IL103713A - Biodegradable thermoplastic polymer preparations and their mixtures with natural biodegradable polymers - Google Patents
Biodegradable thermoplastic polymer preparations and their mixtures with natural biodegradable polymersInfo
- Publication number
- IL103713A IL103713A IL10371392A IL10371392A IL103713A IL 103713 A IL103713 A IL 103713A IL 10371392 A IL10371392 A IL 10371392A IL 10371392 A IL10371392 A IL 10371392A IL 103713 A IL103713 A IL 103713A
- Authority
- IL
- Israel
- Prior art keywords
- polymer composition
- composition
- polymer
- poly
- transition metal
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 77
- 229920002988 biodegradable polymer Polymers 0.000 title claims description 16
- 239000004621 biodegradable polymer Substances 0.000 title claims description 16
- 229920001169 thermoplastic Polymers 0.000 title claims description 14
- 239000004416 thermosoftening plastic Substances 0.000 title description 5
- -1 transition metal salt Chemical class 0.000 claims description 52
- 239000004743 Polypropylene Substances 0.000 claims description 49
- 229920000642 polymer Polymers 0.000 claims description 38
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 27
- 239000000194 fatty acid Substances 0.000 claims description 27
- 229930195729 fatty acid Natural products 0.000 claims description 27
- 239000004698 Polyethylene Substances 0.000 claims description 26
- 150000004665 fatty acids Chemical class 0.000 claims description 24
- 229910052723 transition metal Inorganic materials 0.000 claims description 24
- 230000015556 catabolic process Effects 0.000 claims description 17
- 238000006731 degradation reaction Methods 0.000 claims description 16
- 229920000573 polyethylene Polymers 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 14
- 239000000654 additive Substances 0.000 claims description 13
- 229920001155 polypropylene Polymers 0.000 claims description 12
- 150000003624 transition metals Chemical class 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 11
- 239000003963 antioxidant agent Substances 0.000 claims description 10
- 235000006708 antioxidants Nutrition 0.000 claims description 10
- 229910017052 cobalt Inorganic materials 0.000 claims description 8
- 239000010941 cobalt Substances 0.000 claims description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 8
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims description 8
- 229910052684 Cerium Inorganic materials 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 7
- 229920000098 polyolefin Polymers 0.000 claims description 6
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- KZDCPJDWDXMJRA-UHFFFAOYSA-N 2-hydroxybutanoic acid;pentanoic acid Chemical compound CCCCC(O)=O.CCC(O)C(O)=O KZDCPJDWDXMJRA-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 229920001610 polycaprolactone Polymers 0.000 claims description 3
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229920000881 Modified starch Polymers 0.000 claims description 2
- 239000004368 Modified starch Substances 0.000 claims description 2
- 229920000562 Poly(ethylene adipate) Polymers 0.000 claims description 2
- 235000019426 modified starch Nutrition 0.000 claims description 2
- 239000013110 organic ligand Substances 0.000 claims description 2
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims 1
- 150000004671 saturated fatty acids Chemical class 0.000 claims 1
- 235000003441 saturated fatty acids Nutrition 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- 239000011572 manganese Substances 0.000 description 29
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 18
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 18
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 18
- 239000005642 Oleic acid Substances 0.000 description 18
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 18
