제품 |
| RU2477257C1 (ru) * | 2011-12-26 | 2013-03-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Санкт-Петербургский государственный университет" (СПбГУ) | Композиция на основе нанокристаллического диоксида титана, способ ее изготовления и способ применения композиции для получения фотокаталитического покрытия на стекле |
| JP2015520009A (ja) * | 2012-03-20 | 2015-07-16 | ベーリンゲ、フォトカタリティック、アクチボラグＶａｅｌｉｎｇｅ Ｐｈｏｔｏｃａｔａｌｙｔｉｃ Ａｂ | 二酸化チタン及び抗光灰色化添加剤を含む光触媒組成物 |
| KR101397346B1 (ko) * | 2012-06-15 | 2014-05-22 | 경희대학교 산학협력단 | 자외선 차단 및 피부노폐물 흡수 성능을 갖는 화장품용 다기능성 복합체 제조방법 |
| CN103301856B (zh) * | 2013-05-23 | 2014-10-29 | 河北科技大学 | 纳米贵金属/半导体复合光催化剂在有机物卤化反应中的应用 |
| CN103934017A (zh) * | 2014-04-22 | 2014-07-23 | 苏州聚康新材料科技有限公司 | 一种具有高效光催化活性的微乳液的制备方法 |
| CN104190279A (zh) * | 2014-08-27 | 2014-12-10 | 华南师范大学 | 一种纳米二氧化钛分散液的制备方法 |
| CN106219664A (zh) * | 2016-08-10 | 2016-12-14 | 佛山科学技术学院 | 涤/棉一浴法染色的棉基光催化处理染色废水的方法 |
| US11819580B2 (en) | 2016-10-18 | 2023-11-21 | PurWorld Technologies LLC | Method of chemically disinfecting a vehicle |
| IT201700112570A1 (it) * | 2017-10-06 | 2019-04-06 | Andrea Ferruccio Zoppolato | Apparato automatico per la distribuzione di prodotti |
| CN112351954A (zh) * | 2018-05-02 | 2021-02-09 | 卡罗比亚咨询有限责任公司 | 氮掺杂的TiO2纳米颗粒及其在光催化中的用途 |
| EP4031645A1 (en) * | 2019-09-20 | 2022-07-27 | Reair S.r.l. | Sanitization composition and method for sanitization- purification of surfaces and environments |
| IT201900020122A1 (it) | 2019-10-31 | 2021-05-01 | Colorobbia Consulting S R L | Supporto polimerico nanofunzionalizzato con nanoparticelle fotocatalitiche a base di TiO2 e il suo uso nella fotocatalisi |
| IT202000018007A1 (it) | 2020-07-24 | 2022-01-24 | Colorobbia Consulting S R L | Nanoparticelle, substrato nanofunzionalizzato e dispositivo con attività fotocatalitica antifungina |
| IT202000017995A1 (it) | 2020-07-24 | 2022-01-24 | Colorobbia Consulting S R L | Nanoparticelle, substrato nanofunzionalizzato e dispositivo con attività fotocatalitica antivirale |
| IT202000018004A1 (it) | 2020-07-24 | 2022-01-24 | Colorobbia Consulting S R L | Nanoparticelle, substrato nanofunzionalizzato e dispositivo con attività fotocatalitica antibatterica |
| CN114316723B (zh) * | 2022-01-29 | 2022-12-20 | 重庆交通大学 | 光催化成膜组合物及其制备方法和用途 |
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| EP0403473A1 (en) * | 1988-03-03 | 1990-12-27 | AlliedSignal Inc. | Process for preparing monodisperse titania spheres |
| FR2721615A1 (fr) | 1994-06-24 | 1995-12-29 | Rhone Poulenc Chimie | Procédé de préparation de particules d'oxyde métallique organophiles. |
| JPH11343118A (ja) | 1998-06-01 | 1999-12-14 | Minnesota Mining & Mfg Co <3M> | 酸化チタン膜、その製造方法、それをもった物品及びそれを備えた光化学電池 |
| JP2000044242A (ja) * | 1998-07-28 | 2000-02-15 | Teikoku Chem Ind Corp Ltd | 表面被覆組成物 |
| JP2000219515A (ja) * | 1999-01-27 | 2000-08-08 | Jsr Corp | 二酸化チタン前駆体組成物および二酸化チタン |
| FR2789591B1 (fr) * | 1999-02-17 | 2002-10-04 | Rhodia Chimie Sa | Utilisation de dispersions filmogenes de dioxyde de titane pour la desinfection des surfaces dures, dispersions filmogenes de dioxyde de titane et procede de desinfection |
| JP2000334310A (ja) * | 1999-05-28 | 2000-12-05 | Jsr Corp | 光触媒の製造方法 |
| CN1527797A (zh) | 2001-07-06 | 2004-09-08 | ��ʿ����ѧ | 剥落硅酸盐结构中的金属氧化物纳米颗粒 |
| JP2003232018A (ja) * | 2002-02-08 | 2003-08-19 | Hitachi Chem Co Ltd | 光触媒性路面標示物用材料、光触媒性路面標示物の施工方法及び光触媒性路面標示物 |
| AU2003247771A1 (en) * | 2002-09-17 | 2004-04-08 | 3M Innovative Properties Company | Porous surfactant mediated metal oxide films |
| JP4483172B2 (ja) * | 2002-12-05 | 2010-06-16 | 住友化学株式会社 | 酸化チタン分散液 |
| JP4382607B2 (ja) * | 2004-03-15 | 2009-12-16 | 住友大阪セメント株式会社 | 酸化チタン粒子 |
| JP2008518873A (ja) * | 2004-11-02 | 2008-06-05 | ナノゲート エージー | 二酸化チタンナノ粒子の合成 |
| ITFI20040252A1 (it) * | 2004-12-06 | 2005-03-06 | Colorobbia Italiana Spa | Processo per la preparazione di dispersioni di ti02 in forma di nanoparticelle, e dispersioni ottenibili con questo processo |
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Also Published As
| Publication number | Publication date |
|---|---|
| RU2431604C2 (ru) | 2011-10-20 |
| US20080317959A1 (en) | 2008-12-25 |
| ZA200806991B (en) | 2009-06-24 |
| DK1996515T3 (da) | 2011-03-14 |
| PL1996515T3 (pl) | 2011-05-31 |
| CN101378993A (zh) | 2009-03-04 |
| JP5281415B2 (ja) | 2013-09-04 |
| KR20080094675A (ko) | 2008-10-23 |
| ES2357369T3 (es) | 2011-04-25 |
| DE602007010908D1 (de) | 2011-01-13 |
| NZ570356A (en) | 2010-09-30 |
| EP1996515A1 (en) | 2008-12-03 |
| CN101378993B (zh) | 2012-11-07 |
| BRPI0707256B1 (pt) | 2018-06-19 |
| KR101353850B1 (ko) | 2014-01-20 |
| CA2640938A1 (en) | 2007-08-09 |
| ATE490220T1 (de) | 2010-12-15 |
| JP2009525246A (ja) | 2009-07-09 |
| CA2640938C (en) | 2014-10-28 |
| BRPI0707256A2 (pt) | 2011-04-26 |
| US8431621B2 (en) | 2013-04-30 |
| AU2007211536B2 (en) | 2012-10-04 |
| PT1996515E (pt) | 2011-03-09 |
| EP1996515B1 (en) | 2010-12-01 |
| WO2007088151A1 (en) | 2007-08-09 |
| RU2008135345A (ru) | 2010-03-10 |
| AU2007211536A1 (en) | 2007-08-09 |
| BRPI0707256A8 (pt) | 2018-01-09 |
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