IT1255655B - Processo di decapaggio e passivazione di acciaio inossidabile senza impiego di acido nitrico - Google Patents
Processo di decapaggio e passivazione di acciaio inossidabile senza impiego di acido nitricoInfo
- Publication number
- IT1255655B IT1255655B ITMI921946A ITMI921946A IT1255655B IT 1255655 B IT1255655 B IT 1255655B IT MI921946 A ITMI921946 A IT MI921946A IT MI921946 A ITMI921946 A IT MI921946A IT 1255655 B IT1255655 B IT 1255655B
- Authority
- IT
- Italy
- Prior art keywords
- formula
- bath
- stainless steel
- nitric acid
- passivation process
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
- C23G1/086—Iron or steel solutions containing HF
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
Landscapes
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Chemical Treatment Of Metals (AREA)
- ing And Chemical Polishing (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
Abstract
Procedimento per il decapaggio di acciaio inox consistente nel mettere a contatto il materiale da trattare con un bagno mantenuto a temperatura compresa fra 30°C e 70°C ed avente la seguente composizione iniziale:a) (FORMULA)b) (FORMULA)c) (FORMULA)d) (FORMULA)e) additivi emulsionanti, bagnanti, brillantanti e inibitori di attacco acido; in detto bagno essendo immesso In continuo:- un flusso d'aria pari ad almeno 3m3 /h per m3 di bagno, e un quantitativo di H202 stabilizzata regolato in base al potenziale Redox del bagno che deve essere mantenuto a valore ? 250 mV.
Priority Applications (13)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI921946A IT1255655B (it) | 1992-08-06 | 1992-08-06 | Processo di decapaggio e passivazione di acciaio inossidabile senza impiego di acido nitrico |
| AT93111528T ATE191017T1 (de) | 1992-08-06 | 1993-07-19 | Verfahren zum beizen und passivieren von rostfreiem stahl ohne verwendung von salpetersäure |
| DE69328139T DE69328139T2 (de) | 1992-08-06 | 1993-07-19 | Verfahren zum Beizen und Passivieren von rostfreiem Stahl ohne Verwendung von Salpetersäure |
| EP93111528A EP0582121B1 (en) | 1992-08-06 | 1993-07-19 | Process for stainless steel pickling and passivation without using nitric acid |
| DE0582121T DE582121T1 (de) | 1992-08-06 | 1993-07-19 | Verfahren zum Beizen und Passivieren von rostfreiem Stahl ohne Verwendung von Salpetersäure. |
| ES93111528T ES2143995T3 (es) | 1992-08-06 | 1993-07-19 | Proceso para decapar y pasivar acero inoxidable sin el concurso de acido nitrico. |
| HU9302112A HUT67521A (en) | 1992-08-06 | 1993-07-21 | Process for stainless steel pickling and passivation without using nitric acid |
| FI933474A FI101981B (fi) | 1992-08-06 | 1993-08-05 | Menetelmä ruostumattoman teräksen peittaukseen ja passivointiin ilman typpihappoa |
| RU93046281A RU2126460C1 (ru) | 1992-08-06 | 1993-08-05 | Способ протравливания нержавеющей стали |
| JP5212109A JP2819378B2 (ja) | 1992-08-06 | 1993-08-05 | ステンレス鋼のピックリング法 |