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 18
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 18
- 239000002361 compost Substances 0.000 description 16
- 239000000944 linseed oil Substances 0.000 description 16
- 235000021388 linseed oil Nutrition 0.000 description 16
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 16
- 235000021355 Stearic acid Nutrition 0.000 description 14
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 14
- 239000008117 stearic acid Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000003921 oil Substances 0.000 description 10
- 235000019198 oils Nutrition 0.000 description 10
- 241000894007 species Species 0.000 description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 238000009264 composting Methods 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000007800 oxidant agent Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 229920001684 low density polyethylene Polymers 0.000 description 5
- 239000004702 low-density polyethylene Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229920000520 poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Polymers 0.000 description 5
- 239000002383 tung oil Substances 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 4
- 238000010525 oxidative degradation reaction Methods 0.000 description 4
- 229920001432 poly(L-lactide) Polymers 0.000 description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 description 4
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 3
- 239000002174 Styrene-butadiene Substances 0.000 description 3
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 3
- 235000020778 linoleic acid Nutrition 0.000 description 3
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000008363 phosphate buffer Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 2
- 241001125048 Sardina Species 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- MVLVMROFTAUDAG-UHFFFAOYSA-N ethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC MVLVMROFTAUDAG-UHFFFAOYSA-N 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- XHQSLVIGPHXVAK-UHFFFAOYSA-K iron(3+);octadecanoate Chemical compound [Fe+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XHQSLVIGPHXVAK-UHFFFAOYSA-K 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- SZINCDDYCOIOJQ-UHFFFAOYSA-L manganese(2+);octadecanoate Chemical compound [Mn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O SZINCDDYCOIOJQ-UHFFFAOYSA-L 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
- 229920006254 polymer film Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 235000019512 sardine Nutrition 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- CUXYLFPMQMFGPL-UHFFFAOYSA-N (9Z,11E,13E)-9,11,13-Octadecatrienoic acid Natural products CCCCC=CC=CC=CCCCCCCCC(O)=O CUXYLFPMQMFGPL-UHFFFAOYSA-N 0.000 description 1
- 239000001149 (9Z,12Z)-octadeca-9,12-dienoate Substances 0.000 description 1
- WTTJVINHCBCLGX-UHFFFAOYSA-N (9trans,12cis)-methyl linoleate Natural products CCCCCC=CCC=CCCCCCCCC(=O)OC WTTJVINHCBCLGX-UHFFFAOYSA-N 0.000 description 1
- FDVCQFAKOKLXGE-UHFFFAOYSA-N 216978-79-9 Chemical compound C1CC(C)(C)C2=CC(C=O)=CC3=C2N1CCC3(C)C FDVCQFAKOKLXGE-UHFFFAOYSA-N 0.000 description 1
- LNJCGNRKWOHFFV-UHFFFAOYSA-N 3-(2-hydroxyethylsulfanyl)propanenitrile Chemical compound OCCSCCC#N LNJCGNRKWOHFFV-UHFFFAOYSA-N 0.000 description 1
- JZINNAKNHHQBOS-AATRIKPKSA-N 3-methylcinnamic acid Chemical compound CC1=CC=CC(\C=C\C(O)=O)=C1 JZINNAKNHHQBOS-AATRIKPKSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- JXSRRBVHLUJJFC-UHFFFAOYSA-N 7-amino-2-methylsulfanyl-[1,2,4]triazolo[1,5-a]pyrimidine-6-carbonitrile Chemical compound N1=CC(C#N)=C(N)N2N=C(SC)N=C21 JXSRRBVHLUJJFC-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 241000208140 Acer Species 0.000 description 1
- 239000004953 Aliphatic polyamide Substances 0.000 description 1
