HU229930B1 - Ligandum és komplex katalitikus fehérítéshez - Google Patents
Ligandum és komplex katalitikus fehérítéshez Download PDFInfo
- Publication number
- HU229930B1 HU229930B1 HU0302768A HUP0302768A HU229930B1 HU 229930 B1 HU229930 B1 HU 229930B1 HU 0302768 A HU0302768 A HU 0302768A HU P0302768 A HUP0302768 A HU P0302768A HU 229930 B1 HU229930 B1 HU 229930B1
- Authority
- HU
- Hungary
- Prior art keywords
- alkyl
- group
- bleaching
- formula
- ligand
- Prior art date
Links
- 238000004061 bleaching Methods 0.000 title claims description 55
- 239000003446 ligand Substances 0.000 title claims description 53
- 239000000758 substrate Substances 0.000 title claims description 13
- 239000000203 mixture Substances 0.000 claims description 67
- 125000000217 alkyl group Chemical group 0.000 claims description 36
- 150000001875 compounds Chemical class 0.000 claims description 33
- -1 and the Chemical group 0.000 claims description 30
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 29
- 239000003054 catalyst Substances 0.000 claims description 20
- 229910052723 transition metal Inorganic materials 0.000 claims description 20
- 150000003624 transition metals Chemical class 0.000 claims description 20
- 239000000460 chlorine Chemical group 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 15
- 239000001257 hydrogen Substances 0.000 claims description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 claims description 12
- 239000007844 bleaching agent Substances 0.000 claims description 12
- 125000001072 heteroaryl group Chemical group 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 8
- 239000012736 aqueous medium Substances 0.000 claims description 7
- 125000000592 heterocycloalkyl group Chemical group 0.000 claims description 7
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims description 6
- 125000004429 atom Chemical group 0.000 claims description 6
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 claims description 6
- 150000001450 anions Chemical class 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 125000005842 heteroatom Chemical group 0.000 claims description 5
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims description 5
- 125000006514 pyridin-2-ylmethyl group Chemical group [H]C1=C([H])C([H])=C([H])C(=N1)C([H])([H])* 0.000 claims description 5
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 4
- 125000003386 piperidinyl group Chemical group 0.000 claims description 4
- 210000004556 brain Anatomy 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 3
- RAOIDOHSFRTOEL-UHFFFAOYSA-N tetrahydrothiophene Chemical compound C1CCSC1 RAOIDOHSFRTOEL-UHFFFAOYSA-N 0.000 claims description 3
- 125000003363 1,3,5-triazinyl group Chemical group N1=C(N=CN=C1)* 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical group FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 2
- 125000005213 alkyl heteroaryl group Chemical group 0.000 claims description 2
- 150000001356 alkyl thiols Chemical class 0.000 claims description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 2
- 239000011737 fluorine Chemical group 0.000 claims description 2
- 125000000904 isoindolyl group Chemical group C=1(NC=C2C=CC=CC12)* 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 229960005141 piperazine Drugs 0.000 claims description 2
- 125000004193 piperazinyl group Chemical group 0.000 claims description 2
- 125000003226 pyrazolyl group Chemical group 0.000 claims description 2
- 125000004076 pyridyl group Chemical group 0.000 claims description 2
- 125000000714 pyrimidinyl group Chemical group 0.000 claims description 2
- 125000000168 pyrrolyl group Chemical group 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims 8
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 2
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 claims 1
- 125000003282 alkyl amino group Chemical group 0.000 claims 1
- 150000007942 carboxylates Chemical class 0.000 claims 1
- 201000010099 disease Diseases 0.000 claims 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims 1
- 239000011888 foil Substances 0.000 claims 1
- 229960005181 morphine Drugs 0.000 claims 1
- 125000000160 oxazolidinyl group Chemical group 0.000 claims 1
- 125000000587 piperidin-1-yl group Chemical group [H]C1([H])N(*)C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 claims 1
- 125000003373 pyrazinyl group Chemical group 0.000 claims 1
- 125000002098 pyridazinyl group Chemical group 0.000 claims 1
- 125000000335 thiazolyl group Chemical group 0.000 claims 1
- 150000003852 triazoles Chemical class 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 25
- 239000000243 solution Substances 0.000 description 21
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 150000002894 organic compounds Chemical class 0.000 description 18
- 239000003599 detergent Substances 0.000 description 17
- 238000005406 washing Methods 0.000 description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 13
- 239000004744 fabric Substances 0.000 description 13
- 239000001301 oxygen Substances 0.000 description 13