| CZ931618A CZ285442B6 (cs) | 1992-08-06 | 1993-08-06 | Způsob moření nekorodující oceli |
| BR9400478A BR9400478A (pt) | 1992-08-06 | 1994-02-09 | Processo para a decapagem e passivação de aço inoxidável sem uso de ácido nítrico |
| US08/874,797 US5908511A (en) | 1992-08-06 | 1997-06-13 | Process for stainless steel pickling and passivation without using nitric acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI921946A IT1255655B (it) | 1992-08-06 | 1992-08-06 | Processo di decapaggio e passivazione di acciaio inossidabile senza impiego di acido nitrico |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| ITMI921946A0 ITMI921946A0 (it) | 1992-08-06 |
| ITMI921946A1 ITMI921946A1 (it) | 1994-02-06 |
| IT1255655B true IT1255655B (it) | 1995-11-09 |
Family
ID=11363848
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ITMI921946A IT1255655B (it) | 1992-08-06 | 1992-08-06 | Processo di decapaggio e passivazione di acciaio inossidabile senza impiego di acido nitrico |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US5908511A (it) |
| EP (1) | EP0582121B1 (it) |
| JP (1) | JP2819378B2 (it) |
| AT (1) | ATE191017T1 (it) |
| BR (1) | BR9400478A (it) |
| CZ (1) | CZ285442B6 (it) |
| DE (2) | DE582121T1 (it) |
| ES (1) | ES2143995T3 (it) |
| FI (1) | FI101981B (it) |
| HU (1) | HUT67521A (it) |
| IT (1) | IT1255655B (it) |
| RU (1) | RU2126460C1 (it) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE504733C2 (sv) * | 1994-06-17 | 1997-04-14 | Ta Chemistry Ab | Förfarande för betning |
| EP0776256B1 (en) * | 1994-09-26 | 2005-07-27 | Steris, Inc. | Stainless steel acid treatment |
| IT1276955B1 (it) * | 1995-10-18 | 1997-11-03 | Novamax Itb S R L | Processo di decapaggio e passivazione di acciaio inossidabile senza impiego di acido nitrico |
| IT1276954B1 (it) * | 1995-10-18 | 1997-11-03 | Novamax Itb S R L | Processo di decapaggio e di passivazione di acciaio inossidabile senza impiego di acido nitrico |
| SE510298C2 (sv) * | 1995-11-28 | 1999-05-10 | Eka Chemicals Ab | Sätt vid betning av stål |
| IT1282979B1 (it) * | 1996-05-09 | 1998-04-03 | Novamax Itb S R L | Procedimento per il decapaggio dell'acciaio nel quale la ossidazione dello ione ferroso formatosi viene effettuata per via elettrochimica |
| TW416996B (en) * | 1996-05-24 | 2001-01-01 | Armco Inc | Hydrogen peroxide pickling of stainless steel |
| FR2772050B1 (fr) * | 1997-12-10 | 1999-12-31 | Imphy Sa | Procede de decapage d'acier et notamment d'acier inoxydable |
| DE19755350A1 (de) * | 1997-12-12 | 1999-06-17 | Henkel Kgaa | Verfahren zum Beizen und Passivieren von Edelstahl |
| GB9807286D0 (en) | 1998-04-06 | 1998-06-03 | Solvay Interox Ltd | Pickling process |
| USH2087H1 (en) * | 1998-05-19 | 2003-11-04 | H. C. Starck, Inc. | Pickling of refractory metals |
| IT1302202B1 (it) | 1998-09-11 | 2000-07-31 | Henkel Kgaa | Processo di decapaggio elettrolitico con soluzioni esenti da acidonitrico. |