- 235000019489 Almond oil Nutrition 0.000 description 1
- 241000252203 Clupea harengus Species 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- PKIXXJPMNDDDOS-UHFFFAOYSA-N Methyl linoleate Natural products CCCCC=CCCC=CCCCCCCCC(=O)OC PKIXXJPMNDDDOS-UHFFFAOYSA-N 0.000 description 1
- 229920002274 Nalgene Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 235000019498 Walnut oil Nutrition 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229920003231 aliphatic polyamide Polymers 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- CUXYLFPMQMFGPL-SUTYWZMXSA-N all-trans-octadeca-9,11,13-trienoic acid Chemical compound CCCC\C=C\C=C\C=C\CCCCCCCC(O)=O CUXYLFPMQMFGPL-SUTYWZMXSA-N 0.000 description 1
- 125000000746 allylic group Chemical group 0.000 description 1
- 239000008168 almond oil Substances 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 235000012716 cod liver oil Nutrition 0.000 description 1
- 239000003026 cod liver oil Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- PEVZEFCZINKUCG-UHFFFAOYSA-L copper;octadecanoate Chemical compound [Cu+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O PEVZEFCZINKUCG-UHFFFAOYSA-L 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 description 1
- 150000002194 fatty esters Chemical group 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229940013317 fish oils Drugs 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 235000019514 herring Nutrition 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 208000021267 infertility disease Diseases 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- AJAMRCUNWLZBDF-UHFFFAOYSA-N linoleic acid propyl ester Natural products CCCCCC=CCC=CCCCCCCCC(=O)OCCC AJAMRCUNWLZBDF-UHFFFAOYSA-N 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002362 mulch Substances 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 125000005474 octanoate group Chemical class 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000000135 prohibitive effect Effects 0.000 description 1
- AJAMRCUNWLZBDF-MURFETPASA-N propyl linoleate Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(=O)OCCC AJAMRCUNWLZBDF-MURFETPASA-N 0.000 description 1
- BTAXGNQLYFDKEF-UHFFFAOYSA-N propyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCC BTAXGNQLYFDKEF-UHFFFAOYSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 229940037312 stearamide Drugs 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 229940070710 valerate Drugs 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 239000008170 walnut oil Substances 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0033—Additives activating the degradation of the macromolecular compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
- Y10T428/1341—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1379—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
- Y10T428/1393—Multilayer [continuous layer]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Biological Depolymerization Polymers (AREA)
- Materials For Medical Uses (AREA)
- Prostheses (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/806,769 US5216043A (en) | 1991-12-12 | 1991-12-12 | Degradable thermophastic compositions and blends with naturally biodegradable polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IL103713A0 IL103713A0 (en) | 1993-04-04 |
| IL103713A true IL103713A (en) | 1996-06-18 |
Family
ID=25194808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IL10371392A IL103713A (en) | 1991-12-12 | 1992-11-11 | Biodegradable thermoplastic polymer preparations and their mixtures with natural biodegradable polymers |
Country Status (13)
| Country | Link |
|---|---|
| US (2) | US5216043A (pl) |
| EP (2) | EP0616622B1 (pl) |
| JP (2) | JPH07502221A (pl) |
| AU (1) | AU658547B2 (pl) |
| BR (1) | BR9206906A (pl) |
| CA (2) | CA2119889A1 (pl) |
| DE (1) | DE69208267T2 (pl) |
| DK (1) | DK0616622T3 (pl) |