- 229910052760 oxygen Inorganic materials 0.000 description 13
- 150000002978 peroxides Chemical class 0.000 description 13
- 239000004094 surface-active agent Substances 0.000 description 13
- 230000015572 biosynthetic process Effects 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 238000003786 synthesis reaction Methods 0.000 description 11
- 102000004190 Enzymes Human genes 0.000 description 10
- 108090000790 Enzymes Proteins 0.000 description 10
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 229940088598 enzyme Drugs 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- 125000001424 substituent group Chemical group 0.000 description 10
- 239000004753 textile Substances 0.000 description 10
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 9
- 230000003647 oxidation Effects 0.000 description 9
- 238000007254 oxidation reaction Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 8
- 102000004157 Hydrolases Human genes 0.000 description 8
- 108090000604 Hydrolases Proteins 0.000 description 8
- 239000003945 anionic surfactant Substances 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000002736 nonionic surfactant Substances 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 230000003213 activating effect Effects 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 230000002829 reductive effect Effects 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 108090000854 Oxidoreductases Proteins 0.000 description 4
- 102000004316 Oxidoreductases Human genes 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 241000227653 Lycopersicon Species 0.000 description 3
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 3
- 206010037660 Pyrexia Diseases 0.000 description 3
- 102000004357 Transferases Human genes 0.000 description 3
- 108090000992 Transferases Proteins 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 125000002619 bicyclic group Chemical group 0.000 description 3
- 229940106157 cellulase Drugs 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000003750 conditioning effect Effects 0.000 description 3
- 150000002085 enols Chemical class 0.000 description 3
- 230000002255 enzymatic effect Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 150000002505 iron Chemical class 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 3
- 239000011368 organic material Substances 0.000 description 3
- 239000006072 paste Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 125000006239 protecting group Chemical group 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- WOXFMYVTSLAQMO-UHFFFAOYSA-N 2-Pyridinemethanamine Chemical compound NCC1=CC=CC=N1 WOXFMYVTSLAQMO-UHFFFAOYSA-N 0.000 description 2
- 108010059892 Cellulase Proteins 0.000 description 2
- 108090000317 Chymotrypsin Proteins 0.000 description 2
- 108010001682 Dextranase Proteins 0.000 description 2
- 108010031186 Glycoside Hydrolases Proteins 0.000 description 2
- 102000005744 Glycoside Hydrolases Human genes 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 102000003960 Ligases Human genes 0.000 description 2
- 108090000364 Ligases Proteins 0.000 description 2
- 102000004882 Lipase Human genes 0.000 description 2
- 108090001060 Lipase Proteins 0.000 description 2
- 239000004367 Lipase Substances 0.000 description 2
- 108010059820 Polygalacturonase Proteins 0.000 description 2
- 239000004365 Protease Substances 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 108090000787 Subtilisin Proteins 0.000 description 2
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 229960002376 chymotrypsin Drugs 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 235000005911 diet Nutrition 0.000 description 2
- 230000037213 diet Effects 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 238000005108 dry cleaning Methods 0.000 description 2
- 125000006575 electron-withdrawing group Chemical group 0.000 description 2
- 239000003623 enhancer Substances 0.000 description 2
- JKKFKPJIXZFSSB-CBZIJGRNSA-N estrone 3-sulfate Chemical compound OS(=O)(=O)OC1=CC=C2[C@H]3CC[C@](C)(C(CC4)=O)[C@@H]4[C@@H]3CCC2=C1 JKKFKPJIXZFSSB-CBZIJGRNSA-N 0.000 description 2
- 239000008098 formaldehyde solution Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000002506 iron compounds Chemical class 0.000 description 2
- 238000010409 ironing Methods 0.000 description 2
- 108010011519 keratan-sulfate endo-1,4-beta-galactosidase Proteins 0.000 description 2
- 235000019421 lipase Nutrition 0.000 description 2
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000003094 microcapsule Substances 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- XUZLXCQFXTZASF-UHFFFAOYSA-N nitro(phenyl)methanol Chemical compound [O-][N+](=O)C(O)C1=CC=CC=C1 XUZLXCQFXTZASF-UHFFFAOYSA-N 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 125000000547 substituted alkyl group Chemical group 0.000 description 2
- 125000003107 substituted aryl group Chemical group 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 239000003826 tablet Substances 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- ZIIUUSVHCHPIQD-UHFFFAOYSA-N 2,4,6-trimethyl-N-[3-(trifluoromethyl)phenyl]benzenesulfonamide Chemical compound CC1=CC(C)=CC(C)=C1S(=O)(=O)NC1=CC=CC(C(F)(F)F)=C1 ZIIUUSVHCHPIQD-UHFFFAOYSA-N 0.000 description 1