| DE19850524C2 (de) * | 1998-11-03 | 2002-04-04 | Eilenburger Elektrolyse & Umwelttechnik Gmbh | Nitratfreies Recycling-Beizverfahren für Edelstähle |
| IT1312556B1 (it) | 1999-05-03 | 2002-04-22 | Henkel Kgaa | Processo di decapaggio di acciaio inossidabile in assenza di acidonitrico ed in presenza di ioni cloruro |
| SE515806C2 (sv) * | 2000-01-19 | 2001-10-08 | Avesta Polarit Ab Publ | Långtidsstabilt betmedel innehållande urea samt sätt att tillverka detta |
| CA2300492A1 (en) | 2000-03-13 | 2001-09-13 | Henkel Corporation | Removal of "copper kiss" from pickling high copper alloys |
| JP4549547B2 (ja) * | 2001-01-25 | 2010-09-22 | 新日鐵住金ステンレス株式会社 | ステンレス鋼の耐食性の評価用試験液および評価方法 |
| ATE309397T1 (de) | 2001-04-09 | 2005-11-15 | Ak Steel Properties Inc | Wasserstoffperoxid-beizen von siliciumhaltigen elektrostrahlqualitäten |
| KR100681099B1 (ko) * | 2001-04-09 | 2007-02-08 | 에이케이 스틸 프로퍼티즈 인코포레이티드 | 스테인레스강 그레이드에 대한 과산화수소 산세척 공정 |
| KR20030090720A (ko) | 2001-04-09 | 2003-11-28 | 에이케이 프로퍼티즈 인코포레이티드 | 폐 피클액로 부터 과산화수소를 제거하는 장치 및 방법 |
| DE10160318A1 (de) | 2001-12-07 | 2003-06-18 | Henkel Kgaa | Verfahren zum Beizen von martensitischem oder ferritischem Edelstahl |
| ITRM20010747A1 (it) | 2001-12-19 | 2003-06-19 | Ct Sviluppo Materiali Spa | Procedimento a ridotto impatto ambientale e relativo impianto per descagliare, decapare e finire/passivare, in modo continuo, integrato e fl |
| US6803354B2 (en) | 2002-08-05 | 2004-10-12 | Henkel Kormanditgesellschaft Auf Aktien | Stabilization of hydrogen peroxide in acidic baths for cleaning metals |
| JP4332115B2 (ja) | 2002-10-15 | 2009-09-16 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | 鋼及びステンレス鋼の酸洗い又は光沢化/不動態化用溶液及び方法 |
| US20050234545A1 (en) * | 2004-04-19 | 2005-10-20 | Yea-Yang Su | Amorphous oxide surface film for metallic implantable devices and method for production thereof |
| CN100510140C (zh) | 2004-12-07 | 2009-07-08 | 住友金属工业株式会社 | 油井用马氏体系不锈钢管 |
| KR100650887B1 (ko) | 2005-12-26 | 2006-11-28 | 주식회사 포스코 | 저크롬 페라이트 스테인레스강의 고속전해 산세방법 |
| US8153057B2 (en) * | 2007-07-24 | 2012-04-10 | Nalco Company | Method and device for preventing corrosion in hot water systems |
| BRPI0808453A2 (pt) * | 2007-02-12 | 2014-07-01 | Henkel Ag & Co Kgaa | Método de tratamento de uma superfície de um substrato de metal |
| CA2738724C (en) * | 2008-11-14 | 2013-04-23 | Ak Steel Properties, Inc. | Ferric pickling of silicon steel |
| KR101289147B1 (ko) * | 2010-12-28 | 2013-07-23 | 주식회사 포스코 | 표면품질이 우수한 저크롬 페라이트계 스테인리스 냉연강판을 제조하기 위한 친환경 고속 산세 프로세스 |
| SI2761063T1 (sl) | 2011-09-26 | 2017-01-31 | Ak Steel Properties, Inc. | Dekapiranje nerjavnega jekla v oksidacijski elektrolitski kislinski kopeli |
| WO2014021639A1 (ko) * | 2012-07-31 | 2014-02-06 | 주식회사 포스코 | 오스테나이트계 스테인리스 냉연강판을 제조하기 위한 고속 산세 프로세스 |
| GB2508827A (en) | 2012-12-11 | 2014-06-18 | Henkel Ag & Co Kgaa | Aqueous compositions and processes for passivating and brightening stainless steel surfaces |