| ES (1) | ES2083271T3 (pl) |
| IL (1) | IL103713A (pl) |
| MX (1) | MX9206972A (pl) |
| PL (1) | PL170349B1 (pl) |
| WO (2) | WO1993012171A1 (pl) |
Families Citing this family (81)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5216043A (en) * | 1991-12-12 | 1993-06-01 | Minnesota Mining And Manufacturing Company | Degradable thermophastic compositions and blends with naturally biodegradable polymers |
| US5496295A (en) * | 1991-12-18 | 1996-03-05 | Minnesota Mining And Manufacturing Company | Multilayered barrier structures |
| US5371176A (en) * | 1993-02-05 | 1994-12-06 | Ethicon, Inc. | Castor oil polymers |
| US5359026A (en) * | 1993-07-30 | 1994-10-25 | Cargill, Incorporated | Poly(lactide) copolymer and process for manufacture thereof |
| JPH09505615A (ja) * | 1993-10-15 | 1997-06-03 | エイチ．ビイ．フラー ライセンシング アンド ファイナンシング インク | 乳酸のポリエステルを含む生物分解性／肥料化可能なホットメルト接着剤 |
| US6037039A (en) * | 1994-01-31 | 2000-03-14 | Daiwa Seiko, Inc. | Biodegradable article |
| US5814404A (en) * | 1994-06-03 | 1998-09-29 | Minnesota Mining And Manufacturing Company | Degradable multilayer melt blown microfibers |
| US5511482A (en) * | 1994-07-11 | 1996-04-30 | Dipietropolo; Al | Environmentally degradable munitions |
| BR9508583A (pt) * | 1994-08-12 | 1998-07-14 | Minnesota Mining & Mfg | Adesivo sensível a pressão composição de adesivo sensível a pressão artigo e processo de aderir dois substratos |
| US5854304A (en) * | 1994-12-14 | 1998-12-29 | Epi Environmental Products Inc. | Degradable/compostable concentrates, process for making degradable/compostable packaging materials and the products thereof |
| US5472518A (en) * | 1994-12-30 | 1995-12-05 | Minnesota Mining And Manufacturing Company | Method of disposal for dispersible compositions and articles |
| US6579814B1 (en) | 1994-12-30 | 2003-06-17 | 3M Innovative Properties Company | Dispersible compositions and articles of sheath-core microfibers and method of disposal for such compositions and articles |
| US5759569A (en) * | 1995-01-10 | 1998-06-02 | The Procter & Gamble Company | Biodegradable articles made from certain trans-polymers and blends thereof with other biodegradable components |
| US5726220A (en) * | 1995-08-30 | 1998-03-10 | Shin-Etsu Chemical Co., Ltd. | Biodegradable polymer compositions and shrink films |
| US5866634A (en) * | 1995-09-25 | 1999-02-02 | Shin-Etsu Chemical Co., Ltd | Biodegradable polymer compositions and shrink films |
| DE19536961A1 (de) * | 1995-10-04 | 1997-04-10 | Henkel Kgaa | Polyolefin-basierte Formteile und Folien mit permanent verbesserten Oberflächeneigenschaften |
| US5904980A (en) * | 1996-05-13 | 1999-05-18 | Rivas; Victor A. | Electromagnetic interference (EMI) shielding and electrostatic discharge degradable polymers and monomers |
| US5972145A (en) * | 1996-06-07 | 1999-10-26 | International Business Machines Corporation | Removable passivating polyimide coating and methods of use |
| DE19712378A1 (de) * | 1997-03-25 | 1998-10-08 | Henkel Kgaa | Verwendung von Amphiphilen zur dauerhaften Verbesserung der Farbstoff-Kompatibilität von Polyolefin-basierten Formkörpern, Fasern und Folien |
| DE19712380A1 (de) | 1997-03-25 | 1998-10-01 | Henkel Kgaa | Verwendung von Amphiphilen zur dauerhaften Verbesserung der Klebstoff- und/oder Beschichtungs-Kompatibilität von Polyolefin-basierten Formkörpern, Fasern und Folien |
| US6248430B1 (en) * | 1998-08-11 | 2001-06-19 | Dainippon Ink And Chemicals, Inc. | Lactic acid-based polymer laminated product and molded product |
| DE19851691A1 (de) | 1998-11-10 | 2000-05-11 | Cognis Deutschland Gmbh | Verwendung von Amiden aromatischer Carbonsäuren zur dauerhaften Verbesserung der Klebstoff- und/oder Beschichtungs-Kompatibilität von Polyolefin-basierten Formkörpern, Fasern und Folien |