- DLJPNXLHWMRQIQ-UHFFFAOYSA-N 2-chloro-1-methoxy-4-nitrobenzene Chemical compound COC1=CC=C([N+]([O-])=O)C=C1Cl DLJPNXLHWMRQIQ-UHFFFAOYSA-N 0.000 description 1
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- XPQIPUZPSLAZDV-UHFFFAOYSA-N 2-pyridylethylamine Chemical compound NCCC1=CC=CC=N1 XPQIPUZPSLAZDV-UHFFFAOYSA-N 0.000 description 1
- NNEAKBWZBQOQDH-UHFFFAOYSA-N 3-(1h-inden-2-yl)pyridine Chemical compound C=1C2=CC=CC=C2CC=1C1=CC=CN=C1 NNEAKBWZBQOQDH-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 206010067484 Adverse reaction Diseases 0.000 description 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 102000004400 Aminopeptidases Human genes 0.000 description 1
- 108090000915 Aminopeptidases Proteins 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 241000974482 Aricia saepiolus Species 0.000 description 1
- 108090000145 Bacillolysin Proteins 0.000 description 1
- 102100031697 Basic helix-loop-helix transcription factor scleraxis Human genes 0.000 description 1
- 101710130006 Beta-glucanase Proteins 0.000 description 1
- 102100032487 Beta-mannosidase Human genes 0.000 description 1
- 108010004032 Bromelains Proteins 0.000 description 1
- 101100038180 Caenorhabditis briggsae rpb-1 gene Proteins 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 108010051152 Carboxylesterase Proteins 0.000 description 1
- 102000013392 Carboxylesterase Human genes 0.000 description 1
- 108090000087 Carboxypeptidase B Proteins 0.000 description 1
- 102000003670 Carboxypeptidase B Human genes 0.000 description 1
- 108010080937 Carboxypeptidases A Proteins 0.000 description 1
- 102000000496 Carboxypeptidases A Human genes 0.000 description 1
- 235000005747 Carum carvi Nutrition 0.000 description 1
- 240000000467 Carum carvi Species 0.000 description 1
- 102000003908 Cathepsin D Human genes 0.000 description 1
- 108090000258 Cathepsin D Proteins 0.000 description 1
- 108090000613 Cathepsin S Proteins 0.000 description 1
- 102100035654 Cathepsin S Human genes 0.000 description 1
- 108010022172 Chitinases Proteins 0.000 description 1
- 102000012286 Chitinases Human genes 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical group [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 108090001069 Chymopapain Proteins 0.000 description 1
- 108090000746 Chymosin Proteins 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- 108010052832 Cytochromes Proteins 0.000 description 1
- 102000018832 Cytochromes Human genes 0.000 description 1
- NOQGZXFMHARMLW-UHFFFAOYSA-N Daminozide Chemical compound CN(C)NC(=O)CCC(O)=O NOQGZXFMHARMLW-UHFFFAOYSA-N 0.000 description 1
- 108010028143 Dioxygenases Proteins 0.000 description 1
- 102000016680 Dioxygenases Human genes 0.000 description 1
- 108010059378 Endopeptidases Proteins 0.000 description 1
- 102000005593 Endopeptidases Human genes 0.000 description 1
- 108010013369 Enteropeptidase Proteins 0.000 description 1
- 102100029727 Enteropeptidase Human genes 0.000 description 1
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 108010073178 Glucan 1,4-alpha-Glucosidase Proteins 0.000 description 1
- 102100022624 Glucoamylase Human genes 0.000 description 1
- 239000004366 Glucose oxidase Substances 0.000 description 1
- 108010015776 Glucose oxidase Proteins 0.000 description 1
- 108010068370 Glutens Proteins 0.000 description 1
- 101000654285 Homo sapiens Basic helix-loop-helix transcription factor scleraxis Proteins 0.000 description 1
- 108010028688 Isoamylase Proteins 0.000 description 1
- 102000004195 Isomerases Human genes 0.000 description 1
- 108090000769 Isomerases Proteins 0.000 description 1
- 108060005987 Kallikrein Proteins 0.000 description 1
- 102000001399 Kallikrein Human genes 0.000 description 1
- 239000006125 LAS system Substances 0.000 description 1
- 108090000128 Lipoxygenases Proteins 0.000 description 1
- 102000003820 Lipoxygenases Human genes 0.000 description 1
- 108090000856 Lyases Proteins 0.000 description 1
- 102000004317 Lyases Human genes 0.000 description 1
- 108010074633 Mixed Function Oxygenases Proteins 0.000 description 1
- 102000008109 Mixed Function Oxygenases Human genes 0.000 description 1
- WXOMTJVVIMOXJL-BOBFKVMVSA-A O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)OS(=O)(=O)OC[C@H]1O[C@@H](O[C@]2(COS(=O)(=O)O[Al](O)O)O[C@H](OS(=O)(=O)O[Al](O)O)[C@@H](OS(=O)(=O)O[Al](O)O)[C@@H]2OS(=O)(=O)O[Al](O)O)[C@H](OS(=O)(=O)O[Al](O)O)[C@@H](OS(=O)(=O)O[Al](O)O)[C@@H]1OS(=O)(=O)O[Al](O)O Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)O.O[Al](O)OS(=O)(=O)OC[C@H]1O[C@@H](O[C@]2(COS(=O)(=O)O[Al](O)O)O[C@H](OS(=O)(=O)O[Al](O)O)[C@@H](OS(=O)(=O)O[Al](O)O)[C@@H]2OS(=O)(=O)O[Al](O)O)[C@H](OS(=O)(=O)O[Al](O)O)[C@@H](OS(=O)(=O)O[Al](O)O)[C@@H]1OS(=O)(=O)O[Al](O)O WXOMTJVVIMOXJL-BOBFKVMVSA-A 0.000 description 1
- 108010067372 Pancreatic elastase Proteins 0.000 description 1
- 102000016387 Pancreatic elastase Human genes 0.000 description 1