| CN103882455A (zh) * | 2014-03-18 | 2014-06-25 | 浙江大学 | 一种不含硝酸的不锈钢酸洗液及其制备方法 |
| CN105369266A (zh) * | 2015-12-14 | 2016-03-02 | 浙江大学 | 一种基于Fenton氧化反应的钢材酸洗液及酸洗工艺 |
| CN105862049B (zh) * | 2016-06-06 | 2018-07-13 | 滨中元川金属制品(昆山)有限公司 | 螺钉防发黑处理工艺 |
| CN108300998B (zh) * | 2018-02-02 | 2020-06-09 | 西安热工研究院有限公司 | 显示p91和p92钢原奥氏体晶界的侵蚀剂、制备方法及应用 |
| JP6605066B2 (ja) * | 2018-03-30 | 2019-11-13 | 日鉄ステンレス株式会社 | Fe−Cr合金およびその製造方法 |
| RU2712875C1 (ru) * | 2019-05-28 | 2020-01-31 | Российская Федерация, от имени которой выступает Государственная корпорация по атомной энергии "Росатом" (Госкорпорация "Росатом") | Способ разделки корпуса боеприпаса из коррозионностойкой стали |
| KR102300834B1 (ko) | 2019-11-21 | 2021-09-13 | 주식회사 포스코 | 스테인리스강 산세용 이온성 액체 및 이를 이용한 스테인리스강의 산세방법 |
| IT202000005848A1 (it) | 2020-03-19 | 2021-09-19 | Tenova Spa | Processo per decapare e/o passivare un acciaio inossidabile. |
| CN112941528B (zh) * | 2021-02-01 | 2022-10-21 | 西安航天发动机有限公司 | 一种06Cr19Ni10增材制造薄壁夹层结构内腔粉末颗粒的去除方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1115445A (en) * | 1965-06-18 | 1968-05-29 | Forestal Ind U K Ltd | Descaling solution |
| US3429792A (en) * | 1965-07-30 | 1969-02-25 | Mitsubishi Heavy Ind Ltd | Method of electrolytically descaling and pickling steel |
| US3660353A (en) * | 1970-04-01 | 1972-05-02 | Dow Chemical Co | Monomers and polymers of 10-(alkenyl) oxyphenoxarsines |
| US3722169A (en) * | 1971-01-04 | 1973-03-27 | R Boehmig | Method of building construction |
| JPS549120A (en) * | 1977-06-24 | 1979-01-23 | Tokai Electro Chemical Co | Method of controlling acid cleaning liquid for stainless steel |
| JPS5442850A (en) * | 1977-09-10 | 1979-04-05 | Kubota Ltd | Method of treating raw sewage |
| JPS5551514A (en) * | 1978-10-12 | 1980-04-15 | Osaka Cement | Steel fiber mixing method and its device |
| GB2048311A (en) * | 1979-04-12 | 1980-12-10 | Sumitomo Metal Ind | Chemical pickling stainless steel |
| JPS568109A (en) * | 1979-07-03 | 1981-01-27 | Toshikazu Iwasaki | Reflecting telescope |
| JPS5920752B2 (ja) * | 1980-08-07 | 1984-05-15 | 川崎製鉄株式会社 | オ−ステナイト系ステンレス鋼板の酸洗方法 |
| JPS5844747B2 (ja) | 1980-08-18 | 1983-10-05 | 川崎製鉄株式会社 | ステンレス鋼帯の連続酸洗における過酸化水素の添加方法 |
| JPS57198273A (en) * | 1981-05-28 | 1982-12-04 | Daikin Ind Ltd | Pickling accelerator and pickling agent composition containing it |
| FR2551465B3 (fr) * | 1983-09-02 | 1985-08-23 | Gueugnon Sa Forges | Procede de decapage acide des aciers inoxydables et solution acide pour sa mise en oeuvre |
| SU1289912A1 (ru) * | 1984-03-11 | 1987-02-15 | Всесоюзный Научно-Исследовательский И Проектный Институт По Переработке Газа | Способ очистки стальных изделий |
| ATE121804T1 (de) * | 1985-01-22 | 1995-05-15 | Ugine Sa | Verfahren zum säuren beizen von stahlen, insbesondere von rostfreien stahlen. |
| JPS61235581A (ja) * | 1985-04-12 | 1986-10-20 | C Uyemura & Co Ltd | スケ−ル除去剤及びスケ−ル除去方法 |