| DE19851689A1 (de) | 1998-11-10 | 2000-05-11 | Cognis Deutschland Gmbh | Verwendung von Fettsäureamiden zur dauerhaften Verbesserung der Klebstoff- und/oder Beschichtungs-Kompatibilität von Polyolefin-basierten Formkörpern, Fasern und Folien |
| KR20020000800A (ko) * | 1999-04-16 | 2002-01-05 | 시아이 가세이 가부시키가이샤 | 내후성이 향상된 생분해성 농업용 필름을 위한 수지 조성물 |
| US6576246B1 (en) * | 1999-05-24 | 2003-06-10 | Seefar Technologies, Inc. | Degradable animal chewing article possessing enhanced safety, durability and mouth-feel |
| JP4608628B2 (ja) * | 2000-07-11 | 2011-01-12 | アルケア株式会社 | 排泄物収容装具用面板 |
| JP3848077B2 (ja) * | 2000-11-20 | 2006-11-22 | キヤノン株式会社 | 分解性樹脂組成物およびその処理方法 |
| US7232615B2 (en) * | 2001-10-22 | 2007-06-19 | Ppg Industries Ohio, Inc. | Coating stack comprising a layer of barrier coating |
| CN1363625A (zh) * | 2001-11-15 | 2002-08-14 | 天津丹海股份有限公司 | 生物降解树脂的生产方法 |
| US20090123682A1 (en) * | 2007-11-08 | 2009-05-14 | Weder Donald E | Floral packaging formed of renewable or biodegradable polymer materials |
| US8449601B2 (en) * | 2002-11-19 | 2013-05-28 | Boston Scientific Scimed, Inc. | Medical devices |
| RU2394685C2 (ru) | 2003-03-12 | 2010-07-20 | Эвери Деннисон Копэрейшн | Адгезионное изделие (варианты), способ закрытия упаковок (варианты), лист и рулон адгезионных средств |
| NO324368B1 (no) * | 2003-04-23 | 2007-10-01 | Normors As | Fremgangsmate for fremstilling av tilsetningsmiddel til termoplaster og slik fremstilt tilsetningsmiddel samt termoplast inneholdende slikt tilsetningsmiddel. |
| US20040234791A1 (en) * | 2003-05-19 | 2004-11-25 | Ching Ta Yen | Polypropylene-graft-acrylic acid or polypropylene-graft-maleic anhydride in oxygen scavenging tie layers |
| EP1691736B1 (en) * | 2003-10-21 | 2011-02-16 | Hollister Incorporated | Flushable body waste collection pouch and pouch-in-pouch appliance using the same |
| US7517339B2 (en) * | 2003-10-21 | 2009-04-14 | Hollister Incorporated | Peelable and flushable ostomy pouch and method of use |
| JP2005264111A (ja) * | 2004-03-22 | 2005-09-29 | Hitachi Chemical Filtec Inc | 自然環境下で分解性を有する食品包装用ラップフィルム |
| US20050249899A1 (en) * | 2004-05-06 | 2005-11-10 | Bonutti Peter M | Biodegradable packaging material |
| KR20070045317A (ko) * | 2004-08-11 | 2007-05-02 | 도요 세이칸 가부시키가이샤 | 마개 개방성이 우수한 생분해성 캡 및 생분해성 캡 부착용기 |
| US20060280923A1 (en) * | 2005-06-09 | 2006-12-14 | Jodi Fleck-Arnold | Controlled multilayer degradable film |
| MY176917A (en) * | 2005-06-23 | 2020-08-26 | Gain Mark Tech Limited | A composition of matter for degradable additive and process for making same |
| TR200801372T2 (tr) * | 2005-09-01 | 2008-05-21 | S�Perf�Lm Ambalaj Sanay� Ve T�Caret A.�. | Bozunabi̇li̇r ve/veya bi̇yobozunabi̇li̇r çi̇ft yönlü gp |
| WO2007130402A2 (en) * | 2006-05-03 | 2007-11-15 | Tyco Healthcare Group Lp | Degradable medical sharps and waste container and method of making the same |
| CN101443042A (zh) * | 2006-04-14 | 2009-05-27 | 诺瓦提斯公司 | Il-1抗体用于治疗眼疾病的用途 |
| NO20061768L (no) * | 2006-04-21 | 2007-10-22 | Nor X Industry As | Blanding av tilsetningsmidler til bruk ved fremstilling termoplaster |
| US7951436B2 (en) * | 2006-08-14 | 2011-05-31 | Frito-Lay North America, Inc. | Environmentally-friendly multi-layer flexible film having barrier properties |
| US20100221560A1 (en) * | 2006-08-14 | 2010-09-02 | Frito-Lay North America, Inc. | Bio-Based In-Line High Barrier Metalized Film and Process for its Production |
| US20090061126A1 (en) * | 2007-08-31 | 2009-03-05 | Anthony Robert Knoerzer | Package and Multi-Layer Flexible Film Having Paper Containing Post Consumer Recycled Fiber |
| MY163363A (en) * | 2006-08-18 | 2017-09-15 | Dragonpak Ind (M) Sdn Bhd | A degradable polyolefin resin and process for making same |
| FR2932870B1 (fr) * | 2008-06-18 | 2010-06-18 | Inst Francais Du Petrole | Conduite avec gaine a permeabilite reduite aux composes acides |
| WO2010019251A2 (en) * | 2008-08-13 | 2010-02-18 | Vacumet Corp. | Metallized barrier material |