- 108090000526 Papain Proteins 0.000 description 1
- 108010029182 Pectin lyase Proteins 0.000 description 1
- 108090000284 Pepsin A Proteins 0.000 description 1
- 102000057297 Pepsin A Human genes 0.000 description 1
- 108090000313 Pepsin B Proteins 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- 108010064785 Phospholipases Proteins 0.000 description 1
- 102000015439 Phospholipases Human genes 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 108091007187 Reductases Proteins 0.000 description 1
- 108090000783 Renin Proteins 0.000 description 1
- 102100028255 Renin Human genes 0.000 description 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 1
- 108010055297 Sterol Esterase Proteins 0.000 description 1
- 102000000019 Sterol Esterase Human genes 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 108090000190 Thrombin Proteins 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- ISWQCIVKKSOKNN-UHFFFAOYSA-L Tiron Chemical compound [Na+].[Na+].OC1=CC(S([O-])(=O)=O)=CC(S([O-])(=O)=O)=C1O ISWQCIVKKSOKNN-UHFFFAOYSA-L 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000006838 adverse reaction Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 1
- 108090000637 alpha-Amylases Proteins 0.000 description 1
- 102000004139 alpha-Amylases Human genes 0.000 description 1
- SRBFZHDQGSBBOR-STGXQOJASA-N alpha-D-lyxopyranose Chemical compound O[C@@H]1CO[C@H](O)[C@@H](O)[C@H]1O SRBFZHDQGSBBOR-STGXQOJASA-N 0.000 description 1
- 229940024171 alpha-amylase Drugs 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- OHDRQQURAXLVGJ-HLVWOLMTSA-N azane;(2e)-3-ethyl-2-[(e)-(3-ethyl-6-sulfo-1,3-benzothiazol-2-ylidene)hydrazinylidene]-1,3-benzothiazole-6-sulfonic acid Chemical compound [NH4+].[NH4+].S/1C2=CC(S([O-])(=O)=O)=CC=C2N(CC)C\1=N/N=C1/SC2=CC(S([O-])(=O)=O)=CC=C2N1CC OHDRQQURAXLVGJ-HLVWOLMTSA-N 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 108010019077 beta-Amylase Proteins 0.000 description 1
- 108010051210 beta-Fructofuranosidase Proteins 0.000 description 1
- 108010055059 beta-Mannosidase Proteins 0.000 description 1
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 230000002051 biphasic effect Effects 0.000 description 1
- 235000019835 bromelain Nutrition 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011651 chromium Chemical group 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 229960002976 chymopapain Drugs 0.000 description 1
- 229940080701 chymosin Drugs 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 229940066758 endopeptidases Drugs 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 108010093305 exopolygalacturonase Proteins 0.000 description 1
- RZTAMFZIAATZDJ-UHFFFAOYSA-N felodipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OC)C1C1=CC=CC(Cl)=C1Cl RZTAMFZIAATZDJ-UHFFFAOYSA-N 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229940116332 glucose oxidase Drugs 0.000 description 1
- 235000019420 glucose oxidase Nutrition 0.000 description 1
- 235000021312 gluten Nutrition 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- QMEZUZOCLYUADC-UHFFFAOYSA-N hydrate;dihydrochloride Chemical compound O.Cl.Cl QMEZUZOCLYUADC-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 1
- 125000002632 imidazolidinyl group Chemical group 0.000 description 1
- 125000001041 indolyl group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- 239000001573 invertase Substances 0.000 description 1
- 235000011073 invertase Nutrition 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 201000008633 iridogoniodysgenesis syndrome Diseases 0.000 description 1
- 150000004698 iron complex Chemical class 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- LHOWRPZTCLUDOI-UHFFFAOYSA-K iron(3+);triperchlorate Chemical compound [Fe+3].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O LHOWRPZTCLUDOI-UHFFFAOYSA-K 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 108010062085 ligninase Proteins 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 235000014666 liquid concentrate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- GNOLWGAJQVLBSM-UHFFFAOYSA-N n,n,5,7-tetramethyl-1,2,3,4-tetrahydronaphthalen-1-amine Chemical compound C1=C(C)C=C2C(N(C)C)CCCC2=C1C GNOLWGAJQVLBSM-UHFFFAOYSA-N 0.000 description 1
- 239000006199 nebulizer Substances 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- 150000004028 organic sulfates Chemical class 0.000 description 1
- 238000009896 oxidative bleaching Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229940055729 papain Drugs 0.000 description 1
- 235000019834 papain Nutrition 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 235000015927 pasta Nutrition 0.000 description 1
- 108010087558 pectate lyase Proteins 0.000 description 1
- 108020004410 pectinesterase Proteins 0.000 description 1
- 229940111202 pepsin Drugs 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- DHHVAGZRUROJKS-UHFFFAOYSA-N phentermine Chemical compound CC(C)(N)CC1=CC=CC=C1 DHHVAGZRUROJKS-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 125000005936 piperidyl group Chemical group 0.000 description 1