| US5154774A (en) * | 1985-09-19 | 1992-10-13 | Ugine Aciers De Chatillon Et Gueugnon | Process for acid pickling of stainless steel products |
| FR2587369B1 (fr) * | 1985-09-19 | 1993-01-29 | Ugine Gueugnon Sa | Procede de decapage acide de produits en acier inoxydable |
| GB8922504D0 (en) * | 1989-10-05 | 1989-11-22 | Interox Chemicals Ltd | Hydrogen peroxide solutions |
| SE8903452D0 (sv) * | 1989-10-19 | 1989-10-19 | Lars Aake Hilmer Haakansson | Foerfarande foer betning av jaern och staalytor |
| FR2657888B1 (fr) * | 1990-02-08 | 1994-04-15 | Ugine Aciers | Procedes de decapage de materiaux en acier inoxydable. |
| FR2673200A1 (fr) * | 1991-02-25 | 1992-08-28 | Ugine Aciers | Procede de surdecapage de materiaux en acier tels que les aciers inoxydables et les aciers allies. |
| US5354383A (en) * | 1991-03-29 | 1994-10-11 | Itb, S.R.L. | Process for pickling and passivating stainless steel without using nitric acid |
| IT1245594B (it) * | 1991-03-29 | 1994-09-29 | Itb Srl | Processo di decapaggio e di passivazione di acciaio inossidabile senza acido nitrico |
| JP2947695B2 (ja) * | 1993-07-30 | 1999-09-13 | 日本ペイント株式会社 | アルミニウム系金属の酸性洗浄水溶液及びその洗浄方法 |
-
1992
- 1992-08-06 IT ITMI921946A patent/IT1255655B/it active IP Right Grant
-
1993
- 1993-07-19 ES ES93111528T patent/ES2143995T3/es not_active Expired - Lifetime
- 1993-07-19 EP EP93111528A patent/EP0582121B1/en not_active Revoked
- 1993-07-19 DE DE0582121T patent/DE582121T1/de active Pending
- 1993-07-19 AT AT93111528T patent/ATE191017T1/de not_active IP Right Cessation
- 1993-07-19 DE DE69328139T patent/DE69328139T2/de not_active Expired - Fee Related
- 1993-07-21 HU HU9302112A patent/HUT67521A/hu unknown
- 1993-08-05 JP JP5212109A patent/JP2819378B2/ja not_active Expired - Lifetime
- 1993-08-05 RU RU93046281A patent/RU2126460C1/ru not_active IP Right Cessation
- 1993-08-05 FI FI933474A patent/FI101981B/fi not_active IP Right Cessation
- 1993-08-06 CZ CZ931618A patent/CZ285442B6/cs not_active IP Right Cessation
-
1994
- 1994-02-09 BR BR9400478A patent/BR9400478A/pt not_active IP Right Cessation
-
1997
- 1997-06-13 US US08/874,797 patent/US5908511A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06212463A (ja) | 1994-08-02 |
| DE69328139D1 (de) | 2000-04-27 |
| DE69328139T2 (de) | 2000-10-19 |
| ITMI921946A0 (it) | 1992-08-06 |
| DE582121T1 (de) | 1994-06-16 |
| ATE191017T1 (de) | 2000-04-15 |
| RU2126460C1 (ru) | 1999-02-20 |
| JP2819378B2 (ja) | 1998-10-30 |
| CZ285442B6 (cs) | 1999-08-11 |
| ITMI921946A1 (it) | 1994-02-06 |
| HU9302112D0 (en) | 1993-11-29 |
| HUT67521A (en) | 1995-04-28 |
| FI933474A0 (fi) | 1993-08-05 |
| EP0582121A1 (en) | 1994-02-09 |
| US5908511A (en) | 1999-06-01 |
| BR9400478A (pt) | 1994-05-17 |
| FI101981B (fi) | 1998-09-30 |
| CZ161893A3 (en) | 1995-02-15 |
| FI933474L (fi) | 1994-02-07 |
| EP0582121B1 (en) | 2000-03-22 |
| ES2143995T3 (es) | 2000-06-01 |
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