| EP2186855A1 (en) * | 2008-11-14 | 2010-05-19 | Total Petrochemicals Research Feluy | A polyolefin composition for the production of an article having a controlled degradation, an article comprising said composition and a process for the production of said article. |
| US9181014B2 (en) * | 2009-01-12 | 2015-11-10 | Besatori Llc | Ecologically safe storage bag and transporting system and method of making same |
| US20110200844A1 (en) * | 2010-02-17 | 2011-08-18 | Frito-Lay North America, Inc. | Composition for facilitating environmental degradation of a film |
| JP5733904B2 (ja) | 2010-03-31 | 2015-06-10 | 小林製薬株式会社 | 生分解性樹脂成型体の分解促進剤及びその使用 |
| US20120219790A1 (en) * | 2011-02-25 | 2012-08-30 | Frito-Lay North America, Inc. | Compostable film with paper-like, writable surface |
| US9040120B2 (en) | 2011-08-05 | 2015-05-26 | Frito-Lay North America, Inc. | Inorganic nanocoating primed organic film |
| US9267011B2 (en) | 2012-03-20 | 2016-02-23 | Frito-Lay North America, Inc. | Composition and method for making a cavitated bio-based film |
| US9162421B2 (en) | 2012-04-25 | 2015-10-20 | Frito-Lay North America, Inc. | Film with compostable heat seal layer |
| BR112014029751A2 (pt) | 2012-06-23 | 2017-06-27 | Frito Lay North America Inc | deposição de revestimentos de óxidos inorgânicos ultrafinos em empacotamento |
| US9149980B2 (en) | 2012-08-02 | 2015-10-06 | Frito-Lay North America, Inc. | Ultrasonic sealing of packages |
| US9090021B2 (en) | 2012-08-02 | 2015-07-28 | Frito-Lay North America, Inc. | Ultrasonic sealing of packages |
| WO2014028977A1 (en) * | 2012-08-24 | 2014-02-27 | Tristano Pty Ltd | Polyolefin composition comprising thermoplastic starch |
| US20150037865A1 (en) * | 2013-07-12 | 2015-02-05 | Wanda Weder & William Straeter, not individually but solely as Trustees of The Family Trust U/T/A d | Compositions for causing, enhancing, and/or expediting oxo-biodegradation of articles and methods of production and use thereof |
| US10251770B2 (en) | 2014-01-03 | 2019-04-09 | Hollister Incorporated | Lubricated valve for ostomy pouch |
| DE102014017015A1 (de) * | 2014-11-19 | 2016-05-19 | Bio-Tec Biologische Naturverpackungen Gmbh & Co. Kg | Biologisch abbaubare Mehrschichtfolie |
| KR101528618B1 (ko) * | 2014-11-26 | 2015-06-17 | 박희섭 | 리놀렌산을 함유하는 합성수지 및 합성섬유, 그리고 그 제조방법. |
| CN104494261B (zh) * | 2014-12-11 | 2016-08-17 | 昆山市张浦彩印厂 | 可降解evoh高阻隔复合薄膜 |
| US10155859B2 (en) | 2015-08-26 | 2018-12-18 | Celanese EVA Performance Polymers Corporation | Polymer composition for forming a melt-extruded film and composites thereof |
| JP6309036B2 (ja) * | 2016-02-29 | 2018-04-11 | ユニ・チャーム株式会社 | 吸収性物品 |
| US11155702B2 (en) * | 2016-11-22 | 2021-10-26 | Polymateria Limited | Degradable polymer and method of production |
| PT3545032T (pt) * | 2016-12-02 | 2023-10-09 | Polymateria Ltd | Polímero degradável e método de produção |
| WO2018124122A1 (ja) * | 2016-12-28 | 2018-07-05 | ユニ・チャーム株式会社 | 吸収性物品 |
| JP6529550B2 (ja) | 2016-12-28 | 2019-06-12 | ユニ・チャーム株式会社 | 吸収性物品 |
| JP7425394B2 (ja) * | 2017-06-27 | 2024-01-31 | 三菱ケミカル株式会社 | 樹脂組成物、溶融成形用材料および多層構造体 |
| RU2686179C1 (ru) * | 2017-12-12 | 2019-04-24 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Воронежский государственный университет инженерных технологий" (ФГБОУ ВО "ВГУИТ") | Одностадийный способ получения добавки-прооксиданта к полиолефинам |
| EP3983485A4 (en) * | 2019-06-13 | 2023-04-26 | SWM Luxembourg | DEGRADABLE EXTRUDED MESH OF POLYMER BLEND COMPOSITIONS |
| US11643261B2 (en) * | 2020-02-28 | 2023-05-09 | Illinois Tool Works Inc. | Biodegradable multi-pack carriers |
| US12201172B2 (en) * | 2021-06-03 | 2025-01-21 | Shen Wei (Usa) Inc. | Eco-friendly wearable dipped article and method of manufacturing |
| TWI775537B (zh) * | 2021-07-21 | 2022-08-21 | 南亞塑膠工業股份有限公司 | 生物可分解保鮮膜 |