- 108010004131 poly(beta-D-mannuronate) lyase Proteins 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 101150009632 prx2 gene Proteins 0.000 description 1
- 238000004076 pulp bleaching Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 125000004309 pyranyl group Chemical group O1C(C=CC=C1)* 0.000 description 1
- PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 description 1
- 125000000719 pyrrolidinyl group Chemical group 0.000 description 1
- 125000002943 quinolinyl group Chemical group N1=C(C=CC2=CC=CC=C12)* 0.000 description 1
- 125000001567 quinoxalinyl group Chemical group N1=C(C=NC2=CC=CC=C12)* 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000002390 rotary evaporation Methods 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 229960004072 thrombin Drugs 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- AYNNSCRYTDRFCP-UHFFFAOYSA-N triazene Chemical compound NN=N AYNNSCRYTDRFCP-UHFFFAOYSA-N 0.000 description 1
- VITRLXDSBBVNCZ-UHFFFAOYSA-K trichloroiron;hydrate Chemical compound O.Cl[Fe](Cl)Cl VITRLXDSBBVNCZ-UHFFFAOYSA-K 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- PPPHYGCRGMTZNA-UHFFFAOYSA-M trifluoromethyl sulfate Chemical compound [O-]S(=O)(=O)OC(F)(F)F PPPHYGCRGMTZNA-UHFFFAOYSA-M 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 108010062040 wax-ester hydrolase Proteins 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D471/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00
- C07D471/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, at least one ring being a six-membered ring with one nitrogen atom, not provided for by groups C07D451/00 - C07D463/00 in which the condensed system contains two hetero rings
- C07D471/08—Bridged systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/168—Organometallic compounds or orgometallic complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0030673.8A GB0030673D0 (en) | 2000-12-15 | 2000-12-15 | Ligand and complex for catalytically bleaching a substrate |
| PCT/EP2001/013314 WO2002048301A1 (en) | 2000-12-15 | 2001-11-15 | Ligand and complex for catalytically bleaching a substrate |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| HUP0302768A2 HUP0302768A2 (hu) | 2003-11-28 |
| HUP0302768A3 HUP0302768A3 (en) | 2012-10-29 |
| HU229930B1 true HU229930B1 (hu) | 2015-01-28 |
Family
ID=9905193
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU0302768A HU229930B1 (hu) | 2000-12-15 | 2001-11-15 | Ligandum és komplex katalitikus fehérítéshez |
Country Status (19)
Families Citing this family (83)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0030673D0 (en) * | 2000-12-15 | 2001-01-31 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| JP4104966B2 (ja) * | 2002-03-06 | 2008-06-18 | 花王株式会社 | 漂白触媒 |
| PL374143A1 (en) * | 2002-06-06 | 2005-10-03 | Unilever N.V. | Ligand and complex for catalytically bleaching a substrate |
| GB0212991D0 (en) * | 2002-06-06 | 2002-07-17 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0212995D0 (en) * | 2002-06-06 | 2002-07-17 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| DE10257279A1 (de) * | 2002-12-07 | 2004-06-24 | Clariant Gmbh | Flüssige Bleichmittelkomponenten enthaltend amphiphile Polymere |
| EP2374804A1 (en) * | 2003-04-22 | 2011-10-12 | Genzyme Corporation | Chemokine receptor binding heterocyclic compounds with enhanced efficacy |
| GB0323275D0 (en) * | 2003-10-04 | 2003-11-05 | Unilever Plc | Bleaching composition |
| GB0325432D0 (en) * | 2003-10-31 | 2003-12-03 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0325430D0 (en) * | 2003-10-31 | 2003-12-03 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0413058D0 (en) * | 2004-06-11 | 2004-07-14 | Unilever Plc | Bleaching composition |
| DE602005019640D1 (de) | 2004-09-23 | 2010-04-08 | Unilever Nv | Zusammensetzungen zur Wäschebehandlung |
| EP1700904A1 (en) | 2005-03-11 | 2006-09-13 | Unilever N.V. | Liquid detergent composition |
| EP1700907A1 (en) | 2005-03-11 | 2006-09-13 | Unilever N.V. | Liquid bleaching composition |
| DE102005027619A1 (de) * | 2005-06-15 | 2006-12-28 | Clariant Produkte (Deutschland) Gmbh | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Verbindungen |
| WO2007051255A1 (en) * | 2005-11-04 | 2007-05-10 | The University Of Sydney | Process for the preparation of compounds containing an azacyclic ring system |
| CN101484544B (zh) | 2006-07-07 | 2013-11-06 | Omg英国技术有限公司 | 液体硬化 |
| EP2103735A1 (en) | 2008-03-18 | 2009-09-23 | Unilever PLC | Catalytic bleaching of substrates |
| WO2009124855A1 (en) | 2008-04-09 | 2009-10-15 | Basf Se | Use of metal hydrazide complex compounds as oxidation catalysts |
| DE102008024084A1 (de) * | 2008-05-17 | 2009-11-19 | Clariant International Ltd. | Wasch- und Reinigungsmittel |
| DE102008038376A1 (de) | 2008-08-19 | 2010-02-25 | Clariant International Ltd. | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Verbindungen |
| DE102008045215A1 (de) | 2008-08-30 | 2010-03-04 | Clariant International Ltd. | Verwendung von Mangan-Oxalatenn als Bleichkatalysatoren |