| KR102893352B1 (ko) * | 2022-11-24 | 2025-12-02 | 주식회사 알앤에프케미칼 | 토양생분해성이 확보된 섬유용 내열 컴파운드 조성물의 제조방법 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3647111A (en) * | 1970-06-01 | 1972-03-07 | Biocor Corp | Biodegradable container |
| US3864293A (en) * | 1970-08-25 | 1975-02-04 | Seikisui Chemical Co Ltd | Photo-Degradable Styrene Resin Composition |
| US4038228A (en) * | 1971-11-19 | 1977-07-26 | Owens-Illinois, Inc. | Degradable plastic composition containing a transition metal salt of a highly unsaturated organic acid |
| US3797690A (en) * | 1971-12-08 | 1974-03-19 | Owens Illinois Inc | Preparation of degradable polymeric material |
| US4101720A (en) * | 1972-03-01 | 1978-07-18 | Owens-Illinois, Inc. | Degradable plastic |
| US3941759A (en) * | 1972-03-01 | 1976-03-02 | Owens-Illinois, Inc. | Degradable plastics containing dual-function additive system |
| US4016117A (en) * | 1972-05-18 | 1977-04-05 | Coloroll Limited | Biodegradable synthetic resin sheet material containing starch and a fatty material |
| US4067836A (en) * | 1972-06-28 | 1978-01-10 | Union Carbide Corporation | Environmentally degradable compositions exposed to actinic or ionizing radiation and process |
| US3867324A (en) * | 1972-07-28 | 1975-02-18 | Union Carbide Corp | Environmentally degradable-biodegradable blend of an oxyalkanoyl polymer and an environmentally degradable ethylene polymer |
| US3921333A (en) * | 1972-07-28 | 1975-11-25 | Union Carbide Corp | Transplanter containers made from biodegradable-environmentally degradable blends |
| US3901838A (en) * | 1972-07-28 | 1975-08-26 | Union Carbide Corp | Environmentally degradable biodegradable blends of a dialkanoyl polymer and an environmentally degradable ethylene polymer |
| US3840512A (en) * | 1972-11-09 | 1974-10-08 | Ici Ltd | Degradable plastics composition |
| GB1600496A (en) * | 1977-09-16 | 1981-10-14 | Coloroll Ltd | Plasticsbased composition |
| JPS5471542A (en) * | 1977-11-17 | 1979-06-08 | Nec Corp | Voltage comparator circuit |
| JPS55118221A (en) * | 1979-03-06 | 1980-09-11 | Nec Corp | Comparison circuit |
| EP0045621B1 (en) * | 1980-08-06 | 1985-10-09 | Coloroll Limited | Plastics starch composition |
| US4931230A (en) * | 1986-05-08 | 1990-06-05 | Minnesota Mining And Manufacturing Company | Method for preparing radiation resistant polypropylene articles |
| JPS62269512A (ja) * | 1986-05-19 | 1987-11-24 | Nippon Telegr & Teleph Corp <Ntt> | 電圧比較器 |
| JPS6387014A (ja) * | 1986-09-30 | 1988-04-18 | Sony Corp | ラツチドコンパレ−タ |
| CH671961A5 (pl) * | 1987-02-27 | 1989-10-13 | Amrotex Ag | |
| GB8712009D0 (en) * | 1987-05-21 | 1987-06-24 | Folk Drive Eng Ltd | Degradable plastics |
| US4950549A (en) * | 1987-07-01 | 1990-08-21 | Minnesota Mining And Manufacturing Company | Polypropylene articles and method for preparing same |
| ES2037218T3 (es) * | 1987-07-31 | 1993-06-16 | Shell Internationale Research Maatschappij B.V. | Recipiente degradable para bebidas. |
| US5009648A (en) * | 1989-03-22 | 1991-04-23 | E. R. Squibb & Sons, Inc. | Starch containing film ostomy pouches |
| US5140073A (en) * | 1989-06-26 | 1992-08-18 | Minnesota Mining And Manufacturing Company | Radiation resistant heat sealable polymer blends of compatible polymers and methods of preparing same |
| US5059642A (en) * | 1989-09-14 | 1991-10-22 | Iowa State University Research Foundation, Inc. | Degradable plastics from octenyl succinate starch |
| US4964857A (en) * | 1989-10-23 | 1990-10-23 | Charles Osborn | Biodegradable disposable diaper |
| GB2243327A (en) * | 1990-02-16 | 1991-10-30 | Procter & Gamble | Biodegradable, liquid-impervious sheet laminate |
| US5108807A (en) * | 1990-03-14 | 1992-04-28 | First Brands Corporation | Degradable multilayer thermoplastic articles |
| US5191734A (en) * | 1990-04-24 | 1993-03-09 | Kimberly-Clark Corporation | Biodegradable latex web material |