| DE102008064009A1 (de) | 2008-12-19 | 2010-06-24 | Clariant International Ltd. | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Metall-Komplexen |
| EP2228429A1 (en) | 2009-03-13 | 2010-09-15 | Unilever PLC | Shading dye and catalyst combination |
| EP2343336A1 (en) | 2010-01-06 | 2011-07-13 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Curing liquids |
| DE102010007058A1 (de) * | 2010-02-06 | 2011-08-11 | Clariant International Limited | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Metallkomplex-Lösungen |
| DE102010007059A1 (de) | 2010-02-06 | 2011-08-11 | Clariant International Limited | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Metallkomplexen |
| WO2011120772A1 (en) | 2010-03-31 | 2011-10-06 | Unilever Plc | Microcapsule incorporation in structured liquid detergents |
| CN101811068B (zh) * | 2010-03-31 | 2012-05-30 | 上海师范大学 | 哌嗪功能化有序介孔酚醛树脂固体碱催化剂的制备方法 |
| EP2553072B1 (en) | 2010-04-01 | 2015-05-06 | Unilever PLC | Structuring detergent liquids with hydrogenated castor oil |
| WO2011124282A1 (en) | 2010-04-08 | 2011-10-13 | Dsm Ip Assets B.V. | Unsaturated polyester resin or vinyl ester resin compositions |
| JP5654123B2 (ja) | 2010-06-16 | 2015-01-14 | アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップＡｋｚｏ Ｎｏｂｅｌ Ｃｈｅｍｉｃａｌｓ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｂ．Ｖ． | 硬化性樹脂の硬化のための硬化促進溶液及び方法 |
| WO2012000846A1 (en) | 2010-06-28 | 2012-01-05 | Basf Se | Metal free bleaching composition |
| EP2627658B1 (de) | 2010-10-11 | 2014-08-13 | WeylChem Switzerland AG | Verfahren zur herstellung von 3,7-diaza-bicyclo[3.3.1]nonan-metallkomplexen |
| EP2441820A1 (en) | 2010-10-14 | 2012-04-18 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Laundry detergent particles |
| CN103154220B (zh) | 2010-10-22 | 2015-11-25 | 荷兰联合利华有限公司 | 与洗衣产品有关的改进 |
| PT2652025T (pt) | 2010-12-15 | 2018-11-02 | Ppg Europe B V | Composição secante e a sua utilização |
| EP2474578A1 (en) | 2011-01-06 | 2012-07-11 | Rahu Catalytics Limited | Antiskinning compositions |
| ES2538997T3 (es) | 2011-01-31 | 2015-06-25 | Unilever N.V. | Composiciones detergentes líquidas alcalinas |
| EP2495300A1 (en) | 2011-03-04 | 2012-09-05 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Structuring detergent liquids with hydrogenated castor oil |
| EP2476743B1 (en) | 2011-04-04 | 2013-04-24 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Method of laundering fabric |
| EP2522715A1 (en) | 2011-05-13 | 2012-11-14 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Aqueous concentrated laundry detergent compositions |
| ES2546003T3 (es) | 2011-05-13 | 2015-09-17 | Unilever N.V. | Composiciones concentradas acuosas de detergente para ropa |
| EP2522714A1 (en) | 2011-05-13 | 2012-11-14 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Aqueous concentrated laundry detergent compositions |
| US9145501B2 (en) | 2011-09-26 | 2015-09-29 | Ppg Europe Bv | Coating composition and use thereof |
| US20140298591A1 (en) | 2011-10-25 | 2014-10-09 | Basf Se | Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes |
| BR112014010011A8 (pt) | 2011-10-25 | 2017-12-19 | Basf Se | Uso de um ou mais copolímeros de acrilato, método para impedir a redeposição de sujeira nos artigos têxteis e para a libertação da sujeira dos artigos têxteis, e, composições de detergente |
| CN103174008A (zh) * | 2011-11-24 | 2013-06-26 | 东华大学 | 二吡啶基四氮金属配合物在纺织品低温练漂助剂中的应用 |
| WO2013083632A1 (en) | 2011-12-06 | 2013-06-13 | Dsm Ip Assets B.V. | Multi-component system |
| EP2788443A1 (en) | 2011-12-06 | 2014-10-15 | DSM IP Assets B.V. | Resin composition |
| WO2013092051A1 (en) | 2011-12-20 | 2013-06-27 | Unilever Plc | Liquid detergents comprising lipase and bleach catalyst |
| WO2013092052A1 (en) | 2011-12-20 | 2013-06-27 | Unilever Plc | Isotropic liquid detergents comprising soil release polymer |
| CN104334707B (zh) | 2012-05-16 | 2017-08-22 | 荷兰联合利华有限公司 | 包含聚烷氧基化聚亚乙基亚胺的洗衣洗涤剂组合物 |
| WO2014070661A1 (en) | 2012-10-29 | 2014-05-08 | Ashland Licensing And Intellectual Property Llc | Resin compositions |
| BR112015016586B1 (pt) | 2013-01-23 | 2022-02-01 | Unilever Ip Holdings B.V. | Material aditivo não colorido para lavar roupa para a promoção de anti-redeposição de sujeira particulada, processo para fabricar o material de polietilenoimina polialcoxilado reticulado, composição detergente para lavar roupa uso do material e processo para lavar roupa |
| EP2770044A1 (en) | 2013-02-20 | 2014-08-27 | Unilever PLC | Lamellar gel with amine oxide |
| WO2014154508A1 (en) | 2013-03-27 | 2014-10-02 | Basf Se | Block copolymers as soil release agents in laundry processes |
| EP3024898B1 (en) | 2013-07-25 | 2017-11-08 | OMG UK Technology Limited | Encapsulated catalysts |
| AU2014307707B2 (en) | 2013-08-16 | 2018-08-02 | Chemsenti Limited | Composition |
| CN103602268B (zh) * | 2013-10-10 | 2015-09-02 | 中钞油墨有限公司 | 环保型催干剂及其油墨组合物 |
| EP3074438B1 (en) | 2013-11-27 | 2017-09-06 | Basf Se | Random copolymers as soil release agents in laundry processes |
| DK3077467T3 (da) | 2013-12-03 | 2023-01-09 | Ppg Europe B V | Sikkativsammensætning og anvendelse deraf |
| BR112017019942A2 (pt) | 2015-04-02 | 2018-06-12 | Unilever Nv | composição líquida para lavagem de roupas e uso de polímero para a liberação de sujeira |
| AR104939A1 (es) | 2015-06-10 | 2017-08-23 | Chemsenti Ltd | Método oxidativo para generar dióxido de cloro |
| AR104940A1 (es) | 2015-06-10 | 2017-08-23 | Chemsenti Ltd | Método para generar dióxido de cloro |
| WO2017186480A1 (en) | 2016-04-26 | 2017-11-02 | Basf Se | Metal free bleaching composition |
| BR112018073598B1 (pt) | 2016-05-17 | 2022-09-27 | Unilever Ip Holdings B.V | Composição líquida para lavagem de roupas e uso de uma composição líquida detergente para lavagem de roupas |
| AU2017267050B2 (en) | 2016-05-17 | 2020-03-05 | Unilever Global Ip Limited | Liquid laundry detergent compositions |
| WO2017202923A1 (en) | 2016-05-27 | 2017-11-30 | Unilever Plc | Laundry composition |
| EP3272823A1 (en) * | 2016-07-19 | 2018-01-24 | ALLNEX AUSTRIA GmbH | Drier compositions for alkyd resins |
| WO2018127390A1 (en) | 2017-01-06 | 2018-07-12 | Unilever N.V. | Stain removing composition |
| WO2019038187A1 (en) | 2017-08-24 | 2019-02-28 | Unilever Plc | IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS |
| WO2019038186A1 (en) | 2017-08-24 | 2019-02-28 | Unilever Plc | IMPROVEMENTS RELATING TO THE CLEANING OF FABRICS |
| CN112313298B (zh) | 2018-07-05 | 2022-12-02 | 卡特克塞尔科技有限公司 | 可氧化固化涂料组合物 |
| US20220073735A1 (en) | 2018-07-05 | 2022-03-10 | Borchers Catalyst (UK) Limited | Liquids |
| US11518834B2 (en) | 2019-01-02 | 2022-12-06 | Polynt Composites USA, Inc. | Radically polymerizable compositions |
| CZ309741B6 (cs) | 2020-06-24 | 2023-09-06 | Univerzita Pardubice | Nátěrová hmota obsahující sikativy na bázi sloučenin vanadu s kompenzujícími anionty sulfonových kyselin |
| EP3967742A1 (en) | 2020-09-15 | 2022-03-16 | WeylChem Performance Products GmbH | Compositions comprising bleaching catalyst, manufacturing process thereof, and bleaching and cleaning agent comprising same |
| KR20240051242A (ko) | 2021-08-30 | 2024-04-19 | 보르헤르스 게엠베하 | 수지 성능을 개선하는 방법 |
| CA3230619A1 (en) | 2021-09-30 | 2023-04-06 | Neil J. Simpson | Process for improving resin performance using lewis acids |
| WO2023117421A1 (en) | 2021-12-22 | 2023-06-29 | Borchers Gmbh | Paints containing driers based on vanadium compounds bearing various acid anions |
| EP4299704A1 (en) * | 2022-06-27 | 2024-01-03 | The Procter & Gamble Company | A method of laundering and drying fabric |
| EP4299702A1 (en) * | 2022-06-27 | 2024-01-03 | The Procter & Gamble Company | A solid free-flowing particulate laundry detergent composition |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GR76189B (US06818149-20041116-C00002.png) | 1981-07-13 | 1984-08-03 | Procter & Gamble | |
| GB8803036D0 (en) | 1988-02-10 | 1988-03-09 | Unilever Plc | Liquid detergents |
| GB8813978D0 (en) | 1988-06-13 | 1988-07-20 | Unilever Plc | Liquid detergents |
| US5194416A (en) * | 1991-11-26 | 1993-03-16 | Lever Brothers Company, Division Of Conopco, Inc. | Manganese catalyst for activating hydrogen peroxide bleaching |
| DE69332885T2 (de) | 1992-12-01 | 2004-03-04 | Novozymes A/S | Beschleunigung von Enzymreaktionen |
| DK144192D0 (da) | 1992-12-01 | 1992-12-01 | Novo Nordisk As | Aktivering af enzymer |
| DK144392D0 (da) | 1992-12-01 | 1992-12-01 | Novo Nordisk As | Aktivering af enzymer |
| WO1997011217A1 (en) | 1995-09-19 | 1997-03-27 | Novo Nordisk A/S | Stain bleaching |
| WO1997031090A1 (en) | 1996-02-20 | 1997-08-28 | The Procter & Gamble Company | A cleaning composition comprising peroxidase |
| EP0892844B1 (en) | 1996-04-10 | 2001-05-30 | Unilever N.V. | Cleaning process |
| EP0906402A1 (en) | 1996-06-19 | 1999-04-07 | Unilever N.V. | Bleach activation |
| US5850086A (en) * | 1996-06-21 | 1998-12-15 | Regents Of The University Of Minnesota | Iron complexes for bleach activation and stereospecific oxidation |
| CN1156570C (zh) | 1997-02-26 | 2004-07-07 | 诺沃奇梅兹有限公司 | 微生物木糖葡聚糖内切转糖基酶、其生产方法及用途 |
| US20030017941A1 (en) * | 1997-03-07 | 2003-01-23 | The Procter & Gamble Company | Catalysts and methods for catalytic oxidation |
| EP0993501A1 (en) | 1997-06-23 | 2000-04-19 | The Procter & Gamble Company | Enzymatic detergent compositions |
| JP2001509535A (ja) | 1997-07-09 | 2001-07-24 | ザ、プロクター、エンド、ギャンブル、カンパニー | 特定のオキシゲナーゼを含有してなる洗浄組成物 |
| EP1002039A1 (en) | 1997-07-09 | 2000-05-24 | The Procter & Gamble Company | Detergent compositions comprising a specific oxygenase |
| AU3668397A (en) | 1997-07-09 | 1999-02-08 | Procter & Gamble Company, The | Cleaning compositions comprising a cytochrome |
| EP1002040B2 (en) | 1997-07-09 | 2011-12-21 | The Procter & Gamble Company | Cleaning compositions comprising a specific oxygenase |
| CA2308181A1 (en) | 1997-11-10 | 1999-05-20 | Novo Nordisk A/S | Antimicrobial activity of laccases |
| WO1999065905A1 (en) | 1998-06-15 | 1999-12-23 | Unilever Plc | Bleach catalysts and formulations containing them |
| PH11999002190B1 (en) | 1998-09-01 | 2007-08-06 | Unilever Nv | Composition and method for bleaching a substrate |