| US5135966A (en) * | 1991-11-26 | 1992-08-04 | Shell Oil Company | Environmentally degradable polymer composition |
| US5216043A (en) * | 1991-12-12 | 1993-06-01 | Minnesota Mining And Manufacturing Company | Degradable thermophastic compositions and blends with naturally biodegradable polymers |
-
1991
- 1991-12-12 US US07/806,769 patent/US5216043A/en not_active Expired - Fee Related
-
1992
- 1992-11-11 IL IL10371392A patent/IL103713A/en not_active IP Right Cessation
- 1992-12-03 MX MX9206972A patent/MX9206972A/es not_active IP Right Cessation
- 1992-12-04 DE DE69208267T patent/DE69208267T2/de not_active Expired - Fee Related
- 1992-12-04 CA CA 2119889 patent/CA2119889A1/en not_active Abandoned
- 1992-12-04 ES ES93900185T patent/ES2083271T3/es not_active Expired - Lifetime
- 1992-12-04 CA CA 2125572 patent/CA2125572A1/en not_active Abandoned
- 1992-12-04 EP EP19930900185 patent/EP0616622B1/en not_active Expired - Lifetime
- 1992-12-04 EP EP93900186A patent/EP0616570A1/en not_active Withdrawn
- 1992-12-04 WO PCT/US1992/010717 patent/WO1993012171A1/en not_active Ceased
- 1992-12-04 BR BR9206906A patent/BR9206906A/pt not_active IP Right Cessation
- 1992-12-04 AU AU32480/93A patent/AU658547B2/en not_active Ceased
- 1992-12-04 US US08/104,147 patent/US5470526A/en not_active Expired - Fee Related
- 1992-12-04 DK DK93900185T patent/DK0616622T3/da active
- 1992-12-04 WO PCT/US1992/010718 patent/WO1993011941A2/en not_active Ceased
- 1992-12-04 PL PL92304147A patent/PL170349B1/pl unknown
- 1992-12-04 JP JP5511088A patent/JPH07502221A/ja active Pending
- 1992-12-04 JP JP51108793A patent/JP3362042B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE69208267D1 (de) | 1996-03-21 |
| EP0616622A1 (en) | 1994-09-28 |
| DE69208267T2 (de) | 1996-06-27 |
| CA2119889A1 (en) | 1993-06-24 |
| AU658547B2 (en) | 1995-04-13 |
| JP3362042B2 (ja) | 2003-01-07 |
| JPH07502065A (ja) | 1995-03-02 |
| EP0616570A1 (en) | 1994-09-28 |
| US5216043A (en) | 1993-06-01 |
| US5470526A (en) | 1995-11-28 |
| JPH07502221A (ja) | 1995-03-09 |
| AU3248093A (en) | 1993-07-19 |
| WO1993011941A2 (en) | 1993-06-24 |
| BR9206906A (pt) | 1995-05-30 |
| MX9206972A (es) | 1993-06-01 |
| EP0616622B1 (en) | 1996-02-07 |
| IL103713A0 (en) | 1993-04-04 |
| DK0616622T3 (da) | 1996-06-24 |
| WO1993011941A3 (en) | 1993-08-05 |
| ES2083271T3 (es) | 1996-04-01 |
| WO1993012171A1 (en) | 1993-06-24 |
| CA2125572A1 (en) | 1993-06-24 |
| PL170349B1 (pl) | 1996-12-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5216043A (en) | Degradable thermophastic compositions and blends with naturally biodegradable polymers | |
| US5565503A (en) | Chemically degradable polyolefin films | |
| KR102307277B1 (ko) | 분해성 중합체 및 제조 방법 | |
| EP1317506B1 (en) | Methods for slowing the degradation rate of biodegradable polymer and biodegradable polymer compositions and compositions thereof | |
| US20090149606A1 (en) | Degradable plastic composition and methods | |
| JP3045534B2 (ja) | 生物分解性樹脂組成物およびその製品 | |
| JP2004147613A (ja) | 生分解性農業用マルチ | |
| JP3178692B2 (ja) | 食品包装用フィルム | |
| Baum et al. | Controlled UV degradation in plastics | |
| JP2004057016A (ja) | 生分解性農業用マルチ | |
| JP2010064301A (ja) | ポリ乳酸フィルムおよびその製造方法 | |
| JP4309528B2 (ja) | 連続結束性に優れた生分解性紐の製造方法 | |
| JP2008221551A (ja) | 包装用フィルム | |
| EA039308B1 (ru) | Разлагаемый полимер и способ его получения | |
| NZ286678A (en) | Degradable/compostable additive for polyolefins comprising metal carboxylate and polyhydroxy carboxylic acid | |
| JPH11254611A (ja) | オレフィン系ラップフィルム | |
| HK40014667A (en) | Degradable polymer and method of production | |
| HK40014667B (en) | Degradable polymer and method of production | |
| JPH0524527U (ja) | 封 筒 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FF | Patent granted | ||
| KB | Patent renewed | ||
| KB | Patent renewed | ||
| KB | Patent renewed | ||
| MM9K | Patent not in force due to non-payment of renewal fees |