| PH11999002188B1 (en) | 1998-09-01 | 2007-08-06 | Unilever Nv | Method of treating a textile |
| AU1522300A (en) | 1998-11-13 | 2000-06-05 | Procter & Gamble Company, The | Bleach compositions |
| US6117833A (en) | 1998-12-16 | 2000-09-12 | Lever Brothers Company | Bleaching compositions and method for bleaching substrates directly with air |
| WO2000060045A1 (en) * | 1999-04-01 | 2000-10-12 | The Procter & Gamble Company | Transition metal bleaching agents |
| GB0005090D0 (en) * | 2000-03-01 | 2000-04-26 | Unilever Plc | Bleaching and dye transfer inhibiting composition and method for laundry fabrics |
| GB0030673D0 (en) * | 2000-12-15 | 2001-01-31 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0030877D0 (en) * | 2000-12-18 | 2001-01-31 | Unilever Plc | Enhancement of air bleaching catalysts |
-
2000
- 2000-12-15 GB GBGB0030673.8A patent/GB0030673D0/en not_active Ceased
-
2001
- 2001-11-15 CA CA2429629A patent/CA2429629C/en not_active Expired - Fee Related
- 2001-11-15 EP EP01984742A patent/EP1379618B1/en not_active Expired - Lifetime
- 2001-11-15 CN CNB018205623A patent/CN1246432C/zh not_active Expired - Fee Related
- 2001-11-15 AT AT01984742T patent/ATE329993T1/de not_active IP Right Cessation
- 2001-11-15 BR BRPI0116135-0A patent/BR0116135B1/pt not_active IP Right Cessation
- 2001-11-15 WO PCT/EP2001/013314 patent/WO2002048301A1/en active IP Right Grant
- 2001-11-15 CZ CZ2003-1655A patent/CZ304488B6/cs not_active IP Right Cessation
- 2001-11-15 MX MXPA03004887A patent/MXPA03004887A/es unknown
- 2001-11-15 AU AU3318702A patent/AU3318702A/xx active Pending
- 2001-11-15 DE DE60120781T patent/DE60120781T2/de not_active Expired - Lifetime
- 2001-11-15 ES ES01984742T patent/ES2264707T3/es not_active Expired - Lifetime
- 2001-11-15 AU AU2002233187A patent/AU2002233187B2/en not_active Ceased
- 2001-11-15 RU RU2003121409/04A patent/RU2283342C2/ru not_active IP Right Cessation
- 2001-11-15 HU HU0302768A patent/HU229930B1/hu not_active IP Right Cessation
- 2001-11-15 PL PL366179A patent/PL205956B1/pl unknown
- 2001-12-12 AR ARP010105769A patent/AR031908A1/es not_active Application Discontinuation
- 2001-12-13 MY MYPI20015688A patent/MY127232A/en unknown
- 2001-12-14 US US10/021,884 patent/US6818149B2/en not_active Expired - Lifetime
-
2003
- 2003-05-06 ZA ZA200303456A patent/ZA200303456B/en unknown
-
2004
- 2004-08-11 US US10/916,302 patent/US20050032662A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| ATE329993T1 (de) | 2006-07-15 |
| HUP0302768A2 (hu) | 2003-11-28 |
| AU3318702A (en) | 2002-06-24 |
| GB0030673D0 (en) | 2001-01-31 |
| HUP0302768A3 (en) | 2012-10-29 |
| RU2283342C2 (ru) | 2006-09-10 |
| PL366179A1 (en) | 2005-01-24 |
| WO2002048301A1 (en) | 2002-06-20 |
| CA2429629C (en) | 2011-05-31 |
| US20050032662A1 (en) | 2005-02-10 |
| EP1379618B1 (en) | 2006-06-14 |
| US20020149000A1 (en) | 2002-10-17 |
| ZA200303456B (en) | 2004-08-13 |
| CN1246432C (zh) | 2006-03-22 |
| BR0116135B1 (pt) | 2012-06-12 |
| MXPA03004887A (es) | 2003-08-19 |
| MY127232A (en) | 2006-11-30 |
| US6818149B2 (en) | 2004-11-16 |
| CZ20031655A3 (cs) | 2003-12-17 |
| CZ304488B6 (cs) | 2014-05-28 |
| AU2002233187B2 (en) | 2006-03-30 |
| BR0116135A (pt) | 2003-10-28 |
| DE60120781T2 (de) | 2007-01-25 |
| AR031908A1 (es) | 2003-10-08 |
| PL205956B1 (pl) | 2010-06-30 |
| EP1379618A1 (en) | 2004-01-14 |
| DE60120781D1 (de) | 2006-07-27 |
| CN1481435A (zh) | 2004-03-10 |
| CA2429629A1 (en) | 2002-06-20 |
| ES2264707T3 (es) | 2007-01-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| HU229930B1 (hu) | Ligandum és komplex katalitikus fehérítéshez | |
| EP0909809B1 (en) | Bleach activation | |
| US6153576A (en) | Transition-metal complexes used as activators for peroxy compounds | |
| US8492324B2 (en) | Use of metal hydrazide complex compounds as oxidation catalysts | |
| US20080000032A1 (en) | Use of Metal Complexes Having Bispyridylpyrimidine or Bispyridyltriazine Ligands as Catalysts for Reactions With Peroxy Compounds for Bleaching Coloured Stains on Hard Surfaces | |
| US20090189119A1 (en) | Use of metal complex compounds comprising pyridine pyrimidine or s-triazine derived ligands as catalysts for oxidations with organic peroxy acids and/or precursors of organic peroxy acids and h202 | |
| US20060247144A1 (en) | Use of metal complex compounds as oxidation catalysts | |
| WO1997048787A1 (en) | Bleach activation | |
| AU2002233187A1 (en) | Ligand and complex for catalytically bleaching a substrate | |
| EP1280794B1 (en) | Diazacycloalkane derivatives as bleach catalyst and composition and method for bleaching a substrate | |
| KR102326356B1 (ko) | 전기화학적으로 활성화가능한 음이온성 매개체 화합물을 포함하는 세척제 또는 세정제 | |
| CA2364605A1 (en) | Composition and method for bleaching a substrate | |
| US20070135323A1 (en) | Use of metal complex compounds as oxidation catalysts | |
| EP1208186B1 (en) | Composition and method for bleaching a substrate | |
| CA2383935A1 (en) | Composition and method for bleaching a substrate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Lapse of definitive patent protection due to non-payment of fees |